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Full-Text Articles in Art and Design

Formulating 3-Chloropropyltriethoxysilane Modified Silica Nanoparticle Sprays As Hydrophobic Transparent Coatings Onto Cotton Textiles, Mikaela C. S. Mendoza, Gilbert U. Yu Jun 2021

Formulating 3-Chloropropyltriethoxysilane Modified Silica Nanoparticle Sprays As Hydrophobic Transparent Coatings Onto Cotton Textiles, Mikaela C. S. Mendoza, Gilbert U. Yu

Chemistry Faculty Publications

Cotton textiles were transformed into hydrophobic fabrics via the application of 3-chloropropylthriethoxysilane-functionalized silica nanoparticle spray coatings. Silica particles were measured to be < 50 nm, as determined by dynamic light scattering (DLS). The incorporation of hexadecyltrimethylammonium bromide (HTAB), a surfactant, into the nanosilica alcohol-based sprays resulted in a suspension that was stable for at least a week. Stability and turbidity tests of samples point to smaller particle size (silica nanoparticles = 24.3 ± 8.5 nm) as the main contributor to possibly providing transparency, as evidenced when sprayed in colored (black) textiles, while still contributing to hydrophobicity/ superhydrophobicity of the cloth.


Gold Nanoparticle Colorants As Traditional Ceramic Glaze Alternatives, Raef H. Lambertson, Christie A. Lacy, Samuel D. Gillespie, Michael C. Leopold Sep 2017

Gold Nanoparticle Colorants As Traditional Ceramic Glaze Alternatives, Raef H. Lambertson, Christie A. Lacy, Samuel D. Gillespie, Michael C. Leopold

Chemistry Faculty Publications

Historically, Roman stained glass has been a standard for high‐temperature color stability since biblical times but was not properly characterized as emission from nanoparticle plasmon resonance until the 1990s. The methods under which it was created have been lost, but some efforts have recently been made to recreate these properties using gold nanoparticle inks on glassy surfaces. This body of work employs gold nanoparticle systems ranging from 0.015% to 0.100% (wt/wt), suspended in a clear glaze body. The glazes are fired with traditional ceramic methods—in both gas reduction and electric oxidation kilns—in which nanoparticles are retained and can be imaged …