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Full-Text Articles in Architecture
Quantifying The Workability Of Calcium Sulfoaluminate Cement Paste Using Time-Dependent Rheology, Sukanta K. Mondal, Adam Welz, Carrie Clinton, Kamal Khayat, Aditya Kumar, Monday Uchenna Okoronkwo
Quantifying The Workability Of Calcium Sulfoaluminate Cement Paste Using Time-Dependent Rheology, Sukanta K. Mondal, Adam Welz, Carrie Clinton, Kamal Khayat, Aditya Kumar, Monday Uchenna Okoronkwo
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Poor workability is a common feature of calcium sulfoaluminate (CSA) cement paste. Multiple chemical admixtures, such as set retarders and dispersants, are frequently employed to improve the workability and delay the setting of CSA cement paste. A quantitative assessment of the compatibility, efficiency, and the effects of the admixtures on cement paste workability is critical for the design of an appropriate paste formulation and admixture proportioning. Very limited studies are available on the quantitative rheology-based method for evaluating the workability of calcium sulfoaluminate cement pastes. This study presents a novel and robust time-dependent rheological method for quantifying the workability of …
The Effect Of Sodium Polymethacrylate On The Rheology Of The Positive Paste And Performance Of The Lead-Acid Battery, Julian Kosacki, Dimitri Feys, Fatih Dogan
The Effect Of Sodium Polymethacrylate On The Rheology Of The Positive Paste And Performance Of The Lead-Acid Battery, Julian Kosacki, Dimitri Feys, Fatih Dogan
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Due to its rheological properties, positive lead-acid battery paste can be difficult to spread on lead current collectors accurately and efficiently under industry machinery and setting. Sodium polymethacrylate dispersant was studied as an effective positive paste additive that could lower the yield stress of the paste without affecting paste density and battery performance. Under a four-blade vane rheometer setup, stress growth and oscillatory amplitude strain sweep experiments evaluated the rheological properties of positive paste with the addition of varying amounts of sodium polymethacrylate. Further, the electrochemical effects of sodium polymethacrylate were also evaluated in 2V batteries by testing positive active …
Machine Learning Enabled Closed-Form Models To Predict Strength Of Alkali-Activated Systems, Taihao Han, Eslam Gomaa, Ahmed Gheni, Jie Huang, Mohamed Elgawady, Aditya Kumar
Machine Learning Enabled Closed-Form Models To Predict Strength Of Alkali-Activated Systems, Taihao Han, Eslam Gomaa, Ahmed Gheni, Jie Huang, Mohamed Elgawady, Aditya Kumar
Electrical and Computer Engineering Faculty Research & Creative Works
Alkali-activated mortar (AAM) is an emerging eco-friendly construction material, which can complement ordinary Portland cement (OPC) mortars. Prediction of properties of AAMs—albeit much needed to complement experiments—is difficult, owing to substantive batch-to-batch variations in physicochemical properties of their precursors (i.e., aluminosilicate and activator solution). In this study, a machine learning (ML) model is employed; and it is shown that the model—once trained and optimized—can reliably predict compressive strength of AAMs solely from their initial physicochemical attributes. Prediction performance of the model improves when multiple compositional descriptors of the aluminosilicate are combined into a singular, composite chemostructural descriptor (i.e., network ratio …
Hydration Of High-Alumina Calcium Aluminate Cements With Carbonate And Sulfate Additives, Jonathan Lapeyre, Sai Akshay Ponduru, Monday Uchenna Okoronkwo, Hongyan Ma, Aditya Kumar
Hydration Of High-Alumina Calcium Aluminate Cements With Carbonate And Sulfate Additives, Jonathan Lapeyre, Sai Akshay Ponduru, Monday Uchenna Okoronkwo, Hongyan Ma, Aditya Kumar
Chemical and Biochemical Engineering Faculty Research & Creative Works
This study investigated the influence of limestone (LS) and calcium sulfate (C$) mineral additives on the hydration kinetics of high-α-Al2O3 calcium aluminate cement (CAC) utilizing experimental techniques and thermodynamic simulations. Increasing the replacement level of limestone or calcium sulfate increased the cumulative heat of the hydration reaction. The limestone exhibited limited acceleratory effects to the CAC hydration kinetics due to the coarseness of the powder. The coarse particle size distribution limited any heterogenous nucleation that would have occurred with a finer particle size as well as the intrinsic insolubility kinetically limits the formation of monocarboaluminate phases. Conversely, …
Examining The Effect Of A Chitosan Biopolymer On Alkali-Activated Inorganic Material For Aqueous Pb(Ii) And Zn(Ii) Sorption, Sukanta K. Mondal, Chenglin Wu, Felix C. Nwadire, Ali A. Rownaghi, Aditya Kumar, Yusuf Adewuyi, Monday Uchenna Okoronkwo
Examining The Effect Of A Chitosan Biopolymer On Alkali-Activated Inorganic Material For Aqueous Pb(Ii) And Zn(Ii) Sorption, Sukanta K. Mondal, Chenglin Wu, Felix C. Nwadire, Ali A. Rownaghi, Aditya Kumar, Yusuf Adewuyi, Monday Uchenna Okoronkwo
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Biopolymers and alkali-activated materials have attracted a great deal of attention as adsorbents for the removal of heavy metal contaminants from aqueous solutions. Both materials are sustainable and feature unique properties, but biopolymers are relatively more expensive or difficult to prepare and exhibit low mechanical and surface properties, a narrow pH range, and thermal stability. In this study, hybrid adsorbents were prepared from both types of material, by alkali activation of low-cost fly ash precursors accompanied by incorporation of 0-2%mass chitosan biopolymer. Two types of alkaline activating solutions, NaOH and Na2SiO3, were employed to generate two sets of hybrid adsorbents …