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Sludge-Based Activated Carbon: Characterization And Performance For Removal Of Methylene Blue From Aqueous Solution, Ahmad Anwar Al Madhoon Nov 2022

Sludge-Based Activated Carbon: Characterization And Performance For Removal Of Methylene Blue From Aqueous Solution, Ahmad Anwar Al Madhoon

Theses

Domestic wastewater treatment plants in the United Arab Emirates (UAE) produce 122 thousand tons of dried sludge annually. About 70% of this sludge is dumped in landfills, creating water and soil contamination. Sludge is an energy-rich organic material that could be converted into activated carbon by thermal or chemical processes. Potassium hydroxide has shown great potential as an activating agent for producing high-quality sludge based activated carbon (SBAC). However, its use adds to the cost of the production process. Thus, there is a need for an alternative activating agent that is not costly. One possible chemical is carbide lime which …


Efficient Removal Of Common Organic Pollutants From Water By Zn-Doped Tio2 Nanoparticles With Different Applications, Khaled Elgendy, Ibrahim Elmehasseb, Saleh Kandil May 2022

Efficient Removal Of Common Organic Pollutants From Water By Zn-Doped Tio2 Nanoparticles With Different Applications, Khaled Elgendy, Ibrahim Elmehasseb, Saleh Kandil

Karbala International Journal of Modern Science

Water purification via adsorption without energy consumption was considered a green process. Zn-doped TiO2 nanoparticles were fabricated by the Sol-gel method and characterized by different analysis techniques. Zinc doping of TiO2 increases the surface area to 26.7m2g-1 with adsorption results, 75.1%, 71.1%, and 68.2% for methylene blue, ofloxacin, and SLS, respectively. Variable affecting factors on adsorption have been studied. The adsorption behavior fitted with Langmuir and Freundlich equations than Temkin isotherm, indicating the preferred heterogeneous adsorption at equivalent adsorbent sites. The application of nanoparticles in many synthetic specimens of pollutants gave excellent removal results, which exceeded 75% of detoxification.


Characteristic Studies On The Biochars Produced By Hydro-Thermal And Steam Gasification Of Canola Hull And Canola Meal Fuel Pellets, Franco Berruti, Sonil Nanda, Ajay K. Dalai, Janusz A. Kozinski Sep 2019

Characteristic Studies On The Biochars Produced By Hydro-Thermal And Steam Gasification Of Canola Hull And Canola Meal Fuel Pellets, Franco Berruti, Sonil Nanda, Ajay K. Dalai, Janusz A. Kozinski

Bio-Char II: Production, Characterization and Applications

Biochars, based on their production process and biomass precursor, can have a broad range of structural, compositional, chemical, and physical properties. These properties are important for identifying the biochar performance and stability in further applications. Non-food biomass has a great potential to produce biochars. Two inherent agricultural biomasses from Canadian prairies including canola hull and canola meal were used for the production of fuel pellets. This study provides information on the specific features of biochars produced by steam and hydro-thermal gasification of these fuel pellets compared with those of well-known pyrolysis biochars. For steam gasification, the steam to biomass ratio …


Pyrolysis Of Fiber-Plastic Waste Blends, Shreyas Kolapkar Jan 2018

Pyrolysis Of Fiber-Plastic Waste Blends, Shreyas Kolapkar

Dissertations, Master's Theses and Master's Reports

The main objective of this work is to investigate fast pyrolysis of fiber and plastic feedstocks in order to understand the synergistic effect from their co-pyrolysis. In this on-going work, fiber, plastic and their blend are characterized and pyrolysis oil is produced from them in the fast batch pyrolysis reactor. Based on a heat transfer model it is shown that results of oil produced from batch reactor will be applicable to the continuous paddle reactor. From feedstock characterization, chlorine was observed particularly in the plastic feedstock. Thus, chlorine removal method using torrefaction and high shear mixing was implemented and was …


Characteristic Studies On The Waste Biomass-Based Biochars Produced By Fast Pyrolysis, Ramin Azargohar, Sonil Nanda, Janusz A. Kozinski, Ajay K. Dalai, Ronny Sutarto Aug 2017

Characteristic Studies On The Waste Biomass-Based Biochars Produced By Fast Pyrolysis, Ramin Azargohar, Sonil Nanda, Janusz A. Kozinski, Ajay K. Dalai, Ronny Sutarto

Biochar: Production, Characterization and Applications

Biochar, as carbonaceous product obtained from pyrolysis of biomass, has many applications in diverse areas due to its versatile physicochemical properties. Non-food biomass has a great potential to produce biochars. In the present study, pinewood sawdust (forest residue), wheat straw and flax straw (agricultural residues), and poultry litter (livestock manure) were used as precursors for pyrolysis. Focus of this study was on the effects of fast pyrolysis temperature (400, 475, and 550 oC) on the characteristics of biochars produced by means of a mobile pyrolysis unit. Different characterization techniques are used to study the physical, chemical, and structural characteristics …


Biochar: Product Development In Remote Regions From Mixed Residues, Kelly Hawboldt, Stephanie Macquarrie, Hanieh Bamdad Aug 2017

Biochar: Product Development In Remote Regions From Mixed Residues, Kelly Hawboldt, Stephanie Macquarrie, Hanieh Bamdad

Biochar: Production, Characterization and Applications

Biochar is a particularly interesting pyrolysis product in regions where there is an abundance of waste biomass to convert but limited ability to effectively turn the waste into a product due to distance to market, lack of infrastructure (e.g. pipelines for gas), and the heterogeneous nature of the biomass (e.g. forestry residues, fishery by-product etc.). Biochar is a more homogeneous material (compared to waste biomass) expanding possible applications, is a less dense solid (making transport less costly), and could be used to sustainably develop an industry/product in these regions.

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Thz Spectroscopic Characterization Of Biochar, Lucia Lepodise, R A. Lewis, Stephen D. Joseph, Joseph Horvat Jan 2015

Thz Spectroscopic Characterization Of Biochar, Lucia Lepodise, R A. Lewis, Stephen D. Joseph, Joseph Horvat

Faculty of Engineering and Information Sciences - Papers: Part A

Fertile dark soils made by humans in the Amazon basin, terra preta, have influenced the manufacture of the biochar based fertilizers. Different types of biochar exist but not all of them are good in improving the quality of the soil. FTIR was used to distinguish between the more and the less fertile biochar.


The Characterization And Comparison Of Biochar Produced From A Decentralized Reactor Using Forced Air And Natural Draft Pyrolysis, Leah Herbert, Ian Hosek, Rishi Kripalani Jun 2012

The Characterization And Comparison Of Biochar Produced From A Decentralized Reactor Using Forced Air And Natural Draft Pyrolysis, Leah Herbert, Ian Hosek, Rishi Kripalani

Materials Engineering

The soil additive properties of biochar have proven both effective and globally beneficial, but depend heavily on feedstock used and process conditions. This study characterizes how forced and natural draft air flows affect the biochar’s soil amendment potential. Biochars manufactured from two pine species of feedstock, in timber and pellet form, were compared against a designer biochar. The designer biochar held the lowest C:N ratio (57.43), followed by the natural draft pellets (199.5), forced air timber (282.5), forced air pellets (422.7), and natural draft timber (503.7). The designer char had the largest cation exchange capacity at 138.5 cmolc/kg; the decentralized …