Open Access. Powered by Scholars. Published by Universities.®

Digital Commons Network™

Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics

Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 1 - 30 of 422

Full-Text Articles in Entire DC Network

One-Pot Synthesis Green Zinc Oxide Nanoparticles Immobilized On Activated Carbon Derived From Pineapple Peel For Adsorption Of Pb(Ii), Vienna Saraswaty, Evyka Setya Aji, Ardi Ardiansyah, Ayu Hanifah, Nathania Puspitasari, Shella Permatasari Santoso, Sandy Budi Hartono, Chandra Risdian, Elsy Rahimi Chaldun, Henry Setiyanto Apr 2024

One-Pot Synthesis Green Zinc Oxide Nanoparticles Immobilized On Activated Carbon Derived From Pineapple Peel For Adsorption Of Pb(Ii), Vienna Saraswaty, Evyka Setya Aji, Ardi Ardiansyah, Ayu Hanifah, Nathania Puspitasari, Shella Permatasari Santoso, Sandy Budi Hartono, Chandra Risdian, Elsy Rahimi Chaldun, Henry Setiyanto

Karbala International Journal of Modern Science

The current study introduces a one-pot technique for synthesizing an environmentally benign and cheap composite adsorbent, namely ZnO-PPAC, for the adsorption of Pb(II). The designated adsorbent was prepared by incorporating green synthesized zinc oxide (ZnO) nanoparticles on activated carbon-derived from pineapple peel. The prepared adsorbents were characterized using XRD, SEM, EDS, FTIR, and BET techniques. The XRD pattern verifies that the ZnO was successfully synthesized and immobilized onto the PPAC in a one pot synthesis system. The surface areas of ZnOPPAC and PPAC adsorbents were 13.62 m2/g and 961.96 m2/g, respectively. The FTIR evaluation of the ZnO-PPAC adsorbent revealed several …

Go to article

Water Current, Volume 56, No. 1, Spring 2024 Apr 2024

Water Current, Volume 56, No. 1, Spring 2024

Water Current Newsletter

No abstract provided.

Go to article

Role Of Electronegativity In Environmentally Persistent Free Radicals (Epfrs) Formation On Zno, Syed Monjur Ahmed, Reuben Oumnov, Orhan Kizilkaya, Randall W. Hall, Philip T. Sprunger, Robert L. Cook Mar 2024

Role Of Electronegativity In Environmentally Persistent Free Radicals (Epfrs) Formation On Zno, Syed Monjur Ahmed, Reuben Oumnov, Orhan Kizilkaya, Randall W. Hall, Philip T. Sprunger, Robert L. Cook

Natural Sciences and Mathematics | Faculty Scholarship

Environmentally persistent free radicals (EPFRs), a group of emerging pollutants, have significantly longer lifetimes than typical free radicals. EPFRs form by the adsorption of organic precursors on a transition metal oxide (TMO) surface involving electron charge transfer between the organic and TMO. In this paper, dihalogenated benzenes were incorporated to study the role of electronegativity in the electron transfer process to obtain a fundamental knowledge of EPFR formation mechanism on ZnO. Upon chemisorption on ZnO nanoparticles at 250 °C, electron paramagnetic resonance (EPR) confirms the formation of oxygen adjacent carbon-centered organic free radicals with concentrations between 1016 and 1017 spins/g. …

Go to article

Synthesis And Characterization Of Renewable Heterogeneous Catalyst Zno Supported Biogenic Silica From Pineapple Leaves Ash For Sustainable Biodiesel Conversion, Nadila Pratiwi, Suriati Eka Putri, Yulia Shinta, Arya Ibnu Batara, Diana Eka Pratiwi, Abd Rahman, Nur Ahmad, Heryanto Heryanto Feb 2024

Synthesis And Characterization Of Renewable Heterogeneous Catalyst Zno Supported Biogenic Silica From Pineapple Leaves Ash For Sustainable Biodiesel Conversion, Nadila Pratiwi, Suriati Eka Putri, Yulia Shinta, Arya Ibnu Batara, Diana Eka Pratiwi, Abd Rahman, Nur Ahmad, Heryanto Heryanto

Karbala International Journal of Modern Science

This study reports on the first case of the low-cost and environmentally friendly ZnO/SiO2 heterogeneous catalyst from pineapple leaves ash (PLA). Catalyst shows excellent performance in catalyzing the transesterification of waste cooking oil (WCO) with methanol for biodiesel conversion. This study focuses on assessing the influence of Zn content on physicochemical characteristics, using XRD, FTIR, SEM, and N2 adsorption-desorption methods. In addition, three different Zn content levels (20, 25, and 30 %wt) were applied. The results showed that all ZnO/SiO2 samples exhibited characteristics suitable for use as catalyst with an average crystallite size of 31.83-34.15 nm, and a surface area …

Go to article

Palladium (0) Nanoparticles Distributed On Lanthanum (Iii) Oxide As An Effective Catalyst For The Methanolysis Of Hydrazine-Borane To Produce Hydrogen, Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan Feb 2024

Palladium (0) Nanoparticles Distributed On Lanthanum (Iii) Oxide As An Effective Catalyst For The Methanolysis Of Hydrazine-Borane To Produce Hydrogen, Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan

Turkish Journal of Chemistry

Pd (0) nanoparticles (NPs) distributed on lanthanum (III) oxide were ex situ generated from the reduction of Pd2+ ions using NaBH4 as reducing agent. The Pd/La2O3 displayed good catalytic activity in H2(g) releasing from the hydrazine-borane (HB) methanolysis reaction and it was identified by advanced techniques. Pd/La2O3 was found to be an active catalyst procuring three equiv. H2(g) per mole of HB. The results from TEM images represent the formation of Pd (0) NPs with an average particle size of 1.94 ± 0.1 nm on the surface of La2O3. Moreover, Pd/La2O3 with various Pd loadings were prepared and tested as …

Go to article

New Features Of Laboratory-Generated Epfrs From 1,2-Dichlorobenzene (Dcb) And 2‑Monochlorophenol (Mcp), Lavrent Khachatryan, Marwan Y. Rezk, Divine Nde, Farhana Hasan, Slawomir Lomnicki, Dorin Boldor, Robert Cook, Phillip Sprunger, Randall W. Hall, Stephania Cormier Feb 2024

New Features Of Laboratory-Generated Epfrs From 1,2-Dichlorobenzene (Dcb) And 2‑Monochlorophenol (Mcp), Lavrent Khachatryan, Marwan Y. Rezk, Divine Nde, Farhana Hasan, Slawomir Lomnicki, Dorin Boldor, Robert Cook, Phillip Sprunger, Randall W. Hall, Stephania Cormier

Natural Sciences and Mathematics | Faculty Scholarship

The present research is primarily focused on investigating the characteristics of environmentally persistent free radicals (EPFRs) generated from commonly recognized aromatic precursors, namely, 1,2-dichlorobenzene (DCB) and 2- monochlorophenol (MCP), within controlled laboratory conditions at a temperature of 230 °C, termed as DCB230 and MCP230 EPFRs, respectively. An intriguing observation has emerged during the creation of EPFRs from MCP and DCB utilizing a catalyst 5% CuO/SiO2, which was prepared through various methods. A previously proposed mechanism, advanced by Dellinger and colleagues (a conventional model), postulated a positive correlation between the degree of hydroxylation on the catalyst’s surface (higher hydroxylated, HH and …

Go to article

Trees In Urban Environments: How Soil Quality Impacts Tree Performance, Saidan Qi Feb 2024

Trees In Urban Environments: How Soil Quality Impacts Tree Performance, Saidan Qi

Dissertations, Theses, and Capstone Projects

Cities around the world are increasingly investing in reforestation and afforestation efforts to mitigate impacts from climate change and population growth. However, urban soil conditions can be unfavorable for tree growth. Street trees are widely known to suffer from poor soil quality, but there has been no comprehensive review of this topic so far. Clean soils can be transported from nonurban areas to support cities’ green projects, but this approach is not sustainable. Artificial (constructed) soils can be created from various materials and have been proposed as an alternative medium for urban tree growth, but no research has been done …

Go to article

Perennializing Marginal Croplands: Going Back To The Future To Mitigate Climate Change With Resilient Biobased Feedstocks, Salvador Ramirez Ii, Marty R. Schmer, Virginia L. Jin, Robert B. Mitchell, Catherine E. Stewart, Jay Parsons, Daren D. Redfearn, John J. Quinn, Gary E. Varvel, Kenneth P. Vogel, Ronald F. Follett Jan 2024

Perennializing Marginal Croplands: Going Back To The Future To Mitigate Climate Change With Resilient Biobased Feedstocks, Salvador Ramirez Ii, Marty R. Schmer, Virginia L. Jin, Robert B. Mitchell, Catherine E. Stewart, Jay Parsons, Daren D. Redfearn, John J. Quinn, Gary E. Varvel, Kenneth P. Vogel, Ronald F. Follett

United States Department of Agriculture-Agricultural Research Service / University of Nebraska-Lincoln: Faculty Publications

Managing annual row crops on marginally productive croplands can be environmentally unsustainable and result in variable economic returns. Incorporating perennial bioenergy feedstocks into marginally productive cropland can engender ecosystem services and enhance climate resiliency while also diversifying farm incomes. We use one of the oldest bioenergy-specific field experiments in North America to evaluate economically and environmentally sustainable management practices for growing perennial grasses on marginal cropland. This long-term field trial called 9804 was established in 1998 in eastern Nebraska and compared the productivity and sustainability of corn (Zea mays L.)—both corn grain and corn stover—and switchgrass (Panicum virgatum …

Go to article

Potentially Massive And Global Non-Pyrogenic Production Of Condensed "Black" Carbon Through Biomass Oxidation, Aleksandar I. Goranov, Hongmei Chen, Jianshu Duan, Satish C. B. Myneni, Patrick G. Hatcher Jan 2024

Potentially Massive And Global Non-Pyrogenic Production Of Condensed "Black" Carbon Through Biomass Oxidation, Aleksandar I. Goranov, Hongmei Chen, Jianshu Duan, Satish C. B. Myneni, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

With the increased occurrences of wildfires worldwide, there has been an increase in scientific interest surrounding the chemistry of fire-derived "black" carbon (BC). Traditionally, wildfire research has assumed that condensed aromatic carbon (ConAC) is exclusively produced via combustion, and thus, ConAC is equated to BC. However, the lack of correlations between ConAC in soils or rivers and wildfire history suggests that ConAC may be produced non-pyrogenically. Here, we show quantitative evidence that this occurs during the oxidation of biomass with environmentally ubiquitous hydroxyl radicals. Pine wood boards exposed to iron nails and natural weather conditions for 12 years yielded a …

Go to article

Direct Blue 86 Textile Dye Removal From Aqueous Solution Using Rice Husk-Based Adsorbent, M. Zulbahari M. Zua, Muhammad Raza Ul Mustafa, Mohamed Hasnain Isa, Teh Sabariah Binti Abd Manan, Naimah Ibrahim, Rozeana Hj Md Juani, Wida Susanty Hj Suhaili, Asmaal Muizz Sallehhin Bin Hj Mohammad Sultan, Zuliana Binti Hj Nayan Jan 2024

Direct Blue 86 Textile Dye Removal From Aqueous Solution Using Rice Husk-Based Adsorbent, M. Zulbahari M. Zua, Muhammad Raza Ul Mustafa, Mohamed Hasnain Isa, Teh Sabariah Binti Abd Manan, Naimah Ibrahim, Rozeana Hj Md Juani, Wida Susanty Hj Suhaili, Asmaal Muizz Sallehhin Bin Hj Mohammad Sultan, Zuliana Binti Hj Nayan

ASEAN Journal on Science and Technology for Development

Adsorption by activated carbon is an effective method of dye removal. However, due to high production and regeneration costs of activated carbon, various studies on low-cost adsorbents have been conducted. Agricultural waste such as rice husk (RH) is seen to be a good adsorbent for dye removal. Moreover, rice husk is readily available. In this study, rice husk-based adsorbents were prepared by chemical and thermal treatments. Standard curve (colour vs absorbance) for Direct Blue 86 (DB 86) was prepared to determine the concentration of dye before and after adsorption. The adsorption potential of the adsorbent for textile dye DB 86 …

Go to article

Stabilization Of Pfas-Contaminated Soil With Sewage Sludge- And Wood-Based Biochar Sorbents, Erlend Sørmo, Clara Benedikte Mader Lade, Julie Zhang, Alexandros G. Asimakopoulos, Geir Wold Åsli, Michel Hubert, Aleksandar I. Goranov, Hans Peter H. Arp, Gerard Cornelissen Jan 2024

Stabilization Of Pfas-Contaminated Soil With Sewage Sludge- And Wood-Based Biochar Sorbents, Erlend Sørmo, Clara Benedikte Mader Lade, Julie Zhang, Alexandros G. Asimakopoulos, Geir Wold Åsli, Michel Hubert, Aleksandar I. Goranov, Hans Peter H. Arp, Gerard Cornelissen

Chemistry & Biochemistry Faculty Publications

Sustainable and effective remediation technologies for the treatment of soil contaminated with per- and polyfluoroalkyl substances (PFAS) are greatly needed. This study investigated the effects of waste-based biochars on the leaching of PFAS from a sandy soil with a low total organic carbon content (TOC) of 0.57 ± 0.04% impacted by PFAS from aqueous film forming foam (AFFF) dispersed at a former fire-fighting facility. Six different biochars (pyrolyzed at 700–900°C) were tested, made from clean wood chips (CWC), waste timber (WT), activated waste timber (aWT), two digested sewage sludges (DSS-1 and DSS-2) and de-watered raw sewage sludge (DWSS). Up-flow column …

Go to article

Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül Dec 2023

Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül

Turkish Journal of Chemistry

Technological devices are mostly manufactured by conductive and semiconductive materials. As advancement in the last decades, carbon nanomaterials have been explored in electrical/electronic technology due to their unique performances for manufacturing developing, and prudential miniaturized and flexible electrical/electronic devices. In the era of sustainable and clean carbon technology; renewable, alternative, biodegradable, and eco-friendly new carbon resources are required. Biomass could be the answer to offer inspiring carbon allotropes from nature to be suitable for developing electrical/electronic devices. In this article, deriving of the technological carbonaceous material from biomass, studies although they are very limited in the literature on obtaining the …

Go to article

Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t Dec 2023

Removal Of Toxic Cr(Vi) From Aqueous Medium With Effective Magnetic Carbon-Based Nanocomposites, Ferda Ci̇van Çavuşoğlu, Gülsüm Özçeli̇k, Şahi̇ka Sena Bayazi̇t

Turkish Journal of Chemistry

Cr(VI), which has toxic effects, is a heavy metal and it must be removed from the environment due to the various damages it causes. In this study, the removal of Cr(VI) pollutants from aqueous solutions with Fe3O4-based materials using a batch adsorption technique was investigated. Magnetically modified graphene nanoplatelet (GNP)-based nanocomposites were prepared and their structures were characterized by FTIR, XRD, SEM, BET, and TGA techniques. The effects of various physicochemical parameters such as adsorbent dose, contact time, initial Cr(VI) solution concentration, pH, and the presence of coexisting ions (NaCl) on the adsorption process were investigated. Accordingly, the optimum conditions …

Go to article

Ten Problems And Solutions For Restoration Of Karst Ecosystem In Southwest China, Xiaoyong Bai, Sirui Zhang, Chen Ran, Luhua Wu, Chaochao Du, Lei Dai, Xingyi Yang, Zilin Li, Yingying Xue, Mingkang Long, Minghui Li, Shu Yang, Qing Luo, Xiaoyun Zhang, Xiaoqian Shen, Fei Chen, Qin Li, Yuanhong Deng, Zeyin Hu, Chaojun Li Dec 2023

Ten Problems And Solutions For Restoration Of Karst Ecosystem In Southwest China, Xiaoyong Bai, Sirui Zhang, Chen Ran, Luhua Wu, Chaochao Du, Lei Dai, Xingyi Yang, Zilin Li, Yingying Xue, Mingkang Long, Minghui Li, Shu Yang, Qing Luo, Xiaoyun Zhang, Xiaoqian Shen, Fei Chen, Qin Li, Yuanhong Deng, Zeyin Hu, Chaojun Li

Bulletin of Chinese Academy of Sciences (Chinese Version)

The karst areas in southwest China are one of the key but difficult areas targeted in the “Beautiful China” construction initiative, which focuses on soil erosion, proportion of farmland, water pollution, karst drought, ecological restoration, carbon sink, ecological effects of urbanization, rocky desertification management indicators, and biodiversity and sustainability assessment. The study synthesizes the knowledge accumulated during ecological restoration practice in karst areas into 10 problems and solutions that are strong, universal and empirically supported. These problems and solutions help to explain the challenges of achieving sustainability in karst ecology restoration and thus point to solutions. They constitute a core …

Go to article

Addressing Water Hyacinth (Pontederia Crassipes) Impacts On Aquatic Biota In Lake Okeechobee, Joseph Salerno Dec 2023

Addressing Water Hyacinth (Pontederia Crassipes) Impacts On Aquatic Biota In Lake Okeechobee, Joseph Salerno

All HCAS Student Capstones, Theses, and Dissertations

The incursion of water hyacinth, Pontederia crassipes in Lake Okeechobee has resulted in management systems to be implemented to reduce the coverage of the invasive macrophyte. Its residence in the Lake Okeechobee ecosystem and the effects it has on organisms in the lake, whether it be positive or harmful is unknown. This study attempted to assess the potential effects that water hyacinth has on aquatic biota in Lake Okeechobee. Biotic data were collected on open water, water hyacinth covered, and native vegetation covered habitats via hook-and-line fishing, electrofishing, baited minnow traps, and the sampling of plant roots over a thirteen-month …

Go to article

The Effect Of Amf-Cacao Association On Varying Physicochemical, Nutrient, And Biological Soil Parameters In An Agroforest System, Diana P. Paguntalan, Nelly S. Aggangan, Inocencio E. Buot Jr. Dec 2023

The Effect Of Amf-Cacao Association On Varying Physicochemical, Nutrient, And Biological Soil Parameters In An Agroforest System, Diana P. Paguntalan, Nelly S. Aggangan, Inocencio E. Buot Jr.

The Philippine Agricultural Scientist

The increasing interest in sustainable methods in agroforestry directs the attention of many to arbuscular mycorrhizal fungi (AMF) for their role in maintaining or improving overall plant health and nutrition of many plants including cacao (Theobroma cacao L.) trees. The effects of different treatments of AMF and other soil amendments applied singly or in combination on physicochemical properties, nutrient levels, spore count, and rhizosphere microbial counts, were investigated and compared across different sampling periods of varying climatological conditions in an agroforest system. Results showed that there was a significant effect on the N content using the different treatments. The …

Go to article

Changes In Physico-Chemical Properties Of A Sandy Loam Soil Depending On The Particle Size Of Hazelnut Shell-Derived Biochar, Damla Bender Özenç, Ceyhan Tarakçioğlu, Funda Irmak Yilmaz, Selahattin AygüN Dec 2023

Changes In Physico-Chemical Properties Of A Sandy Loam Soil Depending On The Particle Size Of Hazelnut Shell-Derived Biochar, Damla Bender Özenç, Ceyhan Tarakçioğlu, Funda Irmak Yilmaz, Selahattin AygüN

The Philippine Agricultural Scientist

This study evaluated the effects of hazelnut shell-derived biochar particle sizes on the soil’s physical and chemical properties, and on various nutrient contents present in the sandy loamy soils. For this purpose, an incubation experiment in the plastic high tunnel has been performed under sixteen treatments (control-only soil), and at four incubation times (30, 60, 90, and 120 d), by using three different biochar sizes (≤ 1, 1 - 2, and 2 - 4 mm). The addition of 1 - 2 and 2 - 4 mm biochar during the incubation time decreased the bulk density in the soil by 26%. …

Go to article

Computationally-Driven Insights Into The Ligand Environments Of Materials For Catalysis And Separations, Stephen Vicchio Dec 2023

Computationally-Driven Insights Into The Ligand Environments Of Materials For Catalysis And Separations, Stephen Vicchio

All Dissertations

Designing new catalytic and sorption materials is necessary to limit global temperature rise below 1.5 ◦C by 2050, while also meeting global energy demands. Climate change and energy production are not mutually exclusive; global population growth has direct impacts on global energy demands and climate. In both catalysis and adsorption applications, new technologies are needed to address these challenges. Catalysis can provide alternate, low-energy routes for converting low-value gases into higher-value chemical commodities, thus altering our current energy production. Likewise, new sorption materials can capture previously emitted CO2 from decades of energy production from fossil fuels, thus helping to …

Go to article

Electrochemical And Colorimetric Nanosensors For Detection Of Heavy Metal Ions: A Review, Sayo Fakayode, Charuksha Walgama, Vivian E. Fernand Narcisse, Cidya Grant Dec 2023

Electrochemical And Colorimetric Nanosensors For Detection Of Heavy Metal Ions: A Review, Sayo Fakayode, Charuksha Walgama, Vivian E. Fernand Narcisse, Cidya Grant

Chemistry, Physics and Astronomy Faculty Scholarship

Human exposure to acute and chronic levels of heavy metal ions are linked with various health issues, including reduced children’s intelligence quotients, developmental challenges, cancers, hypertension, immune system compromises, cytotoxicity, oxidative cellular damage, and neurological disorders, among other health challenges. The potential environmental HMI contaminations, the biomagnification of heavy metal ions along food chains, and the associated risk factors of heavy metal ions on public health safety are a global concern of top priority. Hence, developing lowcost analytical protocols capable of rapid, selective, sensitive, and accurate detection of heavy metal ions in environmental samples and consumable products is of global …

Go to article

The Perfect Is The Enemy Of The Good: Carbon Credits And Funding For Decarbonization In Developing Countries, Andrew A. Bernstein Nov 2023

The Perfect Is The Enemy Of The Good: Carbon Credits And Funding For Decarbonization In Developing Countries, Andrew A. Bernstein

New England Journal of Public Policy

Carbon credits issued in the voluntary carbon market are an important source of funding for projects in developing countries designed to reduce greenhouse gas emissions, such as forest preservation and renewable energy. Beyond their potential to provide billions of dollars of private sector financing for decarbonization, carbon credits can generate economic opportunity, employment, and biodiversity. But they are controversial, mainly (but not only) because it is difficult to confirm and to quantify their emissions benefits. This article argues that policymakers should nonetheless support voluntary carbon market growth, so long as companies use carbon credits to mitigate emissions they cannot avoid …

Go to article

University Of Arkansas, Chemistry And Biochemistry Department Research Publications, 2014- November 2023. 107p., Jeremy Smith, Lutishoor Salisbury Nov 2023

University Of Arkansas, Chemistry And Biochemistry Department Research Publications, 2014- November 2023. 107p., Jeremy Smith, Lutishoor Salisbury

University Libraries Faculty Publications and Presentations

This report provides a compilation of the research publications by the Chemistry and Biochemistry faculty for the period: 2014 - November 2023. The information was gathered from major databases in science and technology including Web of Science, SciFinder, Reaxys, PubMed, IEEE Explore and Engineering Index. At least one author in each of the publications has the CHBC department as its affiliation. It includes a table summarizing the research. The listing is organized according to type of publications within specific years.

Go to article

Green Catalyst For Clean Fuel Production Via Hydrodeoxygenation, Selva Bi̇lge Yücel, Yusuf Osman Donar, Samed Ergenekon, Beyza Özoylumlu, Ali̇ Sinağ Oct 2023

Green Catalyst For Clean Fuel Production Via Hydrodeoxygenation, Selva Bi̇lge Yücel, Yusuf Osman Donar, Samed Ergenekon, Beyza Özoylumlu, Ali̇ Sinağ

Turkish Journal of Chemistry

The development of new fuel sources to replace nonrenewable fossil fuels has received substantial attention due to the ongoing demand for fossil fuels. Biomass and raw waste materials are crucial sources to produce suitable alternative fuels instead of nonrenewable fuels and offer a greener approach. Therefore, improving the fuel properties of biooils produced from the thermochemical conversion of biomass and raw waste materials is critical as it is used as an alternative to nonrenewable fuel. Developing an economical and eco-friendly method to produce sustainable and renewable oil by improving biooil containing large amounts of phenolic compounds has become imperative. One …

Go to article

Are Plant–Soil Feedbacks Caused By Many Weak Microbial Interactions?, Julia K. Aaronson, Andrew Kulmatiski, Leslie E. Forero, Josephine Grenzer, Jeanette M. Norton Oct 2023

Are Plant–Soil Feedbacks Caused By Many Weak Microbial Interactions?, Julia K. Aaronson, Andrew Kulmatiski, Leslie E. Forero, Josephine Grenzer, Jeanette M. Norton

Wildland Resources Student Research

We used high-throughput sequencing and multivariate analyses to describe soil microbial community composition in two four-year field plant–soil feedback (PSF) experiments in Minnesota, USA and Jena, Germany. In descending order of variation explained, microbial community composition differed between the two study sites, among years, between bulk and rhizosphere soils, and among rhizosphere soils cultivated by different plant species. To try to identify soil organisms or communities that may cause PSF, we correlated plant growth responses with the microbial community composition associated with different plants. We found that plant biomass was correlated with values on two multivariate axes. These multivariate axes …

Go to article

Water Current, Volume 55, No. 3, Fall 2023 Oct 2023

Water Current, Volume 55, No. 3, Fall 2023

Water Current Newsletter

No abstract provided.

Go to article

Physical-Vapor-Deposited Metal Oxide Thin Films For Ph Sensing Applications: Last Decade Of Research Progress, Mohammad Nur-E-Alam, Devendra K. Maurya, Boon K. Yap, Armin Rajabi, Camellia Doroody, Hassan B. Mohamed, Mayeen U. Khandaker, Mohammad A. Islam, Sieh K. Tiong Oct 2023

Physical-Vapor-Deposited Metal Oxide Thin Films For Ph Sensing Applications: Last Decade Of Research Progress, Mohammad Nur-E-Alam, Devendra K. Maurya, Boon K. Yap, Armin Rajabi, Camellia Doroody, Hassan B. Mohamed, Mayeen U. Khandaker, Mohammad A. Islam, Sieh K. Tiong

Research outputs 2022 to 2026

In the last several decades, metal oxide thin films have attracted significant attention for the development of various existing and emerging technological applications, including pH sensors. The mandate for consistent and precise pH sensing techniques has been increasing across various fields, including environmental monitoring, biotechnology, food and agricultural industries, and medical diagnostics. Metal oxide thin films grown using physical vapor deposition (PVD) with precise control over film thickness, composition, and morphology are beneficial for pH sensing applications such as enhancing pH sensitivity and stability, quicker response, repeatability, and compatibility with miniaturization. Various PVD techniques, including sputtering, evaporation, and ion beam …

Go to article

The Role Of Nanofluids In Renewable Energy Engineering, M. M. Bhatti, K. Vafai, Sara I. Abdelsalam Sep 2023

The Role Of Nanofluids In Renewable Energy Engineering, M. M. Bhatti, K. Vafai, Sara I. Abdelsalam

Basic Science Engineering

No abstract provided.

Go to article

Eggshell-Alginate Composites (Eacs) As Eco-Friendly Adsorbents For Rhodamine B Uptake From Aqueous Solutions, Rusnadi Rusnadi, Mar’Atus Sholihah, Nurrahmi Handayani, Muhammad Ali Zulfikar Sep 2023

Eggshell-Alginate Composites (Eacs) As Eco-Friendly Adsorbents For Rhodamine B Uptake From Aqueous Solutions, Rusnadi Rusnadi, Mar’Atus Sholihah, Nurrahmi Handayani, Muhammad Ali Zulfikar

Karbala International Journal of Modern Science

The contamination of wastewater by Rhodamine B (RhB) poses a significant environmental concern due to its negative impacts on aesthetics, ecosystems, and human well-being. This study successfully synthesized eco-friendly egg-shell-alginate composites (EACs) as adsorbents by combining alginate solution, eggshell powder, and a 2% CaCl2 solu-tion. Characterization techniques including FTIR, SEM, TGA, and SAA were employed to analyze the EACs. FTIR analysis revealed characteristic absorption peaks corresponding to -OH groups, C=O groups, C-O groups, and the pres-ence of CO32-. The structural analysis confirmed the physical mixture of functional groups from eggshells and alginate, resulting in a homogeneous EACs mixture. TGA analysis …

Go to article

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego Sep 2023

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Go to article

Fire Effects On Soil Organic Matter In The Creek Fire, Gracie E. Doolin Sep 2023

Fire Effects On Soil Organic Matter In The Creek Fire, Gracie E. Doolin

Master of Science in Environmental Sciences and Management Projects

Wildfires have increased in frequency and severity over the past few decades due to the increased concertation of CO2 emissions from anthropogenic influence. Soil carbon (C) sequestration has been identified as a climate change mitigation strategy; however, the influx of large-scale wildfires has accelerated landscape processes such as erosion, reducing soil aggradation, and soil C and nitrogen (N) protection. This trend is highlighted by the Creek Fire that occurred in September 2020 and burned 379,895 acres in the Sierra National Forest. This research is designed to close the knowledge gap regarding the impact of burn severity on soil organic matter …

Go to article

Separation Of Perrhenate And Perfluoroalkyl Substances By Ion Chromatography With Customized Stationary Phases, Wai Ning Chan Aug 2023

Separation Of Perrhenate And Perfluoroalkyl Substances By Ion Chromatography With Customized Stationary Phases, Wai Ning Chan

Theses and Dissertations

Ion exchange chromatography (IC) is an analytical technique used to separate charged molecules including ions, proteins, small nucleotides, and amino acids. It can function in anion or cation mode. In this dissertation, anion exchange chromatography was used, and column materials were made in our lab with resorcinarene-based compounds called cavitands. Cavitands create cavities to bind to molecules because of their three-dimensional structure. Two new gradient IC methods were established to identify and quantify perrhenate and perfluoroalkyl substances (PFAS) by customized resorcinarene-based column, zinc cyclen resoecinarene (ZCR) and arginine methyl ester (RUE) columns. The ZCR column accomplished outstanding separation of perrhenate …

Go to article

Next Last