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Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Examining The Relationship Between Lignocellulosic Biomass Structural Constituents And Its Flow Behavior, Ekramul Haque Ehite

Doctoral Dissertations

Lignocellulosic biomass material sourced from plants and herbaceous sources is a promising substrate of inexpensive, abundant, and potentially carbon-neutral energy. One of the leading limitations of using lignocellulosic biomass as a feedstock for bioenergy products is the flow issues encountered during biomass conveyance in biorefineries. In the biorefining process, the biomass feedstock undergoes flow through a variety of conveyance systems. The inherent variability of the feedstock materials, as evidenced by their complex microstructural composition and non-uniform morphology, coupled with the varying flow conditions in the conveyance systems, gives rise to flow issues such as bridging, ratholing, and clogging. These issues …

Understanding Lignin’S Fast Pyrolysis Through Examination Of The Thermolysis Mechanisms Of Model Oligomers, Ross Wesley Houston

Doctoral Dissertations

The lignocellulosic biorefinery is a visionary concept that endeavors to provide an alternative to fossil-based refineries by producing biobased fungible fuels and specialty chemicals almost exclusively derived currently from petroleum refineries. This vision of the lignocellulosic biorefinery can only be realized if all fractions of lignocellulosic biomass are efficiently deconstructed and valorized to generate a diverse portfolio of products to sustain it against market vicissitudes. Of the three main structural constituents of lignocellulosic biomass (i.e., cellulose, hemicellulose, and lignin), lignin is underutilized despite being the most abundant renewable source of aromatic platform chemicals, representing a growing 250 billion dollar market. …

Development Of Mass Transfer Coefficient Correlations Between Carbon Dioxide And Oxygen For Air-Lift Devices, John Walker

All Theses

An experimental method for measurement and determination of carbon dioxide volumetric mass transfer coefficients (k_La) in high pH water was developed. The goal of this research was to develop a relationship between CO₂ and O₂ volumetric mass transfer coefficients for accurate k_La values in order to meet the needs of carbon capture systems and other industries. Results included dissolved oxygen (DO) and total inorganic carbon (TIC) k_La comparisons, as well as polarographic DO (mg/L) and galvanic DO (mV) k_La correlation. CO₂ k_La estimation based on O_{2 …}

Non-Energy Circular Economy Potential Of Rice Husks: A Techno-Eco-Environmental Assessment, Winfred Oppong Yeboah

Graduate Theses and Dissertations

The non-energy circular bioeconomy potential of rice husks was examined via sustainability assessments, namely life cycle assessment (LCA), life cycle impact cost assessment (LCICA), and techno-economic assessment (TEA). The study was conducted with three objectives. The first objective was to review previous studies on the non-energy utilization potential of rice husks by the method of meta-analysis. This review followed a systematic approach where research papers were collected following a defined set of criteria. The study revealed 16 key utilization pathways, all of which showed promising results. However, a comprehensive sustainability assessment was lacking in all of the pathways. The second …

Assessment Of Integrated Nutrient Management Practices On Soil Health And Nitrogen Efficiency In Cropping Systems, María José Oviedo Ventura

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Groundwater quality in Nebraska is threatened by non-point source contributions of nitrate-nitrogen, primarily by agricultural systems. Intensive crop and livestock production that neglects the value of manure in crop fertility plans can contribute to soil degradation and natural resource impairment. The purpose of this study is to evaluate opportunities to improve agricultural nutrient management throughout Nebraska by quantifying opportunities for manure distribution, evaluating soil health implications of organic and inorganic soil amendments, and assessing nutrient management practices focused on reducing nitrate leaching in agricultural soils.

This study described in Chapter 2 provides a spatial illustration of nitrogen and phosphorus balances …

Hydrothermal Liquefaction (Htl) Of Lignocellulosic Biomass For Biocrude Production: Reaction Kinetics And Corrosion-Resistance Performance Of Candidate Alloys For Reactors, Haoyu Wang

Electronic Thesis and Dissertation Repository

In recent years, the rapid increase in the demand for clean energy and green chemicals as well as concerns over the supply and environmental impacts associated with fossil. resources have stimulated intensive research on conversion of bioresources, such as lignocellulosic biomass and biowaste, into energy, fuels, chemicals, and materials.

Hydrothermal liquefaction (HTL) is a unique thermochemical conversion process, particularly applicable for the conversion of wet biomass and biowaste feedstocks. Most of the biomass HTL studies are conducted in batch reactor and focus on the effects of catalysts, reaction temperature and time on production efficiency and chemical properties of the products. …

Life Cycle Assessment Of Air Classification As A Sulfur Mitigation Technology In Pine Residue Feedstocks, Ashlee Edmonson

Theses and Dissertations--Biosystems and Agricultural Engineering

Sulfur accumulation during biofuel production is pollutive, toxic to conversion catalysts, and causes the premature breakdown of processing equipment. Air classification is an effective preprocessing technology for ash and sulfur removal from biomass feedstocks. A life cycle assessment (LCA) sought to understand the environmental impacts of implementing air classification as a sulfur-mitigation technique for pine residues. Energy demand and material balance for preprocessing were simulated using SimaPro and the Argonne National Laboratory’s GREET model, specifically focusing on comparing the global warming potential (GWP) of grid electricity versus bioelectricity scenarios. Overall, the grid electricity scenario had a GWP impact over 7 …

Fate And Transport Of Nanopesticides In Agricultural Field Plots In Central Kentucky, William D. Rud

Theses and Dissertations--Biosystems and Agricultural Engineering

Due to a growing world population, pesticide applications are necessary part to increasing agricultural production on the same arable land, but this has created environmental contamination, human toxicity, and endangerment to non-target species (i.e, honeybees, monarch butterflies) from bulk pesticide application. Nanoengineered particles or ENP are a potential solution with increased efficiency, longer duration, and enhanced stability of pesticides due to their unique formulations at smaller sizes. However, the potential long-term impact to agroecosystems is still unknown. Therefore, the goal of this project was to evaluate the fate, transport, impact, and persistence of two commercially available nanopesticides (copper hydroxide and …

Food Waste Storage Gaseous Emissions Detection And Quantification Using Infrared Spectroscopy, Ryley A. Burton-Tauzer

Cal Poly Humboldt theses and projects

A growing interest in sustainable waste management and the implementation of new policies have prompted a shift towards alternative resource recovery methods for organic waste, including food waste. To effectively assess alternative food waste treatment scenarios, it is important to evaluate the life cycle impacts associated with each scenario. The storage phase of food waste, encompassing its accumulation in kitchens, and storage in bins for collection and transportation, has been overlooked as a source of greenhouse gases in previous studies. This investigation aimed to identify the greenhouse gases emitted during the initial five-day period of low-oxygen storage. An open dynamic …

Interdisciplinary Design Studio: Programming Document Visioning For A Robotic Demonstration, Research, And Engagement Dairy, Steve(N) Hardy, Nate Bicak, Sarah Alduaylij, Noor Al-Maamari, Devyn Beekman, Kelsey Belgum, Lauren Chubb, Nicholas Forte, Mitchell Hill, Joshua Holstein, Dylan Lambe, Phuong Le, Mia Leriger, Elizabeth Loftus, Josh Lorenzen, Megan Lovci, Alex Martino, Zade Miller, Hannah Morgan, Annabelle Nichols, Collin Shearman, Rebecca Sowl, Nalin Theplikhith, Angela Vu, Shaylee Wagner, Ethan Watermeier, Trever Zelenka

Student Creative Activity, Architecture Program

The 2022 COLLABORATE Design Studio brought together students from various disciplines to address a complex, real-world project which required collaborative input from different perspectives. The studio worked to advance the co-creation of knowledge between external stakeholders, students, and instructors. The course was co-taught by faculty from different disciplines, and areas of expertise. During the semester, Nate Bicak and Steven Hardy worked with students from Architecture and Interior Design in collaboration with students in Dr. Tami Brown-Brandl’s students in Biological Systems Engineering and Animal Science to explore the values, spatial qualities, and area requirements of a Robotic Demonstration, Research, and Engagement …

Sustainable Material For Urea Delivery Based On Chitosan Cross-Linked By Glutaraldehyde Saturated Toluene: Characterization And Determination Of The Release Rate Mathematical Model, Jayanudin Jayanudin, Retno S. D. Lestari, Indar Kustiningsih, Dandi Irawanto, Rozak Rozak, Reyonaldo L. A. Wardana, Fakhri Muhammad

Karbala International Journal of Modern Science

The aims of this study were to characterize the urea-loaded chitosan microspheres and determine the release kinetic constants and diffusion coefficients. An emulsion cross-linking method was used to prepare the urea-loaded chitosan microspheres. Urea was dissolved in a solution of chitosan then put into vegetable oil and stirred to form an emulsion. Glutaraldehyde saturated toluene (GST) was added into the emulsion dropwise while continuously stirring for the solidification process. Chitosan microspheres filled with urea were washed, dried, and then analyzed. Characterization of the urea-loaded chitosan microspheres was conducted using a scanning electron microscope (SEM), Raman spectroscopy, X-ray diffraction, and particle …

Biochar Preparation, Investigation Of Properties And Application As A Low-Cost Adsorbent – A Review, A Kh Aripov, S M. Turabdzhanov, Sh Komilova, O Sh Qodirov, G S. Rakhimova, T V. Darabkova, Zh Aimenova, L S. Rakhimova

Technical science and innovation

An overview of current developments in biochar application in water and wastewater treatment is given in this article, along with a brief explanation of the sorption mechanisms for removing contaminants and the techniques for biochar preparation. In order to encourage the continued use of biochar in effective water and wastewater treatment, future research directions and environmental concerns about biochar are also presented.

Studies On Air Injection In A Wastewater-Fed Subsurface Drip Irrigation System, Henry A. Gonzalez Hernandez

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

In 2020, the Ogallala High Plains Aquifer supplied irrigation water for approximately 3.6 million hectares in Nebraska, making it the most irrigated state in the United States. Although Nebraska is highly dependent in groundwater, locations included in the Gering-Fort Laramie Irrigation District (border of Nebraska and Wyoming) rely on surface water resources. In addition to these conventional water sources, using non-conventional alternatives for crop production can be just as important during water shortage times such as the one that e occurred in 2019 with the collapse of the Goshen/Gering-Fort Laramie Canal. Feedlot runoff presents a great opportunity in Nebraska, but …

Co2 Adsorption Using Mg-Mof-74/Activated Biochar Composites Produced From The Pyrolysis Of Lignocellulosic Biomass, Conner Brosdan Pope

Masters Theses

Adsorption is a promising carbon capture and storage (CCS) technology with porous solids like activated biochar (AB), graphene oxides (GO), and metal-organic frameworks (MOF) exhibiting different advantages related to separating carbon dioxide (CO₂) from gas mixtures. Accordingly, the synthesis of MOF/GO composites demonstrates synergism between CO₂ adsorption-driving physicochemical characteristics of MOFs and GOs. However, the synthesis of MOF/AB composites has not been explored in the literature to date even though AB shares many physical and chemical similarities with GO. This research project aimed to synthesize MOF/AB composites with appropriate physicochemical characteristics and CO₂ adsorption capacities for …

Machine Learning Approach To Simulate Soil Co2 Fluxes Under Cropping Systems, Toby A. Adjuik, Sarah C. Davis

Biosystems and Agricultural Engineering Graduate Research

With the growing number of datasets to describe greenhouse gas (GHG) emissions, there is an opportunity to develop novel predictive models that require neither the expense nor time required to make direct field measurements. This study evaluates the potential for machine learning (ML) approaches to predict soil GHG emissions without the biogeochemical expertise that is required to use many current models for simulating soil GHGs. There are ample data from field measurements now publicly available to test new modeling approaches. The objective of this paper was to develop and evaluate machine learning (ML) models using field data (soil temperature, soil …

A Literature Review Of Wetland Treatment Systems Used To Treat Runoff Mixtures Containing Antibiotics And Pesticides From Urban And Agricultural Landscapes, Emily R. Nottingham, Tiffany L. Messer

Biosystems and Agricultural Engineering Faculty Publications

Wetland treatment systems are used extensively across the world to mitigate surface runoff. While wetland treatment for nitrogen mitigation has been comprehensively reviewed, the implications of common-use pesticides and antibiotics on nitrogen reduction remain relatively unreviewed. Therefore, this review seeks to comprehensively assess the removal of commonly used pesticides and antibiotics and their implications for nitrogen removal in wetland treatment systems receiving non-point source runoff from urban and agricultural landscapes. A total of 181 primary studies were identified spanning 37 countries. Most of the reviewed publications studied pesticides (n = 153) entering wetlands systems, while antibiotics (n = 29) had …

Effects Of The Inclusion Of Rice Hull Derived Bio-Oil On Wood Pellet Production, Tyler E. Lowe

Theses and Dissertations

Wood pellet production has become an advancing industry for the sake of reducing greenhouse emissions into the atmosphere especially, in European Union countries. Researchers and industry executives seek new methods and materials to improve the pelletization process. Rice hulls or husks has the potential to aid in wood pelletization as they possess high calorific values. This study focuses on using rice hull derived bio-oil from pyrolysis, which will also decrease ash content, as an additive to aid in the wood pelletization process. Using two groups of rice hull derived bio-oil as an additive in wood pelletization: Group 1 uses heavy …

Evaluation Of A Novel Approach For Assessing Biological Activity In Agricultural Soils, Karla Melgar

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Soil health is a key factor impacting soil resilience and fertility in crop production systems. Favorable soil physical and biological conditions facilitate plant nutrient absorption and nutrient cycling. Demonstrating to farmers the impacts and changes in soil biological activity under different soil management practices has been a challenge due to the limited availability of inexpensive tools for quantifying this component of soil health. The primary goal of this study was to present a simple and readily accessible tool for evaluating soil biological activity to promote the use of organic amendments in crop fields. Research plots were established in two studies …

Uavs For Vegetation Monitoring: Overview And Recent Scientific Contributions, Ana I. De Castro, Yeyin Shi, Joe Mari Maja, Jose M. Peña

Biological Systems Engineering: Papers and Publications

This paper reviewed a set of twenty-one original and innovative papers included in a special issue on UAVs for vegetation monitoring, which proposed new methods and techniques applied to diverse agricultural and forestry scenarios. Three general categories were considered: (1) sensors and vegetation indices used, (2) technological goals pursued, and (3) agroforestry applications. Some investigations focused on issues related to UAV flight operations, spatial resolution requirements, and computation and data analytics, while others studied the ability of UAVs for characterizing relevant vegetation features (mainly canopy cover and crop height) or for detecting different plant/crop stressors, such as nutrient content/deficiencies, water …

Assessment And Improvement Of Performance Of Septic Systems In Cold Climates (Year 1), Stu Geza, Todd Menkhaus, Lianping Li, Galen Hoogestraat

SDWRI Publications and Reports

Onsite septic systems are used for wastewater treatment for households not connected to sewers. There is a concern about surface and groundwater pollution when effectiveness becomes limited due to soil texture, soil temperature, neighborhood density, and distance to water resources. The goal of this study was to assess treatment performance of local soils and selected treatment media. Lab-scale column experiments were conducted using wastewater from Wastewater Reclamation Facility in Rapid City. The experiments were conducted inside and outside the lab to evaluate the effect of temperature. The columns outside the lab were subject to seasonal variation in temperature. Moisture content, …

Develop Biochar-Based Controlled Release Nitrogen Fertilizers, Zhisheng Cen

Electronic Theses and Dissertations

The current efficiency of conventional nitrogenous fertilizers (e.g. urea, ammonium sulfate, etc.) in agricultural practices is low, fluctuating from 30 to 40%. Approximately 60% of nitrogenous fertilizers were wasted due to vaporization into the air, runoff or leaching into water systems. The lost nitrogen (N) resulted in not only high production cost but also serious environmental problems, such as greenhouse gas (N2O) emission in the atmosphere, algal blooms, oxygen depletion, fish kills, and loss of biodiversity in surface water due to eutrophication or pollution. To address these problems, this study aimed to utilize low-cost biochar-based materials to develop a controllable, …

Biomass-Derived Electrode Materials And Sustainable Processes For Supercapacitors, Katelyn M. Shell

Theses and Dissertations

Biomass is one of the most abundant natural resources and has been used as a source of energy for thousands of years. Biomass as a precursor for energy storage materials is still relatively novel and faces several obstacles before becoming commonly used in today’s electrical devices. Currently, energy storage devices, such as batteries, capacitors, and supercapacitors, utilize petroleum-derived graphitic carbons for anodes, generating a need for more sustainable materials. Biomass, as a carbon-rich source for electrode materials, presents a viable and economically feasible alternative due to the prevalent lignocellulosic compounds: lignin, cellulose, and hemicellulose. Preliminary studies on the solid residues …

Development Of Bio-Based Nanocomposites For Biosensor And Indicator Applications In Smart Food Packaging, Abdus Sobhan

Electronic Theses and Dissertations

Smart food packaging based on biosensors has been attracting more and more interest to the industrial community because of the concerns of food quality and safety. A food packaging with biosensor has a scope to enable real-time monitoring of microbial breakdown products of packaged foods. Furthermore, one of the biggest challenges in implementing biosensor for smart packaging materials is the development of bio-sensing active materials that can leverage their electrical, thermal, biodegradable and other functional properties. In this regard, nanocellulose-based activated carbon (NAC) nanocomposite was developed using the activated carbon and nanocellulose gel using the casting method with their different …

Long Term Evaluation Of E. Coli Removal From Stormwater Using Recycled Steel Byproducts, Brenden Olevson

Electronic Theses and Dissertations

Stormwater runoff often carries a variety of pollutants and pathogens that can endanger public health and wildlife. One contaminant of concern often highlighted in stormwater quality is Escherichia Coli (E.Coli) because its presence indicates microbial contamination in water. Different types of media filtration are being studied to reduce contaminant concentrations in stormwater. In this study, steel byproducts were examined as a potential material to use in media filtration to remove E. Coli and other contaminants from stormwater. Batch scale studies were conducted in laboratory to evaluate the E. Coli removal potential of steel chips and steel slag over a 24-hour …

Waste Hemp Fibers (Hfs) Derived Porous Carbons: Preparation, Characterization, And Potential Applications, Manju Gurung

Electronic Thesis and Dissertation Repository

The main objective of the present research was to develop environmentally friendly and cost-effective porous carbon materials of improved properties from waste hemp fibers. Two different types/categories of porous carbons were prepared from hemp fibers. In one type, porous carbon materials were developed by a simple one-step method of carbonization and activation. The other type of carbon materials developed in this study were nitrogen-containing activated carbons, which were developed by introduction of nitrogen-containing functional groups on the surface of hemp fibers followed by activation and carbonization. The pore structure/distribution and surface chemistry of the prepared carbons were investigated through the …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Ethan Phan, Adrian Damian, Kevin Le, Mary Johnson, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective high-density sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Fate And Transport Of Antibiotics And Antibiotic Resistance Genes In Runoff And Soil As Affected By The Timing Of Swine Manure Slurry Application, Renys Enrique Barrios, Himanshu Khuntia, Shannon L. Bartelt-Hunt, John E. Gilley, Amy M. Schmidt Schmidt, Daniel D. Snow, Xu Li

Department of Civil and Environmental Engineering: Faculty Publications

Land application of swine manure slurry is a common practice to supplement nutrients to soil for crop production. This practice can introduce antibiotic residues and antibiotic resistance genes (ARGs) into the environment. Field testing is critical in identifying manure management practices effective in minimizing the environmental impacts of manure-borne antibiotic and ARGs. The objective of this study was to determine how the timing of swine manure application relative to rainfall events impacts the fate and transport of antibiotics and ARGs in surface runoff and manure-amended soil. Swine manure slurry was either broadcast or injected on test plots in the field. …

A Decade Of Unmanned Aerial Systems In Irrigated Agriculture In The Western U.S., Jose L. Chavez, Alfonso F. Torres-Rua, Wayne E. Woldt, Huihui Zhang, Christopher Robertson, Gary W. Marek, Dong Wang, Derek M. Heeren, Saleh Taghvaeian, Christopher M. U. Neale

Biological Systems Engineering: Papers and Publications

Several research institutes, laboratories, academic programs, and service companies around the United States have been developing programs to utilize small unmanned aerial systems (sUAS) as an instrument to improve the efficiency of in-field water and agronomical management. This article describes a decade of efforts on research and development efforts focused on UAS technologies and methodologies developed for irrigation management, including the evolution of aircraft and sensors in contrast to data from satellites. Federal Aviation Administration (FAA) regulations for UAS operation in agriculture have been synthesized along with proposed modifications to enhance UAS contributions to irrigated agriculture. Although it is feasible …

The Effect Of Edge-Of-Field Nutrient Management Practices On Microbial Concentrations In Subsurface Drainage Water And The Associated Risk Of Antibiotic Resistance Dissemination, Sara Mardani

Electronic Theses and Dissertations

Many in-field and edge-of-field management practices have been used to reduce nutrient loads from agricultural fields. The denitrification woodchip bioreactor (WB) is one edgeof- field management practice that has proven to be effective in removing nitrate from subsurface drainage water. The success in nitrate removal achieved with WBs has raised interest in expanding their capabilities for removing other agricultural pollutants, including phosphorus, by using other types of media like phosphorus-sorbing filters or combining these filters with woodchips to remove both nitrate and phosphorus as dual-nutrient removal systems. Despite the extensive research done on WBs and nutrient filter materials, little consideration …