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Timing And Characterization Of The Change In The Redox State Of Uranium In Precambrian Surface Environments: A Proxy For The Oxidation State Of The Atmosphere, Gerald D. Pollack

Geosciences Dissertations

The redox-sensitive geochemical behavior of uranium permits the use of Th/U ratios as a geochemical proxy for the oxidation state of the atmosphere and oceans during sedimentary processes. Due to the effects of post-depositional uranium mobility on Th/U ratios during events involving oxygenated fluids, direct measurements of Th/U ratios are often misleading, but the whole rock Pb isotope composition may be used to determine a sample¡¦s apparent time-integrated Th/U ratio (ƒÛa) and the timing associated with the onset of the U-Th-Pb geochemistry. Rare earth element (REE) concentrations were determined by isotope dilution mass spectrometry to evaluate the influence of multiple …

Using Geoscience Education Graduate Students To Help Faculty Transform Teaching Practice, Teagan L. Tomlin

Theses and Dissertations

Universities make claims about student learning that graduates don't often achieve and are under pressure to show improvement in teaching and learning in their undergraduate programs. This has been the constant focus of university-level professional development programs, but most teachers are still not using the most effective teaching methods. Individual departments need to find ways to help their instructors overcome three main challenges associated with adopting more effective student-centered teaching methods. No matter what strategy is adopted, instructors need considerable support to 1) change their beliefs about what constitutes effective teaching and learning, 2) learn to effectively implement new strategies, …

Assessing The Tree-Ring Oxygen Isotope Hurricane Proxy Along The Atlantic And Gulf Coastal Seaboards, Usa, Whitney L. Nelson

Doctoral Dissertations

A recent increase in hurricane activity has put coastal populations at risk. To better understand hurricane activity, it is necessary to look beyond the modern instrumental record, using proxy records to establish modes of past variability. The utility of a newly developed tree-ring oxygen isotope proxy is further assessed. I present oxygen isotope time series from three sites: Francis Marion and Sandy Island, South Carolina and Eglin Air Force Base, Florida. Proxy results are verified against the instrumental record of hurricane occurrence. The sites record similar percentages (45% for Francis Marion and Sandy Island, 63% for Eglin Air Force Base) …

Solarization Effects On Chemical Properties Of Soils Under Kudu (Pueraria Montana) Invasion, Nicole Gilbert

All Theses

Solarization is an effective method for managing small areas with kudzu (Pueraria montana) invasions that may alter soil chemical properties. Conducted from 2005 to 2007 at the Clemson University Experimental Forest in Clemson, South Carolina on a Cecil clay loam (fine, kaolinitic, thermic Typic Kanhapludult), this study compares soil chemical properties under thermally-treated and non-treated plots at different depths invaded by Kudzu.
The experimental factors of treatment and depth were arranged in a factorial treatment design with 15 treatments arranged in a split plot design. The five thermal treatments were the whole plot factors which were arranged in a randomized …

Insights Into Biogeophysical Signatures Using Polarization Force Microscopy, Elizabeth Bartosik

All Theses

The success of bioremediation strategies is dependent upon effective monitoring of microorganisms in the subsurface. Induced polarization (IP) may represent a cost-effective, complementary technique to existing borehole-based microbe detection schemes. Recent studies show a significant, yet poorly understood IP effect associated with the presence of bacteria in aqueous and porous media. This effect is believed to be rooted in the physicochemical surface interactions between cells and minerals which we probe using polarization force microscopy. Polarization force experiments were conducted on a hydrated mica surface using the gram positive bacterium Bacillus subtilis and the gram negative bacterium Escherichia coli. On all …

Measurement Of Fine Spatial Scale Ecohydrologic Gradients In A Pinyon-Juniper Ecosystem, Matthew David Madsen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

With the dramatic expansion of pinyon-juniper woodlands over the last century, improved understanding of how these woodlands modify infiltration properties is needed, in order for land managers to make informed decisions on how to best manage their specific resources. However, current methods for measuring soil infiltration are often limited by low sample sizes and high experimental error, due to constraints associated with remote, non agricultural settings. This thesis first presents a scheme for automating and calibrating two commercially available infiltrometers, which allows collection of a large number of precise unsaturated infiltration measurements in a relatively short period of time. Secondly, …

Identification Of Subsoil Compaction Using Electrical Conductivity And Spectral Data Across Varying Soil Moisture Regimes In Utah, Jay Murray Payne

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Subsoil compaction is a major yield limiting factor for most agricultural crops. Tillage is the most efficient method to quickly treat compacted subsoil, but it is also expensive, increases erosion, and accelerates nutrient cycling.

The use of real-time electrical conductivity (EC) and near-infrared (NIR) reflectance values to differentiate compacted areas from uncompacted areas was studied. This method has potential to reduce monetary and time investments inherent in traditional grid sampling and the resultant deep tillage of an entire field. EC and NIR reflectance are both very sensitive to spatial variability of soil attributes.

The objective of this research was to …

Sedimentology, Stratigraphy, And Organic Geochemistry Of The Red Pine Shale, Uinta Mountains, Utah: A Prograding Deltaic System In A Mid-Neoproterozoic Interior Seaway, Caroline Amelia Myer

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Red Pine Shale (RPS; ~1120m thick), uppermost formation of the Neoproterozoic Uinta Mountain Group, Utah, is an organic-rich sedimentary succession interpreted as a marine deltaic system that delivered immature sediment from the north that mixed with mature sediment from the east. Multiple data sets suggest regional climate and sea-level changes associated with changing organic-carbon burial rates.

Six facies were identified and represent wave-, tidal-, and river-influenced parts of the distal prodelta to delta front in a marine system. These include the shale facies and associated concretion facies (distal prodelta), the shale-sandstone facies (proximal prodelta to delta front), the slump …

Optimal Irrigation Management For Sloping, Blocked-End Borders, Jorge Jose Escurra

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

A robust mathematical model of one-dimensional flow for sloping, blocked-end border irrigation was developed using the four-point implicit method to solve the Saint-Venant equations, the volume-balance solution method, and the implementation of new algorithms to avoid numerical instability and solution divergence. The model has the capability of successfully simulating all surface irrigation phases in blocked-end borders for a range of inflow rates (0.01 - 0.05 m³/s per m), longitudinal slopes (up to 1.00%), and border lengths (100 - 500 m).

To achieve numerical stability over the specified parameter ranges, the model was divided into three parts: (1) advance-phase …

Decadal-Scale Changes On Coral Reefs In Quintana Roo, Mexico, Thaddeus Allen Nicholls

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

In 1988 data on coral reef community composition were collected from two areas, Akumal and Chemuyil, Quintana Roo, Mexico, ranging from 5-35m depth. These areas were revisited in 2005 and data were collected by the same methods and at the same depths as in 1988. Data from 1988 and 2005 were compared to determine if the coral reefs had undergone significant changes, and what specific changes had occurred. Chi-square analysis determined that community composition data collected in 1988 are significantly different from data collected in 2005 at all sites and depths within the categories of corals, gorgonians, sponges, and macroalgae. …

Life History Observations And Determination Of Potential Host Fish Species For Chipola Slabshell, Elliptio Chipolaensis, Lisa Preister

Theses and Dissertations

North America is home to nearly 300 species of freshwater mussels with approximately 80% being found in the southeastern United States. The Federally threatened species, Elliptio chipolaensis (Chipola slabshell), is considered an endemic species to the Chipola River Basin in the Florida panhandle. E. chipolaensis glochidia are released from the female in conglutinates The potential fish host species for Elliptio chipolaensis are the bluegill and redbreast sunfish. Sixty percent of the bluegill successfully transformed E. chipolaensis glochidia into juvenile mussels while 80% of the redbreast sunfish were successful.

Tolerance And Accumulation Of Copper, Lead And Zinc By Ceratopteris Richardii, Dorothy Jelagat Cheruiyot

Theses and Dissertations

Environmental contamination has increased rapidly in recent years. There is a need to develop cheap and environmentally friendly remediation methods. Numerous studies have evaluated the ability plants to remove contaminants from the environment. The present study evaluated the ability of Ceratopteris richardii gametophytes and sporophytes to tolerate copper, lead and zinc and for the sporophytes to accumulate the three metals in their shoots. Spores were sown in plant medium treated with varying concentrations of Cu, Pb and Zn. Fifteen-day- old sporophytes were transferred into medium mixed with varying concentrations of the three metals. Ceratopteris richardii tolerated and accumulated each of …

Investigating The Margins Of Pleistocene Lake Deposits With High-Resolution Seismic Reflection In Pilot Valley, Utah, John V. South

Theses and Dissertations

A vast area of the northeastern Great Basin of the western USA was inundated by a succession of Plio-Pleistocene lakes, including Lake Bonneville (28 ka to 12 ka). The Pilot Valley playa, located just east of the Utah-Nevada border near Wendover, Utah, within the eastern Basin and Range Province, represents an 8 to 16 km wide and ~50 km long remnant of these lakes. The playa corresponds to the upper surface of a closed basin that is delimited by two mountain ranges, which are mantled by recent alluvial fans over which the playa sediments have prograded. In order to investigate …

Wolfcampian Development Of The Nose Of The Eastern Shelf Of The Midland Basin, Glasscock, Sterling, And Reagan Counties, Texas, Douglas S. Flamm

Theses and Dissertations

The nose of the Eastern shelf of the Midland Basin is a prominent structural and depositional feature present in Glasscock, Sterling, and Howard counties, Texas. This feature has been expressed in many regional maps and mentioned in some literature, but has not otherwise been studied significantly. This study looks at the viability of using an acoustic impedance seismic inversion to interpret the 2nd and 3rd order sequence stratigraphy of the southern portion of the nose of the Eastern shelf along with its shelf to basin transition in Glasscock, Sterling, and Reagan counties during the Wolfcampian (Asselian-Sakmarian) time (Early Permian). The …

Effect Of A Water Treatment Bmp On Nutrient Spiraling And Leaf Litter Breakdown In An Urban Stream, Megan Leclair Wheeler

Theses and Dissertations

Alterations to stream conditions caused by urbanization can compromise valuable ecosystem services, such as nutrient attenuation and carbon processing. A best management practice (BMP) water facility was installed to restore an impaired urban stream in Columbus, GA. This study was conducted to determine the effect of this BMP on nutrient spiraling and leaf litter decomposition in a 2 km stretch of Weracoba Creek. I hypothesized the BMP would (1) reduce leaf mass loss over time and (2) interfere with nutrient concentrations and uptake lengths. I characterized leaf litter decomposition using tulip tree leaves {Liriodendron tulipifera) in 1mm mesh bags deployed …

Ground-Penetrating Radar And Thermal Modeling Of Active Layer Thaw Beneath Arctic Streams, Troy Richard Brosten

Boise State University Theses and Dissertations

Seasonal thaw depth beneath arctic streams significantly impacts physical and biological processes within arctic stream environments. The impact of greater seasonal thaw for extended periods of time can alter ecosystems that have, in the past, resulted from more prevalent permafrost environments. Effects of climatic change on arctic stream environments necessitate the need for more information on characteristics of seasonal thaw and processes that occur within the thawed layer. Multiple ground-penetrating radar (GPR) methods and one-dimensional (1D) thermal modeling were used to investigate seasonal thaw beneath arctic streams and determine the dominant thermal process.

Study sites were selected to include stream …

Erosion And Trail Building: A Case Study Of The East Tennessee State University Trail System., Joshua Callahan

Electronic Theses and Dissertations

Natural and accelerated erosion from trail users affects the sustainability of trail systems. Designing and building sustainable trail systems will greatly decrease the effect that erosion has on a trail. Trails that allow multiple types of users, such as hiking and mountain biking, must be able to sustain both groups. At East Tennessee State University the trail system was originally designed for hiking. Mountain bikers have become the main user group on the trail system leading to erosion problems on certain areas of the trail due to trail design flaws. The study seeks to identify the problem areas of trail …

A Microanalytical Approach To Understanding The Origin Of Cumulate Xenoliths From Mauna Kea, Hawaii, Megan Pickard

Theses and Dissertations

Cumulate xenoliths erupted with alkalic hawaiite lavas from a postshield cinder cone on Mauna Kea, Hawaii include a variety of mafic and ultramafic rock types. Previous studies of major and trace element compositions of minerals in the xenoliths are interpreted to show transitional to alkalic magma parentages from the postshield stage, although any orthopyroxene-bearing xenoliths are considered to have tholeiitic parents. Major element compositions minerals were analyzed using the electron microprobe and trace element compositions of clinopyroxene grains were analyzed by laser ablation inductively coupled plasma mass spectrometry. In this study, major element compositions of clinopyroxene, olivine and plagioclase grains …

Magmatic Sulfur And Chlorine Abundances At Stromboli, Italy And Their Role In The Formation Of Vesicle-Hosted Metal Alloys, Nichelle Lynn Baxter

Theses and Dissertations

Strand et al. (2002) discovered small metal alloy grains rich in Cu, Co, and Sn (maximum size 150 µm) in vesicles of lava from Kilauea Volcano. These alloys are also found in basaltic rocks of several Italian volcanoes. To better understand the origin of these metal-rich grains, bombs from Stromboli Volcano were examined. Two bomb types were collected from Stromboli: pumiceous bombs and scoriaceous bombs. Bulk rock trace element geochemistry indicates that there are no significant differences in Cu, Co, or Sn (the three major components of the metal alloys) between the pumiceous and scoriaceous bombs. Comparison of olivine melt …

Pre-Eruptive Conditions Of The Oligocene Wah Wah Springs Tuff, Southeastern Great Basin Ignimbrite Province, Kurtus Steven Woolf

Theses and Dissertations

The Wah Wah Springs Tuff (30.0 Ma) is one of several very large volume ash-flow tuffs (>3200 km³ of erupted magma) that were emplaced near the peak of the flare-up of activity in the Great Basin ignimbrite province of western North America. It can be characterized as a "monotonous intermediate" ignimbrite because of its intermediate concentrations of silica (~63 to ~70 wt. %), apparent uniform chemical and mineralogical characteristics, and crystal-rich nature (32 ± 10 % phenocrysts on a dense rock basis). The major phase assemblage found throughout deposit is similar to other monotonous intermediates with a few exceptions …

Generating Genetic Resources For Phytophthora Capsici (L.) And Studying P. Capsici And Phytophthora Hybrids In Peru, Oscar Pietro Hurtado-Gonzales

Doctoral Dissertations

The genus Phytophthora includes more than 90 described species infecting over 1000 plant species. Population studies were conducted to investigate the survival and spread of P. capsici in the Peruvian coastal region. A total of 227 P. capsici isolates, recovered at widely distant localities from 2005-2007, were fingerprinted with AFLPs and SNP genotyping. A clonal population (PcPE-1) represented by 221 isolates was found to be distributed throughout the country. Atypical isolates of P. nicotianae were isolated from loquat trees in Peru and nuclear (internal transcribed spacer [ITS], the phenol acid carboxylase gene, and AFLPs) and mitochondrial genotyping (cytochrome oxidase gene …

The Mayan Ice Cap: Glacial Geology And Paleoclimate Of The Northern Guatemalan Highlands, Alex Joseph Roy

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Sierra de los Cuchumatanes region of the northern Guatemalan highlands supported a large plateau ice cap with an area of -40 km2 along with a group of 5 cirque glaciers -1 to 2 km2 during the local last glacial maximum (LLGM). A comprehensive mapping reconstruction of the northern Guatemalan highlands is presented here, including glacial geology and an estimate of maximum ice limits from physical evidence and computer modeling. The glacial geologic map was produced via field mapping with global positioning system (GPS) surveying combined with aerial stereo photographic and topographic map analysis. This new field work on moraine …

Remote Sensing Studies For The Assessment Of Geohazards: Toxic Algal Blooms In The Lower Great Lakes, And The Land Subsidence In The Nile Delta, Richard H. Becker

Dissertations

Remote sensing techniques provide valuable tools for assessing a wide variety of environmental phenomena. They have been used for monitoring and assessment of various types of geologic and environmental hazards occurring on land, in the air, or in oceans. I present results from two studies, the first of which examines the spatial and temporal distribution of algal blooms in the Great Lakes; the second measures subsidence in the Nile Delta.

In the first study, methodologies to investigate the extent and distribution (temporally and spatially) of algal blooms in Lake Erie and Lake Ontario are studied. Millions of people in the …

Relationship Between Slug-Test And Effective Hydraulic Conductivities For 2-Dimensional Heterogeneous Aquifers, Richard Walker Donat

Masters Theses

Slug tests are one of the most common field tests used by hydrogeologists to evaluate the hydraulic conductivity of an aquifer system. Steady-state and transient (slug test) numerical simulations were run in 37, 2-dimensional randomized multifractal hydraulic conductivity fields. Each field consisted of 59,049 individual saturated hydraulic conductivity (K) values with varying numbers of hydrofacies and different degrees of spatial heterogeneity. The K_eff values were determined by examining the flux in and out of the steady-state numerical model. The K_slug values were determined by adding a slug of water to the center node of the field and evaluating …

Origin Of Tunnel Valley And Esker Assemblages In The Saginaw Lobe, Barry County, Michigan, Caleb J. Woolever

Masters Theses

Surficial mapping, borehole analysis, and ground penetrating radar surveys are used to reconstruct conditions leading to the formation of tunnel valley and esker networks within the Dowling 7 .5 minute quadrangle. The relationship between tunnel valleys and eskers has important implications on the subglacial hydrology beneath the Saginaw Lobe of the Laurentide Ice Sheet.

Surficial mapping reveals northeast-southwest trending tunnel valleys, some containing eskers of the same orientation, in hummocky topography mapped as the Saginaw Kalamazoo Moraine. A borehole hole drilled through one such tunnel valley and esker pair reveals sand and gravel fining upwards to fine sand. Stratigraphy suggests …

Influence Of Bioirrigation On Metal Distribution Within Burrows, Terri Shattuck

Masters Theses

Bioirrigation is the increase of solute transport resulting from introduction of oxygenated water from the surface into the more reduced environment deep within the burrow. Fe and Mn hydr-(oxides) accumulate on burrow margins in response to the oxygen flux into suboxic porewaters. This has been shown to trap trace metals (Harding and Risk, 1986; Tessier and Campbell, 1988; Tessier et al., 1979, 1982). The diagenesis, mobility, and transport of metals contribute to the bioavailability of metals in the environment possibly to the extent of harming ecosystems; especially in coastal areas with buried waste. This study assesses Fe and trace metal …

A Comparison Of Sequential And Integrated Data Fusion For Estimating Hydrologic Properties During A Synthetic Gpr Monitored Infiltration Event, Guy Sicilia Jr

All Theses

Constraining parameters that govern variably saturated flow is important for applications ranging from quantifying water availability for ecosystems to constraining recharge rates and contaminant fluxes to groundwater. In this study I explore the effectiveness of sequential versus integrated data fusion for estimating unsaturated flow parameters using ground penetrating radar (GPR) data. In Sequential Data Fusion (SDF), geophysical imaging is used to create a map of the geophysical properties of the subsurface. These properties are then transformed to hydrologic properties that can be used to constrain an independent hydrologic inverse problem. In contrast, Integrated Data Fusion (IDF) uses the geophysical data …

Kinematics And Timing Of Orogen-Parallel Flow, Grouse Creek Mountains, Utah, Tonia Gail Arriola

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alternating contractional and extensional events in orogenic belts play a significant role in dynamically adjusting crustal thickness during regional contraction. Distinguishing between these two contrasting kinematic regimes is not only important for understanding the tectonic setting but also provides insights into the dynamics of evolving orogenic wedges. The earliest pervasive fabric, D ₁ , in the Grouse Creek Mountains of northwest Utah is interpreted to have played an integral role in accommodating such a dynamic adjustment. It is interpreted that focused crustal thickening led to differences in gravitational potential energy along strike, facilitating an episode of mid-Cretaceous synconvergent orogen-parallel extension. …

Improving Summer Drought Prediction In The Apalachicola-Chattahoochee- Flint River Basin With Empirical Downscaling, John Robert Dean

Geosciences Theses

The Georgia General Assembly, like many states, has enacted pre-defined, comprehensive, drought-mitigation apparatus, but they need rainfall outlooks. Global circulation models (GCMs) provide rainfall outlooks, but they are too spatially course for jurisdictional impact assessment. To wed these efforts, spatially averaged, time-smoothed, daily precipitation observations from the National Weather Service cooperative network are fitted to eight points of 700 mbar atmospheric data from the NCEP/NCAR Reanalysis Project for climate downscaling and drought prediction in the Apalachicola-Chattahoochee-Flint (ACF) river basin. The domain is regionalized with a factor analysis to create specialized models. All models complied well with mathematical assumptions, though the …

Microtextures Of Cyanobacterial Mats In Siliciclastic Sedimentary Environments (Modern & Ancient): Applications To The Search For Life On Mars, Dina M. Bower

OES Theses and Dissertations

The current Mars Exploration Rover Program (MER) is one of NASA's most successful missions. The aim of the MER is to explore for possible life on the surface of Mars. My thesis developed new methods of how to detect and to identify microbial mats in siliciclastic sediments (modern and ancient), and to make recommendations on the applicability of MISS as biosignatures. Predominantly, I employed instrumentation portable by future rovers. To search for life on other planets, we need to have information on how this life might look. Most astrobiological studies therefore focus on Earthly analogues of life and its habitats. …