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An Experimental Study Of Semi-Continuous Ph-Parametric Pumping With A Center Feed, John S. Dell'osso

Theses

Parametric pumping represents a new development in separation science. It has attracted considerable attention both because of its novelty and because it permits continuous operation in small equipment with very high separation factors. The basic principle of parametric pumping is to utilize the coupling of periodic changes in equilibrium conditions caused by periodic changes in some intensive variables (temperature, pH, electric field, etc.), and periodic changes in flow direction to separate the components of fluid which flows past a solid adsorbent. Applications of parametric pumping involving the separation of valuable materials such as proteins would be very attractive and profitable …

The Effects Of Angularity On The Compaction And Shear Strength Of A Cohesionless Material, Richard Edward Swiderski

Theses

Several physical methods are described for the practical measurement and rating of angularity (shape) of cohesionless soil particles. Angularity is determined by utilizing the fundamental property of a sphere: a sphere has the smallest contact surface area of any shape for a given volume. Therefore, any other shape will exhibit a greater contact surface area and consequently will have a greater frictional resistance which is a function of its degree of angularity.

The effects of angularity on the physical behavior (e.g. strength) of cohesionless soils was investigated at various relative compaction densities. For this purpose a combined compaction and direct …

Prediction And Correlation Of The Salt-Effect In Vapor-Liquid Equilibrium, Enrique M. Bekerman

Theses

The feasibility of developing a method of correlation and prediction, for mixtures of two solvents containing a dissolved salt has been studied. The procedure consisted of arriving at the interaction parameters for the three binary systems (solvent 1-solvent 2, solvent 1-salt, solvent 2-salt) and using these to calculate the ternary results. Attempts to generate interaction parameters for the solvent-salt binaries by means of the Wilson equation were unsuccessful, whereas, use of the NRTL equation resulted in a very good fit of the binary data.

In correlating the ternary results, it became necessary to redefine the liquid phase mole fractions and …

Reaction Kinetics For The Synthesis Of Benzyl Benzoate From Benzyl Chloride And The Triethylamine Salt Of Benzoic Acid, Michael A. Kolakowski

Theses

The reaction kinetics for the synthesis of benzyl benzoate from benzyl chloride and the triethylamine salt of benzoic acid has been studied over the temperature range of 70-105°C and a mole ratio of benzyl chloride to triethylamine of 0.5 - 10.0.

A reaction mechanism which is consistent with the experimental data has been derived. The experimental data was analyzed by means of the integral method of analysis. The temperature dependency of the reaction was determined from Arrhenius' Law and the activation energy was calculated to be 15,064 cal/g-mole. An empirical equation which explains the effects of the reactant mole ratio …

Subcontracting By The Petrochemical Engineer-Constructor, Michael Peter Skurla

Theses

An analysis has been made of the methods used by a Petrochemical Engineer-Constructor, who has national labor agreements, in deciding if the construction phase of a project should be done by a subcontract method of construction or be accomplished on a direct hire basis. The petrochemical complex under discussion is considered to be in the $75 million range for the total installed cost including design, engineering, procurement, and construction.

The influence of subcontracting portions of the construction phase by the Engineer-Constructor is reviewed with its impact on: the client; project schedule and cost; local and national labor relations, because of …

The Recovery Of Methanol From The Mother Liquor Of A Pharmaceutical Active Ingredient, Richard Lawrence Eichholtz

Theses

The company has been sending to the sewer the filtrate from one of our chemical processes. This filtrate contains 63 vol. % methanol. The recovery of this methanol would reduce the amount of purchased methanol. The recovery would also reduce the Biological Oxygen Demand of the plant effluent. In the near future the local sewer authority will be billing the company for BOD.

The goal of the recovery process is to obtain methanol of satisfactory quality for reuse in the process from which it came. A literature search and a laboratory study verified the non-ideality of the system. Preliminary calculations …

Non-Standard Workweek Scheduling Technique Selection, John Alexander Oak

Theses

This thesis presents a description of non-standard work scheduling techniques and a comparison method which enables decision-makers to differentiate between available work-scheduling alternatives with the purpose in mind of selecting the most appropriate and suitable arrangement. The method developed calls for the decision-maker to follow a five-step sequential process to obtain final results. The ingredients necessary to achieve such final results are obtained in a manner similar to that demanded by decision-making-under-uncertainty conditions commonly followed in actual industrial settings.

Since the primary objective of business management is the achievement of a profit through the manipulation of available resources, initial sections …

A Study Of The Effect Of An Electric Potential On The Saponification Of Ethyl Acetate, Michael Maciupa

Theses

A reactor of rectangular cross-sectional, area was constructed of plexiglass to study the effect of an electric potential on the saponification of ethyl acetate with sodium hydroxide. Three different laminar region flow rates were used and the applied voltage was varied up to four kilovolts in one kilovolt increments for each flow rate. It was found that the apparent rate constant for the reaction was either increased or decreased depending on the voltage and flow rate used. The largest increase was a 4.2 percent change from zero voltage steady state conditions with an applied voltage of one kilovolt at a …