Investigation Of Pyrolysis And Electrokinetics As Remediation Techniques For The Treatment Of Cca-Treated Wood Waste, Amy Marie Parker

Theses and Dissertations

Increasing volumes of Chromated Copper Arsenate (CCA) treated wood materials are being removed from service, either as a result of reaching the end of their service life or being replaced with non-treated wood materials. These materials, while not regulated as hazardous wastes, have the potential to leach toxic metals into the environment. Incineration and landfilling are not ideal disposal methods as incineration could result in the volatilization of carcinogenic arsenic and chromium, while landfilling requires the waste to be sorted and placed in appropriately lined landfills to prevent contaminant release. Viable disposal methods must be considered to manage the significant …

Managing Exoelectrogenic Microbial Community Development Through Bioprocess Control For Conversion Of Biomass-Derived Streams, Alex James Lewis

Doctoral Dissertations

Bioelectrochemical systems are an emerging technology capable of utilizing aqueous waste streams generated during biomass conversion of lignocellulosic feedstocks to produce valuable co-products and thus, have potential to be integrated into biorefineries. In a microbial electrolysis cell, organic compounds are converted to electrons, protons, and CO₂ by fermentative and exoelectrogenic bacteria in the anode compartment. By having the ability to extract electrons from waste streams, these systems can treat water while also producing hydrogen, and thus can improve the efficiency of biomass to fuel production by minimizing external hydrogen requirement and enabling water recycle. The overall goal of this …

Pine Needle Pyrolysis: Bio-Waste Into Biofuel, Alexandra Fuentes

Honors Theses

This project explores the alternate uses of biomass. In particular it focuses on pine needles as a source for biofuels. Pine needles are of interest because in certain Mountain communities they are collected and removed from residential properties. By removing the pine needles, communities create a “defensible space” to prevent wild fires from destroying homes and property. These needles are often placed in regional landfills. The South Tahoe Refuse and Recycling Services alone has more than 4,340 tons of pine needles dumped at their facility annually. This large amount of biomass can be a potential energy source.

The focus of …

Lignin Transformation And Characterization Of Pyrolytic Products, Eric Amo Boakye

Electronic Theses and Dissertations

Lignocellulosic materials derived from plants have the ability to serve as feedstocks in place of depleting petroleum and coal for production of fuels and chemicals. Lignin forms about 30% of lignocellulosic material, and is the second most abundant non-fossil organic carbon source in the biosphere. However, it is often treated as waste or, in some instances, burned to supply energy. Developing an efficient and environmentally benign method to convert lignin to high value-added aromatic monomers (e.g., guaiacol, vanillin, acetovanillone, and eugenol) for synthesis of polymers is of interest. Mineral bases, such as NaOH and CsOH, or supported-metal catalysts (Pt, Ru, …

Assessing The Use Of Food Waste Biochar As A Biodynamic Plant Fertilizer, Rachel Mazac

Departmental Honors Projects

Biochar is a charcoal-like substance produced from plant material such as food waste. Converting food waste into a useful product would mitigate environmental damage through reduced landfill inputs, reduced greenhouse gas production, and increased benefits to soils. I asked (1) if biochar improved plant growth and (2) if the effects of biochar varied among different samples of mixed food waste (batches) and between different biochar preparation times (treatments). Four independent batches of biochar were prepared with assorted, uncooked food waste collected from a university dining facility. Each batch was dried then placed in a covered ceramic pot at 260℃ for …

Emerging Investigators Series: Pyrolysis Removes Common Microconstituents Triclocarban, Triclosan, And Nonylphenol From Biosolids, J. J. Ross, Daniel Zitomer, T. R. Miller, C. A. Weirich, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Reusing biosolids is vital for the sustainability of wastewater management. Pyrolysis is an anoxic thermal degradation process that can be used to convert biosolids into energy rich py-gas and py-oil, and a beneficial soil amendment, biochar. Batch biosolids pyrolysis (60 minutes) revealed that triclocarban and triclosan were removed (to below quantification limit) at 200 °C and 300 °C, respectively. Substantial removal (>90%) of nonylphenol was achieved at 300 °C as well, but 600 °C was required to remove nonylphenol to below the quantification limit. At 500 °C, the pyrolysis reaction time to remove >90% of microconstituents was less than …

Biomass Catalytic Upconversion With A Metallic Catalyst Bed Under Radio Frequency Induction Heating, Mohammad Abu-Laban

LSU Master's Theses

This study investigated the thermal performances of platinum particles when coupled on a steel support, under the application of a radio frequency (RF) field. Platinum nanoparticles were reduced on the surfaces of type-316 stainless steel balls, based on published methods of Pt reduction from chloroplatinic acid. Alternatively, 1wt. % Pt/Al2O3 commercial catalyst pellets were mixed with stainless steel balls and investigated for hydro-deoxygenation of pyrolysis oil from pine sawdust biomass. The catalysts were placed inside an electric insulator tube suspended within a looping copper coil connected to the induction heater, and heated at different power levels. An infrared camera was …

Targeted Products From Fast-Hydropyrolysis And Hydrodeoxygenation Of Biomass, Ian Tad Smith

Open Access Theses

Previously, the H2Bioil process was proposed as a possible way to convert sustainably available intact biomass into liquid fuels. The optimization of this process and possible synergies with other biomass conversion processes are presented in this thesis.

The selectivity of the PtMo hydrodeoxygenation catalyst was tuned using two different hydrogen partial pressures: 25 bar, and 2.5 bar. This effect was studied on cellulose and intact biomass samples to determine the effect that hydrogen has upon the retention of aromatic compounds found in intact biomass. These experiments show that it is possible for the hydrogenation activity of the PtMo catalyst to …

Biochar From Pyrolysis Of Biosolids For Nutrient Adsorption And Turfgrass Cultivation, Daniel Elliott Carey, Patrick J. Mcnamara, Daniel Zitomer

Civil and Environmental Engineering Faculty Research and Publications

At water resource recovery facilities, nutrient removal is often required and energy recovery is an ever-increasing goal. Pyrolysis may be a sustainable process for handling wastewater biosolids because energy can be recovered in the py-gas and py-oil. Additionally, the biochar produced has value as a soil conditioner. The objective of this work was to determine if biochar could be used to adsorb ammonia from biosolids filtrate and subsequently be applied as a soil conditioner to improve grass growth. The maximum carrying capacity of base modified biochar for NH₃−N was 5.3 mg/g. Biochar containing adsorbed ammonium and potassium was …

Pyrolysis Based Biorefineries For The Production Of Fermentable Substrates, Luis Carlos Luque-Moreno

Electronic Thesis and Dissertation Repository

Fast pyrolysis is rapid thermal conversion process capable of transforming multiple feedstocks into various energy carriers, specifically pyrolysis oil, bio gas, and bio char. The oil phase is of high value due to its complex mixtures of organic molecules, along with large number of anhydrous carbohydrates, which can be easily transformed into glucose via acid hydrolysis. These carbohydrates can be either biocatalyzed into fuels and chemicals by microorganisms or converted after further treatment steps. However quantities of these carbohydrates in the oil are a function of feedstock composition and process parameters. The research presented in this thesis focuses on producing …

Rice Husk Derived Engineered Biochar For Glyphosate Removal In Aqueous Media, Indika Herath Mr

21st International Conference on Environmental Indicators (ICEI 2015)

No abstract provided.

Engineering Plant Biomass Lignin Content And Composition For Biofuels And Bioproducts, Cassie Marie Welker, Vimal Kumar Balasubramanian, Carloalberto Petti, Krishan Mohan Rai, Seth Debolt, Venugopal Mendu

Horticulture Faculty Publications

Lignin is an aromatic biopolymer involved in providing structural support to plant cell walls. Compared to the other cell wall polymers, i.e., cellulose and hemicelluloses, lignin has been considered a hindrance in cellulosic bioethanol production due to the complexity involved in its separation from other polymers of various biomass feedstocks. Nevertheless, lignin is a potential source of valuable aromatic chemical compounds and upgradable building blocks. Though the biosynthetic pathway of lignin has been elucidated in great detail, the random nature of the polymerization (free radical coupling) process poses challenges for its depolymerization into valuable bioproducts. The absence of specific …

Production Of Activated Carbons From Pyrolytic Char For Environmental Applications, Anastasia Colomba

Electronic Thesis and Dissertation Repository

Biomass pyrolysis has the potential to become a major component of future biorefineries, since biomass is cracked to produce gases, liquid products (bio-oil) and solid products (bio-char). In order for the process to be economically feasible, it is necessary to obtain the maximum value from each stream, thus no by-product can be regarded as a waste.

Bio-char is normally regarded as a by-product of fast pyrolysis, which is optimized to target bio-oil production. However, there are many potentially attractive applications for it: for example, it can be used for the production of activated carbons, which are the most commonly used …

Pyrolysis For Estrogens Removal From Wastewater Solids, Thomas C. Hoffman

Master's Theses (2009 -)

Wastewater treatment processes are not designed to remove estrogenic micropollutants and therefore when wastewater biosolids are land applied estrogenic micropollutants are discharged to the environment. Release of estrogenic compounds has deleterious effects on the terrestrial environment. Public concern stemming from micropollutants may reduce the value of biosolids which are important to water resource reclamation facilities (WRRF) as by-products. The objective of this research was to evaluate pyrolysis, the partial decomposition of organic material in an oxygen-deprived system under high temperatures, as a sustainable solution to remove estrogenic compounds from biosolids while producing a useable soil conditioner called biochar. Batch pyrolysis …

Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith

Theses and Dissertations--Biosystems and Agricultural Engineering

Biochars have been created and characterized from a variety livestock manure biomass including poultry, dairy, and swine. However, no research has been conducted on the physical and chemical makeup of biochar pyrolyzed from horse muck. Two horse muck derived biochars containing either straw (HS) or woodchip (HW) bedding were pyrolyzed at 700°C and characterized for their physical and chemical properties. Tests revealed both biochars had high alkalinity, moderate specific conductivity, and low surface area as compared to other biochars in the literature. HS contained more mineral structures than HW. Scanning electron microscopy presented differences in particle shape, size, and presence …

Fate Of Micropollutants During Pyrolysis Of Biosolids, John Ross

Master's Theses (2009 -)

Approximately 250 tons of organic micropollutants, including pharmaceuticals, antimicrobials, and hormones, are discharged to the environment during land application of wastewater biosolids annually. Reusing wastewater biosolids is vital to the sustainability of wastewater treatment, but current treatment processes do not remove micropollutants from biosolids in an efficient manner. Pyrolysis―the heating of biomass to temperatures between 400 and 800 °C under oxygen-free conditions―was proposed as a biosolids treatment process that could produce a beneficial soil amendment product, biochar, and remove micropollutants. The objective of this research was to determine the effect of pyrolysis temperature and residence time on the removal of …

Conventional And Catalytic Pyrolysis Of Pinyon Juniper Biomass, Bhuvanesh Kumar Yathavan

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Pinyon and juniper are invasive woody species which has occupied more than 47 million acres of land in Western United States. Pinyon juniper woodlands domination decreases the herbaceous vegetation, increase bare lands which in turn increases soil erosion and nutrition loss. Thus, The US Bureau of Land Management (BLM) has focused on harvesting these woody species to make room for herbaceous vegetation. The major application of harvested pinyon-juniper (PJ) is low value firewood. Thus, there is a need to develop new high value products from this woody biomass to reduce the cost of harvesting. In this study pyrolysis was carried …

Development And Applications Of A Novel Intermittent Solids Feeder For Pyrolysis Reactors, Federico M. Berruti

Electronic Thesis and Dissertation Repository

This PhD research addresses the challenge of feeding biomass residues into fluidized bed reactors for pyrolysis, through the development of a novel intermittent solid slug feeder, both for laboratory-scale and large-scale reactors. The new feeder can successfully handle biomass residues that are either too cohesive or thermally sensitive for traditional feeders.

To optimize the novel feeder performance, a model for the pulsating solids flow was developed from experimental data collected with ideal slugs, as well as real biomass flow. The model was validated using both a laboratory-scale (< 10 kg/hr) and large-scale feeder (> 250 kg/hr). Several important variables were identified. They include the material flow …

Continuous Segregation And Removal Of Biochar From Bubbling Fluidized Bed, Mary O. Adegboye

Electronic Thesis and Dissertation Repository

Abstract

Biochar is a valuable co-product with increasing agronomic and environmental values produced during pyrolysis, which is a thermochemical conversion process of biomass in the absence of oxygen. Accumulation of biochar in the bed may result in poor fluidization performance and product quality. The efficient removal of the separated biochar from the fluidized bed is therefore crucial for economical reasons.

This thesis is structured in three sections. Section 1, provides an introduction and literature review on biomass pyrolysis covering the main types of processes and reactors focusing on fluidized bed technologies. It section addresses the mechanisms associated with mixing and …

A Comparison Of Producer Gas, Biochar, And Activated Carbon From Two Distributed Scale Thermochemical Conversion Systems Used To Process Forest Biomass, Nathaniel Anderson, J. Greg Jones, Deborah Page-Dumroese, Daniel Mccollum, Stephen Baker, Daniel Loeffler, Woodam Chung

Forest Management Faculty Publications

Thermochemical biomass conversion systems have the potential to produce heat, power, fuels and other products from forest biomass at distributed scales that meet the needs of some forest industry facilities. However, many of these systems have not been deployed in this sector and the products they produce from forest biomass have not been adequately described or characterized with regards to chemical properties, possible uses, and markets. This paper characterizes the producer gas, biochar, and activated carbon of a 700 kg h⁻¹ prototype gasification system and a 225 kg h⁻¹ pyrolysis system used to process coniferous sawmill and forest …

Production Of Bio-Coal And Activated Carbon From Biomass, Diana C. Cruz

Electronic Thesis and Dissertation Repository

The slow pyrolysis of different biomasses (maple wood, birch bark, switch grass, coffee pulp and corn stalk) was studied with the aim to produce a solid pyrolysis product (bio-coal) with promising properties and potential for use in traditional fossil-coal applications. Batch pyrolysis experiments were conducted in a Mechanically Fluidized Reactor (MFR) at temperatures ranging from 143 to 665 ^oC, which includes the torrefaction temperature range (200-300 ^oC). The effects of temperature and holding time on bio-coal mass yields were determined. The bio-coals were characterized in detail and a highly-controlled study on bio-coal hygroscopicity is presented. Optimal conditions for …

The Effects Of Biochar Amendment To Soil On Bioenergy Crop Yield And Biomass Composition, Charles Warren Edmunds

Masters Theses

This thesis research aims to improve the understanding of how pyrolysis of native feedstocks and biochar application to soil can be utilized to improve soil fertility, crop yield, and sequester carbon in the Southeastern U.S. An emphasis was placed on understanding how the pyrolysis conditions and feedstock material influence biochar characteristics and what effects biochar amendment has on soil and plant growth and composition.

Biochars were produced from switchgrass and pine wood feedstocks via fast pyrolysis at 450, 600, and 800 ˚C with a continuous auger pyrolysis system. Switchgrass-derived biochars had higher ash content, and as observed by elemental analysis, …

An Investigation Of Biochar Removal Systems For Pyrolysis Reactors, Craig Charles Wilson Mara

Digitized Theses

Fluidized bed biomass pyrolysis is a process that is becoming popular for the conversion of agricultural, municipal and forestry residues into liquid bio-oils, solid biochar and gaseous products. Bio-oil vapors leave the reactor vessel with the produced gases. Also produced however, is a low density biochar particles which accumulate in the bed. Though some fine biochar particles can be elutriated, a significant amount remains in the bed. Accumulation of biochar leads to poor process stability and defluidization of the bed. Moreover, biochar may have negative effects on the pyrolysis reactions. In the current implementation of a mobile pyrolysis unit, the …

Investigating Potential Pathways To Optimize The Effectiveness Of The Pyrolysis Process, Matthew John Klaas

Digitized Theses

Biomass pyrolysis is a method of green fuel production, but the process is still unrefined and has a need for further optimization and process exploration. Since the process has many variables, it is important to try and identify and optimize variables which have a large impact on the process and the products.

The first portion of investigation was the steam reforming of the pyrolytic chars from different biomasses to produce a hydrogen-rich gas. Since there is a need to remove the char from the bed (fluidization disruption, reduction in bio-oil yields) and there is currently no continuous char removal system …

A Comparative Financial Analysis Of Fast Pyrolysis Plants In Southwest Oregon, Colin Brink Sorenson

Graduate Student Theses, Dissertations, & Professional Papers

There are millions of acres of forestland in the Western United States that could benefit from fuel reduction treatments to improve forest health and reduce wildfire fuels. These treatments generate forest residues that are typically piled and burned. However, with increasing concerns about energy security, high oil prices, air quality from pile burning and climate change, there is great interest in examining ways to economically use these residues as a renewable energy source. Pyrolysis of forest biomass is one method that shows promise, though the financial feasibility of doing so has not been previously investigated. This study presents the expected …

Biochar: A Carbon Negative Model For Umass Amherst, Susanne E. Hale

Conference on Cellulosic Biofuels

Biochar is a charcoal by-product of pyrolysis production of biofuels from biomass, which offers the potential for long-term, affordable carbon sequestration. Biochar in Amazonian soils have been found to be stable in the soil for hundreds to thousands of years. New pyrolysis technologies currently being developed may have the potential to be used in the future with the new UMass co-generation Central Heating Plant to produce syngas for powering plant turbines, while at the same time producing biochar for carbon sequestration, yielding a carbon negative system. Other benefits of biochar include increased soil fertility and crop yield, stimulation of the …