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Carbon Dioxide Gasification Of Biochar: A Study On Utilizing Captured Co2 To Mitigate Greenhouse Gas Emission And Improving Carbon Conversion Efficiency, Nnamdi Ofuani

Electronic Theses and Dissertations

With rapidly growing global economies and world population, fossil fuel continues to play a major role in meeting current energy demands. Carbon capture and storage (CCS) technologies have, hence, been implemented to reduce CO₂ emissions in the atmosphere. With the implementation of CCS technologies comes the need to utilize the captured CO₂. This research, therefore, proposes CO₂ gasification of biochar as a viable carbon utilization pathway. With captured CO₂ coming at various concentrations, there is a need to understand how CO₂ concentration affects biochar conversion to useful products. This study, therefore, evaluates the effects …

Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia

Department of Civil and Environmental Engineering: Faculty Publications

This work innovatively explores the bio-methanol production process, conducts comprehensive analyses, develops statistical models, and optimizes operational conditions, contributing valuable insights to the field of sustainable energy production from biomass. Accordingly, bio-methanol production from biomass through gasification route was investigated and simulated using Aspen Plus software. The effects of operational parameters on energy duty of gasification reactor and the methanol production rate in syngas to methanol reactor were investigated. The parameters affecting the process performance including temperature, pressure, and steam/feed ratio were examined using the response surface methodology (RSM) by central composite design (CCD) technique. Analysis of variance (ANOVA) was …

Multi-Factor Optimization Of Bio-Methanol Production Through Gasification Process Via Statistical Methodology Coupled With Genetic Algorithm, Amin Hedayati Moghaddam, Morteza Esfandyari, Dariush Jafari, Hossein Sakhaeinia

Department of Civil and Environmental Engineering: Faculty Publications

This work innovatively explores the bio-methanol production process, conducts comprehensive analyses, develops statistical models, and optimizes operational conditions, contributing valuable insights to the field of sustainable energy production from biomass. Accordingly, bio-methanol production from biomass through gasification route was investigated and simulated using Aspen Plus software. The effects of operational parameters on energy duty of gasification reactor and the methanol production rate in syngas to methanol reactor were investigated. The parameters affecting the process performance including temperature, pressure, and steam/feed ratio were examined using the response surface methodology (RSM) by central composite design (CCD) technique. Analysis of variance (ANOVA) was …

Gasification Of Waste Wood Fractions In A Staged Process – Characterization Of Resulting Bio-Char, Michael Kresta, David Gurtner

Bio-Char III: Production, Characterization and Applications

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Bio-Char Post-Processing – Thermochemical Activation Of Gasification Carbon, David Gurtner, Michael Kresta, Angela Hofmann, Center Innsbruck, Christoph Pfeifer

Bio-Char III: Production, Characterization and Applications

Please click Additional Files below to see the full abstract

Steam Gasification Of Biochar To Produce Hydrogen-Rich Syngas, Nnamdi Ofuani

Honors College Theses

A key greenhouse gas (GHG) emission contributing to climate change is carbon dioxide (CO₂) emission. This emission is largely due to the use of fossil fuel as a major energy source. Biomass is an alternative energy source. Biochar, a byproduct of the pyrolysis process (of biomass), could be gasified to produce syngas (a mixture of CO and H₂). This syngas can further be used to produce different kinds of fuels like biodiesel, bio-gasoline, bioethanol, etc. In the steam gasification of biochar, the quality and yield of syngas is dependent on parameters such as temperature, particle size, …

Artificial Neural Networks And Gradient Boosted Machines Used For Regression To Evaluate Gasification Processes: A Review, Owen Sedej, Eric Mbonimpa, Trevor Sleight, Jeremy M. Slagley

Faculty Publications

Waste-to-Energy technologies have the potential to dramatically improve both the natural and human environment. One type of waste-to-energy technology that has been successful is gasification. There are numerous types of gasification processes and in order to drive understanding and the optimization of these systems, traditional approaches like computational fluid dynamics software have been utilized to model these systems. The modern advent of machine learning models has allowed for accurate and computationally efficient predictions for gasification systems that are informed by numerous experimental and numerical solutions. Two types of machine learning models that have been widely used to solve for quantitative …

Enhancement Of Energy Efficiency For Thermal Energy And Biomass Driven Applications, Osama Mansour Selim Elsayed

Theses and Dissertations

The importance of gas turbine blades is to convert the thermal energy into shaft work output, which makes the turbine blades are one of the critical components of the gas turbines. Besides the mechanical stresses caused by the centrifugal force and the fluid forces, the thermal stresses arise because of the temperature gradient within the blade materials. This paper aims to have a uniform circumferential temperature field at the combustor exit, consequently reducing the thermal stresses caused by the non-uniform temperature distribution along the turbine blade. The validation of the simulation results with the experiments showed an acceptable agreement with …

Hydrogen-Rich Syngas Derived From Smouldering Biomass And Hydrocarbon Wastes, Joshua K. Brown

Electronic Thesis and Dissertation Repository

In the face of climate change, the world is looking to new fuel sources to meet the surging global energy demand. Hydrogen has been proposed as a promising energy vector being both a net-zero carbon emitter and having one of the highest gravimetric energy densities of known fuels. Production of hydrogen, however, is difficult with many of the technologies which exist today failing to be economically feasible or environmentally sustainable. Smouldering has recently been developed as a cost effective and energy efficient technology for destruction of organic wastes. The unique reaction zones created within a smouldering system have the potential …

Bubble Dynamics In A Sand Fluidized Bed In The Presence Of Biomass Pellets, Nicolas Torres Brauer

Electronic Thesis and Dissertation Repository

Given the worldwide concerns regarding fossil fuel availability, global warming, water, and air pollution and economy needs, there is an urgent requirement to develop and implement alternative energies. Biomass gasification can consume vegetal waste to produce syngas, which is a mix of carbon monoxide, hydrogen, and carbon dioxide. When biomass gasification is carried out in a fluidized bed, the process is highly efficient.

The experimental study of the present Ph.D. dissertation took place in a Plexiglas 0.44 m diameter unit, equipped with a CREC Optiprobe system and a video camera. The unit was filled with 200-900 µm sand particles and …

The State Of Technologies And Research For Energy Recovery From Municipal Wastewater Sludge And Biosolids, Zhongzhe Liu, Brooke Mayer, Kaushik Venkiteshwaran, Saba Seyedi, Arun S.K. Raju, Daniel Zitomer, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Wastewater resource recovery facilities produce wastewater solids that offer potential for energy recovery. This opinion article provides a perspective on state-of-the-art technologies to recover energy from sludge (unstabilized wastewater residual solids) and biosolids (stabilized wastewater solids meeting criteria for application on land). The production of biodiesel fuel is an emerging technology for energy recovery from sludge, whereas advancements in pretreatment technologies have improved energy recovery from anaerobic digestion of sludge. Incineration is an established technology to recover energy from sludge or biosolids. Gasification, and to a greater extent, pyrolysis are emerging technologies well-suited for energy recovery from biosolids. While gasification …

Variables Governing The Initial Stages Of The Synergisms Of Ultrasonic Treatment Of Biochar In Water Saturated With Carbon Dioxide, Adedapo Reuben Adeniyi

Electronic Theses and Dissertations

This work investigates the initial stage of the synergistic processes of acoustic treatment of biochar in water saturated with CO2 (AIChE Journal, 2014;60:1054-1065). Treatments with switchgrass and miscanthus biochars have been conducted to examine the effects of acoustic intensity, biochar/H2O ratio, CO2 concentrations of the solution, and that in the headspace above the solution. The changes in biochars’ heating values, carbon and hydrogen contents, internal surface area, and pore size distribution have significant technological implications and are the focal points of this study. The miscanthus and switchgrass biochars were produced via pyrolysis process at 700 oC and 550 oC, respectively. …

Thermal Evolution Of Biochar And Its Physicochemical Properties During Hydrothermal Gasification, Sonil Nanda, Ajay K. Dalai, Franco Berruti, Janusz A. Kozinski

Biochar: Production, Characterization and Applications

Biochar is a recalcitrant carbonaceous material obtained from pyrolysis and gasification of biomass and other biogenic wastes. Some of the promising biochar applications to be discussed in this presentation includes char gasification and combustion for energy production, soil remediation, carbon sequestration, catalysis, and development of activated carbon and specialty materials with biomedical and industrial uses. Several factors such as pyrolysis/gasification temperature, heating rates and residence time are the limiting factors that determine the biochar properties such as fixed carbon, volatile matter, mineral matter, surface area, porosity and pore size distribution, alkalinity, electrical conductivity, cation-exchange capacity, etc. This paper will comprehensively …

Catalytic Property Of Olivine For Bio-Oil Gasification, Mohammad Latifi, Franco Berruti, Cedric Briens

5th International Congress on Green Process Engineering (GPE 2016)

Introduction

Biomass is an attractive renewable source of fuel and energy. Thermochemical processes can convert biomass to a liquid bio-oil or to a syngas. The advantage of using bio-oil as an intermediate is that, in contrast with both raw biomass and gas, it can easily be produced in small distributed units, stored and transported. Not only can platform chemicals and clean fuels be produced from syngas, but hydrogen is itself an alternative fuel. A high hydrogen production is usually desired: for example, methanol production requires a syngas with a molar H₂/CO ratio of 2. Therefore, maximum hydrogen production …

Carbon Abatement And Emissions Associated With The Gasification Of Walnut Shells For Bioenergy And Biochar Production, Engil Isadora Pujol Pereira, Emma C. Suddick, Johan Six

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

By converting biomass residue to biochar, we could generate power cleanly and sequester carbon resulting in overall greenhouse gas emissions (GHG) savings when compared to typical fossil fuel usage and waste disposal. We estimated the carbon dioxide (CO2) abatements and emissions associated to the concurrent production of bioenergy and biochar through biomass gasification in an organic walnut farm and processing facility in California, USA. We accounted for (i) avoided-CO2 emissions from displaced grid electricity by bioenergy; (ii) CO2 emissions from farm machinery used for soil amendment of biochar; (iii) CO2 sequestered in the soil through stable biochar-C; and (iv) direct …

Efecto De Biocarbono Y Fertilizantes Orgánicos En El Desarrollo De Plantas De Morera (Morus Sp) En Fase De Vivero Bajo Condiciones De Suelos Ácidos, Sofía Imelda Mora Lamilla

Maestría en Agrociencias

En suelos ácidos de los Llanos Orientales de Colombia se evaluó el efecto del Biocarbono producido con una estufa de micro-gasificación de corriente ascendente y de fertilizantes orgánicos sobre el comportamiento de morera (Morus sp) en la fase de vivero. El estudio se realizó en dos experimentos: Experimento 1. Se hizo un bioensayo con plantas de maíz como planta indicadora cuyo objetivo fue definir los niveles de biocarbono que permiten la mejor respuesta. El estudio se llevó a cabo bajo un diseño Completamente al Azar con arreglo Factorial 4X5, con cuatro tratamientos (sin fertilización –SF-, con lombricompuesto –LC-, con urea …

Transformation Of Swine Manure And Algal Consortia To Value-Added Products, Mahmoud A. Sharara

Graduate Theses and Dissertations

The swine production sector is projected to grow globally. In the past, this growth manifested itself in increased herd sizes and geographically concentrated production. Although economically sound, these trends had negative consequences on surrounding ecosystems. Over-application of manure resulted in water quality degradation, while long-term storage of manure slurries was found to promote release of potent GHG emissions. There is a need for innovative approaches for swine manure management that are compatible with current scales of production, and increasingly strict environmental regulations.

This study aims to investigate the potential for incorporating gasification as part of a novel swine manure management …

A Comparison Of Producer Gas, Biochar, And Activated Carbon From Two Distributed Scale Thermochemical Conversion Systems Used To Process Forest Biomass, Nathaniel Anderson, J. Greg Jones, Deborah Page-Dumroese, Daniel Mccollum, Stephen Baker, Daniel Loeffler, Woodam Chung

Forest Management Faculty Publications

Thermochemical biomass conversion systems have the potential to produce heat, power, fuels and other products from forest biomass at distributed scales that meet the needs of some forest industry facilities. However, many of these systems have not been deployed in this sector and the products they produce from forest biomass have not been adequately described or characterized with regards to chemical properties, possible uses, and markets. This paper characterizes the producer gas, biochar, and activated carbon of a 700 kg h⁻¹ prototype gasification system and a 225 kg h⁻¹ pyrolysis system used to process coniferous sawmill and forest …