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Biochar Applications To The Remediation Of Lead And Polychlorinated Biphenyl Contaminated Water, Victory Itua Igberase

Theses and Dissertations

This study investigated the performance of biochar materials as adsorbents to remove Pb and polychlorinated biphenyl (PCB) in aqueous solutions. Batch adsorption and column experiment packed with biochar and geomaterials (pumice) in 1:1 volume ratio was evaluated to address the efficacy of biochar in removing Pb while only batch adsorption was employed for PCB removal with biochar materials. Overall, PT biochars performed the best (42–53 mg g−1) followed by BE biochars (10–32 mg g−1) and AB biochars (17–27 mg g−1) while high temperature biochars were favored in terms of maximum Pb adsorption capacity. Column Pb breakthrough showed similar results, with …

Wastewater Remediation Technologies Using Macroscopic Graphene-Based Materials: A Perspective, Rajan Arjan Kalyan Hirani, Abdul Hannan Asif, Nasir Rafique, Lei Shi, Shu Zhang, Hong Wu, Hongqi Sun

Research outputs 2014 to 2021

Three-dimensional (3D) graphene-based macrostructures are being developed to combat the issues associated with two-dimensional (2D) graphene materials in practical applications. The 3D macrostructures (3DMs), for example, membranes, fibres, sponges, beads, and mats, can be formed by the self-assembly of 2D graphene-based precursors with exceptional surface area and unique chemistry. With rational design, the 3D macrostructures can then possess outstanding properties and exclusive structures. Thanks to various advantages, these macrostructures are competing in a variety of applications with promising performances unlike the traditional activated carbons, biochars and hydrochars, which have less flexibilities for modifications towards versatile applications. However, despite having such …

Systematic Mapping On Adsorption Studies Using Spent Coffee Grounds, Therese Jan E. Mangussad, Frence Laurice Ghayle A. Nuñez, Jean E. Topacio

DLSU Senior High School Research Congress

The increase in demand of coffee in the Philippines, led to the increase of production of spent coffee grounds (SCG) waste; utilization of this material is crucial as SCG pose environmental hazards. To evaluate the adsorbent capability of SCG, this study utilized systematic mapping. Research questions that were defined are as follows: 1) What is the research trend on adsorption studies using SCG? 2) What are the processes utilized to produce adsorbent from SCG? 3) What are the different contaminants adsorbed using SCG? 4) What are the important characterizations and performance of SCG adsorbents? It was determined that SCG undergoes …

Low-Cost Adsorbents For Water Purification, Hasara Dilum Samaraweera

Theses and Dissertations

Heavy metals, oxyanions (NO3-, PO4-), pharmaceuticals, and dyes in aquatic environments are inevitable economic and health concerns. Ingestion of these contaminants, even in trace amounts, causes long and short-term serious threats to human health. Conventional pollutant mitigation strategies can be costly or ineffective. Due to high efficiency, simplicity, low price, adsorbent reuse, and pollutant (e.g., phosphates) recovery, adsorption has been widely used for wastewater purification. Many efficient, environmentally compatible, and cost-effective sorbents have been successfully applied in environmental remediation. Chapter I is about characterization of graphene-coated pinewood biochar hybrids and evaluation of their copper removal performances. Here, we synthesized three …

Removal Of Heavy Metals Using Novel Adsorbent Materials, Lesley Joseph

Theses and Dissertations

Heavy metal contamination is a growing concern throughout the world, particularly as industrial and urban activities have increased. Inadequate water and wastewater treatment, coupled with increased industrial activity, have led to increased heavy metal contamination in rivers, lakes, and other water sources in developing countries. To address these concerns, a significant amount of research has been conducted on various novel adsorbents to evaluate their ability to remove heavy metals. Thus, in this study, MIL-100(Fe) and MIL-101(Cr) are fabricated and investigated to determine their ability to remove copper (Cu2+), cadmium (Cd2+), and lead (Pb2+) from aqueous solution. The experimental data fit …

Design Of Hybrid Pah Nanoadsorbents By Surface Functionalization Of Zro2 Nanoparticles With Phosphonic Acids, Nadine Bou Orm, Thomas Grea, Marwa Hamandi, Alexandre Lambert, Florent Lafay, Emmanuelle Vulliet, Stephane Daniele

All Works

This study focuses on the preparation of innovative nanocomposite materials based on surface modification of commercial nano-ZrO2 optimized from Bronsted acid-base surface reactions. This surface modification was carried out by direct grafting of suitable phosphonic acids bearing a vinylic or phenylic substituent in aqueous solution. Different loading quantities of the anchoring organophosphorus compounds were applied for each materials synthesis. The resulting nanohybrids were thoroughly characterized by infrared spectroscopy (DRIFT), solid-state nuclear magnetic resonance (NMR), nitrogen adsorption-desorption (BET), thermogravimetric analysis (TG), and X-ray photoelectron spectroscopy (XPS), demonstrating the reliability and efficient tunability of the surface functionalization based on the starting Zr/P …

Design Of Hybrid Pah Nanoadsorbents By Surface Functionalization Of Zro2 Nanoparticles With Phosphonic Acids, Nadine Bou Orm, Thomas Gréa, Marwa Hamandi, Alexandre Lambert, Florent Lafay, Emmanuelle Vulliet, Stéphane Daniele

All Works

This study focuses on the preparation of innovative nanocomposite materials based on surface modification of commercial nano-ZrO optimized from Brønsted acid–base surface reactions. This surface modification was carried out by direct grafting of suitable phosphonic acids bearing a vinylic or phenylic substituent in aqueous solution. Different loading quantities of the anchoring organophosphorus compounds were applied for each materials synthesis. The resulting nanohy-brids were thoroughly characterized by infrared spectroscopy (DRIFT), solid-state nuclear magnetic resonance (NMR), nitrogen adsorption-desorption (BET), thermogravimetric analysis (TG), and X-ray photoelectron spectroscopy (XPS), demonstrating the reliability and efficient tunability of the surface functionalization based on the starting Zr/P …

Slow Pyrolysis Of Vomitoxin-Contaminated Corn In A Batch Reactor, Shokooh Karami

Electronic Thesis and Dissertation Repository

Maize is one of the most important agricultural products in terms of production, consumption, and economic importance. However, its contamination with mycotoxins, particularly deoxynivalenol (DON), frequently occurs around the world due to high humidity. This mycotoxin appears predominantly in grains associated primarily with pathogens such as Fusarium graminearum (Gibberella zeae) or Fusarium culmorum. This phenomenon, threatening both human and animal health, also affects the economy due to the disposal of large amounts of contaminated corn. The overall objectives of this study were to use thermochemical conversions (i.e. pyrolysis) for managing this seasonal waste by converting it into value-added …

Adsorptive Performance Of Mwcnts For Simultaneous Cationic And Anionic Dyes Removal; Kinetics, Thermodynamics, And Isotherm Study, Zaheer Aslam, Irfan Yousaf, Abdul Zahir, Adnan Akhtar

Turkish Journal of Chemistry

Disposal of contaminated wastewater causes many serious problems especially when it gets mixed with the ground and seawater. It is, therefore, important to apply any remedial action to eradicate dangerous pollutants from the aqueous effluents and to avoid exposure of this wastewater to aquatic life. The research results discussed herein deal with the removal of Rhodamine B (RhB) and Congo Red (CR) dye from wastewater by using multi-walled carbon nanotubes (MWCNTs) as an adsorbent. Different factors like solid dosage, initial pH and concentration, time, and temperature were studied to understand the behavior and mechanism of adsorption. The maximum adsorption capacity …

Use Of Food Waste Activated Carbons For Wastewater Treatment, Abigale Monasterial

Honors Scholar Theses

Activated carbons are often used to remove phenol from wastewater. However, they are usually derived from expendable resources, such as coal and have high regeneration costs. In this work, the adsorption of phenol on activated carbon derived from food waste was studied to understand its kinetics, determine its maximum adsorption capacity, and compare it to commercial activated carbons. Adsorption experiments were performed at 298 K for 48 hours at various pHs and initial phenol concentrations. The adsorption data was then fit to the pseudo-first order, pseudo-second order, and intraparticle diffusion models to understand the kinetics and to the Langmuir and …

Production And Characterization Of Twelve Different Biochars And Evaluating Their Effects On Soil Health And Plant Growth, Shagufta Gaffar

FIU Electronic Theses and Dissertations

Biochar has been a topic of growing interest in the scientific community. It is a product derived from carbon rich organic materials through the process of pyrolysis. It has received wide attention as a means to improve soil fertility and crop productivity, absorb pollutants in soil, and sequester carbon to mitigate climate change. Recent research on biochar explores its impacts on the environment with particular focus on use as a soil amendment in agriculture. Biochar produced from different biomass and under different production process effects the environmental and agronomic impacts of its application in different ways. This means biochar can …

Removal Of Molybdenum From Contaminated Water Using Douglas Fir Biochar/Iron Oxide Composites, Naba Krishna Das

Theses and Dissertations

Molybdenum (Mo) is a naturally occurring trace element that is present in drinking water mostly in the molybdate (MoO42-) form in well water. Recently, the EPA deemed Mo as a potential contaminant because exposure can lead to health effects such as gout, hyperuricemia, and lung cancer. In this work, we have assessed the sorptive removal of Mo using Douglas fir biochar (DFBC) and its chemically-coprecipitated iron oxide analogue (DFMBC). Adsorption was studied varying the batch sorption conditions; pH, equilibrium time (5 min-24 h), initial Mo concentrations (2.5-1000 mg/L), temperatures (5, 25, and 40 °C) and equilibrium method. Langmuir capacities for …

Sorption-Mediated Chemical Processes For The Versatile Treatment Of Per- And Polyfluoroalkyl Substances (Pfas) In Complex Media, Naomi Gevaerd De Souza

Civil Engineering Dissertations

In recent years, per- and polyfluoroalkyl substances (PFAS) have gained notoriety due to environmental and health concerns. These molecules are chemically stable which contributes to their persistence in biological systems and their increased detections in surface waters. Treatment of highly persistent PFAS has been a challenging but significant task. The most practical technique for removal of PFAS is through adsorption onto granular activated carbon (GAC) or other novel materials. Meanwhile, PFAS are resistant to simple oxidation, and although decomposition of specific PFAS has been reported through advanced oxidation technologies, often energy-intense technologies capable of generating electrons such as ultraviolet radiation, …

Insights Into The Adsorption Of Pb(Ii) Over Trimercapto-S-Triazine Trisodium Salt-Modified Lignin In A Wide Ph Range, Qiaorui Wang, Chunli Zheng, Fei He, Yuan Yao, Tian C. Zhang, Chi He

Department of Civil and Environmental Engineering: Faculty Publications

A novel fabrication method for modifying alkaline lignin (AL) was reported, in which trimercapto-s-triazine trisodium salt was used as a modifier to tune surface properties of AL. Molecular structure of modified AL (FAL) was determined by 3D-EEM, synchronous fluorescence, FTIR, 13C MAS NMR and XPS. Two-dimensional correlation spectroscopy and electron localization function demonstrated that both of electrostatic and coordinate bonds formed between these functional groups and Pb(II) at higher pH of 3.0 to 6.0 while only coordinate bond at lower pH of 0.2 to 1.2. The higher the solution pH was, the stronger the adsorption capacity of FAL had. The …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Jacqueline Payne, Mary Johnson, Kevin Le, Michelle Dopp, Courtney Golman, Adrian Damian, Ethan Phan

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Courtney Golman, Kevin Le, Michelle Dopp, Adrian Damian, Mary Johnson, Jacqueline Payne, Ethan Phan

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Michelle Dopp, Kevin Le, Ethan Phan, Mary Johnson, Jacqueline Payne, Adrian Damian, Courtney Golman

Chemical Engineering Undergraduate Honors Theses

The Moo Pig Sooie’s researched, designed, and economically analyzed a full-scale adsorption column system to be applied in mining processes that leave high amounts of fluoride in their effluent. This system was designed to remove fluoride from water saturated with calcium sulfate, as calcium sulfate is present in high amounts in certain mining processes. Currently, high density sludge (HDS) is commonly employed to reduce fluoride concentrations, but due to solubility limits the sludge treatment cannot lower fluoride below 10 mg/L (ppm). The current enforceable EPA standard for discharged water is at 4 mg/L (ppm), although mining companies anticipate that this …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Kevin Le, Adrian Damian, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The team researched, designed, and economically analyzed a full-scale adsorption column system to be applied in mining processes that leave high amounts of fluoride in their effluent. This system was designed to remove fluoride from water saturated with calcium sulfate, as calcium sulfate is present in high amounts in certain mining processes. Currently, high density sludge (HDS) is commonly employed to reduce fluoride concentrations, but due to solubility limits the sludge treatment cannot lower fluoride below 10 mg/L (ppm). The current enforceable EPA standard for discharged water is at 4 mg/L (ppm), although mining companies anticipate that this standard will …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Ethan Phan, Adrian Damian, Kevin Le, Mary Johnson, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective high-density sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Removal Of Fluoride From Mine Water Via Adsorption For Land-Applied Soil Amendment, Adrian Damian, Kevin Le, Mary Johnson, Ethan Phan, Courtney Golman, Michelle Dopp, Jacqueline Payne

Chemical Engineering Undergraduate Honors Theses

The process of mining minerals and elements from ores and rocks creates acid rock drainage (ARD). This drainage is water that contains heavy metals and minerals that can be dangerous for human consumption or damaging to the environment. The mining industry has employed various water treatment methods to prevent these metals and minerals from being discharged into water sources such as ponds, lakes, and streams. Currently, the most used treatment process in the mining industry is a cost-effective highdensity sludge (HDS) process. This method reduces the concentration of metals and elements with the use of lime/limestone. However, the concentration of …

Modified Biochar From Moringa Seed Powder For The Removal Of Diclofenac From Aqueous Solution, Afrouz Bagheri, Emmanuel Abu-Danso, Jibran Iqbal, Amit Bhatnagar

All Works

© 2019, The Author(s). In this study, Moringa seed powder (MSP) was pyrolyzed at 450 °C to synthesize Moringa seed powder biochar (MSPB) and treated with phosphoric acid (H3PO4) to synthesize phosphate-modified Moringa seed powder biochar (MSPB-HPO) as an adsorbent for the removal of diclofenac (Dfc) from aqueous solution. Fourier transform infrared (FTIR) analysis, energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and pH point of zero charge (pHpzc) were conducted to give more insight into the adsorbent’s properties. The SEM analysis showed the transformations in the surface morphology from the parent material to the synthesized materials after the …

Application Of Biochar Derived From Pyrolysis Of Waste Fiberboard On Tetracycline Adsorption In Aqueous Solution, Deliang Xu, Yaxuan Gao, Zixiang Lin, Wenran Gao, Hong Zhang, Karnowo Karnowo, Xun Hu, Hongqi Sun, Syed S. A. Syed-Hassan, Shu Zhang

Research outputs 2014 to 2021

In this study, biochars derived from waste fiberboard biomass were applied in tetracycline (TC) removal in aqueous solution. Biochar samples were prepared by slow pyrolysis at 300, 500, and 800°C, and were characterized by ultimate analysis, Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET), etc. The effects of ionic strength (0–1.0 mol/L of NaCl), initial TC concentration (2.5–60 ppm), biochar dosage (1.5–2.5 g/L), and initial pH (2–10) were systemically determined. The results present that biochar prepared at 800°C (BC800) generally possesses the highest aromatization degree and surface area with abundant pyridinic N (N-6) and …

Treatment Of Combined Acid Black 48 And Coffee Wastewater By Low-Cost Adsorbents, Yung-Tse Hung

Civil and Environmental Engineering Faculty Publications

© 2020, Kaunas University of Technology. All rights reserved. Removal of synthetic dyes from wastewater is essential both from the environmental and human health point of view. A small concentration of synthetic dyes can reduce water transparency and consequently influence photosynthesis and alter aquatic ecosystems. Acid black 48 is an Azo dye that falls under the category of synthetic dyes used in the textile industry. With dyes, coffee wastewater has high chemical oxygen demand (COD) that can affect dissolved oxygen (DO) in surface waters. A mixture of wastes in surface waters creates a need to investigate the efficiency of existing …

Indonesia Natural Mineral For Heavy Metal Adsorption: A Review, Grandprix T. M. Kadja, Moh Mualliful Ilmi

Journal of Environmental Science and Sustainable Development

Indonesia has abundant mineral resources used as natural adsorbent materials for the absorption of heavy metal. Among these are natural zeolites, clay, and ashes. These natural materials showed high performance adsorption capacity with respects to their low cost and high availability. Several research reports had been published for studying the performance of the natural materials as adsorbent of several heavy metals i.e., Hg, Pb, Fe, Cd, Cr, Zn, Ni, and Cu by examining the effect of various factors, including pH, contact time, initial concentration, temperature, and dosage. Furthermore, to determine the adsorption rate, mechanism, and efficiency of natural materials in …

Sand And Pumice Filter Amended With Activated Carbon And Biochar For Phosphorus Retention, James Jihoon Kang, Marissa Davila, Sergio Mireles, Jungseok Ho

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Phosphorus (P) loss via stormwater runoff is a water quality concern. The objective of this study was to investigate two commercial biochars relative to an activated carbon as an additive to geomedia (sand and pumice) for P removal. The batch adsorption experiment was conducted to assess P sorption of the geomedia and carbon materials while the leaching experiment was conducted in sand and pumice columns amended with carbon materials (5 % by weight). The batch adsorption test revealed that only activated carbon showed an appreciable P adsorption up to 19 %. Tested biochar materials showed no adsorption capacity for P …

Lignocellulosic Biomass Derived Activated Carbon For Energy Storage And Adsorption, Changle Jiang

Graduate Theses, Dissertations, and Problem Reports

Lignocellulosic biomass has been converted to hierarchical porous carbon materials which possess macro-, meso- and micro-pores. The natural structure of porous lignocellulosic structure was preserved during activation with further developed porosity by the activation. The activated carbon can be well applied to electrochemical double layer capacitor for transportation storage of ions as well as adsorbent materials for metal ion removal from wastewater.

The first chapter of this dissertation presents an introduction of biomass derived carbon and its applications. In the second chapter, both direct and indirect activation methods using carbon dioxide were adopted in this study. The results show that …

Nitrogen Self-Doped Activated Carbons Derived From Bamboo Shoots As Adsorbent For Methylene Blue Adsorption, Bingbing Mi, Jingxin Wang, Hongzhong Xiang, Fang Liang, Jianfei Yang, Zixing Feng, Tao Zhang, Wanhe Hu, Xianmiao Liu, Zhijia Liu, Benhua Fei

Faculty & Staff Scholarship

Bamboo shoots, a promising renewable biomass, mainly consist of carbohydrates and other nitrogen-related compounds, such as proteins, amino acids and nucleotides. In this work, nitrogen self-doped activated carbons derived from bamboo shoots were prepared via a simultaneous carbonization and activation process. The adsorption properties of the prepared samples were evaluated by removing methylene blue from waste water. The factors that affect the adsorption process were examined, including initial concentration, contact time and pH of methylene blue solution. The resulting that BSNC-800-4 performed better in methylene blue removal from waste water, due to its high specific surface area (2270.9 m2 g−1), …

Escherichia Coli Removal From Stormwater Using Steel Chips Filter, Peng Dai

Electronic Theses and Dissertations

Media filtration has received increasing attention as an effective technology that can facilitate the removal of particles and dissolved pollutions in the stormwater. However, most traditional media filtration systems are generally ineffective in removing bacteria, causing pollution of groundwater and receiving surface water. In this study, recycled steel chips were evaluated as low-cost filter materials for bacterial removal from stormwater. Laboratory column experiments were conducted to evaluate the impact of steel chips particle size, flow rate, initial E.coli concentration, pH, natural organic matter (NOM), steady and intermittent flow on E.coli removal. The results showed that E.coli removal decreased from 99.4% …

Pine-Wood Derived Nanobiochar For Removal Of Carbamazepine From Aqueous Media: Adsorption Behavior And Influential Parameters, Mitra Naghdi, Mehrdad Taheran, Rama Pulicharla, Tarek Rouissi, Satinder K. Brar, M. Verma, R. Y. Surampalli

Department of Civil and Environmental Engineering: Faculty Publications

In recent years, application of biochar for removal of pollutants from aqueous solutions has been of interest due to favorable physicochemical properties and availability of feedstock. However, adsorption behavior has been reported only for raw and micro biochar particles and taking advantage of biochar nanoparticles, which offer superior specific surface area, did not receive any attention. The objective of this study was to investigate the adsorption efficiency of produced nanobiochar from pinewood. For this purpose, removal of carbamazepine (CBZ), a globally prescribed pharmaceutical, at very low concentrations (0.5–20 ppb) on as-produced nanobiochar with average particle size of 60 nm was …

Organic And Inorganic Contaminants Removal From Water With Engineered Biochar, Narada Bombuwala Dewage

Theses and Dissertations

Water pollution represents one of the major concerns of the modern world, after scientific and industrial development that generates hazardous organic and inorganic contaminants. Biochar (BC) has gained tremendous attention in the past decade as a cheap and efficient adsorbent for organic and inorganic contaminants from aqueous solutions. BC is considered to be a low-cost alternative to activated carbon, however, BC typically suffer performance reductions due to their low surface areas and poor mechanical properties. The main objective of this work is to develop novel biochar materials by modifying the biochar surface for the removal of organic and inorganic contaminants …