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LSU Master's Theses

2014

PAHs

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Pah Degradation In Wetland Soils As Influenced By Redox Potential, Haoxuan Zhang Jan 2014

Pah Degradation In Wetland Soils As Influenced By Redox Potential, Haoxuan Zhang

LSU Master's Theses

Polycyclic aromatic hydrocarbons (PAHs) are a common contaminant in wetland soils. They are a group of compounds widely distributed in the environment and tend to accumulate in soils. Major contribution to removal of PAHs is biological degradation. For investigating the biodegradation potential of PAHs influenced by tidal actions, equipment was built for simulating the tidal actions, and concentrations of phenanthrene, pyrene, and benzo[e]pyrene were added to the soils samples which were collected from wetland. Experiments were then conducted over 120 days. Redox potentials and PAHs concentrations were measured and analyzed. Results are concluded: 1) influenced by tidal action, phenanthrene, pyrene, …


Uptake And Deposition Of Pyrogenic And Petrogenic Pahs On Spartina Alterniflora, Yasmin Mohammad Jan 2014

Uptake And Deposition Of Pyrogenic And Petrogenic Pahs On Spartina Alterniflora, Yasmin Mohammad

LSU Master's Theses

Saline marshes dominated by Spartina alterniflora were impacted by MC252 crude oil along Louisiana’s shoreline. Two locations were evaluated in this study; a lightly oiled, saline marsh near Port Fourchon, LA and a less saline, heavily oiled marsh near Bay Jimmy in the Barataria Basin, LA. Objectives of this study were to develop a method to extract polycyclic aromatic hydrocarbons (PAHs) from Spartina leaves and to compare and contrast the relative uptake and deposition of petrogenic and pyrogenic PAHs in Spartina leaves. A three-step sequential extraction procedure was developed for the extraction and analysis of PAHs on Spartina leaves. In …


Biogeochemical Controls On Fate Of Subsurface Oiled Sands On A Coastal Headland Beach, Autumn Anastasia Westrick Jan 2014

Biogeochemical Controls On Fate Of Subsurface Oiled Sands On A Coastal Headland Beach, Autumn Anastasia Westrick

LSU Master's Theses

The fate of subsurface oiled sands collected from Fourchon Beach in Louisiana were determined while modifying biogeochemical controls on the degradation of PAHs. Groundwater on the beach has intrinsically low dissolved oxygen concentrations, which may limit natural biodegradation of the crude oil components. The intent of this research was to characterize the biogeochemical properties and degradability of oiled sands (with >10% of pore filled with MC252 oil) using a combination of laboratory flow-through reactor studies, field measurements and time-series microelectrode profiles of down-flow and cross flow geometries. Reactor experiments indicate that optimal conditions for substantial oil degradation are aerobic under …