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O-Xloratsetiltimol Sintezi Va Uni Kimyoviy Modifikatsiyalash, Azimjon U. Choriev, Anvar K. Abdushukurov, Ilyos U. Normurodov, Sarvinoz K. Mirzayeva

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study is to develop a convenient method for the synthesis of O-chloroacetylthymol and to propose the mechanism of the O-chloroacetylation reaction. Thin-layer chromatography of chloroacetylation and nucleophilic substitution reaction products was studied and their composition was confirmed by reference substances. Nucleophilic exchange reactions of O-chloroacetylthymol with sodium oxalate, sodium tartrate, potassium rhodanides were studied. Favorable conditions for carrying out the nucleophilic exchange reaction were searched and 3 new substances unknown in the literature were synthesized. The structure of the synthesized substances was proved by IR and NMR spectra.

Synthesis And Study Of The Complex Compound Of Copper(Ii) Acetylacetonate With 2-Amino-1-Methylbenzimidazole, Daminbek Ziyatov, Kizlarkhon Siddikova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is the synthesis and study of the physicochemical properties of the complex compound of copper (II) acetylacetonate with a 2-aminobenzimidazole derivative. A heteroligand copper (II) complex compound containing acetylacetone and 2-amino-1-methylbenzimidazole was synthesized for the first time. The structure of the synthesized coordination compound was studied by SEM-EDX, IR spectroscopy, and thermogravimetric analysis. It has been established that in the complex 2-amino-1-methylbenzimidazole is coordinated monodentately to the copper ion through the heterocyclic nitrogen atom and, in this case, a complex of tetragonal-bipyramidal structure is formed.

The Interaction Mechanism Of Calcium Hydrosilicate With Aqueous Solution Of Copper Chloride, Karen Grigiryan, Lyusya Baginova, Galina Harutyunyan, Anna Khachatryan, Suren Hayrapetyan

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research is study the mechanism of calcium silicate hydrates (CSH) interaction with an aqueous solution of copper chloride (CuCl2) to further develop optimal parameters of the technological process of wastewater treatment from copper ions. The effect of the temperature and duration of the process, the concentration of CaCl2 and the CSH/CuCl2 molar ratio on the synthesis of copper silicate hydrate was studied. X-ray, IR-spectroscopic and chemical analyzes methods confirmed the formation of copper silicate hydrate.

Synthesis And Research Of Silicon-Containing Phthalocyanine, Dilmurod Shukurov, Hayit Turayev, Abdulakhat Djalilov, Masud Karimov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this study is to synthesize, and study a new form of dye based on phthalocyanine, a silicon-containing phthalocyanine pigment used as a dye for dye-sensitive solar cells, which are currently third generation solar cells as one of the energy source alternatives. To achieve this goal, a silicon-containing phthalocyanine pigment containing urea, phthalic anhydride and sodium fluorosilicate was synthesized and studied. Based on the results of IR spectroscopy, the reaction of pigment formation is proposed and the data of scanning electron microscopy is presented. Its differential thermal analysis, photodynamic analysis and its relationship with inorganic and organic solvents …

Heterogeneous Catalytic Conversions Of Acetylene, Abduvakhab Ikramov, Sevara Kholikova, Noryigit Musulmanov

CHEMISTRY AND CHEMICAL ENGINEERING

The reactions of interaction of acetylene with water vapor, acetic acid and ammonia in the presence of heterogeneous catalysts have investigated. Depending on the nature of the starting components used, acetaldehyde and acetone, vinyl acetate, pyridine bases and pyrrole synthesized. Heterogeneous catalysts selected for each studied reaction based on some scientific prerequisites for the selection of catalysts. Active catalysts for the investigated reactions were determined, which contain compounds of cadmium, zinc, bismuth, chromium, iron and copper, in general, d-group metals. γ-Al₂O₃, bentonite and kaolin used as a catalyst carrier. Hydrofluoric acid, acetic acid, ammonium fluoride and …

Synthesis Of Superabsorbing Hydrogels Based On Starch Copolymers, Baxodir Kholnazarov, Khayit Turaev, Abdulakhat Jalilov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to synthesize highly swellable superabsorbent hydrogels based on starch copolymers. To achieve this goal, mineral-containing superabsorbent hydrogels based on starch, acrylamide, binder and initiator were synthesized. The optimal synthesis conditions were determined and studies were carried out on the influence of the molar ratios of the starting substances on the composition and physicochemical properties of the synthesized superabsorbent hydrogel. In the course of research, the optimum copolymerization temperature was 60 ° C, and the reaction time was 3 hours.

As a result of the study, a superabsorbent hydrogel based on starch, acrylamide and bentonite …

Synthesis And Research Of Chelate Forming Sorbent Based On Carbamide, Formaldehyde, Ditizone, Chorieva Nigora, Ermuratova Nilufar, Turaev Khayit, Kasimov Sherzod

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this study is the synthesis and study of a chelating sorbent for the extraction of ions of non-ferrous and noble metals. To achieve this goal, a sulfur-containing chelating sorbent based on carbamide, formaldehyde, and dithizone was synthesized and studied. The optimal conditions for the synthesis of the sorbent have been determined and studies have been carried out on the influence of the molar ratios of the starting materials on the composition, and physicochemical properties of the synthesized sorbent. The optimum temperature of polycondensation was taken as 90 °C, the reaction time is 2.5-3 hours, as a result, …

Mixed Complex Compounds Of Palmitate, Oleate Calcium With Acetamide, Nicotinamide And Thiocarbamide, Ibadullaeva Tursunoy, Azizov Tokhir, Ibragimova Мavluda

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of the study was the synthesis and study of the structure of mixed complexes of palmitate, calcium oleate with acetamide, nicotinamide and thiocarbamide. The mixed coordination compounds of palmitate and calcium oleate were synthesized. The composition, individuality, thermal behavior, methods of coordinating the palmitate and oleate fragments, acetamide, nicotinamide and thiocarbamide molecules have been established. Comparison of the diffraction patterns of calcium palmitate and oleate, free ligand molecules and synthesized compounds showed the mismatch of the diffractograms, conseqently that the synthesized complexes have an individual crystal lattice different from the starting materials. The method of coordination of amide …

Low-Resistance Bi/Pb Ceramics Containing Ts = 295К-315k Phases Synthesized In A Solar Furnace (Parkent), Gulamova Dilbara, Gulamov Timur

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to obtain bulk textured superconducting ceramics based on glass-crystalline precursors of the Bi1.7Pb0.3Sr2Ca(n-1)CunOy (n=5-9) series. Technologies for obtaining superconducting materials are presented. The advantages of melt methods and “Super Fast Aloys Quenching–T” technology is shown. Compositions, methods of synthesis and study of properties of precursors and ceramics obtained by solar energy are presented. The interrelation of the morphology of glass-crystalline precursors and superconducting ceramics based on them is revealed. It is shown that nano-sized nuclei are the basis on which superconducting phases with Ts = 295-315K are formed as a result of the peritectic …

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part 2. Zn, Fe, Ni), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes Zn(II), Cu(II), Ni(II), Fe(III), which is necessary for understanding the electronic structure of coordination compounds with chelating ligands.

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes of Au(III), Pt(II), Ag(I), Cu(II), Ni(II), Fe(III), which are necessary for understanding the electronic structure of coordination compounds with chelating ligands.

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes of Au(III), Pt(II), Ag(I), Cu(II), Ni(II), Fe(III), which are necessary for understanding the electronic structure of coordination compounds with chelating ligands.

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).

Bi/Pb Superconducting Phases, With An Elevated Superconducting Transition Temperature, Synthesized By Solar Energy, Gulamova Dilbara

CHEMISTRY AND CHEMICAL ENGINEERING

Superconductors superconductor line Bi1,7Pb0,3Sr2Ca(n-1)CunO10-δ(n=5,9,12,19) microstructure, phases compositions, critical temperature to superconducting state transition Tc was investigated. Precursors for superconductors phases synthesis by solar energy have been elaborated. The formation of superconducting homologous phases with a superconducting transition temperature in the range of 240-270 K is determined