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Crystal Structure Of Hexakis(Dimethyl Sulfoxide-Κo)Cobalt(Ii) Bis[Trichlorido(Quinoline-Κn)Cobaltate(Ii)], Tyler K. Brescia, Kaltrina Mulosmani, Shivani Gulati, Demosthenes Athanasopoulos, Rita K. Upmacis
Crystal Structure Of Hexakis(Dimethyl Sulfoxide-Κo)Cobalt(Ii) Bis[Trichlorido(Quinoline-Κn)Cobaltate(Ii)], Tyler K. Brescia, Kaltrina Mulosmani, Shivani Gulati, Demosthenes Athanasopoulos, Rita K. Upmacis
Faculty Papers and Publications
There are few reports that describe crystal structures of compounds containing cobalt complexed to either dimethyl sulfoxide (Me2SO) or quinoline (C9H7N). The title compound, [Co(C2H6OS)6][CoCl3(C9H7N)]2, is a cobalt salt in which the metal ion is complexed to both Me2SO and quinoline. In particular, we observed that anhydrous cobalt(II) chloride reacts with quinoline in Me2SO to form a salt that is to be formulated as [CoII(Me2SO)6]2+{[CoIICl3quinoline]2 ‾ }. …