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Simulation And Fabrication Of All Oxide-Based Ito/Tio2/Cuo/Au Heterostructure For Solar Cell Applications, Sajal Islam
Simulation And Fabrication Of All Oxide-Based Ito/Tio2/Cuo/Au Heterostructure For Solar Cell Applications, Sajal Islam
MSU Graduate Theses
Oxide heterostructures have drawn great attention lately, due to their environment-friendly properties and potential applications in optoelectronic devices. In this work, a simulation study of a heterojunction solar cell was performed with SCAPS (a solar cell simulator) using TiO2 as an n-type and CuO as a p-type layer. The thickness and the dopant-dependent simulations have shown that the solar cell operates at a maximum efficiency of 19.2% when the thickness of the TiO2/CuO layers is chosen 1.4µm/1.2µm compared to the 11.5% efficiency when FTO is replaced with ITO. An indium-doped tin oxide (ITO) vs fluorine-doped tin oxide (FTO) comparison study …
Raman Spectroscopic Investigation Of The Speciation Of Uranyl (Vi) And Thorium (Iv) Ions In Chloride-Bearing Aqueous Solutions Under Hydrothermal Conditions, Nadib Akram
MSU Graduate Theses
Raman spectra were acquired for a uranyl chloride aqueous solution at temperatures ranging from 25°C to 500°C at the chloride concentration of 6M and uranium (vi) concentration of 0.05M. The measurements were taken by sealing the sample in a hydrothermal diamond anvil cell (HDAC) which enabled spectra acquisition at non-ambient conditions. The pressure inside the cell was measured by estimating the liquid-vapor homogenization temperature (TH) and using the isochoric equation of state diagram of water. The acquired spectra were then fitted to determine the speciation distribution of the various uranyl chloride species for the mentioned concentration. The developed …
Study Of Iron Ion Transit Through Three-Fold Channel Of Ferritin Cage, Shah Alam Limon
Study Of Iron Ion Transit Through Three-Fold Channel Of Ferritin Cage, Shah Alam Limon
MSU Graduate Theses
Ferritin is an iron-storage globular protein with an ability to uptake, mineralize and release iron ions in a controllable manner. The globular hollow shell allows storage of mineralized iron, with several channels responsible for the transit of ions into the shell and out of it. Understanding of the detailed molecular functioning of ferritin is required for rational design of biomimetic conjugate nano-biosystems containing ferritin-like constituents. In this work, ferritin was investigated both numerically by all-atom molecular dynamics (MD) simulations, and experimentally by Raman spectroscopy. Molecular dynamic simulations of a model system comprising iron ions (Fe2+) and a ferritin trimer expressing …
Application Of Raman Spectroscopy To Study Of Biological Systems, Neva Agarwala
Application Of Raman Spectroscopy To Study Of Biological Systems, Neva Agarwala
MSU Graduate Theses
Raman spectroscopy is an important tool of molecular characterization based on inelastic scattering of monochromatic light by molecules. Since Raman spectra reflect unique vibrational properties of materials, the method offers a potential of selective molecular identification. Furthermore, surface-enhanced Raman spectroscopy (SERS) also is capable of a high sensitivity, since inelastic scattering of light from the molecules is strongly enhanced when Raman-active molecules are located close to roughened noble metal surfaces. In this thesis, Raman characterization protocols of liquid biological samples are optimized. Raman spectra of two different cell cultures, yeast cells and HeLa cells, were collected and interpreted. The potentiality …
A Study On The Synthesis And Properties Of Gold Nanoparticles And Their Applications To Surface Enhanced Raman Spectroscopy, Daniel Robert Soden
A Study On The Synthesis And Properties Of Gold Nanoparticles And Their Applications To Surface Enhanced Raman Spectroscopy, Daniel Robert Soden
MSU Graduate Theses
Surface enhanced Raman substrates represent a critical step in the sensitivity augmentation of Raman spectroscopy, but due to the time and expertise currently required in the synthesis process, they have not been fully realized within an industrial setting. This thesis aims to investigate a new technique in surface enhanced Raman spectroscopy (SERS) substrate fabrication designed to decrease synthesis time and map the most effective growth parameters for a successful Raman intensity boost. Sputter physical vapor deposition was utilized to deposit a gold (Au) layer on an insulating substrate, and annealing treatments were applied to agglomerate the Au atoms into the …
Investigation Of Electrical And Magneto Transport Properties Of Reduced Graphene Oxide Thin Films, Ariful Haque
Investigation Of Electrical And Magneto Transport Properties Of Reduced Graphene Oxide Thin Films, Ariful Haque
MSU Graduate Theses
Large area uniform thin films of reduced graphene oxide (RGO) was synthesized by pulsed laser deposition (PLD) technique. A number of structural properties including the defect density, average size of sp2 clusters, and degree of reduction were investigated by Raman spectroscopy and X-ray diffraction (XRD) analysis. The temperature dependent (5K - 350K) four terminal electrical transport property measurement confirms variable range hopping and thermally activated transport mechanism of the charge carriers at low (5K - 210K) and high temperature (210K - 350K) regions, respectively. The calculated localization length, density of states (DOS) near Fermi level (EF), hopping energy, and Arrhenius …