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Geochemical Fractionation, Speciation, And Bioavailability Of Heavy Metals In Stream Sediments In Aurora, Mo, Miles Pearson Aug 2017

Geochemical Fractionation, Speciation, And Bioavailability Of Heavy Metals In Stream Sediments In Aurora, Mo, Miles Pearson

MSU Graduate Theses

Stream sediments from Chat Creek in Aurora, MO, part of the former Tristate Mining District, were digested via a sequential extraction procedure modeled after the Tessier method. Prior sampling had shown elevated levels of zinc, lead, and cadmium in sediments located near former chat piles. Metals in sediments were divided into four geochemical fractions: 1) easily exchangeable, 2) carbonate-bound, 3) iron-manganese oxides-bound, and 4) organic matter-bound. The distribution of the metals within these fractions can help predict the bioavailability and speciation of said metals. The majority of metals were contained in the third and to a lesser extent the fourth …


Channel Bar Morphology, Distribution, And Mining-Related Geochemistry In The Big River, St. Francois County, Missouri: Implications For Geomorphic Recovery, Lindsay Marie Olson May 2017

Channel Bar Morphology, Distribution, And Mining-Related Geochemistry In The Big River, St. Francois County, Missouri: Implications For Geomorphic Recovery, Lindsay Marie Olson

MSU Graduate Theses

Tailings releases associated with large-scale historical Pb mining in St. Francois County, Missouri resulted in system-wide contamination of Pb and excess sediment in the Big River. Previous studies have addressed basin and segment scale variability of the contaminants; however, little is known about reach and bar scale variability. This study addresses how mining sediment inputs influence bar form and geochemistry across a range of scales. Bar sediment samples were collected at 21 reaches and analyzed for particle size and geochemistry, while air photo analysis was used to evaluate channel morphology, bar type, and area. Bar area is initially low in …


Using Survey Data And Hec-Ras Modeling To Assess A Riffle-Remediation Structure On The Big River, Bonne Terre, Missouri, Nichole Renee Weedman May 2017

Using Survey Data And Hec-Ras Modeling To Assess A Riffle-Remediation Structure On The Big River, Bonne Terre, Missouri, Nichole Renee Weedman

MSU Graduate Theses

Sediment transport and deposition in river channels can vary for many reasons including flooding, dredging, channel velocity, and grain size. On the Big River, the Army Corps of Engineers constructed a riffle ramp structure to trap and remediate lead-contaminated sediments. The performance of the structure is unknown. The goal of this study is to evaluate the storage capabilities of the riffle structure. To do this, survey data was collected to analyze sediment storage and entered into the HEC-RAS 5.0 to model the hydraulics of the channel before and after the riffle installation. Samples were collected to assess the level of …