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Mining-Contaminated Sediment And Metal Storage In Channel Deposits In Turkey Creek, Tri-State Mining District, Missouri And Kansas, Max Quinn Hillermann Jan 2022

Mining-Contaminated Sediment And Metal Storage In Channel Deposits In Turkey Creek, Tri-State Mining District, Missouri And Kansas, Max Quinn Hillermann

MSU Graduate Theses

The Joplin subdistrict, within the Tri-State Mining District (TSMD), was a major producer of lead (Pb) and zinc (Zn) ore between the 1880s to 1920s. Metalliferous mining wastes are still stored in the channel deposits of local streams raising environmental and health concerns. This study quantifies the volume, sediment size, and metal concentrations in channel bed, bar, bench, and chute deposits to quantify the spatial variability of contaminated sediment storage in Turkey Creek (119 km2). Sample reaches (n=14) contained metal concentrations elevated above the Tri-State Mining District specific probable effects concentration at every site with mean concentrations in …


The Legacy Of Contamination By Lead Smelters In Missouri, Robert S. Armstrong Dec 2020

The Legacy Of Contamination By Lead Smelters In Missouri, Robert S. Armstrong

MSU Graduate Theses

Missouri has a rich history of lead mining. In the smelting process lead particles are emitted, which may be toxic to plants and animals. This study focuses on two primary lead smelters, Herculaneum and Glover, in Missouri. Smelting operations have ceased at these two sites, and unlike Herculaneum, Glover has no reported lead concentrations. Findings from air and sediments of these two sites were compared to background conditions and to each other. Thirty-three samples were collected from Herculaneum and Glover (thirty samples and three replicates) and eleven samples (ten samples and one replicate) for background. For Herculaneum sediment, lead levels …


The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan Aug 2020

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

MSU Graduate Theses

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …


Spatial And Temporal Trends Of Mining-Related Lead-Zinc Sediment Contamination, Galena River Watershed, Sw Wisconsin-Nw Illinois, Dylan Alexander King Aug 2018

Spatial And Temporal Trends Of Mining-Related Lead-Zinc Sediment Contamination, Galena River Watershed, Sw Wisconsin-Nw Illinois, Dylan Alexander King

MSU Graduate Theses

Alluvial sediments within the Galena River Watershed were severely contaminated with heavy metals by historical zinc (Zn) and lead (Pb) mining operations during the early 1800s until 1979. Since the mines closed, there have been efforts to remediate on-site mine waste. However, the effectiveness of these efforts to reduce metal concentrations in stream sediments is unknown. This study compares present-day (2017) contamination trends in the Galena River Watershed to trends reported 25 years ago. A total of 415 sediment/soil samples were collected and analyzed using X-ray florescence spectrometry to determine sediment metal concentrations. The highest concentrations of zinc measured were …


Geochemical Fractionation, Speciation, And Bioavailability Of Heavy Metals In Stream Sediments In Aurora, Mo, Miles Pearson Aug 2017

Geochemical Fractionation, Speciation, And Bioavailability Of Heavy Metals In Stream Sediments In Aurora, Mo, Miles Pearson

MSU Graduate Theses

Stream sediments from Chat Creek in Aurora, MO, part of the former Tristate Mining District, were digested via a sequential extraction procedure modeled after the Tessier method. Prior sampling had shown elevated levels of zinc, lead, and cadmium in sediments located near former chat piles. Metals in sediments were divided into four geochemical fractions: 1) easily exchangeable, 2) carbonate-bound, 3) iron-manganese oxides-bound, and 4) organic matter-bound. The distribution of the metals within these fractions can help predict the bioavailability and speciation of said metals. The majority of metals were contained in the third and to a lesser extent the fourth …


Channel Bar Morphology, Distribution, And Mining-Related Geochemistry In The Big River, St. Francois County, Missouri: Implications For Geomorphic Recovery, Lindsay Marie Olson May 2017

Channel Bar Morphology, Distribution, And Mining-Related Geochemistry In The Big River, St. Francois County, Missouri: Implications For Geomorphic Recovery, Lindsay Marie Olson

MSU Graduate Theses

Tailings releases associated with large-scale historical Pb mining in St. Francois County, Missouri resulted in system-wide contamination of Pb and excess sediment in the Big River. Previous studies have addressed basin and segment scale variability of the contaminants; however, little is known about reach and bar scale variability. This study addresses how mining sediment inputs influence bar form and geochemistry across a range of scales. Bar sediment samples were collected at 21 reaches and analyzed for particle size and geochemistry, while air photo analysis was used to evaluate channel morphology, bar type, and area. Bar area is initially low in …


Using Survey Data And Hec-Ras Modeling To Assess A Riffle-Remediation Structure On The Big River, Bonne Terre, Missouri, Nichole Renee Weedman May 2017

Using Survey Data And Hec-Ras Modeling To Assess A Riffle-Remediation Structure On The Big River, Bonne Terre, Missouri, Nichole Renee Weedman

MSU Graduate Theses

Sediment transport and deposition in river channels can vary for many reasons including flooding, dredging, channel velocity, and grain size. On the Big River, the Army Corps of Engineers constructed a riffle ramp structure to trap and remediate lead-contaminated sediments. The performance of the structure is unknown. The goal of this study is to evaluate the storage capabilities of the riffle structure. To do this, survey data was collected to analyze sediment storage and entered into the HEC-RAS 5.0 to model the hydraulics of the channel before and after the riffle installation. Samples were collected to assess the level of …


Channel Sediment And Mining-Lead Storage In Flat River Creek, Old Lead Belt, Missouri, Ralph Joseph Hill Dec 2016

Channel Sediment And Mining-Lead Storage In Flat River Creek, Old Lead Belt, Missouri, Ralph Joseph Hill

MSU Graduate Theses

Historical mining for lead (Pb) in the Old Lead Belt District introduced large volumes of tailings into nearby streams resulting in the large-scale contamination of channel bed and bar deposits in Big River which drains the southeastern Missouri Ozarks. Tailings pile sites have been remediated so that present contamination sources to the river are primarily from the remobilization of Pb stored in channel and floodplain deposits. This study examined the channel geomorphology and sediment geochemistry of Flat River Creek (FRC), a major tributary to the Big River which drains an area that includes three of the six major mines in …


Fabrication, Characterization, And Application Of Carbon Nanoparticles For The Detection Of Heavy Metal Ions In Aqueous Media, Aaron Michael Simpson Dec 2015

Fabrication, Characterization, And Application Of Carbon Nanoparticles For The Detection Of Heavy Metal Ions In Aqueous Media, Aaron Michael Simpson

MSU Graduate Theses

This research set out to develop a method for producing Carbon nanoparticles (CNPs) from glycerol and use them to detect Cu2+, Hg2+, and Pb2+ ions in aqueous solution. Three synthesis methods were developed using the following mixtures: (1) glycerol and silica, (2) glycerol, silica, and H3PO4, and (3) glycerol with H3PO4. The structure of the particles was characterized using a variety of spectroscopic techniques. Size distributions were obtained from scanning electron microscopy images. The particles were spherical with average diameters of 66, 58, and 89 nm respectively and believed to consist of a carbon core with carboxylic acid and alcohol …