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2006

Electrodeposition

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High-Pressure Torsion-Induced Grain Growth In Electrodeposited Nanocrystalline Ni, X. Z. Liao, A. R. Kilmametov, R. Z. Valiev, Hongsheng Gao, Xiaodong Li, A. K. Mukherjee, J. F. Blingert, Y. T. Zhu Jan 2006

High-Pressure Torsion-Induced Grain Growth In Electrodeposited Nanocrystalline Ni, X. Z. Liao, A. R. Kilmametov, R. Z. Valiev, Hongsheng Gao, Xiaodong Li, A. K. Mukherjee, J. F. Blingert, Y. T. Zhu

Faculty Publications

Deformation-induced grain growth has been reported in nanocrystalline (nc) materials under indentation and severe cyclic loading, but not under any other deformation mode. This raises an issue on critical conditions for grain growth in nc materials. This study investigates deformation-induced grain growth in electrodeposited nc Ni during high-pressure torsion (HPT). Our results indicate that high stress and severe plastic deformation are required for inducing grain growth, and the upper limit of grain size is determined by the deformation mode and parameters. Also, texture evolution suggests that grain-boundary-mediated mechanisms played a significant role in accommodating HPT strain.


Development Of An Electroless Method To Deposit Corrosion-Resistant Silicate Layers On Metallic Substrates, Swaminatha P. Kumaraguru, Basker Veeraraghavan, Branko N. Popov Jan 2006

Development Of An Electroless Method To Deposit Corrosion-Resistant Silicate Layers On Metallic Substrates, Swaminatha P. Kumaraguru, Basker Veeraraghavan, Branko N. Popov

Faculty Publications

A novel electroless method for depositing corrosion-resistant silicate layers on metallic substrates from aqueous solutions has been developed. The silicate layer was deposited from an aqueous solution of sodium silicate (3.22 weight ratio sodium silicate, 37.5% solution in water from PQ Corporation) and sodium borohydride. The technique is demonstrated by forming a passive film on galvanized steel. Deposition parameters such as concentration of the bath, temperature, and pH have been optimized based on the corrosion characteristics of the final coating. Studies on the coating reveal the formation of a very thin (5 nm) zinc disilicate layer followed by a much …