Digital Commons Network^™

Lithofacies Characterization Of Marine Shelf Shale And Implicaitons On Depositional Conditions And Processes On The Continental Shelf — A Case Study Of The Upper-Cretaceous Tuscaloosa Marine Shale In Louisiana And Mississippi, U.S.A., Efren Mendez Jr

Masters Theses

"The Upper Cretaceous Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir deposited on the continental shelf of the northern Gulf of Mexico Basin. Previous studies have focused on sequence stratigraphy, thermal modeling, and well-log correlations. However, a limited understanding of the stratigraphic heterogeneity of the TMS is yet to be studied. This study aims to characterize the stratigraphic heterogeneity of the TMS using core, petrographic, and well-log analyses to better understand the depositional conditions and processes that occur on the continental shelf. The TMS has been classified into four lithofacies of very fine sands – coarse silts (LF1), medium-fine …

Adsorption Of Arsenic Onto River Sediments, Leticia Augusta Dos Santos Ferreira

Masters Theses

“Previous studies have noted the relationship between shallow groundwater rich in sodium (Na) and bicarbonate (HCO₃) and elevated levels of dissolved arsenic. However, most experimental work on arsenic adsorption in the presence of HCO₃ and differing Na/Ca ratios has proven difficult to extrapolate to natural systems because of differences in tested mineral compositions and component concentrations. In this study, I performed a series of adsorption experiments using river sediments to evaluate the influence of HCO₃ and monovalent/divalent cations on the extent of arsenic adsorption onto natural sediment in groundwater.

Batch adsorption (kinetics, equilibrium, and metal loading) …

Quantifying Surface Water Capture By Municipal Pumping Wells In An Urban Watershed Impacted By Road Salt, Austen York

Masters Theses

The Spring Valley sub-watershed is located within the Kalamazoo Township contains Spring Valley Lake, a man-made impoundment that ultimately discharges into the Kalamazoo River. Elevated chloride levels in pumped water from the Kalamazoo Station 14 municipal wellfield, located along the shoreline of Spring Valley Lake, has resulted in less than ideal corrosivity values for the water distribution system. Specific project objectives include: (1) identifying the cause of elevated chloride, (2) assessing surface water capture by the Station 14 wellfield, and (3) characterizing of water quality in Spring Valley Lake. Monitoring along a series of sampling transects spanning the sub-watershed, focused …

Using Sedimentary Mercury Geochemistry To Evaluate The Niagara-Salina Transition, Silurian Michigan Basin, Usa, Sara Hayes

Masters Theses

The Niagara-Salina boundary in the Michigan Basin is marked by an abrupt transition from carbonates to evaporites. Though the cause is uncertain, previous work suggests the onset of Salina evaporites was driven by basin restriction, but the presence of several global carbon isotope excursions (CIE) suggest a global driver. This study builds on this discussion using two relatively new geochemical proxies - elemental mercury concentrations [Hg] and Hg isotopes.

Mercury concentrations [Hg] were measured in 88 samples from the State Kalkaska #2-15 core from 6604.03 ft to 6797.42 ft. [Hg] ranges from 0.11 to 0.62 mg/kg and [Hg]/TOC from 0.038 …

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …

Vorticity And Kinematic Analysis Of The Cordillera Blanca Shear Zone, Peru, Corey Flynn

Masters Theses

Quantitative vorticity analyses applied to naturally deformed rocks are essential for studying kinematics in shear zones and can be performed using a range of methods, which have been developed over the last two decades. An understanding of vorticity, or the contribution of pure vs. simple shear, can permit for the modeling of shear zone development in a deformed region. Recent (5 Ma-present) deformation in the Cordillera Blanca Shear Zone of the Peruvian Andes has exposed sections of the middle crust at the surface, allowing for observation and analysis of shear zone processes. Oblique grain-shape (OGS) analysis and crystallographic vorticity analysis …

Hydrologic Controls On Phosphorus Speciation And Mobilization In A Subalpine Watershed (East River, Colorado), Lucia Isobel Arthen-Long

Masters Theses

The cycling of phosphorus (P) through floodplain environments is critical to ecosystem productivity and has significant implications on both water quality and soil fertility. P export from soils in response to saturation has been well documented, but the relative vulnerability of specific P pools to mobilization remains poorly constrained, as do the mechanisms mediating its release. The prediction of P availability in and export from mountainous floodplain soils is of great importance as global climate change is projected to significantly alter precipitation regimes in alpine systems. This study combined a thorough characterization of P distribution across a hillslope to floodplain …

Sedimentary Processes Influencing Divergent Wetland Evolution In The Hudson River Estuary, Kelly Mckeon

Masters Theses

Consistent shoreline development and urbanization have historically resulted in the loss of wetlands. However, some construction activities have inadvertently resulted in the emergence of new tidal wetlands, with prominent examples of such anthropogenic wetlands found within the Hudson River Estuary. Here, we utilize two of these human-induced tidal wetlands to explore the sedimentary and hydrologic conditions driving wetland development from a restoration perspective. Tivoli North Bay is an emergent freshwater tidal marsh, while Tivoli South Bay is an intertidal mudflat with vegetation restricted to the seasonal growth of aquatic vegetation during summer months. Using a combination of sediment traps, cores, …

Testing The Impact Of A Freshwater Wetland Restoration On Water Table Elevation And Soil Moisture Using A Parametric Groundwater Modeling Approach, Erika T. Ito

Masters Theses

Wetlands are now recognized for the many social, environmental, ecological, and economic benefits they provide. They improve water quality, support biodiversity, abate floods and storms, and provide local recreational areas. Historically, many wetlands have been drained or altered for residential, commercial, or agricultural use. Effective wetland restoration projects reestablish ecosystem services and mitigate legacy effects of land use change to create self-sustaining systems. However, a persisting lack of scientifically-vetted methodological and evaluation guidelines in the field of restoration ecology has caused many restoration efforts to fail to restore natural wetland hydrologic conditions. By definition, wetlands must be saturated, permanently or …

Algorithm Performance On The Estimation Of Cdom And Doc In The North Slopes Of Alaska, Monica Weisenbach

Masters Theses

Use of satellite imagery makes environmental monitoring easy and convenient with little of the logistics involved in planning sampling campaigns. Colored dissolved organic matter (CDOM) is an important component to track as a proxy for the large pool of dissolved organic carbon (DOC). In a world contending with the looming issue of global climate change, the ability to investigate the carbon cycle of inland to coastal environments allows for examination of the magnitude of carbon flowing through the system and potential changes over years. The Arctic region is a critical area for climate change impacts but is a difficult landscape …

Benjamin Smith Lyman: Geologist At The Intersection Of Hokkaido, Japan, And The United States, Benjamin Ashby

Masters Theses

Benjamin Smith Lyman was a geologist from Northampton, Massachusetts, who was contracted by the Japanese government in 1872 to carry out coal surveys on the island of Hokkaidō 北海道. What started out as a standard geological survey, quickly evolved into a lifelong interest in Japan for Lyman. The large collection of letters, books, photographs, and other documents housed under the Benjamin Smith Lyman Collection at the University of Massachusetts Amherst, serve as a primary source on both early relations between the Japanese and the West and the beginnings of the large network of academic writings which today can be classified …

Coastal Groundwater Catchments Of The Gulf Of Alaska, Aeon Russo

Masters Theses

High latitude mountain environments are experiencing disproportionately adverse effects in a currently changing climate. The Gulf of Alaska (GoA) region is an exemplar of this. Dramatic shifts are occurring in the region’s freshwater reservoirs as glaciers retreat more with each passing year. Research in the region places much focus on observing and predicting climate driven shifts in glacier mass balance, surface discharge, and associated nutrient fluxes to the ocean. On the other hand, coastal groundwater discharge (CGD) is given very little attention. Global and near-global estimates of CGD indicate variable results spanning an order of magnitude. Focusing on regionally specific …

Cover Crop Treatment Impacts On Selected Soil Health Indicators In Two Tennessee Long-Term No-Till Corn-Soybean Rotations, Adam A. Zimmerman

Masters Theses

Soil hydraulic conductivity (K_sat) and soil microbial biomass carbon (SMB-C) estimates in Tennessee no-till corn (Zea mays L.) and soybean (Glycine max L.) rotation systems may be changed with cover crops. This study assessed differences in K_sat rates and SMB-C values under common cover crop treatments of two no-till corn and soybean rotation systems in west and middle Tennessee. Wheat (Triticum aestivum L.), cereal rye (Secale cereale L.), wheat/crimson clover (Trifolium incarnatum L.), cereal rye/crimson clover, a five species mix (containing cereal rye, crimson …

Impact Of Calcium Carbonate Reactant Size And Mineralogy On Dolomite Stoichiometry, Katharine G. Rose

Masters Theses

Dolomite is a common, diagenetic, Mg-Ca carbonate mineral. Dolomitization occurs by a dissolution-precipitation reaction between a CaCO₃ precursor (calcite or aragonite) and Mg bearing fluids. The amount of Mg in dolomite, referred to as dolomite stoichiometry (mol% MgCO₃), varies in natural dolomites (38-50 mol% MgCO₃). Laboratory experiments have shown that dolomite stoichiometry is dependent on physiochemical factors of the diagenetic fluids (i.e., temperature, salinity, and Mg/Ca). The impact of the CaCO₃ precursor on stoichiometry, however, has not been studied directly. This study tests how the CaCO₃ precursor size (sieve size) and mineralogy (calcite …

Experimental Alteration Of Venusian Surface Basalts In A Hybrid Co2-So2 Atmosphere, Robert B. Reid

Masters Theses

Venus’ surface and interior dynamics remain largely unconstrained, due in great part to the major obstacles imposed by its 470°C, 90 bars surface conditions and its thick, opaque atmosphere. Orbiter-based thermal emission data provide an opportunity to characterize the Venus surface. However, interpretations of such spectra critically depend on understanding interactions between the planet’s surface basaltic rocks and its caustic, SO₂-bearing CO₂ atmosphere. Several studies, using remote sensing, thermodynamic modeling, and laboratory experiments have placed constraints on alteration mineralogies and rates. Yet constraint with respect to SO₂-mediated reactions with basalts of contrasting compositions remains incomplete. …

Using Low-Flow Sampling Data To Estimate Hydraulic Conductivity In Aquifers, Joy Kiefer

Masters Theses

Hydrogeologists sample wells to test aquifer water quality and use slug tests to estimate aquifer permeability. Robbins et al. (2009) proposed a more efficient way to obtain the goals of the two tests—the use of low-flow sampling and the use of the resulting flow rate and drawdown data to estimate aquifer hydraulic conductivity (K). The Robbins et al. method calculates K by using the slope of the best fit line from the graph of flow rate vs. drawdown for all low-flow pumping data collected at a well. When the method was applied to low-flow data from four Kalamazoo, MI, it …

Investigating Gallium Inclusion In Aluminum And Iron Oxyhydroxides, Corey A. Palmer

Masters Theses

Because Ga shares many physicochemical properties with Al and Fe, Ga may be able to incorporate into Al and Fe oxy-hydroxides. Understanding how Ga incorporates into these oxy-hydroxides may be crucial for finding Ga-rich bauxite deposits. In order to find the difference in Ga inclusion rates into oxy-hydroxides, as well as understand the mechanisms for this Ga inclusion, Al and Fe oxy-hydroxides were synthesized in the lab with Ga additions of 2 mol % Ga and 20 mol % Ga for a low-Ga and high-Ga treatment, respectively, along with a no added Ga control. X-Ray diffraction analyses confirmed the formation …

Preclassic Cultural Eutrophication Of Lake Petén Itzá, Lowland Guatemala, By The Early Maya Of Nixtun-Ch'ich', Brooke A. Birkett

Masters Theses

"Paleolimnological evidence indicates the ancient Maya transformed lowland terrestrial ecosystems by felling forest vegetation to construct large civic-ceremonial centers and expand agriculture. The effects of prehistoric Maya land alterations on lake trophic status, however, remain poorly understood. We analyzed a 515-cm-long sediment core from Lake Petén Itzá, lowland Guatemala, to infer paleoenvironmental changes resulting from Maya occupation of the riparian archaeological site of Nixtun-Ch'ich'. Substantial increases in charcoal and fecal stanol concentrations indicate Maya occupation of the Candelaria Peninsula by the late Early Preclassic period beginning ca. 1400 cal yr Before the Common Era (hereafter BCE), despite scant archaeological evidence …

Multiple Generations Of Phlogopite In An Alnöite Diatreme: Insights Into The Petrogenesis Of The Avon Alkaline Igneous Province, Missouri, Nathan Gregory Limbaugh

Masters Theses

“Alkaline Ultramafic Carbonatite (AUC) complexes, although rare, are valued for diamonds and REEs, and as windows into subcontinental and mantle processes as recorded by rock fabrics, mineral spatial relationships, and mineral compositions. We report specifically on olivine and phlogopite petrographic relationships and compositions from the Devonian alnoite diatreme-facies of the Avon Alkaline Igneous Province, Missouri. The diatreme alnoite is a mixture of domains of olivine magmaclasts (OM) set in a crystal-rich melilite matrix. OM are highly fractured, serpentinized olivine pseudomorphs with variable amounts of pristine olivine fragments. Larger olivine domains typically exhibit clear crystal faces and irregular “channels” indicative of …

Relationships Among Mineralogy, Geochemistry, And Oil And Gas Production In The Tuscaloosa Marine Shale, Hayley Roxana Beitel

Masters Theses

"The Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir located in southeast Louisiana and southwest Mississippi. Limited mineralogical and geochemical data for the TMS have been published. The data that do exist indicate that the formation is heterogeneous. Consequently, previous investigators and oil and gas companies have not managed to effectively link mineralogical and chemical changes to oil and gas production in the TMS. These linkages are critical to establish for future exploration efforts. In this study, we attempt to establish these relationships by gathering all existing mineralogical and chemical data in the TMS, including newly acquired data from …

Does Invasion Science Encompass The Invaded Range? A Comparison Of The Geographies Of Invasion Science Versus Management In The U.S., Lara Munro

Masters Theses

Biases in invasion science lead to a taxonomic focus on plants, particularly a subset of well-studied plants, and a geographic focus on invasions in Europe and North America. Geographic biases could also cause some branches of invasion science to focus on a subset of environmental conditions in the invaded range, potentially leading to an incomplete understanding of the ecology and management of plant invasions. While broader, country-level geographic biases are well known, it is unclear whether these biases extend to a finer scale and thus affect research within the invaded range. This study assessed whether research sites for ten well-studied …

Crustal Evolution Of The New England Appalachians: The Rise And Fall Of A Long-Lived Orogenic Plateau, Ian Hillenbrand

Masters Theses

The rise and demise of mountain belts, caused by growth, modification, or removal of the continental lithosphere are fundamental processes that influence almost all Earth systems. Understanding the nature, timing, and significance of active processes in the creation and evolution of modern mountain belts is challenged by a lack of middle crustal and lower crustal exposures. Analogues can be found in ancient orogens, whose deeply eroded roots offer a window into deeper processes, yet this record is complicated by overprinting events and complex deformational histories. Research presented herein constrains the tectonic history of multistage Appalachian Orogen, type locality of the …

Magnetite Mineralization Of The Hammondville Pluton: Poly-Phase Kiruna Type Iocg Magnetite-Apatite Deposits In The Lyon Mountain Granite, Phillip Geer

Masters Theses

Recent mapping of the Eagle Lake Quadrangle, NY, coupled with whole-rock geochemistry and microscopy has offered insight into the petrogenesis of the magnetite-apatite deposits of the Hammondville mining district in the eastern Adirondack Mountains. This study provides insight into the magmatic history of the ca. 1060-1050 Ma Lyon Mountain Granite (Hammondville Pluton) which is intimately related to, and hosts the deposits in this area. Magnetite seams are commonly surrounded by well layered magnetite gneiss, which typically parallel the seams, although in some outcrops appear to be slightly truncated by them. Mineralization is generally concordant with the weak layering found throughout …

Enforcing Higher Standards For Flood Hazard Mitigation In Vermont, Tamsin Flanders

Masters Theses

The state of Vermont faces increasing risk of costly damage from catastrophic flooding events as climate change increases the frequency of heavy rains and cumulative precipitation. In addition to increasing flood inundation risk, extreme precipitation events are leading to high rates damage from fluvial erosion—erosion caused by the force of floodwater and the materials it carries. As in all U.S. states, flood hazard governance in Vermont is shared by multiple levels of government and involves a complex compliance model that relies on local governments to regulate private property owners to achieve community, state, or federal goals.

To encourage municipalities to …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

Carbon Metabolism In Cave Subaerial Biofilms, Victoria E. Frazier

Masters Theses

Subaerial biofilms (SABs) grow at the interface between the atmosphere and rock surfaces in terrestrial and subterranean environments around the world. Multi-colored SABs colonizing relatively dry and nutrient-limited cave surfaces are known to contain microbes putatively involved in chemolithoautotrophic processes using inorganic carbon like carbon dioxide (CO₂) or methane (CH₄). However, the importance of CO₂ and CH₄ to SAB biomass production has not been quantified, the environmental conditions influencing biomass production and diversity have not been thoroughly evaluated, and stable carbon and nitrogen isotope compositions have yet to be determined from epigenic cave SABs. …

Late Paleozoic Ophiuroid Biodiversity Based On A Diverse Fauna From The Indian Springs Shale Member Of The Big Clifty Formation, Sulphur, Indiana, Usa, Nicholas Scott Smith

Masters Theses

Ophiuroids (brittle stars and basket stars) are a diverse echinoderm group (i.e. star fish, sea urchins, and sea lilies) found in almost all marine environments and often major components of seafloor communities. Originating in the early to middle Devonian, the group quickly diversified and is today the most species rich echinoderm clade. Unfortunately, our knowledge of their diversity and evolutionary pathways during the Late Paleozoic has been understudied leaving a large gap in our understanding of their true biodiversity. This can be attributed to study methods and a poor understanding of Paleozoic ophiuroid skeletal morphology. Ophiuroid skeletons are composed of …

Electron Microprobe In Situ Monazite Dating Of The Slide Lake Shear Zone, Jeremy Leierzapf

Masters Theses

The Colorado mineral belt (CMB) shear zone system records Proterozoic deformation episodes documenting the progressive tectonic accretion of Laurentia. Regional fold formation (D₁ & D₂) is coeval with the ca. 1700 – 1600 Ma Yavapai and Mazatzal orogenies, while Mesoproterozoic sub-vertical shear zones (D₃ & D₄) are a response to 1450 – 1300 Ma intracontinental deformation. The Slide Lake shear zone (SLSZ) is a sub-horizontal shear zone located in the Northern Sawatch Range, central Colorado. Aside from its orientation, the SLSZ records similar deformational structures to other shear zones in the CMB, but there …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Experimental Study Of The Alteration Of Basalt On The Surface Of Venus, Hannah Teffeteller

Masters Theses

Venus is the second planet from the sun, distinguished by its thick atmosphere which prevents visible observations of the surface. Our understanding of its surface is therefore dominated by surface interactions with electromagnetic radiation (e.g. radar, visible-to-infrared, and X-ray wavelengths) which have been collected by a series of missions including the Soviet’s Venera missions, the National Aeronautics and Space Administration’s (NASA) Magellan mission, and the European Space Agency’s (ESA) Venus Express orbiter (Barsukov et al. 1982; Head et al. 1992; Smrekar et al. 2010). The atmosphere of Venus is composed almost entirely (~97%) of CO2 gas with trace amounts of …