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The Chemistry Of My Affections, David Scott Smith Jan 2005

The Chemistry Of My Affections, David Scott Smith

LSU Master's Theses

Although I have always been interested in the origins of my thought processes and the methods and compulsions that motivate my work, in past work I have avoided self portraiture, or blatant explorations into my own sense of self. With my thesis project I wanted to conduct an express exploration into the psychology of my motivations. My initial goal was to create an environment, a sense of place, where both the viewer and myself are drawn into the work, and confronted with a unique experience of personal expression. The focal point is a bath enclosed within a grotto, which symbolizes …


Shear Induced Orientation In Polymer-Clay Solutions And Their Influence On The Structure In Multilayered Films, Matthew Michael Malwitz Jan 2005

Shear Induced Orientation In Polymer-Clay Solutions And Their Influence On The Structure In Multilayered Films, Matthew Michael Malwitz

LSU Doctoral Dissertations

The influence of shear on viscoelastic solutions of poly(ethylene oxide) (PEO) and clay (Cloisite, CNA) was investigated by rheology and small angle neutron scattering (SANS) under shear. These measurements determined the shear-induced orientation of the clay and the polymer as well as their relaxation behavior after cessation of shear. Comparison of PEO-CNA solutions (~100 nm diameter platelets) to previously studied PEO-Laponite gels (~30 nm diameter platelets) found that the orientation of CNA platelets occurs at much lower shear rates. Additionally, the relaxation times were much longer for CNA platelets than for Laponite platelets. From these solutions and gels, multilayered nanocomposite …