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Experimental Studies And Modeling Of Mechanical Properties And Morphologies Of In Situ Polymer Composites, Zhigang Li
Experimental Studies And Modeling Of Mechanical Properties And Morphologies Of In Situ Polymer Composites, Zhigang Li
Dissertations
In this study, a series of experiments was set up in order to analyze the morphology development and mechanical properties of poly(ethylene terephthalate) (PET)/ liquid crystalline polymer (LCP) blends. Simulations of the injection molded blends at various process conditions were performed using CMOLD. In order to determine the effect of the processing parameters on the deformation of the LCP domains during the injection molding, a new analytical method to analyze the melt flow in the advancing melt front (AMF) region was developed. By combining the simulations of the injection molding and analysis of the melt flow in the AMF region, …
Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn
Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn
Faculty Publications
Plasticizers modify the mechanical properties of polymericmaterials. The effects of plasticizers on glass transition temperatures can be most clearly observed in isochronal temperature sweep profiles of viscoelastic dynamic moduli. However, no simple mathematical models of plasticization are available to those who wish to design and employ plasticized materials in specific applications. We extend a phenomenological, molecular-level model (known as the tube–junction model) for crosslinked polymers to describe the effect of plasticizers on dynamic moduli. We show that the increase in free volume fraction due to the presence of the plasticizer can account for the shift in the glass transition in …