Digital Commons Network^™

Optimal Molecular Dynamics System Size For Increased Precision And Efficiency For Epoxy Materials, Khatereh Kashmari, Sagar Patil, Josh Kemppainen, Shankara Gowtham, Gregory Odegard

Michigan Tech Publications, Part 2

Molecular dynamics (MD) simulation is an important tool for predicting thermo-mechanical properties of polymer resins at the nanometer length scale, which is particularly important for efficient computationally driven design of advanced composite materials and structures. Because of the statistical nature of modeling amorphous materials on the nanometer length scale, multiple MD models (replicates) are typically built and simulated for statistical sampling of predicted properties. Larger replicates generally provide higher precision in the predictions but result in higher simulation times. Unfortunately, there is insufficient information in the literature to establish guidelines between MD model size and the resulting precision in predicted …

Wire Texture C-Axis Distribution Of Strontium Ferrite/Pa-12 Extruded Filament, Gabriela Espinosa-Rodriguez, Oluwasola Arigbabowo, Jonathan Alvarado, Jitendra Tate, Wilhelmus J. Geerts

Mechanical Engineering Faculty Publications and Presentations

The magnetic anisotropy of strontium ferrite (SF)/PA12 filament, a popular hard magnetic ferrimagnetic composites that is used for 3D-printing of permanent magnets, is studied by vibrating sample magnetometry. The studied filaments have a composition of SF/PA-12 thermoplastic composite with a 40% wt.  ratio of SF. SF particles are non-spherical platelets with an average diameter of 1.3 um and a diameter to thickness ratio of 3. Filaments are produced by a twin-screw extruder and have a diameter of 1.5 mm. SEM images show that the SF particles are homogeneously distributed through the filament. VSM measurements on different parts of the filaments …

Rapid Prediction Of Phonon Density Of States By Graph Neural Network And High-Throughput Screening Of Candidate Substrates For Wide Bandgap Electronic Cooling, Mohammed Saif Ali Al-Fahdi

Theses and Dissertations

Machine learning has demonstrated superior performance in predicting vast materials properties. However, predicting a continuous material property such as phonon density of states (DOS) is more challenging for machine learning due to the inherent issues of data smoothing and sensitivity to peak positions. In this work, phonon DOS of 2,931 inorganic cubic structures with 63 unique elements from the Open Quantum Materials Database are calculated by high precision density functional theory (DFT). With these training data, we build an equivariant graph neural network (GNN) for total phonon DOS of crystalline materials that utilizes site positions and atomic species as input …

Non-Destructive Infrared Thermographic Curing Analysis Of Polymer Composites, Md Ashiqur Rahman, Javier Becerril, Dipannita Ghosh, Nazmul Islam, Ali Ashraf

Mechanical Engineering Faculty Publications and Presentations

Infrared (IR) thermography is a non-contact method of measuring temperature that analyzes the infrared radiation emitted by an object. Properties of polymer composites are heavily influenced by the filler material, filler size, and filler dispersion, and thus thermographic analysis can be a useful tool to determine the curing and filler dispersion. In this study, we investigated the curing mechanisms of polymer composites at the microscale by capturing real-time temperature using an IR Thermal Camera. Silicone polymers with fillers of Graphene, Graphite powder, Graphite flake, and Molybdenum disulfide (MoS₂) were subsequently poured into a customized 3D printed mold for …

Study Of Nanocomposite Materials Using Molecular Dynamics, Prashik Sunil Gaikwad

Dissertations, Master's Theses and Master's Reports

There is an increase in demand for new lightweight structural materials in the aerospace industry for more efficient and affordable human space travel. Polymer matrix composites (PMCs) with reinforcement material as carbon nanotubes (CNTs) have shown exceptional increase in the mechanical properties. Flattened carbon nanotubes (flCNTs) are a primary component of many carbon nanotube (CNT) yarn and sheet materials, which are promising reinforcements for the next generation of ultra-strong composites for aerospace applications. These flCNT/polymer materials are subjected to extreme pressure and temperature during curing process. Therefore there is a need to investigate the evolution of properties during the curing …

Monitoring Of State Transitions In Extreme Environment Application Materials Using Fiber Bragg Grating Sensors, Sabuj Khadka

Electronic Theses and Dissertations

By embedding both a single fiber Bragg grating (FBG) sensor and a thermocouple (TC) during the manufacturing for extreme environment applications of certain classes of materials such as metals and polymers, a novel in-situ approach was developed to precisely monitor their entire manufacturing processes. This novel monitoring technique was able to identify many characteristic points during the curing of room and high-temperature epoxies and the solidification processes of metal alloys composed of tin and bismuth which were selected in this research purely for verification purposes. Some of the characteristic points identified for the epoxies were: (i) the gel point, (ii) …

Testing And Characterization Of Polymer Laminates For Swelling, Absorption, And Cracking, Matthew W. Carlson

Master's Theses

A polymer laminate consisting of multiple layers of proprietary blends of Ethylene Vinyl Alcohol (EVOH) and Thermoplastic Polyurethane (TPU) and used in the construction of air bladders was evaluated for hygroscopic effects driving delamination and multiple layer fragmentation. These air bladders are observed to suffer delamination during a manufacturing process that involves immersion in an alcohol/water solution. A plausible underlying mechanism is differential swelling and absorption by the laminate constituents. Both room and elevated temperature swelling tests were carried out to find the absorption and swelling coefficients of the constituents. These coefficients served as input into a Finite Element Analysis …

Open Source Waste Plastic Granulator, Arvind Ravindran, Sean Scsavnicki, Walker Nelson, Peter Gorecki, Jacob Franz, Shane Oberloier, Theresa K. Meyer, Andrew Barnard, Joshua M. Pearce

Michigan Tech Publications

In order to accelerate deployment of distributed recycling by providing low-cost feed stocks of granulated post-consumer waste plastic, this study analyzes an open source waste plastic granulator system. It is designed, built, and tested for its ability to convert post-consumer waste, 3D printed products and waste into polymer feedstock for recyclebots of fused particle/granule printers. The technical specifications of the device are quantified in terms of power consumption (380 to 404 W for PET and PLA, respectively) and particle size distribution. The open source device can be fabricated for less than $2000 USD in materials. The experimentally measured power use …

Prototyping A Conductive Polymer Steering Pad For Rail Freight Service, Anthony A. Villarreal, Constantine Tarawneh, Miguel Ontiveros, James Aranda, Robert Jones

Mechanical Engineering Faculty Publications and Presentations

The AdapterPlus™ steering pad is a polymer component on a railcar that helps to reduce stresses on the axle as a railcar rounds a curve. One railway application requires a minimum of 240 mA to be passed through the steering pad to the rail, which activates air valves that control automated cargo gates. Currently, two copper studs are inserted into the pad to provide a conductive path. However, after continuous cyclic loading caused by normal service operation, the copper studs deform, wear, and eventually lose contact between the two surfaces rendering the pad nonconductive. One proposed solution to this problem …

Mechanical Properties And Applications Of Recycled Polycarbonate Particle Material Extrusion-Based Additive Manufacturing, Matthew J. Reich, Aubrey Woern, Nagendra Gautam Tanikella, Joshua M. Pearce

Michigan Tech Publications

Past work has shown that particle material extrusion (fused particle fabrication (FPF)/fused granular fabrication (FGF)) has the potential for increasing the use of recycled polymers in 3D printing. This study extends this potential to high-performance (high-mechanical-strength and heat-resistant) polymers using polycarbonate (PC). Recycled PC regrind of approximately 25 mm² was 3D printed with an open-source Gigabot X and analyzed. A temperature and nozzle velocity matrix was used to find useful printing parameters, and a print test was used to maximize the output for a two-temperature stage extruder for PC. ASTM type 4 tensile test geometries as well as ASTM-approved …

Impact Of Pulse Length On The Accuracy Of Defect Depth Measurements In Pulse Thermography, James Pierce, Nathan B. Crane

Faculty Publications

Pulse thermography is a nondestructive testing method in which an energy pulse is applied to a surface while the surface temperature evolution is measured to detect sub surface defects and estimate their depth. This nondestructive test method was developed on the assumption of instantaneous surface heating, but recent work has shown that relatively long pulses can be used to accurately determine defect depth in polymers. This paper examines the impact of varying input pulse length on the accuracy of defect depth quantification as a function of the material properties. Simulations using both thermoplastics and metals show that measurement error is …

Use Of Flexible Sensor To Characterize Biomechanics Of Canine Skin, Austin Downey, Jin Yan, Eric M. Zellner, Karl H. Kraus, Iris V. Rivero, Simon Laflamme

Faculty Publications

Background Suture materials and techniques are frequently evaluated in ex vivo studies by comparing tensile strengths. However, the direct measurement techniques to obtain the tensile forces in canine skin are not available, and, therefore, the conditions suture lines undergo is unknown. A soft elastomeric capacitor is used to monitor deformation in the skin over time by sensing strain. This sensor was applied to a sample of canine skin to evaluate its capacity to sense strain in the sample while loaded in a dynamic material testing machine. The measured strain of the sensor was compared with the strain measured by the …

Chemo-Thermo Cure Of Viscoelastic Materials For Semiconductor Packaging Applications, Anjali Pradeep Kumar

Dissertations and Theses

Viscoelastic polymer materials are being actively considered as a novel material for semiconductor packaging applications as a result of their ability to develop strong adhesive bonds at lower temperatures. Viscoelastic thermoset materials are impacted by the stresses generated during the curing process, which is also accompanied by a dissipation of thermal energy. There is a need to develop a generic modeling formulation that is applicable to any material of interest in order to enable the study of different bonding materials and develop optimized curing cycles. This study reports a numerical formulation to evaluate the stress generated and energy dissipated during …

Gnygrens18.Pdf, Garrett Nygren

Garrett Nygren

Microstructural Characterization Of Shear Transformation Zones And Modeling Indentation Size Effect In Amorphous Polymers, Leila Malekmotiei

LSU Doctoral Dissertations

The first aim of this work is developing a procedure for experimental and analytical characterization of nano-scale microstructures which mediate large scale deformation in amorphous polymers. Glassy polymers are extensively used as high impact resistant, low density, and clear materials in industries. Nevertheless, their response under severe loading conditions is yet to be appropriately unraveled. Due to the lack of long-range order in the microstructures of glassy solids, their plastic deformation is different from that in crystalline solids. Shear Transformation Zones (STZs) are believed to be the main plasticity carriers in amorphous solids and defined as the localized atomic or …

Impact Of Hysteresis Heating Of Railroad Bearing Thermoplastic Elastomer Suspension Pad On Railroad Bearing Thermal Management, Oscar O. Rodriguez, Arturo A. Fuentes, Constantine Tarawneh

Mechanical Engineering Faculty Publications and Presentations

It is a known fact that polymers and all other materials develop hysteresis heating due to the viscoelastic response or internal friction. The hysteresis or phase lag occurs when cyclic loading is applied leading to the dissipation of mechanical energy. The hysteresis heating is induced by the internal heat generation of the material, which occurs at the molecular level as it is being disturbed cyclically. Understanding the hysteresis heating of the railroad bearing elastomer suspension element during operation is essential to predict its dynamic response and structural integrity, as well as to predict the thermal behavior of the railroad bearing …

Fabrication And Characterizations Of Lithium Aluminum Titanate Phosphate Solid Electrolytes For Li-Based Batteries, Anurag Yaddanapudi

Browse all Theses and Dissertations

Demands for electric vehicles and flexible electronics have escalated research in developing high-performance lithium batteries based on solid-state chemistry. The present work is to develop highly-conductive and flexible solid electrolyte for such applications. Lithium aluminum titanate phosphate (LATP or Li1.3Al0.3Ti1.7(PO4)3), both in ceramic pellets and free-standing composite membranes, have been fabricated. The crystal structure, surface morphology, and ionic conductivity are systematically studied. LATP pellets are prepared using solid state reaction approach. The results indicate that calcine temperature has significant impacts on the phase impurity and sintering temperature and duration have more impacts on the grain size and porosity of LATP …

Design, Fabrication, And Properties Of 2-2 Connectivity Cement/Polymer Based Piezoelectric Composites With Varied Piezoelectric Phase Distribution, Xu Dongyu, Cheng Xin, Sourav Banerjee, Huang Shifeng

Sourav Banerjee

The laminated 2-2 connectivity cement/polymer based piezoelectric composites with variedpiezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramicas active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction ofpiezoelectric phase have large piezoelectric strain constant and relative permittivity, and thepiezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction of piezoelectric phase have large …

Synthesis, Characterization, And Electrochemical Properties Of Polyaniline Thin Films, Soukaina Rami

USF Tampa Graduate Theses and Dissertations

Conjugated polymers have been used in various applications (battery, supercapacitor, electromagnetic shielding, chemical sensor, biosensor, nanocomposite, light-emitting-diode, electrochromic display etc.) due to their excellent conductivity, electrochemical and optical properties, and low cost. Polyaniline has attracted the researchers from all disciplines of science, engineering, and industry due to its redox properties, environmental stability, conductivity, and optical properties. Moreover, it is a polymer with fast electroactive switching and reversible properties displayed at low potential, which is an important feature in many applications. The thin oriented polyaniline films have been fabricated using self-assembly, Langmuir-Blodgett, in-situ self-assembly, layer-by-layer, and electrochemical technique. The focus of …

Investigating The Surface Tribology Of Roller-Burnished Polymer Using The Fuzzy Rule-Based Approach

Faculty of Engineering University of Malaya

Burnishing is specified as the plastic deformation cold working process applied as surface treatment and smoothing following machining to obtain a superior surface roughness finish. The present experimental study was carried out on roller-burnished polyurethane using a roller burnishing tool. An analysis was done to investigate the effect of burnishing depth, speed, feed rate, and roller width on the surface roughness of the polymer workpiece. Roughness (R-a) prediction was achieved with a fuzzy rule-based system. The results indicate 95% accuracy between the fuzzy predicted roughness values and experimental results. Link to Full-Text Articles : www.tandfonline.com/doi/abs/10.1080/10402004.2014.962205

Fabrication And Characterization Of Silver- And Copper-Coated Nylon 6 Forcespun Nanofibers By Thermal Evaporation, Dorina M. Mihut, Karen Lozano, Heinrich D. Foltz

Mechanical Engineering Faculty Publications and Presentations

Silver and copper nanoparticles were deposited as thin films onto substrates consisting of Nylon 6 nanofibers manufactured using forcespinningR equipment. Different rotational speeds were used to obtain continuous nanofibers of various diameters arranged as nonwoven mats. The Nylon 6 nanofibers were collected as successive layers on frames, and a high-vacuum thermal evaporation method was used to deposit the silver and copper thin films on the nanofibers. The structures were investigated using scanning electron microscopy–scanning transmission electron microscopy, atomic force microscopy, x-ray diffraction, and electrical resistance measurements. The results indicate that evaporated silver and copper nanoparticles were successfully deposited on Nylon …

Phase Field Modeling Of Shear Yielding And Crazing In Glassy Polymer, Yunzhe Mao

Open Access Theses

Glassy polymers are very important in industrial and commercial components manufacturing. For instance, it is used to manufacture polymer-matrix composites, the type of composite used in the Dreamliner 787. But this kind of material is also limited by its tendency to fail in brittle manner. In this study, we use phase field model to characterize the yielding condition of glassy amorphous polymer under a wide range of loading conditions. The main failure mechanisms in amorphous glassy polymers, such as poly-methyl-methacrylate (PMMA), are crazing and shear yielding. Crazing is formed because of the nucleation of micro-voids in the location of stress …

Design, Fabrication, And Properties Of 2-2 Connectivity Cement/Polymer Based Piezoelectric Composites With Varied Piezoelectric Phase Distribution, Xu Dongyu, Cheng Xin, Sourav Banerjee, Huang Shifeng

Faculty Publications

The laminated 2-2 connectivity cement/polymer based piezoelectric composites with variedpiezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramicas active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction ofpiezoelectric phase have large piezoelectric strain constant and relative permittivity, and thepiezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction of piezoelectric phase have large …

New Topics On Nanoindentation Of Polymers And Composite Materials, Ricardo Martinez-Hernandez

Open Access Theses & Dissertations

In this study, nanoindentation was used to determine Young's modulus of homogeneous plastic materials as well as inhomogeneous epoxy woven fabric composites using various indenters. In the first part, homogeneous PMMA and polycarbonate were characterized using conical and spherical indenters. The conventional approach of the inverse analysis was modified in order to account for effects obtained during spherical nanoindentation. The experimental results were verified using FEA analysis in ABAQUS. It was found that viscous effects were present in conical nanoindentations which led to an overestimation of contact stiffness. The second part, the response of carbon and glass fiber woven fabric …

Thromboresistance Characterization Of Extruded Nitric Oxide Releasing Silicone Catheters, Kagya Amoako, Christopher Archangeli, Hitesh Handa, Terry Major, Mark E. Meyerhoff, Gail M. Annich, Robert H. Bartlett

Mechanical and Industrial Engineering Faculty Publications

Intravascular catheters used in clinical practice can activate platelets, leading to thrombus formation and stagnation of blood flow. Nitric oxide (NO)-releasing polymers have been shown previously to reduce clot formation on a number of blood contacting devices. In this work, trilaminar NO-releasing silicone catheters were fabricated and tested for their thrombogenicity. All catheters had specifications of L = 6 cm, inner diameter = 21 gauge (0.0723 cm), outer diameter = 12 gauge (0.2052 cm), and NO-releasing layer thickness = 200 ± 11 µm. Control and NO-releasing catheters were characterized in vitro for their NO flux and NO release duration by …

Long Term Outdoor Testing Of Low Concentration Solar Modules, Lewis Fraas, James Avery, Leonid Minkin, H. X. Huang, Tim Hebrink, Robert F. Boehm

Mechanical Engineering Faculty Research

A 1‐axis carousel tracker equipped with four 3‐sun low‐concentration mirror modules has now been under test outdoors at the University of Nevada in Las Vegas (UNLV) for three years. There are three unique features associated with this unit. First, simple linear mirrors are used to reduce the amount of expensive single crystal silicon in order to potentially lower the module cost while potentially maintaining cell efficiencies over 20% and high module efficiency. Simple linear mirrors also allow the use of a single axis tracker. Second, the azimuth carousel tracker is also unique allowing trackers to be used on commercial building …

Stress-Strain Behavior Of Perfluorosulfonic Acid Membranes At Various Temperatures And Humidities: Experiments And Phenomenological Modeling, Ahmet Kusoglu, Yaliang Tang, Michael Santare, Anette M. Karlsson, Simon Cleghorn, William B. Johnson

Mechanical Engineering Faculty Publications

The constitutive response of perfluorinated sulfonic acid (PFSA) membranes based on tensile testing is investigated, and a phenomenological constitutive model for the elastoplastic flow behavior as a function of temperature and humidity is proposed. To this end, the G'Sell–Jonas (1979, “Determination of the Plastic Behavior of Solid Polymers at Constant True Strain Rate,” J. Mater. Sci., 14, pp. 583–591) constitutive model for semicrystalline polymers is extended by incorporating, in addition to temperature, relationships between the material constants of this model and the measured relative humidity. By matching the proposed constitutive model to the experimental stress-strain data, useful material constants …

Characterizationn Of Polumer-Based Mems Pyroelectic Infrared Detector, Mark E. Allard

Theses and Dissertations

AFRL/MLPJE had developed a novel thermal sensing material termed protein-impregnated-polymer (PIP). Thus far, a proof-of-concept has been demonstrated using a macro-sized pixel (0.64 mm²) as a bolometric detector. In an effort to better characterize this novel thermal sensing material, experimental data was used to determine figures of merit (FOMs) comparative to off-the-shelf thermal detectors. Microelectromechanical (MEMS) pixels were designed and used as the support structure for an inkjet-deposited droplet of the PIP. During the material characterization, two observations were made: PIP is a pyroelectric material, and the polymer (polyvinyl alcohol (PVA)) without the protein was found to be …

Acoustic Emission Detection And Prediction Of Fatigue Crack Propagation In Composite Patch Repairs Using Neural Networks, Navdeep Singh, Navrag Singh, Anthony Chukwujekwu Okafor

Mechanical and Aerospace Engineering Faculty Research & Creative Works

An aircraft is subjected to severe structural and aerodynamic loads during its service life. These loads can cause damage or weakening of the structure especially for aging military and civilian aircraft, thereby affecting its load carrying capabilities. Hence composite patch repairs are increasingly used to repair damaged aircraft metallic structures to restore its structural efficiency. This paper presents the results of Acoustic Emission (AE) monitoring of crack propagation in 2024-T3 Clad aluminum panels repaired with adhesively bonded octagonal, single sided boron/epoxy composite patch under tension-tension fatigue loading. Crack propagation gages were used to monitor crack initiation. The identified AE sensor …

Solid State Aircraft Concept Overview, M. Shahinpoor, P. Jenkins, C. Smith, Kakkattukuzhy M. Isaac, T. Dalbello, Anthony Colozza

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Due to recent advances in polymers, photovoltaics, and batteries a unique type of aircraft may be feasible. This is a "solid-state" aircraft, with no conventional mechanical moving parts. Airfoil, propulsion, energy production, energy storage and control are combined in an integrated structure. The key material of this concept is an ionic polymeric-metal composite (IPMC) that provides source of control and propulsion. This material has the unique capability of deforming in an electric field and returning to its original shape when the field is removed. Combining the IPMC with thin-film batteries and thin-film photovoltaics provides both energy source and storage in …