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Corrosion Mechanism Of Copper In Palm Biodiesel
Corrosion Mechanism Of Copper In Palm Biodiesel
A.S. Md Abdul Haseeb
Biodiesel is a promising alternative fuel. However, it causes enhanced corrosion of automotive materials, especially of copper based components. In the present study, corrosion mechanism of copper was investigated by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Compositional change of biodiesel due to the exposure of copper was also investigated. Corrosion patina on copper is found to be composed of Cu2O, CuO, Cu(OH)2 and CuCO3. Dissolved O2, H2O, CO2 and RCOO- radical in biodiesel seem to be the leading factors in enhancing the corrosiveness of biodiesel. © 2012 Elsevier Ltd.
Stress Enhanced Tio2 Nanowire Growth On Ti-6al-4v Particles By Thermal Oxidation
Stress Enhanced Tio2 Nanowire Growth On Ti-6al-4v Particles By Thermal Oxidation
A.S. Md Abdul Haseeb
Titanium dioxide (TiO2) nanowires were grown on Ti - 6wt% Al - 4wt% V (Ti64) particles by thermal oxidation. To investigate the effect of stress on nanowire growth, the particles were milled in a planetary ball mill prior to the thermal oxidation. Thermal oxidation of the Ti64 particles was carried out in a horizontal tube furnace in a controlled oxygen atmosphere in the temperature range of 700-900 °C. The oxygen concentration was varied from 20 ppm to 80 ppm in Ar atmosphere. Nanostructures were characterized by high resolution field emission scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. TiO2 …
Effect Of Temperature On The Corrosion Behavior Of Mild Steel Upon Exposure To Palm Biodiesel
Effect Of Temperature On The Corrosion Behavior Of Mild Steel Upon Exposure To Palm Biodiesel
A.S. Md Abdul Haseeb
Recently biodiesel, as an alternative fuel is getting more significance to replace diesel fuel completely or partially. However, corrosion of automotive materials in biodiesel is a major concern as this can reduce engine life. This study aims to investigate the corrosion behavior of mild steel at three different temperatures such as room temperature, 50 and 80 °C. Static immersion tests in B0 (diesel), B50 (50% biodiesel in diesel), B100 (biodiesel) were carried out for 1200 h. At the end of the tests, corrosion characteristic was investigated by weight loss measurements and changes of the exposed metal surface. Fuels were analyzed …
Interfacial Reaction And Dissolution Behavior Of Cu Substrate In Molten Sn-3.8ag-0.7cu In The Presence Of Mo Nanoparticles
A.S. Md Abdul Haseeb
Purpose - In electronic packaging, when solid copper comes in contact with liquid solder alloy, the former dissolves and intermetallic compounds (IMCs) form at the solid-liquid interface. The purpose of this paper is to study the effect of the presence of molybdenum nanoparticles on the dissolution of copper and the formation of interfacial IMC. Design/methodology/approach - Cu wire having a diameter of 250 μm is immersed in liquid composite solders at 250° up to 15 min. Composite solder was prepared by adding various amount of Mo nanoparticles into the Sn-3.8Ag-0.7Cu (SAC) solder paste. The dissolution behavior of Cu substrate is …
Chemical And Structural Nature Of Tribo-Surface Of Aluminium-Sic Composites At Nanometre And Micrometre Length Scales
A.S. Md Abdul Haseeb
The worn surface of Al-SiC metal matrix composites (MMC) sliding against phenolic brake pad at a linear sliding speed of 1.62 m s-1 under contact pressures of 0.75-3.00 MPa in a pin-on-disc apparatus was investigated. XPS was used to extract information from the top few nanometres of the worn surface, while scanning electron microscopy and energy dispersive X-ray microanalysis (SEM-EDX) provided information from within a few micrometres. Results reveal that the surface of Al-SiC undergoes significant chemical and physical changes during wear. The tribo-surface on Al-SiC is converted into a mixture that contains the constituents of Al-SiC and the phenolic …
Velocity Effects On The Wear, Friction And Tribochemistry Of Aluminum Mmc Sliding Against Phenolic Brake Pad
A.S. Md Abdul Haseeb
Two aluminum metal matrix composites (MMC) reinforced with 13 vol.% of SiC or B4C particles were made by stir casting followed by hot extrusion. Effects of sliding velocity on the wear, friction and tribochemistry of the worn surfaces of both composites sliding against a commercial phenolic brake pad have been investigated under dry condition. The wear tests were carried out using a pin-on-disc type apparatus at two linear sliding speeds: 1.62 and 4.17 m s-1 under a constant contact pressure of 0.75 MPa for a sliding distance of 5832 m. The coefficient of friction was recorded and wear rate of …
Velocity Effects On The Wear, Friction And Tribochemistry Of Aluminum Mmc Sliding Against Phenolic Brake Pad
A.S. Md Abdul Haseeb
Two aluminum metal matrix composites (MMC) reinforced with 13 vol.% of SiC or B4C particles were made by stir casting followed by hot extrusion. Effects of sliding velocity on the wear, friction and tribochemistry of the worn surfaces of both composites sliding against a commercial phenolic brake pad have been investigated under dry condition. The wear tests were carried out using a pin-on-disc type apparatus at two linear sliding speeds: 1.62 and 4.17 m s-1 under a constant contact pressure of 0.75 MPa for a sliding distance of 5832 m. The coefficient of friction was recorded and wear rate of …