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Steady-State Kinetics Of Br(2P1/2) Yields Co2(101) Electronic-To-Vibrational Energy Transfer Laser System, Stephen J. Karis Nov 1995

Steady-State Kinetics Of Br(2P1/2) Yields Co2(101) Electronic-To-Vibrational Energy Transfer Laser System, Stephen J. Karis

Theses and Dissertations

Steady state photolysis experiments were conducted to gain information relevant to the construction of a continuous wave electronic to vibrational pumped infrared laser. An Ar+ laser =488 µm) was used to produce the electronically excited state Br(2P1/2) (Br*) via photolysis of molecular bromine. Energy was then transferred to the near resonant vibrational state CO2(101) (CO2) via the collisional quenching of Br* by CO2. The dependence of the 2.71 µm Br* and 4.3 µm CO2 emissions on CO2 pressure was measured, as well as …


Non-Imaging Infrared Spectral Target Detection, Matthew R. Whiteley Sep 1995

Non-Imaging Infrared Spectral Target Detection, Matthew R. Whiteley

Theses and Dissertations

Automatic detection of time-critical mobile targets using spectral-only infrared radiance data is explored. A quantification of the probability of detection, false alarm rate, and total error rate associated with this detection process is provided. A set of classification features is developed for the spectral data, and these features are utilized in a Bayesian classifier singly and in combination to provide target detection. The results of this processing are presented and sensitivity of the class separability to target set, target configuration, diurnal variations, mean contrast, and ambient temperature estimation errors is explored. This work introduces the concept of atmospheric normalization of …


Optical Characterization Of Indium Arsenide Antimonide Semiconductors Grown By Molecular Beam Epitaxy, Michael A. Marciniak Sep 1995

Optical Characterization Of Indium Arsenide Antimonide Semiconductors Grown By Molecular Beam Epitaxy, Michael A. Marciniak

Theses and Dissertations

The material parameters and crystalline quality of undoped, MBE-grown InAs1-xSbx nearly lattice-matched to (100) GaSb (-0.617% ≤ Δ a-a ≤ +0.708%) similar to material used for mid-infrared semiconductor lasers were determined by optical characterization. Absorption measurements at temperatures between 6-295 K determined the energy gap and wavelength-dependent absorption coefficient for each sample. The compositional dependence of the energy gap was anomalous when compared to previously reported data, suggesting phase separation existed in the material. The samples were also studied by temperature- and excitation-dependent photoluminescence (PL), which, for the majority of cases, showed only a single band-edge peak, …


Collisional Dynamics Of The Rubidium 52P Levels, Matthew D. Rotondaro Sep 1995

Collisional Dynamics Of The Rubidium 52P Levels, Matthew D. Rotondaro

Theses and Dissertations

The collisional dynamics of the 52P levels in rubidium has been examined using steady-state laser absorption and spectrally-resolved laser induced fluorescence techniques. State-to-state cross-sections for energy transfer between Zeeman split levels ranged from 16-248 °A2 for collisions with nitrogen and rare gases. These energy transfer cross-sections exhibit a significant dependence on (J,mj) state and certain symmetry relationships are demonstrated. A sub-Doppler spectrum of the Zeeman split levels indicating the isotopic shift in the D1 line of 106 ± 35 was obtained using laser saturation spectroscopy.


Ohmic Contact To Ion Implanted Gallium Arsenide Antimonide For Application To Indium Aluminum Arsenide-Gallium Arsenide Antimonide Heterostructure Insulated-Gate Field Effect Transistors, Kenneth G. Merkel Ii Jul 1995

Ohmic Contact To Ion Implanted Gallium Arsenide Antimonide For Application To Indium Aluminum Arsenide-Gallium Arsenide Antimonide Heterostructure Insulated-Gate Field Effect Transistors, Kenneth G. Merkel Ii

Theses and Dissertations

The p-channel In0.52Al0.48As-GaAs1-xSbx heterostructure insulated-gate field effect transistor (p-HIGFET) is a candidate for complementary integrated circuits due to superior cutoff characteristics and low gate leakage current. Advancement of the In0.52Al0.48As-GaAs1-xSbx p-HIGFET requires improved source-drain design. Five main tasks were accomplished to achieve this goal. First, thermal limits of the In0.52Al0.48As-GaAs0.51Sb0.49 HIGFET were investigated. Second, the temperature dependence of band gap and impurity energies were determined for beryllium doped In0.52Al0.48. Third, high acceptor concentrations were obtained …


Optimal Wavefront Reconstruction For A Coherent Diffracted Field, William W. Arrasmith Jun 1995

Optimal Wavefront Reconstruction For A Coherent Diffracted Field, William W. Arrasmith

Theses and Dissertations

In sheared coherent beam interferometric imaging, an estimate of the average reflectivity profile of the object can be computed from measurements of point to point phase differences in the far field interference pattern and a suitable phase reconstruction technique. The phase difference information is encoded in the irradiance of three identical, shifted and superimposed speckled laser beam patterns. A minimum variance phase reconstruction technique is presented to estimate the phase of the field in the measurement plane from the phase differences and evaluate its performance. Prior knowledge of the phase covariance is used in the minimum variance reconstructor. Analytic calculations …


Generation Of A Single-Lobe, Far-Field Intensity Pattern From A Laser Diode Array Using An Optical Delay Line, Thomas A. Summers Dec 1994

Generation Of A Single-Lobe, Far-Field Intensity Pattern From A Laser Diode Array Using An Optical Delay Line, Thomas A. Summers

Theses and Dissertations

A simple and practical technique is demonstrated to generate a stable, single-lobe, far-field intensity pattern from a one-dimensional, antiphased, laser diode array with gain-guided elements. The two far-field lobes of the array are combined after introducing an optical delay line into the path of one of the lobes to make the lobes mutually incoherent. The incoherent superposition of intensities produces a near-diffraction-limited, single-lobe, far-field intensity pattern containing 84% of the power, exceeding any previous (known) phase control experiments. This technique compares favorably with more elaborate schemes advanced previously using integrated phase plates, etc. The method is directly applicable to one-dimensional …


Laser Beam Propagation In Non-Kolmogorov Atmospheric Turbulence, Bruce E. Stribling Dec 1994

Laser Beam Propagation In Non-Kolmogorov Atmospheric Turbulence, Bruce E. Stribling

Theses and Dissertations

Several observations of atmospheric turbulence statistics have been reported which do not obey Kolmogorov's power spectral density model. These observations have prompted the study of optical propagation through turbulence described by non-classical power spectra. This thesis presents an analysis of optical propagation through turbulence which causes index of refraction fluctuations to have spatial power spectra that obey arbitrary power laws. The spherical and plane wave structure functions are derived using Mellin transform techniques and are applied to the field mutual coherence function (MCF) using the extended Huygens-Fresnel principle. The MCF is used to compute the Strehl ratio of a focused, …


Feasibility Exploration Of Throughfold As A Predictor For Target Loading And Associated Error Bounds, Kris G. Rongone Dec 1994

Feasibility Exploration Of Throughfold As A Predictor For Target Loading And Associated Error Bounds, Kris G. Rongone

Theses and Dissertations

Various applications of the Fredholm integral equation appear m different fields of study. An application of particular interest to the Air Force arises in determination of target loading from nuclear effects simulations. Current techniques first unfold the incident spectrum then determine target loading; resulting spectrum and loading are assumed exact. This study investigates the feasibility of a new method, through-fold, for directly determining defensible error bounds on target loading. Through-fold uses a priori information to define input data and represents target response with a linear combination of instrument responses plus a remainder to derive a quadratic expression for exact target …


Measurement Of N2+ Mobility In He Via Fourier Transform Emission Spectroscopy, Patrick D. Kee Dec 1994

Measurement Of N2+ Mobility In He Via Fourier Transform Emission Spectroscopy, Patrick D. Kee

Theses and Dissertations

Recently, Hong and Miller used Fourier Transform Emission (FTE) spectroscopy to determine the N2+ mobility in helium by relating the observed Doppler shift of the N2+ (B-X) transition to the measured electric field in the discharge as determined by probes. In order to establish the technique in-house, this effort duplicated that experiment and investigated the sensitivity and utility of the method. Doppler shift measurements in this experiment disagreed significantly with those reported by Hong and Miller. Attempts to reduce the data (and thus determine the mobility) using a model developed by Hong and Miller were unsuccessful. …


Detecting Alpha Particles Through Scintillation In Porous Materials, Martin E. Keillor Dec 1994

Detecting Alpha Particles Through Scintillation In Porous Materials, Martin E. Keillor

Theses and Dissertations

This thesis presents the results of a preliminary study of parameters essential to the development of a scintillation flow-cell detector with improved characteristics over existing cells. Such a detector with better than 10% alpha energy resolution could provide in situ capability to detect and identify important alpha-emitting radionuclides in dilute aqueous solutions. Gel-silica is a potential candidate that may provide the needed improvement in resolution while maintaining 100% detection efficiency; however, gel-silica with useful light output is yet to be developed. As a step toward realizing the system described, the dependence of alpha detection efficiency and intrinsic energy resolution on …


Analysis Of Instability Growth And Collisionless Relaxation In Thermionic Converters Using 1-D Pic Simulations, Bret B. Kreh Dec 1994

Analysis Of Instability Growth And Collisionless Relaxation In Thermionic Converters Using 1-D Pic Simulations, Bret B. Kreh

Theses and Dissertations

This work investigates the role that the beam-plasma instability may play in a thermionic converter. The traditional assumption of collisionally dominated relaxation is questioned, and the beam-plasma instability is proposed as a possible dominant relaxation mechanism. Theory is developed to describe the beam-plasma instability in the cold-plasma approximation, and the theory is tested with two common Particle-in- Cell (PIC) simulation codes. The theory is first confirmed using an unbounded plasma PIC simulation employing periodic boundary conditions, ES1. The theoretically predicted growth rates are on the order of the plasma frequencies, and ESl simulations verity these predictions within the order of …


Flow Visualization Of A Turbulent Shear Flow Using An Optical Wavefront Sensor, Daniel W. Jewell Dec 1994

Flow Visualization Of A Turbulent Shear Flow Using An Optical Wavefront Sensor, Daniel W. Jewell

Theses and Dissertations

The research reported here investigated the use of a shearing interferometer (SI) wavefront sensor to determine the effects of shear-layer turbulence on an optical wavefront. A collimated helium-neon laser beam was propagated through a plane shear-layer produced by mixing helium and nitrogen at different velocities. Since the gases have different indices of refraction, the optical wavefront was distorted by different amounts by each gas. The SI measured the wavefront slope across the sampled area of the wavefront. The shear-layer was viewed from two orthogonal directions. This document contains shadow graphs, interference patterns imaged by each of the SI's six cameras, …


Frame Selection Performance Limits For Statistical Image Reconstruction Of Adaptive Optics Compensated Images, Stephen D. Ford Dec 1994

Frame Selection Performance Limits For Statistical Image Reconstruction Of Adaptive Optics Compensated Images, Stephen D. Ford

Theses and Dissertations

The U.S. Air Force uses adaptive optics systems to collect images of extended objects beyond the atmosphere. These systems use wavefront sensors and deformable mirrors to compensate for atmospheric turbulence induced aberrations. Adaptive optics greatly enhance image quality; however, wavefront aberrations are not completely eliminated. Therefore, post-detection processing techniques are employed to further improve the compensated images. Typically, many short exposure images are collected, recentered to compensate for tilt, and then averaged to overcome randomness in the images and improve signal-to-noise ratio. Experience shows that some short exposure images in a data set are better than others. Frame selection exploits …


Multispectral Detection Of Ground Targets In Highly Correlated Backgrounds, Jason E. Thomas Dec 1994

Multispectral Detection Of Ground Targets In Highly Correlated Backgrounds, Jason E. Thomas

Theses and Dissertations

Multispectral detection methods attempt to discriminate targets in a dominant clutter background using multiple images of the same real-world scene taken in different narrow spectral bands in the infrared. Detection is possible due to the empirically observed phenomenon that the radiance of man-made objects, such as a tank or truck, often lies off the main spectral correlation axis of that of natural backgrounds. Radiometric measurements of several vehicles and a tree canopy background taken over three days in June. 1994 were used to examine the factors affecting multispectral detection. Results clearly showed that the processes which provide for higher spectral …


Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt Sep 1994

Experiment Using Infrared Spectroscopy To Study The Effect Of Soil Characteristics Upon The Rate Of Trichloroethylene Desorption, Benjamin T. Kindt

Theses and Dissertations

This research investigated the influence of soil characteristics on the desorption of trichloroethylene (TCE). TCE is one of the most common contaminants at Superfund sites. Unfortunately, extraction of TCE from contaminated soils has been hindered by its slow and poorly understood desorption from soil particles. The rate and progress of desorption of TCE from seven types of soil with varying particle diameters and elemental compositions was measured using optical absorption techniques. Fitting the data to the Langmuir Isotherm functional form predicted in the literature yielded parameters for the desorption rate and total amount desorption each soil type. These parameters were …


High Resolution Fourier Transform Spectroscopy Of The First Overtone Of The N-O Stretch In Nitrosyl Bromide, Todd E. Wiest Sep 1994

High Resolution Fourier Transform Spectroscopy Of The First Overtone Of The N-O Stretch In Nitrosyl Bromide, Todd E. Wiest

Theses and Dissertations

Infrared Fourier transform spectroscopy of the first overtone of the nitric oxide (NO) bond stretch in nitrosyl bromide (ONBr) has been performed at a resolution of 0.02cm-1 to obtain the rotational parameters of the V1 = 2 energy level. Roughly 1000 transitions have been observed for rotational levels up to J = 80 and Ka = 7. The calculation of the complete set of rotational energy levels of this asymmetric molecule requires the numerical diagonalization of four, tridiagonal matricies for each J. From a non-linear least squares fit of observed transitions with J ≤ 40 using an …


A Three Region Analysis Of A Bounded Plasma Using Particle In Cell And Fluid Techniques, Don F. Nichols Sep 1994

A Three Region Analysis Of A Bounded Plasma Using Particle In Cell And Fluid Techniques, Don F. Nichols

Theses and Dissertations

A detailed collisionless sheath theory and a three-region collisional model of a bounded plasma are presented, and the suitability of the collisional model for analysis of ignited mode thermionic converters is investigated. The sheath theory extends previous analyses to regimes in which the sheath potential and electron temperatures are comparable in magnitude. In all operating regimes typical of a ignited mode thermionic converter, the predicted sheaths extend several mean-free paths. The apparent collisionality of the sheaths prompted development of a collisional, three-region model of the converter plasma. By interfacing Particle-in-Cell regions for the sheaths and fluid regions for the bulk …


Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares Aug 1994

Use Of Infrared Spectrometry To Determine The Effect Of Temperature On The Description Rates Of Trichloroethylene From Plastic Clay 98b, Abdellatif Fares

Theses and Dissertations

This thesis investigated the influence of temperature on the desorption rated of trichloroethylene (TCE) from plastic clay. It was expected that an increase in temperature will cause an increase in both the desorption rates of TCE and in the desorbed quantity. Previous studies on other chemicals indicated a faster decrease in the remaining sorbed concentration with an increase in temperature. This research made use of the infrared optical absorption technique. IR spectroscopy was used to measure the concentration of the vapor TCE that desorbed from the soil. The soil was exposed to liquid TCE for 2 days then placed inside …


The Optical Emission And Absorption Properties Of Silicon-Germanium Superlattice Structures Grown On Non-Conventional Silicon Substrate Orientation, Theodore L. Kreifels Aug 1994

The Optical Emission And Absorption Properties Of Silicon-Germanium Superlattice Structures Grown On Non-Conventional Silicon Substrate Orientation, Theodore L. Kreifels

Theses and Dissertations

Optical emission and absorption properties of Si1-x Gex/Si superlattices grown on (100), (110), and (111) Si substrates were investigated to determine the optimal growth conditions for these structures to be used as infrared detectors. Fully-strained Si1-x Gex/Si superlattices were grown by molecular beam epitaxy MBE and examined using low-temperature photoluminescence PL to identify no-phonon and phonon-replica interband transitions across the alloy bandgap. Phonon-resolved emission was most intense for undoped quantum wells grown at 710°C for all three silicon orientations. Room temperature absorption measurements were conducted on (100) and (110) Si1-x Gex/Si …


The Excitation Mechanism Of Praseodymium-Doped Semiconductors, Paul L. Thee Jun 1994

The Excitation Mechanism Of Praseodymium-Doped Semiconductors, Paul L. Thee

Theses and Dissertations

This study on praseodymium Pr luminescence in AlxGa1-xAs was conducted to enhance the understanding of the excitation mechanism. Pr was implanted at 390 keV with doses from 5 x 1012 to 5 x 1013 sq cm into AlxGa1-xAs x0.0 to 0.50 wafers which were annealed using the rapid thermal annealing RTA method. Low temperature photoluminescence PL was conducted using an Ar-ion laser and Ge detector. PL emissions of Pr from all hosts include peaks near 1.3 and 1.6 µm which are assigned to the intra-4f transitions of 1G4 yielding 3H5 …


Spatio-Temporal Pattern Recognition Using Hidden Markov Models, Kenneth H. Fielding Jun 1994

Spatio-Temporal Pattern Recognition Using Hidden Markov Models, Kenneth H. Fielding

Theses and Dissertations

A new spatio-temporal method for identifying 3D objects found in 2D image sequences is presented. The Hidden Markov Model technique is used as a spatio-temporal classification algorithm to identify 3D objects by the temporal changes in observed shape features. A new information theoretic argument is developed that proves identifying objects based on image sequences can lead to higher classification accuracies than single look methods. A new distance measure is proposed that analyzes the performance of Hidden Markov Models in a multi-class pattern recognition problem. A three class problem identifying moving light display objects provides experimental verification of the sequence processing …


A Diffraction-Based Model Of Anisoplanatism Effects In Adaptive Optic Systems, Steven E. Troxel Jun 1994

A Diffraction-Based Model Of Anisoplanatism Effects In Adaptive Optic Systems, Steven E. Troxel

Theses and Dissertations

This dissertation presents a new model for computing the angle dependent performance measures of an adaptive-optics system. By incorporating diffraction caused by the index-of-refraction variations of the atmosphere, the phase and amplitude fluctuations of the propagating wave are computed. New theory is presented, that uses the diffraction-based propagation model to yield optical transfer function (OTF) expressions that are more accurate as compared to current theory that neglects diffraction. An evaluation method for calculating the OTF is presented that utilizes a layered atmospheric model and normalized OTF expressions. The diffraction model is also used to present the first OTF signal-to-noise ratio …


Feasibility Analysis For Predicting A Kinetic Kill Zone For Aircraft Homing Missile Defense, Mark E. Ennis Mar 1994

Feasibility Analysis For Predicting A Kinetic Kill Zone For Aircraft Homing Missile Defense, Mark E. Ennis

Theses and Dissertations

An extended Kalman filter is used to predict a kinetic kill zone for use in aircraft self defense versus homing missiles. The analysis is limited to an in-the-plane analysis and focuses on finding the model parameters which have the largest impact on the predicted kill zone. No attempt is made to optimize the design of the filter model itself. The analysis computes the kill zone relative to an assumed aircraft trajectory using strictly filter computed statistics. No Monte-Carlo simulations are used throughout the thesis. The filter assumed to be on the evading aircraft, uses an onboard laser radar (ladar) to …


Einstein's Equations In Vacuum Spacetimes With Two Spacelinke Killing Vectors Using Affine Projection Tensor Geometry, Miles D. Lawrence Jan 1994

Einstein's Equations In Vacuum Spacetimes With Two Spacelinke Killing Vectors Using Affine Projection Tensor Geometry, Miles D. Lawrence

Theses and Dissertations

Einstein's equations in vacuum spacetimes with two spacelike killing vectors are explored using affine projection tensor geometry. By doing a semi-conformal transformation on the metric, a new "fiducial" geometry is constructed using a projection tensor fields. This fiducial geometry provides coordinate independent information about the underlying structure of the spacetime without the use of an explicit form of the metric tensor.


Vibrational Energy Transfer Within The B3Π(0+U) State Of 79Br2 Upon Collision With N2, O2, No, And Sf6, Gregory S. Williams Dec 1993

Vibrational Energy Transfer Within The B3Π(0+U) State Of 79Br2 Upon Collision With N2, O2, No, And Sf6, Gregory S. Williams

Theses and Dissertations

Vibrational transfer and electronic quenching in the lower vibrational levels of the 79Br2(B; v'≤3) were investigated using spectrally resolved, temporally resolved pulsed laser induced fluorescence techniques. Spectrally resolved emissions from collisionally populated Br2(B) vibrational levels were observed for N2, O2, NO, and SF6collision partners. The vibrational transfer was efficient in the nonpredissociative vibrational levels and is adequately described by the Montroll-Shuler model. An average fundamental vibrational transfer rate coefficient of kv(l,0)=3.4(±0.6) x 10-11 cm3/molec-sec predicts the vibrational transfer rates for the 0≤v'≤3 collisions with …


System Design Analysis Of A Lightweight Laser Satellite Terminal, Brian C. Page Dec 1993

System Design Analysis Of A Lightweight Laser Satellite Terminal, Brian C. Page

Theses and Dissertations

This study investigated the technological feasibility of a man- portable satellite laser communications system. Areas of interest were an end- to-end system analysis on the communications link evaluation of atmospheric effects and evaluation of semi-conductor lasers as the laser source. A literature search revealed that satellite laser communication research is primarily directed at inter-satellite links. There have been some proposed systems for space-to-ground laser communications systems, but they all utilize large fixed ground stations. The focus of this research effort is directed at a small man-portable ground station capitalizing on recent advances in semiconductor laser devices. Baseline satellite communication systems …


Hyperspectral Analysis Of Space Objects: Signal To Noise Evaluation, Daniel Hrovat Dec 1993

Hyperspectral Analysis Of Space Objects: Signal To Noise Evaluation, Daniel Hrovat

Theses and Dissertations

Hyperspectral analysis of space objects is being considered as a means of enhancing Space Object Identification. SOI capabilities. This study develops a mathematical simulation based on fundamental radiometry principles to evaluate the feasibility of hyperspectral analysis of space objects. The study uses Signal to Noise Ratio SNR as the basis for the feasibility evaluation, and addresses the question Is there enough target signal in narrow wavelength bandwidths to conduct hyperspectral measurements of space objects The analysis characterizes the target signal and noise sources using fundamental radiometry, and develops a flexible radiometry model which calculates the target signal count rate, and …


Infrared Fluorescence Studies Of Electronic-To-Vibrational Energy Transfer In A Br2:No System, Michael R. Hawks Dec 1993

Infrared Fluorescence Studies Of Electronic-To-Vibrational Energy Transfer In A Br2:No System, Michael R. Hawks

Theses and Dissertations

Steady-state photolysis techniques were used to study electronic-to- vibrational energy transfer mechanisms from atomic bromine to nitric oxide. Molecular bromine was photodissociated by 488nm radiation to produce equal parts Br(2P1/2) and Br(2P3/2). Side fluorescence intensity from Br(2P1/2) at 2.7 µm and from NO (v=1 and 2) around 5.3 µm measured as a function of bromine pressure and nitric oxide pressure. The branching ratio collisional transfer into the first and second states of NO was determined, and previously reported rates for quenching of NO by molecular bromine were verified.


Characterization Of An Lcd For Use As A Programmable Phase Shifter To Produce A Single-Lobed Far-Field Pattern In A Phased Array, Gregory S. Kenyon Dec 1993

Characterization Of An Lcd For Use As A Programmable Phase Shifter To Produce A Single-Lobed Far-Field Pattern In A Phased Array, Gregory S. Kenyon

Theses and Dissertations

The liquid crystal display LCD from an inexpensive pocket television was converted to a spatial light modulator SLM for the purpose of altering the phase front of a ten element diode laser array to produce a single lobe far field pattern. Characterization of the SLM determined the amount of phase shift, amplitude modulation and polarization rotation properties. Nonuniformities within the phase shifter and insufficient phase shift prevented the formation of a single lobe. However, a very limited phase grating was created and analyzed. LCDs from inexpensive commercial pocket televisions were found unsuitable for use as phase shifting spatial light modulators.