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Articles 1 - 15 of 15
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The Effects Of Ultrasonic Vibration, Tension And Torsion On The Charge Acceptance Of The Alkaline Silver Electrode ; Ii. Potentiostatic Studies Of The Oxide Growth Rate Law For The Alkaline Silver Electrode ; Iii. The Determination Of Ionic Transport In Silver Oxide Using Radiotracer Techniques With Ag[Superscript 110m], Reed Harold Chase
Theses and Dissertations
The effect of ultrasonic vibration on the anodic oxidation of silver foil in KOH was studied. An increase in charging capacity of approximately 20% was found to be the result of cavitation erosion. Silver wire was exposed to tension and torsion during oxidation but no change in charge acceptance was caused by these stresses. The oxide growth rate on silver foil electrodes was compared to rate equations that have been proposed for other metals. Uhlig's equations for the growth of semiconductor oxides was found to describe most of the data. The data did not fit other rate equations. Determination of …
Voltammetric And Electrochemical Kinetic Studies Of The Halides And Halogens At A Platinum Rotating Ring-Disk Electrode In Anhydrous Acetic Acid, Donald Harrison Cranney
Voltammetric And Electrochemical Kinetic Studies Of The Halides And Halogens At A Platinum Rotating Ring-Disk Electrode In Anhydrous Acetic Acid, Donald Harrison Cranney
Theses and Dissertations
The electrochemical behavior of the iodine-iodide couple was investigated in both basic and neutral acetic acid solutions at a platinum rotating ring-disk electrode. Voltammetric curves were obtained and discussed. Various kinetic parameters were determined and by comparing to theoretical kinetic parameters a probable reaction mechanism was deduced. The mechanism that best fit experimental results is the following I- + S = I(S) + e- I(S) + I- = I2 + S + e (slow). The electrochemical behavior of bromine, bromide, and chloride was also investigated in the same media. Voltammetric curves were recorded and discussed with emphasis on the hysteresis …
A Study Of Selected Photo Fries Rearrangements, Elwood Lloyd Loveridge
A Study Of Selected Photo Fries Rearrangements, Elwood Lloyd Loveridge
Theses and Dissertations
The Fries rearrangement of phenyl esters is reviewed and compared to the reaction when light is the source of energy. The products are different due to different mechanism of reaction. Light energy causes either free radical or concerted reactions. The S-phenylthiol esters and anilides were studied also. Although many of the rearrangements are the same, we did not see any alkyl migration nor decarboxylation type reactions with either the sulfur or nitrogen compounds. Three papers have been published from this work: Bradshaw, J. S., Knudsen, R. D. and Loveridge, E. L., J. Org. Chem., 35, 1219 (1970); Bradshaw, J. S., …
Computer Model Of A Fast Toroidal Plasma Compression, With Application To The Topolotron, H. Mark Nelson, Keith H. Brown, Charles A. Hart
Computer Model Of A Fast Toroidal Plasma Compression, With Application To The Topolotron, H. Mark Nelson, Keith H. Brown, Charles A. Hart
Faculty Publications
The method is developed for a comuputer sequence which models a fast toroidal theta or screw pinch for a highly conducting axially symmetric plasma. The computer sequence takes into account the self-inductances of the plasma and the external conductors which drive the compression as well as the mutual inductance which electromagnetically couples the two. The computer sequence is divided into three phases: a snowplow compression phase, an adiabatic compression phase, and a crowbarred circuit phase. The computer sequence is applied to a topolotron and an example is given of a magnetohydrodynamic equilibrium geometry for which the plasma surface possesses an …
Behavior Of A Manganin Coil At Elevated Temperatures And Pressures, Jonathan D. Weiss, Daniel L. Decker, H. B. Vanfleet
Behavior Of A Manganin Coil At Elevated Temperatures And Pressures, Jonathan D. Weiss, Daniel L. Decker, H. B. Vanfleet
Faculty Publications
We have determined the temperature dependence in the first-order pressure coefficient of a manganin coil to be dBetaB/dT= (4.2±0.8) ×10^-7 (kbar degrees C)^-1 in the equation R (T,P) =R (T,0)(1+BetaP+GammaP2), where R (T,P) is the coil resistance at temperature T and pressure P. The measurements were performed by simultaneously measuring the coil resistance and temperature at the transitions of mercury and bismuth, which were observed by differential thermal analysis.
A Comparison Of Free Radical Detection Methods, Danny Kiang-Wah Pan
A Comparison Of Free Radical Detection Methods, Danny Kiang-Wah Pan
Theses and Dissertations
The methods used for free radical detection are chemical titration, spectrophotometry, Gouy magnetic measurements and NMR shift technique. The free radicals chosen for this study are Fremy' s salt (ON(SO_3 )K_2),2,2-diphenyl-1-picryl hydrazyl (DPPH) 3-carbamoyl-2,2,5,5-tetramethylpyrrolidin-1-yloxy (CTM-pyrrolidin), 3-carbamoyl-2,2,5,5-tetramethyl-3-pyrrolin-1-yloxy (CTM-pyrrolin), 4-acetamido-2,2,6,6-tetramethylpiperidino-1- oxyl (ATMP) and galvinoxyl. The detectable range for each method is given. The NMR method is a fast and convenient method for the magnetic susceptibility determination of a sample in solution, with. accuracy up to ± 1%.
A Potentiometric Method, A Convenient And Rapid Technique For Determination Of The Thermodynamics Of Ionization Reactions For Water, Weak Acids, And Some Slightly Soluble Salts In Aqueous Organic Mixed Solvents, Charanai Panichajakul
Theses and Dissertations
A potentiometric method which is devised to be rapid and convenient for determining ionization constants for water, weak acids (or bases), and certain solids in mixed solvents is described. The method has been applied to the determination of ionization for water, acetic acid, benzoic acid, and phenol and the solubility product constant for silver chloride in mixtures of water with methanol, ethanol, acetone, tetrahydrofuran, and p-dioxane containing from 0 to 70 mass percent organic co-solvent at several temperatures between 10 and 40°C. Results are used to study the thermodynamics of ionization in each mixture which is discussed relative to various …
The Intermolecular Potential And Vibrational Relaxation Of The Ar-Co System, Gregory Allen Parker
The Intermolecular Potential And Vibrational Relaxation Of The Ar-Co System, Gregory Allen Parker
Theses and Dissertations
The angle, distance and vibration dependence of the Ar-CO intermolecular potential is calculated using the electron gas model to obtain the short range interaction which is smoothly joined onto the long range van der Waals tail which is obtained from accurate C_6, C_7, and C_8 coefficients. Our calculated second interaction virial coefficients are compared with experiment and with a simple adjustment of the Ar-CO potential an excellent agreement is obtained. Our spherically averaged potential is also in excellent agreement with a spherical potential inferred from high energy scattering data. Simplified expressions for the scattering amplitude and differential cross section are …
Esr Study Of Free Radicals In Irradiated Single Crystals Of Potassium Hydroxylamine Disulfonate, B. J. Wilson, Robert W. Holmberg
Esr Study Of Free Radicals In Irradiated Single Crystals Of Potassium Hydroxylamine Disulfonate, B. J. Wilson, Robert W. Holmberg
Faculty Publications
Two free radicals formed when single crystals of potassium hydroxylamine disulfonate are irradiated with gamma rays at 77degrees K were studied by ESR. The ESR spectra result from a predominant center (radical A) exhibiting large 14N and 1H hyperfine splittings and from lesser amounts of Fremy's radical [O-dotN(SO3)2-2]. The g and hyperfine tensors of these radicals have been evaluated and are discussed. Radical A, whose identity remains in doubt, may be regarded as the precursor to Fremy's radical; on warming its lines decay and those of Fremy's radical are formed. Lines from radical A decrease in strength and those of …
Solid-Liquid Phase Equilibria In Systems Of (I) Para-Xylene, (Ii) Mesitylene, And (Iii) N,N-Dimethylformamide ; Excess Volume Determination In Systems Containing Cyclohexane ; Calculations Of Activities For The N-Hexane + Cyclohexane System, John F. Moellmer
Theses and Dissertations
Solid-liquid phase equilibria studies were used to investigate possible compolllld formation in solutions of (i) para-xylene, (ii) mesitylene, and (iii) N,N-dimethyl-formamide (DMF) with mono- and di- halobenzenes that were selected to give a wide range of acceptor properties. Solid 1:1 intermolecular compounds were identified from solutions of p-C_6H_4F_2 with mesitylene, p-C_6H_4Br_2 with p-xylene, and p-C_6H_4Cl_2 with p-xylene. The results suggest that compound formation occurs because of favorable geometry rather than a charge transfer process. A vibrating tube densimeter was used to determine, with high precision, the densities and subsequently excess volumes of mixing of the n-hexane plus cyclohexane system. Temperature …
The Synthesis Of Analogs Of Toxoflavin And Fervenulin As Potential Antimetabolites, Bernadette Kuo Billings
The Synthesis Of Analogs Of Toxoflavin And Fervenulin As Potential Antimetabolites, Bernadette Kuo Billings
Theses and Dissertations
The synthesis of analogs of toxoflavin: 1,3,4,6-tetramethyl-1,5,6, 7-tetrahydropyrimido[4,5-c]-5,7-pyridazinedione; 1,6-dimethyl-3,4-diphenyl-1,5,6,7-tetrahydropyrimido[4,5-c]-5,7-pyridazinedione; 3,5,7-trimethyl-8-phenyl-2,3,4,8-tetrahydropyrido[2,3-d]-2,4-pyrimidinedione are discussed. The synthesis of analogs of fervenulin: 3,4,6-trimethyl-5,6,7,8-tetrahydropyrimido[4,5-c]-5,7-pyridazinedione; 6-methyl-3,4-diphenyl-5,6,7,8-tetrahydropyrimido[4,5-c]-5,7-pyridazinedione; 2-hydroxy-3,5,7-trimethyl-4(3H)pyrido[2,3-d]-2,4-pyrimidinone are discussed. Several intermediates have been prepared: 6 -methylamino-3-methyluracil by a new method; 6-n-propylamino-3-methyluracil: 6-n-butylamino-3-methyluracil and 3-ethyl-2-ethylthio-2-hydroxy-4(3H)pyrimidinone.
Hard And Soft Nucleophilic Substitution Patterns In Amino-Methylsulfonylazines, Calvin Wilson Mccausland
Hard And Soft Nucleophilic Substitution Patterns In Amino-Methylsulfonylazines, Calvin Wilson Mccausland
Theses and Dissertations
The selectivity observed with 2,4,7-triamino-6-methylsulfonyl-pteridine when reacted with "hard" aliphatic amines and "soft" aryl-thiols resulting in amine exchange at the 2-, 4-, and 7-positions and displacement of the 6-methylsulfonyl moiety, respectively, was further investigated in other ring systems. The substrates tested were disubstituted with amino- and methylsulfonyl- moieties, and included the benzene, pyridine, pyrazine, quinoxaline, quinazoline and pteridine ring systems. The methylsulfonyl moiety is preferentially displaced by both thiols and amines with quinoxaline and quinazoline substrates, and is more reactive towards displacement by thiol than amine nucleophiles. Amine exchange occurs with the quinoxaline substrate subsequent to displacement of the methylsulfonyl …
Van Der Waals Interactions Of Carbon Monoxide, Gregory A. Parker, Russell T. Pack
Van Der Waals Interactions Of Carbon Monoxide, Gregory A. Parker, Russell T. Pack
Faculty Publications
Pade approximant methods and experimental frequency dependent polarizabilities are used to calculate reliable van der Waals C6 coefficients for the interaction of CO with He, Ne, Ar, Kr, Xe, H, Li, Na, K, Rb, Cs, H2, N2, O2, CO2, and CO. Error bounds are given for the C6 coefficients and for the CO oscillator strength sums.
Van Der Waals Interactions Of Ii-State Linear Molecules With Atoms. C6 For No(X 2Π) Interactions, Glen C. Nielson, Gregory A. Parker, Russell T. Pack
Van Der Waals Interactions Of Ii-State Linear Molecules With Atoms. C6 For No(X 2Π) Interactions, Glen C. Nielson, Gregory A. Parker, Russell T. Pack
Faculty Publications
Formulas are derived for the van der Waals Cn coefficients for the interaction of a diatomic molecule in a II electronic state with an S-state atom. Two triatomic states arise from the degenerate IIstate. The average of the two energies has the usual Legendre polynomial (PL) angular dependence, but the difference in energies of the two states is shown to have associated Legendre polynomial (PML with M=2) angular dependence. Procedures for including spin orbit coupling are included, and the extension to interactions of Delta- and Phi-state molecules is discussed. Values of the spherical part of the C6 coefficients for the …
Comment On ''Inelastic Scattering In Atom-Diatomic Molecule Collisions. I. Rotational Transitions In The Sudden Approximation'', Russell T. Pack
Comment On ''Inelastic Scattering In Atom-Diatomic Molecule Collisions. I. Rotational Transitions In The Sudden Approximation'', Russell T. Pack
Faculty Publications
It is argued that conflicting approximations in a recent paper [J. R. Stallcop, J. Chem. Phys. 61, 5085 (1974)] render the resulting theory invalid.