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Groundwater-Surface Water Interaction In The Headwater Of The White River, Manistee National Forest, Michigan, Ziqian Li

Masters Theses

Groundwater is a significant fresh water source in most areas and can be affected by potential changes to climate and precipitation from anthropogenic influences. Considering groundwater and surface water can be regarded as one hydrologic system, it is significant to understand the dynamics between precipitation, shallow groundwater and surface water in order to manage these resources.

Water samples were collected roughly biweekly from July 2016 to June 2017, and analyzed for electrical conductivity and stable isotopes of oxygen and hydrogen. During sample collection site visits, stream discharge and the groundwater heads from different wells were measured.

The stable isotopes of …

Phase Transitions And The Casimir Effect In Neutron Stars, William Patrick Moffitt

Masters Theses

What lies at the core of a neutron star is still a highly debated topic, with both the composition and the physical interactions in question. In this thesis, we made assumptions regarding the composition to further study the interactions of matter during the transition phases. These phases, also known as nuclear pasta, come from the unique physical conditions which occur within neutron stars. We examine the feasibility of the Casimir effect manifesting during these phases, as well as the effects it would have on the total energy of the system. We find that the crust-core transition cannot support the proper …

Apan Production Through Photooxidation Of Isoprene In The Presence Of NoX, Timothy Glidewell

Masters Theses

Peroxyacyl nitrates (PANs, RC(O)OONO₂) are of great importance in atmospheric chemistry. They act as transporters of reactive nitrogen, and radical delivery agents. There are no known natural emission sources of PANs; they are produced through reaction of volatile organic compounds (VOCs) and nitrogen oxides (NO_x) in the atmosphere.

VOCs can enter the atmosphere through biogenic and anthropogenic pathways. It has been estimated that isoprene makes up 70% of the biogenic VOCs (BVOCs) emitted annually. Isoprene has been shown to impact ozone levels in both rural and urban areas by sequestering and transporting NO_x in the form …

The Influence Of Road Salt On Seasonal Mixing And Redox Stratification In Three Southwest Michigan Kettle Lakes, Danielle Dupuis

Masters Theses

Influxes of saline water from roads treated with deicers can alter the density structure of urban lakes. This can delay or halt turnover events, which may lead to persistent hypolimnetic anoxia in nutrient-rich lakes. In this study, the lake columns of two urban lakes (Woods Lake and Asylum Lake) and one rural lake (North Lake), were sampled once a month from March 2016 to June 2017. Lake column water was analyzed for conductivity, temperature, dissolved oxygen, ferrous iron, manganese, sulfide, calcium, magnesium, sodium, chloride and methane concentrations as a function of depth. All three lakes are eutrophic with anoxic hypolimnia …

The Effect Of Plant Source On Lignin-Based Polyurethanes And The Interdiffusion Dynamics Of Semi-Rigid Polymers, Jason Michael Lang

Masters Theses

The work reported in this thesis increases our understanding of the effect of lignin plant source on the mechanical and morphological properties of lignin-based polyurethanes and the interdiffusion of glassy/liquid bilayer thin films. The interdiffusion of glassy/liquid polymer pairs has received much less attention than liquid/liquid bilayers, leading to conflicting results and unresolved discrepancies. Therefore, the reported study of interdiffusion between polysulfone glassy/liquid polymer layers provides insight into the dynamics of these systems.

This thesis first reports the correlation between the mechanical properties of lignin-based polyurethanes and the lignin plant source. Lignin is a molecule that can be used as …

Avian Ecology During Oak Savanna And Woodland Restoration In The Mid-South, Christine Ann Henderson

Masters Theses

Disturbance-dependent ecosystems in the eastern United States have been declining since European settlement, and, in recent years, early-successional species have followed. My objective for this research was to determine if oak savanna and woodland restoration (i.e., overstory thinning and prescribed fire) was a viable method of recovering declining earlysuccessional species to the landscape of the Mid-South. At 3 sites, Catoosa Wildlife Management Area (CWMA; Tennessee), Green River Game Lands (GRGL; North Carolina), and Land Between the Lakes National Recreation Area (LBL; Tennessee), oak savanna and woodland restoration projects were established and maintained. Closed-canopy stands were thinned and a 2-year burn …

Developing Leading And Lagging Indicators To Enhance Equipment Reliability In A Lean System, Dhanush Agara Mallesh

Masters Theses

With increasing complexity in equipment, the failure rates are becoming a critical metric due to the unplanned maintenance in a production environment. Unplanned maintenance in manufacturing process is created issues with downtimes and decreasing the reliability of equipment. Failures in equipment have resulted in the loss of revenue to organizations encouraging maintenance practitioners to analyze ways to change unplanned to planned maintenance. Efficient failure prediction models are being developed to learn about the failures in advance. With this information, failures predicted can reduce the downtimes in the system and improve the throughput.

The goal of this thesis is to predict …

Automated Program Profiling And Analysis For Managing Heterogeneous Memory Systems, Adam Palmer Howard

Masters Theses

Many promising memory technologies, such as non-volatile, storage-class memories and high-bandwidth, on-chip RAMs, are beginning to emerge. Since each of these new technologies present tradeoffs distinct from conventional DRAMs, next-generation systems are likely to include multiple tiers of memory storage, each with their own type of devices. To efficiently utilize the available hardware, such systems will need to alter their data management strategies to consider the performance and capabilities provided by each tier.

This work explores a variety of cross-layer strategies for managing application data in heterogeneous memory systems. We propose different program profiling-based techniques to automatically partition program allocation …

The Synthesis Of Memristive Neuromorphic Circuits, Austin Richard Wyer

Masters Theses

As Moores Law has come to a halt, it has become necessary to explore alternative forms of computation that are not limited in the same ways as traditional CMOS technologies and the Von Neumann architecture. Neuromorphic computing, computing inspired by the human brain with neurons and synapses, has been proposed as one of these alternatives. Memristors, non-volatile devices with adjustable resistances, have emerged as a candidate for implementing neuromorphic computing systems because of their low power and low area overhead. This work presents a C++ simulator for an implementation of a memristive neuromorphic circuit. The simulator is used within a …

The Oxidation State Of Hawaiian Magmas, Michael Vollinger

Masters Theses

In order to estimate the oxygen fugacity of Hawaiian lavas I have measured the ferric/ferrous ratios of samples from the 1984 eruption of Mauna Loa volcano and from the ongoing (1983-2017) Puu Oo eruption of Kilauea volcano. Fifteen samples were studied from the 21 day Mauna Loa eruption and 86 samples, erupted between 1983 and 2004, of the 34 year long Kilauea eruption. Both studies show that, in order to obtain reliable estimates of oxygen fugacity when, where, and how basaltic lava is sampled is of critical importance. Water-quenched lavas and spatter sampled at, or near vents, are less oxidized …

Exploring Long-Term Fault Evolution In Obliquely Loaded Systems Using Tabletop Experiments And Digital Image Correlation Techniques, Kevin Toeneboehn

Masters Theses

This thesis focuses on the use of scaled physical experiments to better understand the development and long-term evolution of fault systems that are otherwise impossible to observe directly. The document is divided into three chapters. The first chapter documents the implementation of an inexpensive stereo vision method for acquiring high resolution three-dimensional strain data for table-top experiments. The second chapter applies the stereo vision method to a tectonic problem—the development of slip partitioning in obliquely loaded crustal systems. Slip partitioned fault systems accommodate oblique convergence with different slip rake on two or more faults and are well documented in the …

How The E. Coli Hsp70 Molecular Chaperone, Dnak, Binds A Client Protein, Joseph Tilitsky

Masters Theses

Protein folding is essential for all cellular life. While some proteins are able to reach their folded state reliably using nothing but their amino acid sequence, a great number of essential proteins are unable to do so without the aid of molecular chaperones. One family of molecular chaperone, the Hsp70 family, is found in virtually all cell types and across all domains of life. Certain to the function of Hsp70s are how they bind their client proteins. Substantial effort has been expended to study how Hsp70s work on model peptides as a substrate mimic, but relatively little work has been …

Non-Equispaced Fast Fourier Transforms In Turbulence Simulation, Aditya M. Kulkarni

Masters Theses

Fourier pseudo-spectral method on equispaced grid is one of the approaches in turbulence simulation, to compute derivative of discrete data, using fast Fourier Transform (FFT) and gives low dispersion and dissipation errors. In many turbulent flows the dynamically important scales of motion are concentrated in certain regions which requires a coarser grid for higher accuracy. A coarser grid in other regions minimizes the memory requirement. This requires the use of Non-equispaced Fast Fourier Transform (NFFT) to compute the Fourier transform, by solving a system of linear equations.

To achieve similar accuracy, the NFFT needs to return more Fourier coefficients than …

Juvenile River Herring In Freshwater Lakes: Sampling Approaches For Evaluating Growth And Survival, Matthew T. Devine

Masters Theses

River herring, collectively alewives (Alosa pseudoharengus) and blueback herring (A. aestivalis), have experienced substantial population declines over the past five decades due in large part to overfishing, combined with other sources of mortality, and disrupted access to critical freshwater spawning habitats. Anadromous river herring populations are currently assessed by counting adults in rivers during upstream spawning migrations, but no field-based assessment methods exist for estimating juvenile densities in freshwater nursery habitats. Counts of 4-year-old migrating adults are variable and prevent understanding about how mortality acts on different life stages prior to returning to spawn (e.g., juveniles …

Influence Of Biomimetic Chelating Packaging On Natural Antimicrobial Efficacy, Paul Castrale

Masters Theses

The iron chelating molecule, ethylenediaminetetraacetic acid (EDTA) is used in food applications for the preservation of oxidation prone ingredients. Research has suggested that EDTA is also capable of enhancing the antimicrobial effectiveness of various compounds including naturally-derived antimicrobials. With consumer demand for cleaner food labels, there remains an opportunity to introduce new chelating technology to replace synthetically-derived EDTA. Through photographting and chemical conversion, hydroxamic acid ligands were covalently bound to polypropylene films resulting in polypropylene-graft-poly(hydroxamic acid) (PP-g-PHA). The resulting films demonstrated an ability to chelate 64 nmol/cm² from an iron saturated environment or 163 nmol/cm …

Modelling Bird Migration With Motus Data And Bayesian State-Space Models, Justin Baldwin

Masters Theses

Bird migration is a poorly-known yet important phenomenon, as understanding movement patterns of birds can inform conservation strategies and public health policy for animal-borne diseases. Recent advances in wildlife tracking technology, in particular the Motus system, have allowed researchers to track even small flying birds and insects with radio transmitters that weigh fractions of a gram. This system relies on a community-based distributed sensor network that detects tagged animals as they move through the detection nodes on journeys that range from small local movements to intercontinental migrations. The quantity of data generated by the Motus system is unprecedented, is on …

Multiple Testing Correction With Repeated Correlated Outcomes: Applications To Epigenetics, Katie Leap

Masters Theses

Epigenetic changes (specifically DNA methylation) have been associated with adverse health outcomes; however, unlike genetic markers that are fixed over the lifetime of an individual, methylation can change. Given that there are a large number of methylation sites, measuring them repeatedly introduces multiple testing problems beyond those that exist in a static genetic context. Using simulations of epigenetic data, we considered different methods of controlling the false discovery rate. We considered several underlying associations between an exposure and methylation over time.

We found that testing each site with a linear mixed effects model and then controlling the false discovery rate …

A Predictive Model For Brook Trout Restoration In The Cherokee National Forest, Caylor Garrett Romines

Masters Theses

Over the course of the last century, Brook Trout (Salvelinus fontinalis) have been reduced in abundance and extirpated from many high elevation streams throughout the southern Appalachian Mountains. These fish have been threatened by anthropogenic factors that restrict their distribution across the longitudinal gradient of the streams they occupy. A large portion of Tennessee's Brook Trout streams are located within the Cherokee National Forest (CNF). Many agencies in the southern Appalachian Mountains are working to restore Brook Trout populations throughout this species’ historic native range. The purpose of this research is to develop a model of important habitat …

Classification Results Of Hadamard Matrices, Gregory Allen Schmidt

Masters Theses

In 1893 Hadamard proved that for any n x n matrix A over the complex numbers, with all of its entries of absolute value less than or equal to 1, it necessarily follows that

|det(A)| ≤ n^n/2 [n raised to the power n divided by two],

with equality if and only if the rows of A are mutually orthogonal and the absolute value of each entry is equal to 1 (See [2], [3]). Such matrices are now appropriately identified as Hadamard matrices, which provides an active area of research in both theoretical and applied fields …

A Gpu Implementation Of Distance-Driven Computed Tomography, Ryan D. Wagner

Masters Theses

Computed tomography (CT) is used to produce cross-sectional images of an object via noninvasive X-ray scanning of the object. These images have a wide range of uses including threat detection in checked baggage at airports. The projection data collected by the CT scanner must be reconstructed before the image may be viewed. In comparison to filtered backprojection methods of reconstruction, iterative reconstruction algorithms have been shown to increase overall image quality by incorporating a more complete model of the underlying physics. Unfortunately, iterative algorithms are generally too slow to meet the high throughput demands of this application. It is therefore …

Bats Roosting In Buildings In Great Smoky Mountains National Park: Ecology, Human Dimensions, And Management Implications, Kirstin Emily Fagan

Masters Theses

During summer, bats are regularly observed in buildings of Great Smoky Mountains National Park (GRSM or the Park), the most visited National Park in the USA. As a result, natural and cultural resources managers seek to ensure public safety and protect historic structures while minimizing impacts on bats, especially in light of declines in bat populations as a result of white-nose syndrome. To inform management decisions, I examined the ecological and human dimensions of bats roosting in buildings in GRSM.

To assess roost selection by building-roosting bats, I surveyed 140 buildings in the Park for bats during May to August, …

Petrogenesis And Concentric Zonation Of The Belchertown Intrusive Complex, West-Central Massachusetts, Karen June Van Wagner

Masters Theses

The Belchertown Intrusive Complex is a ~164 km2 Devonian pluton that intruded Paleozoic metasedimentary and metavolcanic rocks in west-central Massachusetts. Intrusion of the pluton was synchronous with Acadian deformation (Ashwal, 1974). The complex is concentrically zoned, with a core of orthopyroxene-biotite monzodiorite, a middle zone of clinopyroxene-hornblende-biotite granodiorite, and an outermost zone of hornblende-biotite granodiorite. Zoning from a more to less hydrous mineral suite from the outside to the inside of the pluton led Ashwal (1974) to suggest that metamorphic hydration most strongly affected the outermost zones of the complex. Basaltic inclusions occur most commonly near the edges of …

A Combined Historical And Sedimentological Reconstruction Of Extratropical Cyclone Derived Coastal Flooding In Boston, Ma, Zachary D. Stromer

Masters Theses

Many flood risk assessments are based on instrumental records less than a century in length. Sedimentary and historical archives provide the opportunity to extend flood records by several centuries to millennia. In doing so these longer flood records provide opportunities for improving upon current flood risk assessment and gaining additional insight on the various climatic and geomorphic processes that drive changes in flood frequency. Such a reconstruction has not been attempted previously for Boston, MA where extratropical cyclones (ETC) are currently the dominant mechanism of coastal flooding. Here, we present both a historical reconstruction of extreme storm tides to affect …

Microtransplantation Of Rat Brain Neurolemma Into Xenopus Laevis Oocytes To Study The Effect Of Environmental Toxicants On Endogenous Voltage-Sensitive Ion Channels, Edwin Murenzi

Masters Theses

Microtransplantation of mammalian neurolemma into Xenopus laevis oocytes has been used to study ion channels in terms of their structure and function in the central nervous system. Use of microtransplanted neurolemma is advantageous in that tissue can be obtained from various sources, ion channels and receptors are present in their native configuration and they can be used to evaluate numerous channelpathies caused by environmental toxicants. Here we show that Xenopus oocytes injected with fragments of rat brain neurolemma successfully express functional native ion channels that are assembled in their own plasma membrane. Using a high throughput two electrode voltage clamp …

Botswana’S Elephant-Back Safari Industry – Stress-Response In Working African Elephants And Analysis Of Their Post-Release Movements, Tanya Lama

Masters Theses

Understanding how African elephants (Loxodonta africana) respond to human interactions in ecotourism operations is critical to safeguarding animal and human welfare and sustaining wildlife ecotourism activities. We investigated the stress response of elephants to a variety of tourist activities over a 15-month period at Abu Camp in northern Botswana. We compared fecal glucocorticoid metabolite (FGM) concentrations across three elephant groups, including: eight elephants in an elephant-tourism operation (Abu herd), three elephants previously reintroduced back into the wild from the Abu herd, and wild elephants. There were no differences in FGM concentrations between the three groups of elephants. The highest observed …

Novel Spectroscopic Tools To Differentiate Drug-Dna Binding Interactions, Fadwa Dhafer Hamad

Masters Theses

DNA-drug interactions play a major role in therapeutics, diagnostics, forensics and imaging. Drugs bind to DNA in several ways based on the mode of interaction and they alter protein-DNA interactions or breaks/cleaves DNA that can lead to the cure of the disease. The major goal of the research carried out in this thesis is to develop novel optical spectroscopic tools that can differentiate Drug-DNA binding interactions mode whether its intercalation or minor-groove binding. To achieve this goal, we developed two-photon absorption (2PA) cross-section based technique to differentiate between Drug-DNA binding modes. The investigations were carried out on two drug molecules, …

Characterization Of Γ-Butyrolactone Rings: A Computational And Toxicological Study, Donald C. Kidd

Masters Theses

Given the declining state of the natural environment, identifying green methodologies in synthetic chemistry is becoming paramount. An under explored area of green chemistry, is the use of catalytic systems in green solvents. One interesting concept in green chemistry is the use of N-Heterocyclic Carbenes (NHCs) as organocatalysts.

Thiamine or vitamin B1 was one of the first NHCs recognized. Thiamine is required for carbohydrate metabolism and helps the cell produce adenosine triphosphate (ATP). Over the last 20 years NHCs have been found to be efficient catalysts in carbon-carbon bond forming reactions.

But to date, little research has been done exploring …

Convective Mode Climatology Of Tennessee Tornado Events And Effect On National Weather Service Warning Processes, Kelly Nicole Gassert

Masters Theses

Tennessee resides in the Southeastern United States, a region prone to violent tornadoes on a year-round basis. With one of the highest tornado fatality rates in the country, and a climatology that varies across the state, analysis of storms resulting in Tennessee tornadoes is necessary for improving forecasting techniques and decreasing loss of life. This study analyzed convective modes responsible for Tennessee tornadoes from 2003 to 2014 to determine an association with fatalities, seasonality, day and night, tornado magnitude, regionality, and multiple-tornado days. Chi-squared tests were conducted to determine if these patterns were significant. National Weather Service forecasters from the …

Characterization Of Reactor Background Radiation At Hfir For The Prospect Experiment, Blaine Alexander Heffron

Masters Theses

This work describes an investigation of the background radiation present at the High Flux Isotope Reactor (HFIR) on behalf of the PROSPECT collaboration. The PROSPECT experiment is designed to make a precision measurement of the antineutrino spectrum at HFIR and search for sterile neutrinos. Temporal and spacial variation of neutron and gamma backgrounds at the experiment site for the PROSPECT detector are measured in order to determine if the reactor correlated radiation will contribute a significant background to the inverse beta decay signal. Knowledge of spacial background variation will also be used to inform the design of a local shield …

On The Role Of Genetic Algorithms In The Pattern Recognition Task Of Classification, Isaac Ben Sherman

Masters Theses

In this dissertation we ask, formulate an apparatus for answering, and answer the following three questions: Where do Genetic Algorithms fit in the greater scheme of pattern recognition? Given primitive mechanics, can Genetic Algorithms match or exceed the performance of theoretically-based methods? Can we build a generic universal Genetic Algorithm for classification? To answer these questions, we develop a genetic algorithm which optimizes MATLAB classifiers and a variable length genetic algorithm which does classification based entirely on boolean logic. We test these algorithms on disparate datasets rooted in cellular biology, music theory, and medicine. We then get results from these …