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William & Mary

Theses/Dissertations

2023

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Impacts And Uncertainties Of Climate Change On The Chesapeake Bay, Kyle E. Hinson Jan 2023

Impacts And Uncertainties Of Climate Change On The Chesapeake Bay, Kyle E. Hinson

Dissertations, Theses, and Masters Projects

Climate change impacts in the Chesapeake Bay will limit the efficacy of nutrient reduction efforts and decrease dissolved oxygen, but uncertainties associated with the magnitude of these effects remain. An understanding of underlying mechanisms that have driven recent warming trends will narrow uncertainties for future pathways of temperature change. Additionally, future simulations of climate impacts in the estuary are dependent on multiple different sources of uncertainty, many of which have not yet been fully evaluated. This dissertation used a three- dimensional coupled hydrodynamic-biogeochemical model to investigate recent warming trends as well as underlying uncertainties likely to influence regional projections of …


Intelligent Software Tooling For Improving Software Development, Nathan Allen Cooper Jan 2023

Intelligent Software Tooling For Improving Software Development, Nathan Allen Cooper

Dissertations, Theses, and Masters Projects

Software has eaten the world with many of the necessities and quality of life services people use requiring software. Therefore, tools that improve the software development experience can have a significant impact on the world such as generating code and test cases, detecting bugs, question and answering, etc. The success of Deep Learning (DL) over the past decade has shown huge advancements in automation across many domains, including Software Development processes. One of the main reasons behind this success is the availability of large datasets such as open-source code available through GitHub or image datasets of mobile Graphical User Interfaces …


Climate Impacts On Spatiotemporal Habitat Usage Of Mid-Atlantic Fishes, Adena Jade Schonfeld Jan 2023

Climate Impacts On Spatiotemporal Habitat Usage Of Mid-Atlantic Fishes, Adena Jade Schonfeld

Dissertations, Theses, and Masters Projects

Climate change has altered marine environments, most notably by increasing water temperatures and reducing dissolved oxygen concentrations. These persistent changes have impacted the phenology and spatiotemporal habitat usage of mobile species, often through distributional shifts poleward or to deeper water. Climate-driven distributional shifts have been documented for numerous species inhabiting the Atlantic Ocean along the US East Coast, a region disproportionately affected by climate change. Adjacent estuaries are experiencing similar alterations to their physical environments and biotic community composition. Many estuarine species are seasonal residents and changes to environmental conditions within an estuary can result in altered usage and residence …


Development Of 3d And 360 Gis-Based Models To Visualize Projected Sea Level Rise In Coastal Virginia, Candice M. Vinson Jan 2023

Development Of 3d And 360 Gis-Based Models To Visualize Projected Sea Level Rise In Coastal Virginia, Candice M. Vinson

Dissertations, Theses, and Masters Projects

Science communication is a skill that can be strengthened with practice. Like any skill, it helps to know what you need to practice in order to get better at it. When presenting information to an audience, the skill of science communication comes into play as early as the first draft of a presentation. As you think about how you will tell your story to the audience, you likely consider including text on slides, images, graphs, maps, or even videos. However, it is crucial to remember that accessibility barriers are something we must often consciously work to rid our presentations of, …


Appearance Driven Reflectance Modeling, James Christopher Bieron Jan 2023

Appearance Driven Reflectance Modeling, James Christopher Bieron

Dissertations, Theses, and Masters Projects

Creating realistic computer generated imagery is essential for modern movies and video games. Recreating the appearance of materials is integral to generating such photo-realistic images. While the problem of how to model materials is well studied, here we will focus on the question of how to recreate the appearance of specific materials found in the real world. In this dissertation we will begin with a short introduction to rendering, followed by a discussion of various material models, techniques for measuring reflectance, and strategies for fitting these models to reflectance data. We will then introduce a novel two-stage process for fitting, …


Matfusion: A Generative Diffusion Model For Svbrdf Capture, Samuel Lee Sartor Jan 2023

Matfusion: A Generative Diffusion Model For Svbrdf Capture, Samuel Lee Sartor

Dissertations, Theses, and Masters Projects

We formulate SVBRDF estimation from photographs as a diffusion task. To model the distribution of spatially varying materials, we first train a novel unconditional SVBRDF diffusion backbone model on a large set of 312,165 synthetic spatially varying material exemplars. This SVBRDF diffusion backbone model, named MatFusion, can then serve as a basis for refining a conditional diffusion model to estimate the material properties from a photograph under controlled or uncontrolled lighting. Our backbone MatFusion model is trained using only a loss on the reflectance properties, and therefore refinement can be paired with more expensive rendering methods without the need for …


Exploring Pah Partitioning In Oysters Using Immunological Techniques, Kristen Madison Prossner Jan 2023

Exploring Pah Partitioning In Oysters Using Immunological Techniques, Kristen Madison Prossner

Dissertations, Theses, and Masters Projects

Anthropogenic activities such as oil spills are major sources of polycyclic aromatic hydrocarbon (PAH) pollution in the environment. Bivalves such as C. virginica can accumulate high levels of PAHs in tissue due to a limited metabolic capacity for these compounds. Accordingly, bivalves have served as key biomonitoring species for contaminants and exposure to PAH through seafood consumption can also be an important risk to human health due to the toxic and carcinogenic potential of these compounds. For evaluating bivalve PAH levels, conventional analyses are limited due to extensive time and expense and unreliability. This work demonstrates the application of immunological …


Tracing Atlantic Sea Scallops Using Radio Frequency Identification (Rfid) Technology, Will Shoup Jan 2023

Tracing Atlantic Sea Scallops Using Radio Frequency Identification (Rfid) Technology, Will Shoup

Dissertations, Theses, and Masters Projects

Traceable seafood can be linked back to its origin and method of catch. Improving the traceability of marine organisms involves establishing a transparent Chain of Custody (CoC) by collecting data at checkpoints throughout the supply chain, from ship to shore to store. This report explores the feasibility of integrating Radio Frequency Identification (RFID) technology into the United States Atlantic sea scallop (Placopecten magellanicus) fishery in order to improve traceability. This report serves as a forward-looking evaluation of RFID technology that is intended to inform interested stakeholders of its functionality and capabilities. It is not intended to serve as a management …


Mattanock Town Restoration Plan, Katlin Mccarter Grigsby Jan 2023

Mattanock Town Restoration Plan, Katlin Mccarter Grigsby

Dissertations, Theses, and Masters Projects

Mattanock Town's Restoration Plan is a science-based restoration process that evaluates the site's history, the tribal history, and the most current research to maximize native habitats, enhance coastal resilience, and reconnect the Nansemond people to the local river. Restoration priorities include increasing native plant species, incorporating oyster habitat, and addressing erosion. This plan details how synthesizing existing and new physical, biological, and cultural information can help the Nansemond Indian Nation prioritize projects that benefit their community and the surrounding environment.


From Field To Shore: Policy Improvements To Better Protect Ecosystem And Human Health From Poultry Wastes In Virginia, Rachael A. King Jan 2023

From Field To Shore: Policy Improvements To Better Protect Ecosystem And Human Health From Poultry Wastes In Virginia, Rachael A. King

Dissertations, Theses, and Masters Projects

Commercial poultry production is a large industry with economic importance in Virginia. However, mismanagement of manures and wastes generated from the poultry industry can be a serious threat to ecosystem and human health. Primarily, there is a concern about nutrient pollution related to runoff and infiltration of poultry wastes. High nutrient loading can cause groundwater contamination, eutrophication, and harmful algal blooms (HABs). Additional concerns include metals, antibiotics, and pesticides that can be found in poultry wastes. To determine existing threats to ecosystem and human health from the poultry industry, Virginia policies regulating the industry are reviewed and their strengths and …


Achieving Equitable Offshore Wind Development: Lessons From European Stakeholders, Kacey Hirshfeld Jan 2023

Achieving Equitable Offshore Wind Development: Lessons From European Stakeholders, Kacey Hirshfeld

Dissertations, Theses, and Masters Projects

The Biden Administration has set aggressive offshore wind energy goals, aiming to have 30 gigawatts of offshore energy in place by 2030. This amount of energy has the potential to power 10 million homes (White House, 2022), helping the administration to reach larger clean energy goals. In Virginia, Dominion Energy aims to have 2.6 gigawatts of offshore wind energy by 2026, enough to power up to 660,000 homes (Dominion Energy).

While the upcoming offshore wind energy development will create clean energy and green jobs, the ocean is no longer an open field for development and already supports a complex matrix …


Experimental Studies Of Neutral Particles And The Isotope Effect In The Edge Of Tokamak Plasmas, Ryan Chaban Jan 2023

Experimental Studies Of Neutral Particles And The Isotope Effect In The Edge Of Tokamak Plasmas, Ryan Chaban

Dissertations, Theses, and Masters Projects

The H-mode plasma edge is a region of steep gradients in density and temperature known as the “pedestal” which greatly increases energy confinement. The complex links between neutral-plasma interactions and both diffusive and convective transport in the pedestal must be understood to model, predict, and achieve the high performance required for a fusion power plant. This dissertation explores the effects of different hydrogenic isotope neutral particles and plasma transport from the edge pedestal region into the Scrape-Off Layer. Current experiments typically use deuterium (H with amu=2 or D), however future fusion power plants may startup with hydrogen (H), and eventually …


Gas-Phase Proton Affinities Of Proline- And Pipecolic Acid-Containing Dipeptides, Trinh Ton Jan 2023

Gas-Phase Proton Affinities Of Proline- And Pipecolic Acid-Containing Dipeptides, Trinh Ton

Dissertations, Theses, and Masters Projects

Mass spectrometry (MS) is one of the most used techniques in proteomics because it allows for both high-throughput and quantitative analyses. Bottom-up MS-based proteomics involves breaking down proteins into smaller chains of amino acids called peptides, ionizing and fragmenting the peptides, and identifying the fragments using sequencing databases. These databases depend on the random fragmentation at the backbone peptide bond of the peptides, as predicted by the mobile proton model. Research has shown that peptides containing proline or pipecolic acid have selective fragmentations that could lead to incorrect identification in the sequencing algorithms. These selective cleavages are called “the proline …


Recoverable Memory Bank For Class-Incremental Learning, Jiangtao Kong Jan 2023

Recoverable Memory Bank For Class-Incremental Learning, Jiangtao Kong

Dissertations, Theses, and Masters Projects

Incremental learning aims to enable machine learning systems to sequentially learn new tasks without forgetting the old ones. While some existing methods, such as data replay-based and parameter isolation-based approaches, achieve remarkable results in incremental learning, they often suffer from memory limits, privacy issues, or generation instability. To address these problems, we propose Recoverable Memory Bank (RMB), a novel non-exemplar-based approach for class incremental learning (CIL). Specifically, we design a dynamic memory bank that stores only one aggregated memory representing each class of the old tasks. Next, we propose a novel method that combines a high-dimensional space rotation matrix and …


Characterizing Molecular Environments In Acrylic Paint Via Single-Sided Nmr, Lyndi Kiple Jan 2023

Characterizing Molecular Environments In Acrylic Paint Via Single-Sided Nmr, Lyndi Kiple

Dissertations, Theses, and Masters Projects

Acrylic paint is a modern artistic material made of colored pigment and polymeric binder. Acrylic binder requires fundamental study at the molecular level to understand its physical properties for purposes of art conservation and general polymer chemistry. The research presented in this thesis uses single-sided nuclear magnetic resonance (NMR) as a non-invasive and non-destructive way to measure relaxation and self-diffusion, which provide insight to molecular mobility and physical properties of proton-containing samples. Specifically, this study relies on T2 relaxation to gain insight to regions within acrylic paint with different molecular mobilities. In both dry and wet paint, relaxometry data revealed …


Succession Of The Late Summer Phytoplankton Blooms In The York River Estuary, Va, Heather Kathleen Corson Jan 2023

Succession Of The Late Summer Phytoplankton Blooms In The York River Estuary, Va, Heather Kathleen Corson

Dissertations, Theses, and Masters Projects

The influence of bottom-up and top-down controls on the formation and persistence of phytoplankton blooms has been well studied. However, the relative importance of these bottom-up and top-down controls vary spatially and temporally. In the tidal tributaries and mainstem of Chesapeake Bay, the summer dinoflagellate population follows a succession of bloom-producing species. The dinoflagellate species Margalefidinium polykrikoides and Alexandrium monilatum are currently considered the end of this succession. These species form near-annual blooms in the lower half of Chesapeake Bay and are considered harmful algal bloom (HAB) species due to their negative ecological impacts. However, analysis of long-term monitoring data …


Biotic And Abiotic Factors Associated With Temporal And Spatial Variability Of Constitutive Mixotroph Abundance And Proportion, Marcella Dobbertin Da Costa Jan 2023

Biotic And Abiotic Factors Associated With Temporal And Spatial Variability Of Constitutive Mixotroph Abundance And Proportion, Marcella Dobbertin Da Costa

Dissertations, Theses, and Masters Projects

Mixotrophic protists, which combine the use of photosynthesis and prey ingestion to obtain nutrients for growth, comprise a substantial portion of the plankton community. However, there is a major gap in our understanding of how mixotroph prevalence varies spatially and temporally and under what conditions they dominate. I utilized a recently developed molecular technique to experimentally identify active mixotrophs (taxa identified to be grazing when samples were collected) and combined this with microscopy data to estimate active mixotroph abundance and proportion at two locations in a temperate estuary over a year. Active mixotroph abundance was compared to potential mixotroph (taxa …


A Comprehensive Study Of Bills Of Materials For Software Systems, Trevor Stalnaker Jan 2023

A Comprehensive Study Of Bills Of Materials For Software Systems, Trevor Stalnaker

Dissertations, Theses, and Masters Projects

Software Bills of Materials (SBOMs) have emerged as tools to facilitate the management of software dependencies, vulnerabilities, licenses, and the supply chain. Significant effort has been devoted to increasing SBOM awareness and developing SBOM formats and tools. Despite this effort, recent studies have shown that SBOMs are still an early technology not adequately adopted in practice yet, mainly due to limited SBOM tooling and lack of industry consensus on SBOM content, tool usage, and practical benefits. Expanding on previous research, this paper reports a comprehensive study that first investigates the current challenges stakeholders encounter when creating and using SBOMs. The …


Efficient Parallelization Of Irregular Applications On Gpu Architectures, Qihan Wang Jan 2023

Efficient Parallelization Of Irregular Applications On Gpu Architectures, Qihan Wang

Dissertations, Theses, and Masters Projects

With the enlarging computation capacity of general Graphics Processing Units (GPUs), leveraging GPUs to accelerate parallel applications has become a critical topic in academia and industry. However, a wide range of irregular applications with a computation-/memory-intensive nature cannot easily achieve high GPU utilization. The challenges mainly involve the following aspects: first, data dependence leads to a coarse-grained kernel; second, heavy GPU memory usage may cause frequent memory evictions and extra overhead of I/O; third, specific computation patterns produce memory redundancies; last, workload balance and data reusability conjunctly benefit the overall performance, but there may exist a dynamic trade-off between them. …