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Differentiation Of Human, Animal And Synthetic Hair By Atr Ftir Spectroscopy, Jeremy Manheim May 2015

Differentiation Of Human, Animal And Synthetic Hair By Atr Ftir Spectroscopy, Jeremy Manheim

Chemistry

Hair fibers are ubiquitous to every environment and are the most commonly found form of trace evidence at crime scenes. The primary difficulty forensic examiners face after retrieving a hair sample is determining who it came from. Currently, the methodology of microscopic examination of potential hair evidence is absent of statistical probability and is inherently subjective. Another method, involving DNA analysis, takes months to conduct and the majority of times is unsuccessful due to its degradation and absence from the hair. Here, Attenuated Total Reflectance (ATR) Fourier Transform Infrared (FTIR) Spectroscopy coupled with advanced statistics was used to identify a …


The Van Der Pol Oscillator As A Model Of The Hair Cell Auditory Response: A Numerical Study, Thomas Yocono May 2015

The Van Der Pol Oscillator As A Model Of The Hair Cell Auditory Response: A Numerical Study, Thomas Yocono

Physics

Hair cells, which detect and encode sound stimuli, have been shown to have a non-linear response and self sustaining oscillations. Here, we look at the Van der Pol oscillator, which has these properties, and numerically calculate its response to multiple driving frequencies. Any nonlinear system's response to multiple driving frequencies will have not just the driving frequencies present, but also combination tones, or heterodyne frequencies, which have order defined by the number of driving frequency combinations. This phenomenon has been experimentally confirmed in the human auditory response [1]. In the frequency specture of the Van der Pol steady state response …


Strain Relaxation In Nm-Thick Cu And Cu-Alloy Films Bonded To A Rigid Substrate, Ashley Herrmann Jan 2015

Strain Relaxation In Nm-Thick Cu And Cu-Alloy Films Bonded To A Rigid Substrate, Ashley Herrmann

Legacy Theses & Dissertations (2009 - 2024)

In the wide scope of modern technology, nm-thick metallic films are increasingly used as lubrication layers, optical coatings, plating seeds, diffusion barriers, adhesion layers, metal contacts, reaction catalyzers, etc. A prominent example is the use of nm-thick Cu films as electroplating seed layers in the manufacturing of integrated circuits (ICs). These high density circuits are linked by on-chip copper interconnects, which are manufactured by filling Cu into narrow trenches by electroplating. The Cu fill by electroplating requires a thin Cu seed deposited onto high-aspect-ratio trenches. In modern ICs, these trenches are approaching 10 nm or less in width, and the …


Initiated Chemical Vapor Deposition (Icvd) Polymer Thin Films : Structure-Property Effects On Thermal Degradation And Adhesion, Vijay Jain Bharamaiah Jeevendrakumar Jan 2015

Initiated Chemical Vapor Deposition (Icvd) Polymer Thin Films : Structure-Property Effects On Thermal Degradation And Adhesion, Vijay Jain Bharamaiah Jeevendrakumar

Legacy Theses & Dissertations (2009 - 2024)

Opportunities and challenges for chemical vapor deposition (CVD) of polymer thin films stems from their applications in electronics, sensors, and adhesives with demands for control over film composition, conformity and stability. Initiated chemical vapor deposition (iCVD) is a subset of the CVD technique that conjoins bulk free-radical polymerization chemistry with gas-phase processing. The novelty of iCVD technique stems from the use of an initiator that can be activated at low energies (150 – 300 °C) to react with surface adsorbed monomer to form a polymer film. This reduces risk for potential unwarranted side-reactions.


Luminescence Of Lanthanide Ions In Octahedral Coordinations With Comparison To The Centroid Shift And Host Lattice Exciton Energy, Sam J. Camardello Jan 2015

Luminescence Of Lanthanide Ions In Octahedral Coordinations With Comparison To The Centroid Shift And Host Lattice Exciton Energy, Sam J. Camardello

Legacy Theses & Dissertations (2009 - 2024)

In this dissertation, we have studied the luminescence of the lanthanide ions (Ce3+, Eu2+, Eu3+, Tb3+, and Pr3+), specifically in the highly symmetric octahedral coordination. This high symmetry coordination readily permits the optical properties of the luminescent ions to be determined spectroscopically. Relevant optical parameters such as the Stokes Shift (∆S), red shift (D(2+, 3+, A), crystal field splitting (Ɛcfs), and centroid sift (Ɛc), along with the excitation and emission spectra, are presented. Three different crystal structures were studied, namely, M2+Al2B2O7 (M2+ = Ca, Sr, Ba) doped with Eu2+ and Ce3+, KBaLn3+(BO3)2 (M3+ = all lanthanides, Y, Sc) doped with …


Using Storm-Watersheds And A Multi-Criteria Decision Model For Biodiversity Conservation In An Urban Environment, Christina M. Chiappetta Jan 2015

Using Storm-Watersheds And A Multi-Criteria Decision Model For Biodiversity Conservation In An Urban Environment, Christina M. Chiappetta

Legacy Theses & Dissertations (2009 - 2024)

Many planning and land use decisions in New York State are controlled at the local (town or municipal) level, not an optimal scale for planning and implementing resource conservation management. Watershed boundaries provide a more ecologically meaningful scale for conservation, because they capture a full range of natural ecosystem processes that span political boundaries. However, defining an urban watershed is complicated by stormwater infrastructure, so standard topographic watershed boundaries may be inadequate for urban resource conservation even when applied at the watershed scale. Storm-watersheds distort both municipal and watershed boundaries, because the flows are redirected in ways that are often …


Extraction Of Carrier Mobility And Interface Trap Density In Ingaas Metal Oxide Semiconductor Structures Using Gated Hall Method, Thenappan Chidambaram Jan 2015

Extraction Of Carrier Mobility And Interface Trap Density In Ingaas Metal Oxide Semiconductor Structures Using Gated Hall Method, Thenappan Chidambaram

Legacy Theses & Dissertations (2009 - 2024)

III-V semiconductors are potential candidates to replace Si as a channel material in next generation CMOS integrated circuits owing to their superior carrier mobilities. Low density of states (DOS) and typically high interface and border trap densities (Dit) in high mobility group III-V semiconductors provide difficulties in quantification of Dit near the conduction band edge. The trap response above the threshold voltage of a MOSFET can be very fast, and conventional Dit extraction methods, based on capacitance/conductance response (CV methods) of MOS capacitors at frequencies <1MHz, cannot distinguish conducting and trapped carriers. In addition, the CV methods have to deal with high dispersion in the accumulation region that makes it a difficult task to measure the true oxide capacitance, Cox value. Another implication of these properties of III-V interfaces is an ambiguity of determination of electron density in the MOSFET channel. Traditional evaluation of carrier density by integration of the C-V curve, gives incorrect values for Dit and mobility. Here we employ gated Hall method to quantify the Dit spectrum at the high-κ oxide/III-V semiconductor interface for buried and surface channel devices using Hall measurement and capacitance-voltage data. Determination of electron density directly from Hall measurements allows for obtaining true mobility values


Visual Saliency Estimation : A Pre-Attentive Cognitive And Context-Aware Approach, Amanda Shannon Danko Jan 2015

Visual Saliency Estimation : A Pre-Attentive Cognitive And Context-Aware Approach, Amanda Shannon Danko

Legacy Theses & Dissertations (2009 - 2024)

At each glance, biological vision systems organize a tremendous amount of input and


Evolution Of African Easterly Waves And Their Relationship To Tropical Cyclogenesis, Alan Brammer Jan 2015

Evolution Of African Easterly Waves And Their Relationship To Tropical Cyclogenesis, Alan Brammer

Legacy Theses & Dissertations (2009 - 2024)

The research in this thesis explores the relationship between African easterly waves (AEWs) and tropical cyclogenesis over the eastern Atlantic. This research utilises 33 years of reanalysis and satellite data to investigate the interaction between AEW troughs, the surrounding environment and the embedded vortex.


Optical Metrology For Directed Self-Assembly Patterning Using Mueller Matrix Spectroscopic Ellipsometry Based Scatterometry, Dhairya J. Dixit Jan 2015

Optical Metrology For Directed Self-Assembly Patterning Using Mueller Matrix Spectroscopic Ellipsometry Based Scatterometry, Dhairya J. Dixit

Legacy Theses & Dissertations (2009 - 2024)

The semiconductor industry continues to drive patterning solutions that enable devices with higher memory storage capacity, faster computing performance, lower cost per transistors, and higher transistor density. These developments in the field of semiconductor manufacturing along with the overall minimization of the size of transistors require cutting-edge metrology tools for characterization.


Evaluating Preferred Direction Tropical Cyclone Track Variability In An Operational Global Ensemble Prediction System, Travis Elless Jan 2015

Evaluating Preferred Direction Tropical Cyclone Track Variability In An Operational Global Ensemble Prediction System, Travis Elless

Legacy Theses & Dissertations (2009 - 2024)

Ensemble forecasts of Tropical Storm Debby and Hurricane Sandy (2012) highlight instances where variability in tropical cyclone (TC) position forecasts are stretched along a preferred direction. The goal of this thesis is to analyze this stretching of variability in a global ensemble prediction system, particularly the European Centre for Medium-Range Weather Forecasts (ECMWF), to determine how often and under what conditions does variability stretching occur, and ultimately what feature(s) are responsible for generating this variability.


Deciding Static Inclusion For Delta-Strong And Omega [Upside Down Triangle]-Strong Intruder Theories : Applications To Cryptographic Protocol Analysis, Kimberly Ann Gero Jan 2015

Deciding Static Inclusion For Delta-Strong And Omega [Upside Down Triangle]-Strong Intruder Theories : Applications To Cryptographic Protocol Analysis, Kimberly Ann Gero

Legacy Theses & Dissertations (2009 - 2024)

In this dissertation we will be studying problems relating to indistinguishability. This topic


A Study Of The Emergence Of Student Tacit Knowledge In Response To Environmental Images And Science Instruction, Rory J. Glass Jan 2015

A Study Of The Emergence Of Student Tacit Knowledge In Response To Environmental Images And Science Instruction, Rory J. Glass

Legacy Theses & Dissertations (2009 - 2024)

The purpose of this study was to identify the presence of students’ tacit understandings as they apply to environmental science content, and to discover how these understandings emerge and are viewed and interpreted by teachers. Towards that end over ten hours of classroom video was recorded and analyzed, from both large urban and smaller urban classrooms. Additionally, interviews were conducted with 15 students and two teachers to gain insight into their thinking on an array of topics related to the environment and environmental reasoning. It was hypothesized that students’ understandings and teachers’ interpretations of them may be influenced by their …


Swan Modules Of Elementary Abelian 2-Groups Over Quadratic Imaginary Fields, Maxine Guzman Jan 2015

Swan Modules Of Elementary Abelian 2-Groups Over Quadratic Imaginary Fields, Maxine Guzman

Legacy Theses & Dissertations (2009 - 2024)

We show that every quadratic imaginary extension of the field of rationals has a biquadratic extension without a normal integral basis.


Generators For K₁ Of A Category With Cofibrations, Emily Hepworth Jan 2015

Generators For K₁ Of A Category With Cofibrations, Emily Hepworth

Legacy Theses & Dissertations (2009 - 2024)

We describe generators for the first algebraic K-theory group of categories with cofibrations, generalizing previous results by Gillet-Grayson and Sherman in the case of exact categories.


Coherent Scattering Imaging Monte Carlo Simulation, Laila Hassan Jan 2015

Coherent Scattering Imaging Monte Carlo Simulation, Laila Hassan

Legacy Theses & Dissertations (2009 - 2024)

Conventional mammography has poor contrast between healthy and cancerous tissues due to the small difference in attenuation properties. Coherent scatter potentially provides more information because interference of coherently scattered radiation depends on the average intermolecular spacing, and can be used to characterize tissue types. However, typical coherent scatter analysis techniques are not compatible with rapid low dose screening techniques. Coherent scatter slot scan imaging is a novel imaging technique which provides new information with higher contrast. In this work a simulation of coherent scatter was performed for slot scan imaging to assess its performance and provide system optimization. In coherent …


Two-Dimensional Chalcogenides : Material Synthesis And Nano-Device Applications, Robin Bay Jacobs-Gedrim Jan 2015

Two-Dimensional Chalcogenides : Material Synthesis And Nano-Device Applications, Robin Bay Jacobs-Gedrim

Legacy Theses & Dissertations (2009 - 2024)

Low-dimensional nanostructures exhibit distinct properties from their bulk counterparts. Here the synthesis of novel low-dimensional nanostructures is demonstrated using both top down and bottom up processes and their properties are investigated. Two-dimensional (2D) binary sesquichalcogenides are introduced as a viable material platform for phase change random access memory, photodetection, and the investigation of topological insulator surface states. An exponential relationship is observed between layer thickness and energy consumption during switching of 2D phase change devices, ultra-high responsivity in 2D photoresistors, and surface-rich conduction in 2D topological insulator nanoplates. Additionally, methods for the assessment of chemical purity, stoichiometry, and dimensions of …


Phase Imaging Using X-Ray Optics, Bushra Kanwal Jan 2015

Phase Imaging Using X-Ray Optics, Bushra Kanwal

Legacy Theses & Dissertations (2009 - 2024)

Conventional x-ray imaging is a widely used imaging technique in medical diagnostics as well as material analysis. It utilizes only absorption-contrast imaging, which records intensity attenuation due to absorption. A major limitation of this technique for medical imaging is the poor contrast of weakly absorbing details in the soft tissue. Mammography and angiography are two examples where improved contrast is required. In the quest for better contrast in x-ray imaging, a number of different phase contrast imaging techniques have been explored. Phase contrast imaging offers an improvement over traditional absorption contrast because the x-ray wave field traversing an object experiences …


Black Hole Microstates In String Theory, Joseph Lewkowicz Jan 2015

Black Hole Microstates In String Theory, Joseph Lewkowicz

Legacy Theses & Dissertations (2009 - 2024)

String theory has resolved the information paradox associated with entropy of black holes by identifying microscopic states contributing to this entropy. This thesis reviews the origin of the paradox, and discusses the progress in resolving it, starting from the counting of states by Strominger and Vafa, and culminating in the current work on constructing fuzzball geometries. A particular emphasis is given to a promising technique for constructing new geometries known as spectral flow.


Mixed Ligand Approach To Design Heterometallic Single-Source Precursors For Low-Temperature Preparation Of Oxide Materials, Craig Matthew Lieberman Jan 2015

Mixed Ligand Approach To Design Heterometallic Single-Source Precursors For Low-Temperature Preparation Of Oxide Materials, Craig Matthew Lieberman

Legacy Theses & Dissertations (2009 - 2024)

There is a considerable interest in the use of metal oxides for development of novel high-technological materials such as gas sensors, multiferroics, and electrocatalysts. In particular, the design of complex oxides, which incorporate more than one type of metal atom, is focused on enriching chemical and physical properties of the target materials and allowing for increased functionality. In order to replace the harsh conditions associated with traditional synthetic routes that often require high temperatures and/or pressures, new soft chemistry methods for the preparation of mixed-metal oxide materials have been developed. One of the most promising directions is the emergence of …


Novel Nmr Based Technologies To Study Macromolecular Structures, Subhabrata Majumder Jan 2015

Novel Nmr Based Technologies To Study Macromolecular Structures, Subhabrata Majumder

Legacy Theses & Dissertations (2009 - 2024)

Nuclear Magnetic Resonance Spectroscopy (NMR) is one of the principle tools in structural biology to probe macromolecular structures and interactions. The atomic resolution afforded by this technique has been widely used to probe protein-protein, and protein-ligand interactions in-vitro. However, the natural milieu of the proteins is the living cell and the cellular cytoplasm is extremely heterogeneous. The NMR studies of folded protein in-cell, till now, have been limited by non-specific interactions of the cytosol. This thesis outlays a general methodology to study protein structure/interactions inside the living cells using NMR. In a closely related objective, it also describes the use …


Comparison Of Glucose, Fructose And Sucrose Amperometric And Thermal Sensors For Detection Of Carbohydrates In Living Plant Tissue, Scott Mcadoo Jan 2015

Comparison Of Glucose, Fructose And Sucrose Amperometric And Thermal Sensors For Detection Of Carbohydrates In Living Plant Tissue, Scott Mcadoo

Legacy Theses & Dissertations (2009 - 2024)

Ecologists currently cannot test concentrations of carbohydrates in sap in vivo. Testing carbohydrates with current technology would require destructive tissue sampling. The tissue sampling involves large amounts of time and money to collect and test. Aphids are an insect that can bypass a tree’s passive immune system and feed off a phloem region for weeks. A series of enzymatic biosensors could be used to detect the concentration changes of specific carbohydrates. A calcium chelant can be added to defeat a tree’s immune system like an aphid. The detection of three carbohydrates, fructose, glucose and sucrose are involved in this study. …


Diagnosis Of The Source Of Medium-Range Forecast Errors For An Extratropical Cyclone, William Lamberson Jan 2015

Diagnosis Of The Source Of Medium-Range Forecast Errors For An Extratropical Cyclone, William Lamberson

Legacy Theses & Dissertations (2009 - 2024)

Medium-range forecasts of an extratropical cyclone set to impact Western Europe on 16 Dec 2011 consistently predicted that the cyclone would be intense, with a minimum pressure as low as 930-hPa and an expansive area of high winds. In actuality, the cyclone never deepened below 965-hPa and its impact on Western Europe was minimal.


Two Step Parsimonious Variable Selection For Right Censored Continuous Survival Time Models, Anju Menon Jan 2015

Two Step Parsimonious Variable Selection For Right Censored Continuous Survival Time Models, Anju Menon

Legacy Theses & Dissertations (2009 - 2024)

Variable selection is fundamental in any kind of statistical modeling. There has been ex- tensive research by different authors on methods of variable selection from linear regression models to more complex non-linear applications. Modeling survival data especially poses challenges because of a more complicated data structure as the time variable T is usually subject to censoring. This thesis presents a two step objective approach to choose between several candidate models based on the the ability of the model to predict survival times using loss functions. Once potentially important variables are selected using a screening method called Iterative Sure Independence Screening(ISIS) …


The Impacts Of Varability In Temperature And Humidity On Electricity Consumption In New York State, Eric Adamchick Jan 2015

The Impacts Of Varability In Temperature And Humidity On Electricity Consumption In New York State, Eric Adamchick

Legacy Theses & Dissertations (2009 - 2024)

A seasonal harmonic linear regression approach is presented to model the seasonal and diurnal relationships between surface weather observations and electricity load data in New York State. The relationships between dry-bulb, dew point, and wet-bulb temperatures with electricity load were evaluated using the correlation coefficient to test the strength of the relationships, while the regression slope coefficient provided an interpretable scale for those relationships. We found that the strongest seasonal and diurnal relationships occur during boreal summer from the afternoon through the overnight hours, while similar but negative relationships are observed during the winter. Using the same seasonal harmonic linear …


Monitoring Soil Response To Decreasing Acidic Deposition In A Western Adirondack Tributary Over A 16 Year Period, Michael Robert Antidormi Jan 2015

Monitoring Soil Response To Decreasing Acidic Deposition In A Western Adirondack Tributary Over A 16 Year Period, Michael Robert Antidormi

Legacy Theses & Dissertations (2009 - 2024)

Abstract


Phase Imaging Using Focusing Polycapillary Optics, Sajid Bashir Jan 2015

Phase Imaging Using Focusing Polycapillary Optics, Sajid Bashir

Legacy Theses & Dissertations (2009 - 2024)

The interaction of X rays in diagnostic energy range with soft tissues can be described by Compton scattering and by the complex refractive index, which together characterize the attenuation properties of the tissue and the phase imparted to X rays passing through it. Many soft tissues exhibit extremely similar attenuation, so that their discrimination using conventional radiography, which generates contrast in an image through differential attenuation, is challenging. However, these tissues will impart phase differences significantly greater than attenuation differences to the X rays passing through them, so that phase-contrast imaging techniques can enable their discrimination.


Identical Particles In Quantum Mechanics : Operational And Topological Considerations, Klil H. Neori Jan 2015

Identical Particles In Quantum Mechanics : Operational And Topological Considerations, Klil H. Neori

Legacy Theses & Dissertations (2009 - 2024)

This dissertation reports our investigation into the existence of anyons, which interpolate between bosons and fermions, in light of the Symmetrization Postulate, which states that only the two extremes exist. The Symmetrization Postulate can be understood as asserting that there are only two consistent ways of combining the behavior of distinguishable particles to obtain the behavior of identical ones. We showed that anyonic behavior then arises because of the way in which the probability amplitudes of distinguishable particles in two dimensions are affected by the topology of the space. These can then be combined in one of the ways arising …


Developing A Weibull Model Extension To Estimate Cancer Latency Times, Diana L. Nadler Jan 2015

Developing A Weibull Model Extension To Estimate Cancer Latency Times, Diana L. Nadler

Legacy Theses & Dissertations (2009 - 2024)

More than one-third of all Americans will be diagnosed with cancer sometime in their lives. Though their illness may be invisible now, it presents a great, and largely unexamined, opportunity to find and treat their cancers early. Early detection represents one of the most promising approaches to reduce the growing cancer burden by identifying cancer while it is localized and curable, preventing not only mortality, but also reducing morbidity and costs.


Distributions And Formations Of Hono In The Troposphere, Dennis Pu Jan 2015

Distributions And Formations Of Hono In The Troposphere, Dennis Pu

Legacy Theses & Dissertations (2009 - 2024)

Nitrous acid (HONO) is an important reactive nitrogen species and a precursor to the hydroxyl radical. It plays important roles in reactive nitrogen recycling and in photo-oxidant formation in the troposphere. However, much is still unknown about its formation mechanisms and distributions in the troposphere. This research is part of NOMADSS (Nitrogen, Oxidants, Mercury, and Aerosol Distributions, Sources and Sinks) field study contributed by over 10 research groups in the United States to investigate the tropospheric chemistry of reactive nitrogen, mercury, oxidant and aerosols. One of the goals was to study the HONO distribution and formation mechanisms in the troposphere. …