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Precision Of Parameter Estimation In Quantum Metrology, Chenglong You

LSU Doctoral Dissertations

The fundamental precision limit of an interferometer is crucial since it bounds the best possible sensitivity one could achieve using such a device. This thesis will focus on several different interferometers and try to give the ultimate precision bounds by carefully counting all the resources used in the interferometers.

The thesis begins with the basics of the quantum state of light. The fundamentals of quantum metrology are also reviewed and discussed. More specifically, the terminology of classical and quantum Cram\'er-Rao bound and classical and quantum Fisher information are introduced.

Chapter 3 discusses the conclusive precision bounds in two-mode interferometer such …

Vulnerability Of Industrial Facilities In The Lower Mississippi River Industrial Corridor To Relative Sea Level Rise And Tropical Cyclone Storm Surge, Joseph Blake Harris

LSU Doctoral Dissertations

Relative sea level rise (RSLR) and tropical cyclone-induced storm surge are major threats to the Lower Mississippi River Industrial Corridor (LMRIC) which has approximately 120 industrial complexes located within the corridor. Spatial interpolation methods were applied to the 2004 National Oceanic and Atmospheric published Technical Report #50 subsidence dataset and cross-validation techniques were used to determine the accuracy of each method. Digital elevation models (DEMs) were created for the years 2025, 2050, and 2075, based on these predictive surface of subsidence rates. Future DEMs were utilized to model RSLR and determine the extent of storm surge on the LMRIC by …

Fate Of Selected Pollutants Of Concern On Particulate Matter (Pm) Surface, Ajit Ghimire

LSU Doctoral Dissertations

This research focuses on the environmental fate of particle associated pollutants such as Polybrominated Diphenyl Ethers (PBDEs), Polyaromatic Hydrocarbons (PAHs), and Environmentally Persistent Free Radicals (EPFRs) with a special emphasis on their transformation due to interaction with a matrix or co-pollutants. It encompasses two approaches to the stated problems: analysis of samples collected in the environment and laboratory simulation of the molecular transformations.

The PBDE studies relied on the ambient air Particulate Matter (PM) samples collected from Bangkok, Thailand. Results showed the presence of various PBDE homologs from tri- to hepta-PBDEs on both PM_2.5and Total Suspended Particle (TSP) …

The Modern Mississippi: Provenance Indicators And Human Impact, Brittney Anne Gregory

LSU Doctoral Dissertations

Given the significant degree to which the modern Mississippi River and its tributaries have been altered through dams, levees, and diversions, it is important to understand how sediment is transported from source to sink. The objective of this dissertation is to explore how the modern Mississippi River transports sediment from its tributaries to its delta using three independent proxies. Provenance indicators have traditionally been an effective way with which to characterize sediment transport in large river systems. First, detrital U-Pb zircon dating is used to investigate modern flux and possible anthropogenic influences on coarse-grained sediment within the modern Mississippi River. …

Infrared Laser Ablation For Biomolecule Sampling, Kelin Wang

LSU Doctoral Dissertations

In this research, an infrared laser at a wavelength of 3 µm was used to ablate material from tissue sections for biomolecule analysis. Pulsed infrared (IR) irradiation of tissue with a focused laser beam efficiently removed biomolecules, such as proteins, enzymes, DNA, and RNA from tissue sections for further analysis. In a proteomics project, matrix-assisted laser desorption/ionization mass spectrometry imaging (MALDI-MSI) was used to determine regions of interest (ROI) for laser ablation. The matrix was then washed off. By overlaying the MSI generated heat-map, the section was sampled using IR laser ablation and custom stage-control software. Two ROI were selected …

Improving Coupled Enzyme Assays With Capillary Electrophoresis, Thu Hoai Nguyen

LSU Doctoral Dissertations

The goal of this project is to address limitations of coupled enzyme assays using capillary electrophoresis (CE). In some enzyme assays, it is ineffective to directly detect products and substrates spectroscopically (absorption or fluorescence). Coupling the enzyme-catalyzed reaction of interest with another enzyme-catalyzed reaction allows for indirect detection of product formation or substrate depletion for the target enzyme. While conventional coupled enzyme assays are facile for kinetic measurements, they can be problematic for inhibition screening due to spectral and inhibitor interferences. To address these limitations of coupled assays, CE has been used to develop enzyme assays for acetyl-coenzyme A carboxylase …

Deltaic Wetland Dynamics From Seasonal To Centennial Scales, Giancarlo A. Restreppo

LSU Doctoral Dissertations

The lower plain of the Mississippi River Delta contains approximately five coastal sedimentary basins that are topographically defined, and one shelf-crossing depocenter (the Birds Foot Delta). These depositional systems receive varying quantities of sediment from fluvial and marine sources and have rates of coastal land loss that are roughly inversely proportional to fluvial sediment supply. To combat land loss along these regions, Louisiana has launched a historic campaign to sustain and regrow coastal lands using, in part, river sediment diversions. Fine sediments constitute the majority of sediment load in the Mississippi River, but are under-studied with respect to dispersal processes, …

Determination Of Conversion Factors For Various Calibration Geometries Using Barium-133 In A Silver Zeolite Cartridge, Amin Hamideh

LSU Master's Theses

Iodine-131 (I-131) is a major fission product among other radionuclides released during a nuclear incident. This radioiodine has a half-life of 8.02 days and the primary organ of uptake through ingestion or inhalation is the thyroid gland. For these reasons, nuclear power plants must routinely monitor I-131 through air sampling. Currently, there are two adsorbing media to collect I-131: activated charcoal and silver zeolite cartridges. Silver zeolite cartridges are generally used during a post nuclear incident due to its affinity for iodine while not adsorbing noble gases such as krypton-85 and xenon-135. After an air sample is taken from a …

Investigating Cationic Metal Centers For Hydroformylation, Ryan Alexander Johnson

LSU Doctoral Dissertations

Bimetallic cooperativity can potentially increase activity of reactions. This concept is another way to increase reactivity besides simply focusing on the steric and electronic effects of a ligand. A binucleating tetrasphosphine ligand has been developed to showcase bimetallic cooperativity between two rhodium metal centers. Hydroformylation is a widely used industrial process to produce aldehydes from alkenes, H₂, and CO. The dirhodium catalyst, [Rh₂(μ-CO)(CO)₃(rac-et,ph-P4-Ph)](BF₄)₂,is highly active leading to favorable results when using a DMF/water solvent system, 1-hexene, 90 psi 1:1 H₂/CO, and 90° C: initial turnover frequency …

Reflector Dip Trends In Seismic Sh-Wave Imaging Of A Modern Lower Mississippi River Point Bar, Adam Gostic

LSU Master's Theses

Various studies of ancient point bars have noted that a relationship can be observed between the dip angle and grain size of point bar lateral accretion deposits, with the most mud-rich deposits tending to exhibit the greatest dip. No analysis and only cursory explanations for this relationship have been provided. Additionally, buried mid-channel bars are absent from typical models of point bar architecture.

We successfully image the architecture of late-stage point bar deposits with a near surface 2D seismic SH-wave reflection survey and generate an SH-wave velocity model of the subsurface in the study area in order to interpret the …

Phase Estimation In Linear And Nonlinear Interferometers, Sushovit Adhikari

LSU Doctoral Dissertations

Phase estimation has a wide range of applications. Over the years, several strategies have been studied to improve precision in phase estimation. These strategies include using exotic quantum states to quantum detection schemes. This dissertation summarizes my effort in improving the precision of phase estimation with a linear and nonlinear interferometer.

Chapter 1 introduces quantum optics and quantum metrology. I introduce all relevant quantum states of light used. We also look into tools and terminologies of quantum metrology such as Fisher information, shot-noise limit, Heisenberg limit, etc., along with examples of phase estimation with a Mach-Zehnder interferometer.

In Chapter 2, …

The Effect Of Invasive Aquatic Vegetation On Odonate Diversity In An Urban Area, Sarah Thomas

Honors Theses

No abstract provided.

Assessing Knowledge Of Coastal Land Loss In Louisiana High School Graduates, Madelyn Smith

Honors Theses

No abstract provided.

Peerra: An Extensible And Structured Web Service For Peer-To-Peer Assistance, Drake Lambert

Honors Theses

No abstract provided.

Voc Emission Factors From 3d Printers - Abs (Acrylonitrile-Butadiene-Styrene) Type Filaments, Dean Lay

LSU Master's Theses

Acrylonitrile-butadiene-styrene (ABS) is a polymer that is widely used in many plastic products and is receiving new attention due to its use as a filament for fused deposition modelling (FDM) 3D printers. It has been shown to emit potentially dangerous volatile organic compounds (VOCs) when heated at temperatures used in the 3D printing process. Many new products are becoming available that contain various additives to the polymer matrix, which have an unknown effect on the emission profiles and rates. In this study a method is developed using a modified system for thermal diagnostic studies (STDS) to evaluate VOC emission from …

Evaluation Of Naturally Occurring Radioactive Material In Seafood From The Gulf Of Mexico, Charles Algeo Wilson Iv

LSU Doctoral Dissertations

Radioactive disintegration of naturally occurring radioactive material was modeled with high precision and no assumptions to better understand serial decay in high order disequibrlia. This model helped develop a new method of quick analysis of NORM, where radioactivity can be measured with reasonable certainty before secular equilibrium is established. This approach was a significant improvement on previous similar approaches, halving time required for the same results and reduced wait time compared to classical approaches by 92%. Consequentially, NORM was measured in selected seafood samples from three areas in the Gulf of Mexico. Red Snapper, Red Drum, Northern Whiting, Spotted Trout …

Habitat Usage Patterns Of Bottlenose Dolphins (Tursiops Truncatus) In Terrebonne And Timbalier Bays, Louisiana, Mary Allison Manning

LSU Master's Theses

I coupled fine-scale environmental data with observed behavior and group composition data to examine overall distribution within the bay system and to characterize the habitat associated with foraging and the presence of calves. Semi-isolated populations of bottlenose dolphins (Tursiops truncatus) along Louisiana’s coast are undergoing increased risks from boat traffic, oil spills, land subsidence, and planned water diversions (CPRA 2017). Characterizing the habitat use of bottlenose dolphins in Terrebonne and Timbalier bays, Louisiana, is important given the likely high site fidelity, small home ranges, and low exchange of individuals with nearby coastal populations (Lane et al. 2015, McDonald …

Monitoring Sediment Dynamics And Vegetation Competition Based On Micro-Topography And Terrestrial Lidar For Wetland Restoration, Xukai Zhang

LSU Doctoral Dissertations

With the ability to attenuate wave and limit erosion, coastal wetlands are important to protect shoreline for coastal communities. Micro-topography in coastal wetlands has a significant influence on hydrology, habitat variability and ecosystem functions. However, when mapping micro-topography by terrestrial LiDAR in coastal environments, the coverage of dense vegetation leads to a relatively low chance of laser penetration through the canopy to the ground. This dissertation proposes a rapid and flexible terrain mapping solution for the densely vegetated coastal environment by integrating crown structure from terrestrial LiDAR with terrain samples from GPS. The validated results in the study site demonstrate …

An Airlifted Tidal Mesocosm For Oil Degradation Studies, Daniel Christopher Alt

LSU Doctoral Dissertations

Mesocosms were constructed to allow scientists to isolate variables in a microtidal marsh environment, mimicking the natural conditions found in Terrebonne Bay. The control offered by these mesocosms is given by a process control system that takes user inputs and automates water movement. Twelve mesocosms were constructed, each holding 4.02 m³ (142 ft³) of marsh soil and 3.88 m³ (137 ft³) of water to give 3 experimental levels and a control, all in triplicate.

Each mesocosms that was constructed contained marsh plants in soil plugs 9 feet in diameter and 3 feet deep. These …

Atomic Force Microscopy Tip-Enhanced Laser Ablation, Fan Cao

LSU Doctoral Dissertations

In the present work, an apertureless atomic force microscope (AFM) tip-enhanced laser ablation (TELA) system was developed and investigated. An AFM was coupled to an optical parametric oscillator (OPO) wavelength tunable laser for sample ablation with a submicron sampling size. The AFM was used to image the surface and hold the AFM tip 10 nm above the sample surface. The AFM tip is coated with a layer of gold with a thickness of 35 nm. The incident laser wavelength was tuned in the visible and near-infrared (IR) region and focused on the AFM tip. With the tip-enhancement effect, ablation craters …

Photo-Induced Remote C-H Functionalization And New Thioglycoside Donor Development For O-Glycosylation, Shaofu Du

LSU Doctoral Dissertations

This dissertation focuses on the method development of C-H functionalization using photo-redox catalysis and the synthesis of new thioglycoside donors towards O-glycosylation. Chapter 1 describes the remote Csp³-H functionalization using photo-redox catalysis. The site-selective and high-yielding conversion of unreactive aliphatic C-H bonds has been a challenge for organic chemists for many years. In this work, inert C-H bonds were successfully converted to more useful C-C, C-N, and C-O bonds via hydrogen atom transfer (HAT), radical translocation and polar crossover. This mechanistic manifold was enacted by visible-light irradiation of o-diazoniaphenyl alkyl sulfones in the presence of Ru(bpy) …