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The Structure And Ferroelectric Properties Of Iron-Doped Lead Titanate, Michael Bartlein

Theses and Dissertations

Multiferroics are a class of poorly understood, but technologically important materials. Lead(II) titanate (PbTiO$_3$) is a known perovskite ferroelectric. By doping PbTiO$_3$ with Fe$^{3+}$ at the Ti site, we produce the multiferroic PbTi$_{1-x}$Fe$_x$O$_3$ (PTFO). Using selected area electron diffraction on a transmission electron microscope, the structure of PTFO is investigated. Of particular interest is identifying the cubic-to-tetragonal transition at the Curie temperature. As the concentration of Fe increases, the crystal becomes more cubic and experiences a lower transition temperature. I also establish a procedure for preparing bulk PTFO samples for ferroelectric testing and present preliminary results establishing ferroelectricity in these …

Molecular Dynamics (Md) Study On The Electrochemical Properties Of Electrolytes In Lithium-Ion Battery (Lib) Applications, Negin Salami

Theses and Dissertations

While the high energy density and the power along with longer cycle life and less requirements of maintenance distinguish the rechargeable lithium-ion batteries (LIBs) from other energy storage devices, development of an electrolyte of LIBs with optimized properties still constitutes a challenge towards next-generation LIB systems with robust electrochemical performance. The electrolytes serve as the medium to provide ionic conduction path between the electrodes as their basic function. Conductivity of the solutions are mainly affected by their transport properties and the electrolyte electrode/separator interfacial phenomena. Although many contributions on thermodynamic properties of the electrolytes consist of alkyl carbonates mixed with …

Novel Substrate-Bound Hybrid Nanomaterials For Anode Electrodes In Lithium-Ion Batteries, Haejune Kim

Theses and Dissertations

Li-ion batteries (LIBs) are commercially dominant in electrochemical energy storage devices. Their wide applications as power sources, from portable electronics to electric vehicles/hybrid electric vehicles, are mainly attributed to their superior energy density based on unit volume and unit weight over other battery systems. Growing demands for lighter, longer-lasting, and more powerful devices spur the development of new electrode materials, because the performance of LIBs is highly dependent on the characteristics of electrodes. The ideal candidate for anode materials of LIBs should have high lithium storage capability and stable structure after repeated charge/discharge cycles. Since its first commercialization by Sony …

Thermal Cooling Effects In The Microstructure And Properties Of Cast Cobalt-Base Biomedical Alloys, Vladimir Vega Valer

Theses and Dissertations

Joint replacement prosthesis is widely used in the biomedical field to provide a solution for dysfunctional human body joints. The demand for orthopedic knee and hip implants motivate scientists and manufacturers to develop novel materials or to increase the life of service and efficiency of current materials. Cobalt-base alloys have been investigated by various researchers for biomedical implantations. When these alloys contain Chromium, Molybdenum, and Carbon, they exhibit good tribological and mechanical properties, as well as excellent biocompatibility and corrosion resistance.

In this study, the microstructure of cast Co-Cr-Mo-C alloy is purposely modified by inducing rapid solidification through fusion welding …

Effects Of Ball Milling And Sintering On Alumina And Alumina-Boron Compounds, Thomas Cross

Theses and Dissertations

Alumina has a wide variety of applications, but the processing of alumina based materials can be costly. Mechanically milling alumina has been shown to enhance the sintering properties while decreasing the sintering temperature. Additions of boron have also proven to increase sintering properties of alumina. These two processes, mechanical milling and boron additions, will be combined to test the sintering properties and determine if they are improved upon even further compared to the individual processes.

Multiple samples of pure alumina, 0.2 weight percent boron, and 1.0 weight percent boron are batched and processed in a ball mill for different time …

Characterization Of Carbon-Fiber Reinforced Polyetherimide Thermoplastic Composites Using Mechanical And Ultrasonic Methods, Mohannad A. Alhaidri

Theses and Dissertations

Continuous fiber-reinforced thermoplastics (CFRT) have the potential for being a mass-produced material for high-performance applications. The primary challenge of using CFRT is achieving fiber wet-out due to the high viscosity of thermoplastics. This results in higher temperatures and pressures required for processing the composites. Co-mingling thermoplastic fibers with a reinforcing fiber, potentially, can enable better wetting by reducing the distance the matrix needs to flow. This could result in shorter cycle times and better consolidation at lower temperatures and pressures. In this study, a polyetherimide (PEI) fiber was comingled with carbon fibers (CF). The resultant fibers were woven into fabrics …

Stress Ratio Effects In Fatigue Of Lost Foam Cast Aluminum Alloy 356, David Elijah Palmer

Theses and Dissertations

Lost foam casting is a highly versatile metalcasting process that offers significant benefits in terms of design flexibility, energy consumption, and environmental impact. In the present work, the fatigue behavior of lost foam cast aluminum alloy 356, in conditions T6 and T7, was investigated, under both zero and non-zero mean stress conditions, with either as-cast or machined surface finish. Scanning electron microscopy was used to identify and measure the defect from which fatigue fracture initiated. Based on the results, the applicability of nine different fatigue mean stress equations was compared. The widely-used Goodman equation was found to be highly non-conservative, …

Wetting, Superhydrophobicity, And Icephobicity In Biomimetic Composite Materials, Vahid Hejazi

Theses and Dissertations

Recent developments in nano- and bio-technology require new materials. Among these new classes of materials which have emerged in the recent years are biomimetic materials, which mimic structure and properties of materials found in living nature. There are a large number of biological objects including bacteria, animals and plants with properties of interest for engineers. Among these properties is the ability of the lotus leaf and other natural materials to repel water, which has inspired researchers to prepare similar surfaces. The Lotus effect involving roughness-induced superhydrophobicity is a way to design nonwetting, self-cleaning, omniphobic, icephobic, and antifouling surfaces. The range …

Modeling Of Instabilities And Self-Organization At The Frictional Interface, Vahid Mortazavi

Theses and Dissertations

The field of friction-induced self-organization and its practical importance remains unknown territory to many tribologists. Friction is usually thought of as irreversible dissipation of energy and deterioration; however, under certain conditions, friction can lead to the formation of new structures at the interface, including in-situ tribofilms and various patterns at the interface.

This thesis studies self-organization and instabilities at the frictional interface, including the instability due to the temperature-dependency of the coefficient of friction, the transient process of frictional running-in, frictional Turing systems, the stick-and-slip phenomenon, and, finally, contact angle (CA) hysteresis as an example of solid-liquid friction and dissipation. …

Experimental And Analytical Characterization Of Regenerated/Nano Cellulose Composites, Issam I A Qamhia

Theses and Dissertations

Fiber-reinforced composite materials are increasingly used for structural and engineering purposes. In particular, composites reinforced with natural fiber systems are becoming more and more popular due to their biodegradability and abundance; added to that other properties such as transparency, dimensional stability and good mechanical behavior. However, major issues remain to properly understand their behavior and enable their widespread use.

In this thesis, the mechanical behavior of cellulose fiber/epoxy composites is investigated. The natural fiber systems studied fall into three categories: unidirectional regenerated cellulose fibers, triaxially braided quasi-isotropic regenerated cellulose fibers and micro-fibrillated cellulose in the form of nanocellulose scaffolds. Different …

Enhancing The Structure And Performance Of P3ht/Pc70bm Polymer Solar Cells With N-Dodecylthiol, Mahmoud Ismail Algazzar

Theses and Dissertations

Polymer solar cells (PSCs) have attracted much attention because of their low cost, high flexibility, lightweight, and large surface area compared to long-established silicon solar cells. In most cases, bulk heterojunction type solar cells (BHJ) use a phase-separated blend of organic electron donor and acceptor components, where a conductive polymer is the donor and a fullerene derivative is the acceptor. To achieve high performance BHJ-type PSCs, the electron-donating conjugated polymer needs to be strong absorbent of a wide range of solar light waves and possess good hole mobility. This results in short-circuit current (Jsc) and/or open-circuit voltage (Voc) at their …