Digital Commons Network^™

Direct Blue 86 Textile Dye Removal From Aqueous Solution Using Rice Husk-Based Adsorbent, M. Zulbahari M. Zua, Muhammad Raza Ul Mustafa, Mohamed Hasnain Isa, Teh Sabariah Binti Abd Manan, Naimah Ibrahim, Rozeana Hj Md Juani, Wida Susanty Hj Suhaili, Asmaal Muizz Sallehhin Bin Hj Mohammad Sultan, Zuliana Binti Hj Nayan

ASEAN Journal on Science and Technology for Development

Adsorption by activated carbon is an effective method of dye removal. However, due to high production and regeneration costs of activated carbon, various studies on low-cost adsorbents have been conducted. Agricultural waste such as rice husk (RH) is seen to be a good adsorbent for dye removal. Moreover, rice husk is readily available. In this study, rice husk-based adsorbents were prepared by chemical and thermal treatments. Standard curve (colour vs absorbance) for Direct Blue 86 (DB 86) was prepared to determine the concentration of dye before and after adsorption. The adsorption potential of the adsorbent for textile dye DB 86 …

Removal Of Phosphorous, Copper And Zinc From Stormwater Using Powdered Activated Carbon (Pac) Based Water Treatment Residuals, Foysol Mahmud

Electronic Theses and Dissertations

The main aim of this research was to evaluate the efficacy of Powdered Activated Carbon (PAC) based water treatment residual (WTR) in eliminating phosphorus (P), Copper (Cu), and Zinc (Zn) from stormwater. The characteristics of the PAC WTR were analyzed, and a series of batch and column tests were conducted to determine its capacity to remove P, Cu, and Zn from stormwater and synthetic solutions. The PAC WTR conformed to the Langmuir isotherm model, demonstrating P adsorption capacities of 3.51 mg/g at pH 5. Regarding Cu and Zn removal, the PAC WTR also adhered to the Langmuir isotherm model, showing …

Wastewater Treatment Using Encapsulated Chabazite In Polyvinyl Alcohol-Sodium Alginate Hydrogel Biofilm Carriers, Susieanna Nevada Persaud

USF Tampa Graduate Theses and Dissertations

Nitrogen discharge from wastewater is a global issue and with increased urbanization as well as industrialization, it has become even more essential to develop more efficient wastewater treatment systems. The dominant form of nitrogen in wastewater is ammonium. Biological oxidation of ammonium to nitrite and nitrate is the first step in biological nitrogen removal processes. If left untreated, nitrogen can cause toxicity to aquatic life, unsafe changes in water quality, and eutrophication.

Biofilm carriers can help to improve the efficiency of traditional activated sludge wastewater treatment systems by reducing operating costs and reducing hydraulic retention time. Biofilm carriers also promote …

Wastewater Treatment Using Encapsulated Chabazite In Polyvinyl Alcohol-Sodium Alginate Hydrogel Biofilm Carriers, Susieanna Nevada Persaud

USF Tampa Graduate Theses and Dissertations

Nitrogen discharge from wastewater is a global issue and with increased urbanization as well as industrialization, it has become even more essential to develop more efficient wastewater treatment systems. The dominant form of nitrogen in wastewater is ammonium. Biological oxidation of ammonium to nitrite and nitrate is the first step in biological nitrogen removal processes. If left untreated, nitrogen can cause toxicity to aquatic life, unsafe changes in water quality, and eutrophication.

Biofilm carriers can help to improve the efficiency of traditional activated sludge wastewater treatment systems by reducing operating costs and reducing hydraulic retention time. Biofilm carriers also promote …

The Cr(Iii) Exchange Mechanism Of Macroporous Resins: The Effect Of Functionality And Chemical Matrix, And The Statistical Verification Of Ion Exchange Data, Khizar Hussain Shah, Noor S. Shah, Gul Afshan Khan, Sadaf Sarfraz, Jibran Iqbal, Aneeqa Batool, Ahmad Jwuiyad, Shabnam Shahida, Changseok Han, Monika Wawrzkiewicz

All Works

This study focuses on investigating and comparing the influence of the surface functional groups and chemical matrices of macroporous resin on the Cr(III) exchange mechanism. The results discussed herein indicate that sulfonic resin removed Cr(III) ions with faster kinetics than carboxylic resin. Equilibrium was established within 15 and 7 min for the carboxylic and sulfonic resins, respectively, with a 99.5% removal efficiency at 333 K. The Langmuir exchange capacity was observed to be higher for the sulfonic resin (1.5 mmol∙g−1) than the carboxylic resin (0.80 mmol∙g−1) at 333 K. The adsorption isotherms obtained for the carboxylic and sulfonic resins were …

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

A Hybrid Lateral Flow Sand Filter Wastewater Treatment System: An Evaluation On The Treatment And Disposal Capabilities Of A Modified Sand Filter, Harry Mccaskill Iv

<strong> Theses and Dissertations </strong>

Decentralized wastewater treatment exists primarily in suburban and rural areas where centralized treatment is not an option. Traditional on-site treatment systems usually include the use of a septic tank and a drain field. This orthodox method works well when implemented into environments that are accommodating for the infiltration of effluents, and thus allowing for soil treatment. Unfortunately, there are some circumstances that prevent traditional systems from working such as impermeable soil conditions. The Wastewater Treatment System analyzed in this thesis was created to overcome such inhospitable environments. More specifically, this system is catered towards the rural residences of The Alabama …

Characteristics And Hydraulic Behavior Of Adsorptive Media For Use In Permeable Reactive Barriers, Shelby Rocha

USF Tampa Graduate Theses and Dissertations

The Cargill ditch is located on the property of Se7en Wetlands, a 1600-ac treatment wetland system in Lakeland, Polk County, Florida. The Se7en Wetlands property was previously utilized for phosphate mining prior to the construction of the system. Nonpoint nutrient sources derived from remnants of abandoned phosphate mines – known as “legacy phosphorus” – become mobilized by stormwater runoff and impair surface water bodies by promoting harmful algal blooms (HABs). Thus, the Cargill ditch likely conveys nutrient rich flow resulting from legacy phosphorus and is thought to be one contributing factor in the occurrence of HABs within the treatment wetland …

Fate And Transport Of Per- And Polyfluoroalkyl Substances (Pfas) At Aqueous Film Forming Foam (Afff) Discharge Sites: A Review, Jeffery T. Mcgarr, Eric G. Mbonimpa, Drew C. Mcavoy, Mohamad R. Soltanian

Faculty Publications

Per- and polyfluorinated alkyl substances (PFAS) are an environmentally persistent group of chemicals that can pose an imminent threat to human health through groundwater and surface water contamination. In this review, we evaluate the subsurface behavior of a variety of PFAS chemicals with a focus on aqueous film forming foam (AFFF) discharge sites. AFFF is the primary PFAS contamination risk at sites such as airports and military bases due to use as a fire extinguisher. Understanding the fate and transport of PFAS in the subsurface environment is a multifaceted issue. This review focuses on the role of adsorbent, adsorbate, and …

Potential Bioavailability Of Representative Pyrogenic Organic Matter Compounds In Comparison To Natural Dissolved Organic Matter Pools, Emily B. Graham, Hyun-Seob Song, Samantha Grieger, Vanessa A. Garayburu-Caruso, James C. Stegen, Kevin D. Bladon, Allison N. Myers-Pigg

Biological Systems Engineering: Papers and Publications

Pyrogenic organic matter (PyOM) from wildfires impacts river corridors globally and is widely regarded as resistant to biological degradation. Though recent work suggests PyOM may be more bioavailable than historically perceived, estimating bioavailability across its chemical spectrum remains elusive. To address this knowledge gap, we assessed potential bioavailability of representative PyOM compounds relative to ubiquitous dissolved organic matter (DOM) with a substrate-explicit model. The range of potential bioavailability of PyOM was greater than natural DOM; however, the predicted thermodynamics, metabolic rates, and carbon use efficiencies (CUEs) overlapped significantly between all OM pools. Compound type (e.g., natural versus PyOM) had approximately …

Modeling Leachate Treatment Processes In Adsorbent-Amended Hybrid Constructed Wetland, Ishfaqun Nisa

USF Tampa Graduate Theses and Dissertations

Due to their efficiency in removing ammonia nitrogen, Constructed Wetlands (CW) are currently considered a very useful method for on-site leachate treatment. In recent years, the use of adsorbent media in CWs, such as zeolite and biochar, to improve pollutant removal efficiency has been explored and these studies indicate that incorporating zeolite can improve the nitrification process, while the addition of biochar can enhance the denitrification process and the removal of organic compounds. However, studies on mechanistic/process models simulating performance of adsorbent-amended CWs for treating landfill leachate are limited. This study presents simulation results for both unamended and adsorbent-amended hybrid …

Value Added Products From Nonconventional Agricultural Biomass Waste Through Thermochemical Transformation, Nicolas A. Sarmiento

Electronic Thesis and Dissertation Repository

The alteration of temperature patterns around the world has become noticeable in the recent decade. Sea level rise, wildfires, and high temperatures have made people realize that climate change is affecting humans more tangibly than ever. Therefore, the United Nations have pushed to make policies to mitigate this problematic situation. This research investigated the production of biochar from agricultural waste through pyrolysis for fighting climate change and adding value to waste. Experiments in a laboratory scale reactor were conducted to obtain yields of pyrolytic products. Then, analysis of products provided data for characterization and the LCA of the tomato plant …

Comparing Phosphorus Removal Efficiencies And Mechanisms Via Two Cost-Effective Specialty Adsorbents In A Cascade Upflow Filtration System, Sydney Kilgus-Vesely

Honors Undergraduate Theses

Finding solutions to treat water that contains phosphorus is an important effort due to the harmful impacts it presents to both human health and the environment. Phosphorus is considered a limiting factor in water oftentimes and therefore controls the growth of algal bloom in a water body. The increase of algal populations due to wastewater effluent, stormwater runoff, and agricultural discharge in Florida waters has a direct link to the event of harmful algal blooms such as red tide in coastal regions, eutrophication of waterbodies, and fish kills. Finding low cost, energy efficient, and low maintenance green sorption media (GSM) …

Exploring A Lab-Scale Cascade Upflow Bioreactor System For Nitrogen Removal Via Biosorption Activated Media, Alejandra Robles Lecompte

Graduate Thesis and Dissertation 2023-2024

Many Best Management Practices (BMPs) have been developed to reduce excessive nutrients in stormwater runoff and mitigate harmful algal blooms in downstream receiving water bodies. This study demonstrates a new BMP by comparing two green sorption media (i.e., specialty adsorbents) for nutrient removal in cascade upflow biofiltration systems operated in parallel. The proposed filtration technology can control hydraulic gradients, prevent clogging and settlements, and increase hydraulic loading while removing more nutrients in an integrated physicochemical and microbiological treatment process. The two green sorption media being tested in this study include zero-valent-iron and perlite-based green sorption media (ZIPGEM) and biochar, iron, …

Rapid-Throughput Analysis Of 1,4-Dioxane In Plants By Centrifugal Sampling And Phytoforensic Analysis For Site Delineation And Assessing Enhanced Rhizodegradation, Anthony Eberechukwu Oha

Masters Theses

"Owing to its broad use and environmental persistence, 1,4-dioxane (dioxane) poses a notable threat to public health and is recalcitrant to traditional remedial systems. Dioxane moves readily in an aqueous environment and is an emerging contaminant in drinking water, surface water, groundwater, and wastewater. The extent of dioxane in the biosphere is also difficult to delineate, particularly in the subsurface. Phytoremediation has demonstrated the potential for dioxane groundwater remediation. Recent findings indicate that plant-microbial symbiosis may be more advantageous for limiting potential transport and transfer into plant tissues and the atmosphere. Bioaugmentation of the rhizosphere paired with soil amendments has …

Evaluación De Bioproductos Derivados De Biomasa Lignocelulósica A Partir De Residuos Agroindustriales Para Su Aplicación En El Sector Viverista, Angie Lorena Sánchez Ocampo, Nicole Estefanía Prada Monsalve

Ingeniería Ambiental y Sanitaria

No abstract provided.

Livestock Wastewater And Air Quality Management Using Microalgae, Capacitive Deionization, And Biofilters, Augustina Kwesie Osabutey

Electronic Theses and Dissertations

No abstract provided.

Analyzing Residential Curbside Collection For Food Waste In Humboldt County, Yvette Lindler

Cal Poly Humboldt theses and projects

The most prevalent material in the California landfill-destined solid waste stream is food. Food waste is not only an economic and social concern, but a significant environmental challenge as well. Most food waste is disposed of in landfills, where it anaerobically decomposes and releases methane, an extremely potent greenhouse gas and driver of climate change. Policies passed in California, including AB 1826 and SB 1383, aim to implement organic waste recycling programs and reduce methane emissions by diverting organic waste from landfills. The technology to process this food waste exists, but these facilities are limited or nonexistent in rural areas …

Food Waste Storage Gaseous Emissions Detection And Quantification Using Infrared Spectroscopy, Ryley A. Burton-Tauzer

Cal Poly Humboldt theses and projects

A growing interest in sustainable waste management and the implementation of new policies have prompted a shift towards alternative resource recovery methods for organic waste, including food waste. To effectively assess alternative food waste treatment scenarios, it is important to evaluate the life cycle impacts associated with each scenario. The storage phase of food waste, encompassing its accumulation in kitchens, and storage in bins for collection and transportation, has been overlooked as a source of greenhouse gases in previous studies. This investigation aimed to identify the greenhouse gases emitted during the initial five-day period of low-oxygen storage. An open dynamic …

Enzymatic Removal Of Sulfa Drugs From Synthetic Wastewater By Soybean Peroxidase, Maryam Sharifzadeh

Electronic Theses and Dissertations

Sulfa drugs are a broad family of antibiotics that are widely used in the treatment of a wide range of infections, and they have been found in surface and groundwater, as well as present in sewage and effluent (treated sewage and sludge)municipal or industrial wastewater treatment plants (WWTPs). in concentrations of ng/L to >g/L. The continued presence of these so-called emerging pollutants (ECs) and their metabolites can cause adverse ecological effects, including bacterial resistance, even at very low concentrations. In this study, the first aim was to explore the feasibility of oxidation processes catalyzed by soybean peroxidase as an eco-friendly …

Evaluation For Using Expended Bioelectrochemical Systems As Soil Amendments For Improved Corn Plant Growth And A Drought Resistant Soil., Jackson Lee Sauers

Theses and Dissertations

A long-held practice is to mix agricultural soil with a soil amendment to improve growing conditions in crops. A common soil amendment is biosolids produced from both municipal and dairy wastewater due to the macro- and micronutrients within it. Both the agricultural and wastewater industries are participating in the Circular Economy concept (CEC). Two experiments explored using expended bioelectrochemical systems (BES) that treated either synthetic dairy wastewater (DWW) or synthetic municipal wastewater (SWW) as soil amendments to improve corn plant growth when treated with three different nutrient treatments: 100%- 50%- and 0% Hoagland Nutrient Solutions. Biochar and used terracotta clay …

Biochar Amended Biological Systems For Enhanced Landfill Leachate And Lignocellulosic Banana Waste Treatment, Xia Yang

USF Tampa Graduate Theses and Dissertations

Biochar is an inexpensive and environmentally friendly carbonaceous pyrolysis byproduct with a high surface area, pore volume, and adsorption capacities for inorganic and organic compounds. The goal of this dissertation is to evaluate the feasibility of biochar application in biological treatment systems for enhanced waste management. Three major objectives guided this research to provide a compressive understanding of biochar enhancement effects on biological treatment systems for contaminant removal, energy recovery, and environmental impacts as well as essential factors influencing biochar production and properties.

In Objective 1 a low-cost hybrid Constructed Wetland (CW) system modified with biochar/zeolite was developed for enhanced …

The Novel Application Of Electrical Resistivity Tomography For Spatiotemporal Monitoring Of Urban Stormwater Bioretention Systems, Darren Alvarenga

Electronic Thesis and Dissertation Repository

Bioretention systems are an increasingly popular low-impact development (LID) stormwater management approach that are used to reduce the water quantity and quality impacts of urban stormwater. The study investigated the feasibility and benefits of using non-invasive time-lapse electrical resistivity tomography (ERT) to understand the infiltration and soil moisture dynamics within bioretention systems. This was achieved through monitoring two field-scale operational bioretention systems in London, Ontario, Canada. High-resolution two-dimensional time-lapse ERT surveys were first completed during synthetic and natural rain events to assess the viability of time-lapse ERT to monitor soil moisture changes during events. Following this, three-dimensional ERT surveys were …

Integration Of Techno-Economic Analysis (Tea) And Life Cycle Assessment (Lca) For Sustainable Process Design, Roksana Mahmud

All Dissertations

For sustainable design, technology developers need to consider not only technical and economic aspects but also potential environmental impacts while developing new technologies. Techno-economic analysis (TEA) evaluates the technical performance and economic feasibility of a technology. Life cycle assessment (LCA) evaluates the potential environmental impacts associated with a product system throughout its life cycle from raw material extraction to disposal. Generally, TEA and LCA are performed separately for technology assessment. Understanding of the trade-off between economic and environmental performances is crucial for sustainable process design, which is not fully available if TEA and LCA is performed separately. In contrast, integration …

Modified Biosand Filtration Using Aluminum Hydroxide Filter Media To Enhance Fluoride Removal, Joshelyn Guimaray

USF Tampa Graduate Theses and Dissertations

There are over 20 countries whose citizens consume groundwater containing high levels of fluoride, including Nigeria, Mexico, India, China, and Ghana, which all have major health crises when it comes to the safety of their drinking water. Minerals like fluorite contain fluoride which is often found in groundwater aquifers. The minerals release fluoride into the groundwater. Per the World Health Organization (WHO) standard, the maximum contaminant limit for fluoride consumption should be less than 1.5 mg/L. Chronic exposure of elevated levels of fluoride can cause people to suffer debilitating health effects, such as dental and skeletal fluorosis. Dental fluorosis causes …

Environmental Impact And Life Cycle Assessment Of Biomass Supported Power Systems For Rural Communities, Hariteja Nandimandalam

Theses and Dissertations

Dependence on fossil fuels in the electric sector is one of the major contributors towards Greenhouse gas (GHG) emissions. The increase in renewable contribution has been observed in recent years but there is still potential to utilize wood waste in rural communities for electricity generation promoting energy independence and sustainable development. For this study, a life cycle assessment approach was utilized to estimate the emissions of electricity produced from wood residue in a rural community. Therefore, the process from planting to supply for bioenergy facility to generate electricity are included. The results showed a decrease of 92-96 % in global …

Application Of Lanthanides In Wastewater Treatment And Water Reuse, George William Kajjumba

UNLV Theses, Dissertations, Professional Papers, and Capstones

Much of the world’s population feed on grains (wheat, rice, and corn). Corn is as sensitive as it is productive. This thirsty, fast-growing plant goes into thermal shock in drought. In 2014, California lost over $2.2 billion in crop production due to drought. The Horn of Africa (in 2011) and Sahel (in 2012) faced humanitarian disasters due to food and water scarcity. The higher frequency of climate change and the erratic nature of rain, combined with underlying economic and social vulnerabilities, has meant that food and water scarcity is here to stay. To improve food and water scarcity, water reclamation …

Hydrogen-Rich Syngas Derived From Smouldering Biomass And Hydrocarbon Wastes, Joshua K. Brown

Electronic Thesis and Dissertation Repository

In the face of climate change, the world is looking to new fuel sources to meet the surging global energy demand. Hydrogen has been proposed as a promising energy vector being both a net-zero carbon emitter and having one of the highest gravimetric energy densities of known fuels. Production of hydrogen, however, is difficult with many of the technologies which exist today failing to be economically feasible or environmentally sustainable. Smouldering has recently been developed as a cost effective and energy efficient technology for destruction of organic wastes. The unique reaction zones created within a smouldering system have the potential …

Activated Carbon As Superadsorbent And Sustainable Material For Diverse Applications, Gaurav Sharma, Shweta Sharma, Amit Kumar, Chin Wei Lai, Mu. Naushad, Shehnaz (Panjab University Shehnaz (Panjab University, Jibran Iqbal, Florian J. Stadler

All Works

Activated carbon is a carbonaceous material with highly porous structure. Different functionalities can be introduced to its surface by various physical and chemical treatments. Various precursors can be used for the synthesis of activated carbon such as fossil fuels, agricultural wastes, and lignocellulosic wastes, etc. Number of papers have been reported in literature devoted to the synthesis, characterization, and various applications of activated carbon. Herein, in this review, special attention has been paid to the basic properties of activated carbon and its surface chemistry originated due to physical and chemical treatment. In addition, a general introduction to adsorption process, various …

Biochar Application In Anaerobic Digestion Of Food Waste For Inhibition Mitigation And Biogas Production Improvement, Mehrsa Hosseini

Major Papers

The production of large quantities of food waste due to population growth is a serious global issue. Improper management of food waste and the deficiency of appropriate administration approaches have adversely affected the environment and society. Traditional methods of disposal (i.e., landfill) and treatment (i.e., incineration and composting) are not considered efficient for food waste management. Therefore, an efficient and cost-effective alternative is anaerobic digestion (AD), a dual-purpose and mature technology for digesting and converting food waste into renewable energy and valuable chemicals. However, Anaerobic digestion (AD) as an environmentally friendly and widely applied technology still faces some challenges, including …