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Environmental Chemistry

2002

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Full-Text Articles in Entire DC Network

Clear-Column Radiative Closure During Ace-Asia: Comparison Of Multiwavelength Extinction Derived From Particle Size And Composition With Results From Sun Photometry, J. Wang, Richard C. Flagan, John H. Seinfeld, Haflidi Jonsson, D. R. Collins, P. B. Russell, Beat Schmid, Jens Redemann, J. M. Livingston, Song Gao, Dean A. Hegg, E. J. Welton Dec 2002

Clear-Column Radiative Closure During Ace-Asia: Comparison Of Multiwavelength Extinction Derived From Particle Size And Composition With Results From Sun Photometry, J. Wang, Richard C. Flagan, John H. Seinfeld, Haflidi Jonsson, D. R. Collins, P. B. Russell, Beat Schmid, Jens Redemann, J. M. Livingston, Song Gao, Dean A. Hegg, E. J. Welton

Chemistry and Physics Faculty Articles

From March to May 2001, aerosol size distributions and chemical compositions were measured using differential mobility analyzers (DMA), an aerodynamic particle sizer (APS), Micro-Orifice Uniform Deposit Impactors (MOUDI), and denuder samplers onboard the Twin Otter aircraft as part of the Aerosol Characterization Experiment (ACE)-Asia campaign. Of the 19 research flights, measurements on four flights that represented different aerosol characteristics are analyzed in detail. Clear-column radiative closure is studied by comparing aerosol extinctions predicted using in situ aerosol size distribution and chemical composition measurements to those derived from the 14-wavelength NASA Ames Airborne Tracking Sun photometer (AATS-14). In the boundary layer, …


An Examination Of Predatory Pressures On Piping Plovers Nesting At Breezy Point, New York, Brook Lauro, John Tanacredi Ph.D. Dec 2002

An Examination Of Predatory Pressures On Piping Plovers Nesting At Breezy Point, New York, Brook Lauro, John Tanacredi Ph.D.

Faculty Works: CERCOM

This study examines predatory threats to Piping Plovers (Charadrius melodus) nesting at Breezy Point, Gateway National Recreation Area, New York. Several methods used include: 1) an evaluation of reproductive success data with documentation of predation to eggs and chicks, 2) predator surveys, and 3) an artificial nest study. The range of breeding pairs nesting from 1988-1996 was 11-19, with an average of 15.8 (SE ± 0.79) pairs/season. The average number of eggs hatched and chicks fledged per year for pairs was 2.2 ± 0.23 and 0.8 ± 0.16 respectively. Reasons for egg losses often went undetected (68%) but …


Organic Geochemical Analysis Of Late-Glacial And Early-Holocene Ecosystem Changes: A Case Study From Northern New England Lakes, Michael A. Kruge, Andrea Lini Jun 2002

Organic Geochemical Analysis Of Late-Glacial And Early-Holocene Ecosystem Changes: A Case Study From Northern New England Lakes, Michael A. Kruge, Andrea Lini

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lacustrine sedimentary archive of organic remains provides important evidence for the reconstruction of the environmental histories of lakes and their watersheds, recording the response of the Earth's biota to changes on scales varying from the local to the global. The last Glacial-Interglacial transition presents an opportunity to investigate how, and at what rates, watershed and lake ecosystems were established on once glaciated, carbon and nutrient-poor landscapes. The small lakes of northern Vermont (USA) provide an appropriate setting in which to investigate such changes.

As part of a multidisciplinary study of three Vermont lake sediment cores, samples ranging in age …


Styrene Monomer Solubility In Artificial And Natural Seawaters Of The Lower Chesapeake Bay, Eric Joseph Miller Apr 2002

Styrene Monomer Solubility In Artificial And Natural Seawaters Of The Lower Chesapeake Bay, Eric Joseph Miller

Chemistry & Biochemistry Theses & Dissertations

Used for making a variety of plastic products, styrene monomer is an aromatic hydrocarbon frequently shipped in bulk quantities through the Port of Hampton Roads, Virginia. Despite its common use around the world and its high aquatic toxicity, little research has been conducted on the chemical's aqueous solubility and reactions during a major spill. In this study, the solubility of styrene monomer was measured in artificial seawater and natural waters collected from four sites on the lower Chesapeake Bay and Elizabeth River. The samples represented a range of different water chemistries in terms of salinity (13.8 — 29.0%) and the …


An Anion Characterization Of A Constructed Wetland Used For Chlorinated Ethene Remediation, Bradley M. Bugg Mar 2002

An Anion Characterization Of A Constructed Wetland Used For Chlorinated Ethene Remediation, Bradley M. Bugg

Theses and Dissertations

Chlorinated ethenes physical properties as well as its ubiquitous state at DOD installations makes it a priority for innovative remediation efforts. Current techniques are expensive and time consuming to maintain. Constructed wetlands suggest an inexpensive and operational alternative to conventional technologies. Sub-surface flow wetlands provide the anaerobic zones necessary to reduce the recalcitrant chlorinated solvents prior to anaerobic or aerobic mineralization of its daughter products. A vertical flow cell to include sequential sedimentary layers of two hydric soil lifts and a mix of hydric soil and woody compost was the subject of this investigation. This study focused on the statistical …


Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Perchlorate Contaminated Groundwater, Jeffrey C. Parr Mar 2002

Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Perchlorate Contaminated Groundwater, Jeffrey C. Parr

Theses and Dissertations

Groundwater contamination by perchlorate has recently been recognized as a significant environmental problem across the United States, and especially at Department of Defense facilities. In this study, a model is used to evaluate the potential of a innovative in situ bioremediation technology using Horizontal Flow Treatment Wells (HFTWs) to manage perchlorate-contaminated groundwater. The technology uses HFTWs to mix an electron donor into perchlorate-contaminated groundwater in order to promote reduction of the perchlorate by indigenous microorganisms in bioactive zones within the aquifer, as well as recirculate the contaminated water between treatment well pairs to achieve multiple passes of contaminated water through …


On-Road Emissions Of Motor Vehicles In Brazil: Current Status And Future Possibilities {Presentation}, Donald H. Stedman Jan 2002

On-Road Emissions Of Motor Vehicles In Brazil: Current Status And Future Possibilities {Presentation}, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Remote Sensing: A New Tool For Automobile Inspection & Maintenance, Donald H. Stedman Jan 2002

Remote Sensing: A New Tool For Automobile Inspection & Maintenance, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Parameters Affecting Partitioning Of 6 Pcb Congeners In Natural Sediments, Eid A. Alkhatib, Carl Weigand Jan 2002

Parameters Affecting Partitioning Of 6 Pcb Congeners In Natural Sediments, Eid A. Alkhatib, Carl Weigand

Chemistry & Physics Faculty Publications

Polychlorinated biphenyls (PCBs) released by bottom sediments were determined by experiments in which the sediments were artificially resuspended using sediment contaminated with PCBs in a particle entrainment simulator (PES). Sediment cores, spiked with PCBs, were collected from the Housatonic River in Connecticut and run in the PES at simulated shear stresses from 0 to 0.6 N m(-2). Experimental results from these simulations have shown that mean concentration of PCBs in the solid phase for sites with high volatile organic carbon (VOC) were significantly greater than samples with low VOC; the reverse was true for the water phase. In addition, on …


On-Road Remote Sensing Of Automobile Emissions In The Denver Area: Year 3, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman Jan 2002

On-Road Remote Sensing Of Automobile Emissions In The Denver Area: Year 3, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


On-Road Remote Sensing Of Automobile Emissions In The Los Angeles Area: Year 3 (Riverside), Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman Jan 2002

On-Road Remote Sensing Of Automobile Emissions In The Los Angeles Area: Year 3 (Riverside), Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


On-Road Remote Sensing Of Automobile Emissions In The Phoenix Area: Year 3, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman Jan 2002

On-Road Remote Sensing Of Automobile Emissions In The Phoenix Area: Year 3, Sajal S. Pokharel, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Opacity Enhancement Of The On-Road Remote Sensor For Hc, Co And No, Donald H. Stedman, Gary A. Bishop Jan 2002

Opacity Enhancement Of The On-Road Remote Sensor For Hc, Co And No, Donald H. Stedman, Gary A. Bishop

Fuel Efficiency Automobile Test Publications

No abstract provided.


Strontium Isotopic Signatures Of The Streams And Lakes Of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering In A Polar Climate, W. B. Lyons, Carmen A. Nezat, Larry V. Benson, Thomas D. Bullen, Elizabeth Y. Graham, Jesicca Kidd, Kathleen A. Welch, James M. Thomas Jan 2002

Strontium Isotopic Signatures Of The Streams And Lakes Of Taylor Valley, Southern Victoria Land, Antarctica: Chemical Weathering In A Polar Climate, W. B. Lyons, Carmen A. Nezat, Larry V. Benson, Thomas D. Bullen, Elizabeth Y. Graham, Jesicca Kidd, Kathleen A. Welch, James M. Thomas

United States Geological Survey: Staff Publications

We have collected and analyzed a series of water samples from three closed-basin lakes (Lakes Bonney, Fryxell, and Hoare) in Taylor Valley, Antarctica, and the streams that flow into them. In all three lakes, the hypolimnetic waters have different 87Sr/86Sr ratios than the surface waters, with the deep water of Lakes Fryxell and Hoare being less radiogenic than the surface waters. The opposite occurs in Lake Bonney. The Lake Fryxell isotopic ratios are lower than modern-day ocean water and most of the whole-rock ratios of the surrounding geologic materials. A conceivable source of Sr to the system …


Biological Reduction Of Perchlorate In Ion Exchange Regenerant Solutions Containing High Salinity And Ammonium Levels, Tina M. Gingras, Jacimaria R. Batista Jan 2002

Biological Reduction Of Perchlorate In Ion Exchange Regenerant Solutions Containing High Salinity And Ammonium Levels, Tina M. Gingras, Jacimaria R. Batista

Civil and Environmental Engineering and Construction Faculty Research

The most promising technologies to remove perchlorate from water are ion exchange and biological reduction. Although successful, ion exchange only separates perchlorate from water; it does not eliminate it from the environment. The waste streams from these systems contain the caustic or saline regenerant solutions used in the process as well as high levels of perchlorate. Biological reduction could be used to treat the regenerant waste solutions from the ion exchange process. A treatment scheme, combining ion exchange and biodegradation, is proposed to completely remove perchlorate from the environment. Perchlorate-laden resins generate brines containing salt concentrations up to 6% or …


Stimulation And Modeling Of Pond Formations On The Asteroid 433 Eros, Justin Thompson Jan 2002

Stimulation And Modeling Of Pond Formations On The Asteroid 433 Eros, Justin Thompson

Inquiry: The University of Arkansas Undergraduate Research Journal

"Ponds" are surface features that appear to be the result of the deposition of finer material on the asteroid's regolith, the layer of loose sediment that blankets the entire asteroid. Ponds were discovered by the NEAR Shoemaker spacecraft in January, 2001, on the asteroid 433 Eros. The objective of experimentation is to simulate the development of these ponds in the Andromeda planetary sciences environmental chamber. The Andromeda Chamber offers a unique ability to simulate surface environments that occur on Eros. The chamber was used to simulate the processes that occur as Eros emits gas through its outer surface, including the …