Digital Commons Network^™

Ultrathin Microporous Metal Oxide Coatings: Preparation By Molecular Layer Deposition, Characterization And Application, Zhuonan Song

Theses and Dissertations

Molecular layer deposition (MLD), a gas phase deposition technique, was applied to deposit conformal organic-inorganic hybrid coatings by conducting a series of sequential, self-limiting surface reactions on substrates with exquisite thickness control at the sub-nanometer level. Obtained organic-inorganic hybrid coatings can subsequently be converted into porous coatings by removing the organic compound. Potential of functional coatings and membranes prepared by MLD was explored for applications from adsorptive separation, water purification, to gas storage.

We demonstrated a new concept, pore misalignment, to continuously fine tune the molecular-sieving “gate” of 5A zeolite by adjusting the external porous Al2O3 MLD coating thickness. For …

Study Of Friction Extrusion And Consolidation, Xiao Li

Theses and Dissertations

Friction extrusion and consolidation was invented by The Welding Institute (Cambridge, UK) in the early 1990’s. It is related to simple extrusion processes with the primary difference being that the extrusion die rotates about the extrusion axis and the die is required to impart substantial deformation to the initially, finely divided charge (like metal waste or chips) in order to consolidate it prior to extrusion. It can produce high quality wire and fully consolidated bulk material from low-cost precursors like metal chips or powders. The advantages lie in that it is a direct method to recycle metal chips or scraps …

Highly Conductive In-Sno2/Rgo Nano-Heterostructures With Improved Lithium-Ion Battery Performance, Ying Liu, Alessandro Palmieri, Junkai He, Yongtao Meng, Nicole Beauregard, Steven L. Suib, William E. Mustain

Faculty Publications

The increasing demand of emerging technologies for high energy density electrochemical storage has led many researchers to look for alternative anode materials to graphite. The most promising conversion and alloying materials do not yet possess acceptable cycle life or rate capability. In this work, we use tin oxide, SnO2, as a representative anode material to explore the influence of graphene incorporation and In-doping to increase the electronic conductivity and concomitantly improve capacity retention and cycle life. It was found that the incorporation of In into SnO2 reduces the charge transfer resistance during cycling, prolonging life. It is also hypothesized that …

Thermal Stability And Crystallinity In Sputtered Scandia Stabilized Zirconia Thing Films, Patrick Mackenzie Barboun

Senior Theses

This senior thesis project studies the synthesis of solid oxide fuel cell electrolytes using magnetron sputtering. Materials used in bilayer electrolytes were studied individually for phase stability.

Next Generation Electrode, Joseph Daniel Bivona, Samuel Scott Dacus, Mary Harrell, James Frederick Weber Pike

Senior Theses

This senior thesis involves the results of a biomedical engineering senior design project where the group worked with Rhythmlink International LLC. The project involved the improvement of the manufacturing process of the Invisa Electrode, a CT compatible electrode sold and manufactured by Rhythmlink. The design of the electrode pin was altered to have a hollow center, where the lead wire can be inserted and heat welded, eliminating two key components of the original design and reducing production time and cost. The type of plastic used in the electrodes was also altered to be a 40% carbon loaded conductive plastic.

Orthopedic Drill System With Screw Length Measurement And Heat Sink System, Hunter Wilcox Rafoth, John Patrick Metz

Senior Theses

Most orthopedic drills currently on the market are rudimentary tools that serve only one purpose: to drill holes through bone. Biosphinx envisions a more versatile orthopedic drill that could serve multiple purposes in the operating room. This report outlines Biosphinx’s solution to design a new orthopedic drill system that would include several key features to improve bone screw length measurement, increase patient safety, and reduce time spent in the operating room.

Dynamic 3d Zverse Models On The Web, Alexa Ann Breeland, Ming Wong

Senior Theses

ZVerse is a 3D printing company that is responsible for converting 2D objects into 3D objects. This company specializes in generating 3D collegiate products. Whenever a customer orders a 3D model, such as an alumni brick, it is often helpful to allow customers to see what the object looks like before the purchase. Unfortunately, previewing the brick at runtime is quite a challenging task. The purpose of our project is to create a shopping website that models the existing ZVerse company website and incorporates dynamic 3D rendering of the brick model with the user­input text. The project can be divided …

Hybrid Sulfur Process For Solar Production Of Hydrogen, John Jacob Isenhower, Katherine Cross Henderson, Nicholas Joseph Eigenbrot

Senior Theses

Lowering dependence on fossil-based fuels has become a major area of focus in research, especially in transportation fuels. One particularly interesting field is that of hydrogen production. Hydrogen is promising because it has the potential to emit no greenhouse gases when used as fuel and is an excellent vessel for energy storage. Because traditional methods for its generation are inefficient and require nonrenewable fuel use, researchers have begun to focus on thermochemical cycles.

Thermochemical cycles are systems that require heat transfer intrinsically and do not consume fossil fuels nor emit greenhouse gases if renewable energy is used for heating. The …

Ubisol-Q10 Prevents Glutamate-Induced Cell Death By Blocking Mitochondrial Fragmentation And Permeability Transition Pore Opening, Santosh Kumari, Suresh L. Mehta, Gaolin Z. Milledge, Xinyu Huang, P Andy Li

Faculty Publications

Mitochondrial dysfunction and oxidative stress are the major events that lead to the formation of mitochondrial permeability transition pore (mPTP) during glutamate-induced cytotoxicity and cell death. Coenzyme Q10 (CoQ10) has widely been used for the treatment of mitochondrial disorders and neurodegenerative diseases. Comparing to traditional lipid-soluble CoQ10, water soluble CoQ10 (Ubisol-Q10) has high intracellular and intra-mitochondrial distribution. The aims of the present study are to determine the neuroprotective effects of Ubisol-Q10 on glutamate-induced cell death and to explore its functional mechanisms. HT22 neuronal cells were exposed to glutamate. Cell viability was measured and mitochondrial fragmentation was assessed by mitochondrial imaging. …

Ray-Based Statistical Propagation Modeling For Indoor Corridor Scenarios At 15 Ghz, Qi Wang, Bo Ai, David W. Matolak, Ruisi He, Xin Zhou

Faculty Publications

According to the demands for fifth-generation (5G) communication systems, high frequency bands (above 6 GHz) need to be adopted to provide additional spectrum. This paper investigates the characteristics of indoor corridor channels at 15 GHz. Channel measurements with a vector network analyzer in two corridors were conducted. Based on a ray-optical approach, a deterministic channel model covering both antenna and propagation characteristic is presented. The channel model is evaluated by comparing simulated results of received power and root mean square delay spread with the corresponding measurements. By removing the impact of directional antennas from the transmitter and receiver, a path …

High Temperature Electrochemical Engineering And Clean Energy Systems, Brenda L. Garcia-Diaz, Luke Olson, Michael Martinez-Rodriguez, Roderick Fuentes, Hector Colon-Mercado, Josh Gray

Journal of the South Carolina Academy of Science

Global power demand is projected to more than double by 2050 and meeting this increased power demand will require maintaining or increasing power output from all existing energy sources while adding a large amount of new capacity. The power sources that have the greatest opportunity to fulfill this demand gap over this time period are clean energy sources including solar and nuclear power. One of the areas of expertise that SRNL has been applying to help with a variety of clean energy technologies is in high temperature electrochemistry. Savannah River National Laboratory (SRNL) in collaboration with industrial and university partners …

Hydro-Geological Flow Analysis Using Hidden Markov Models, Chandrahas Raj Venkat Gurram

Theses and Dissertations

Hidden Markov Models a class of statistical models used in various disciplines for understanding speech, finding different types of genes responsible for cancer and much more. In this thesis, Hidden Markov Models are used to obtain hidden states that can correlate the flow changes in the Wakulla Spring Cave. Sensors installed in the tunnels of Wakulla Spring Cave have recorded huge correlated changes in the water flows at numerous tunnels. Assuming the correlated flow changes are a consequence of system being in a set of discrete states, a Hidden Markov Model is calculated. This model comprising all the sensors installed …

Physics Based Modeling Of Guided Waves For Detection And Characterization Of Structural Damage In Nde And Shm, Banibrata Poddar

Theses and Dissertations

Guided waves based damage detection techniques are popular for their ease of generation and detection along with their ability to travel long distances. Accurate and efficient modeling is a key for successful implementation of guided waves for NDE/SHM. However, efficient prediction of scattering from various damage is challenging due to the complex nature of these guided waves.

This dissertation presents as physics based efficient and accurate modeling techniques to predict ultrasonic wave propagation and their interaction with various damage. Detection and characterization of damage in structures can typically be divided into two categories, active and passive. This research is aimed …

Distributed Optimization And Control Of Islanded Microgrids, Md Rishad Hossain

Theses and Dissertations

A microgrid may have numerous multi-functional power electronic converters connecting sources, loads, and storage to the system. Systems where converters are the interface between many of the main sources of energy and load centers have the ability to direct the flow of energy if the control of the converters is coordinated. The influence of energy flow in a microgrid by coordinated action of converters is referred to here as ‘energy routing’. Energy routing allows for reduction of systems losses by optimizing source operating points and reducing transmission and distribution path losses. Energy ramp rates at various points in the system …

Revealing Malicious Contents Hidden In The Internet, Muhammad Nazmus Sakib

Theses and Dissertations

In this age of ubiquitous communication in which we can stay constantly connected with the rest of the world, for most of the part, we have to be grateful for one particular invention - the Internet. But as the popularity of Internet connectivity grows, it has become a very dangerous place where objects of malicious content and intent can be hidden in plain sight. In this dissertation, we investigate different ways to detect and capture these malicious contents hidden in the Internet. First, we propose an automated system that mimics high-risk browsing activities such as clicking on suspicious online ads, …

Life-Cycle Analysis Of A Cement Manufacturing Plant Co-Firing Hazardous Waste In The Usa, Stephen P. Holt

Theses and Dissertations

The purpose of this work was to determine the overall environmental impacts associated with the co-firing hazardous waste by burning in a cement kiln to replace the use of coal in the cement manufacturing process. This environmental assessment was conducted using LCA methodology. Understanding the environmental impacts associated with burning hazardous waste in a cement factory could help shape national environmental policy, regulations and the need for site specific human health risk assessments in the environmental regulatory permitting processes. Accordingly, the primary objective of this study was to evaluate the environmental impacts from the hazardous waste burning for energy recovery …

Internet Of Things To Smart Iot Through Semantic, Cognitive, And Perceptual Computing, Amit P. Sheth

Publications

Rapid growth in the Internet of Things (IoT) has resulted in a massive growth of data generated by these devices and sensors put on the Internet. Physical-cyber-social (PCS) big data consist of this IoT data, complemented by relevant Web-based and social data of various modalities. Smart data is about exploiting this PCS big data to get deep insights and make it actionable, and making it possible to facilitate building intelligent systems and applications. This article discusses key AI research in semantic computing, cognitive computing, and perceptual computing. Their synergistic use is expected to power future progress in building intelligent systems …

Interest Detection In Image, Video And Multiple Videos: Model And Applications, Yuewei Lin

Theses and Dissertations

Interest detection is detecting an object, event, or process that draws attention. In this dissertation, we focus on interest detection in images, video and multiple videos. Interest detection in an image or a video is closely related to visual attention. However, the interest detection in multiple videos needs to consider all the videos as a whole rather than considering the attention in each single video independently.

Visual attention is an important mechanism of human vision. The computational model of visual attention has recently attracted a lot of interest in the computer vision community mainly because it helps find the objects …

Improving Cooling Tower Chemistry Control And Cost Savings Through Automation, Ryan Matthew Maxwell

Theses and Dissertations

Proper chemistry control of cooling towers reduces corrosion, biological growth, and precipitation of solids. Therefore, improving control can lead to increased equipment life, operating efficiency, and safety. Chemistry of cooling towers is highly dependent on loading, weather, and time. As such, cooling tower chemistry varies day to day and even hour to hour, requiring either continuous controls or large operating bands. Through automation, 24/7 monitoring and control can be achieved, allowing for deliberate operation within tight operating bands. As a direct result of automation water consumption has been reduced by 9.1 million gallons per year, CL-49 use has been reduced …

Synthesis Of Well Dispersed Supported Metal Catalysts By Strong Electrostatic Adsorption And Electroless Deposition, John Meynard Macasero Tengco

Theses and Dissertations

Enhancing the catalytic performance of heterogeneous catalysts can be done by increasing active site count as well as modification of the physico-chemical characteristics of the catalyst material. For supported metal nanoparticles this can be achieved by decreasing particle size, thus increasing dispersion or metal utilization on the surface of the particles, while modification of metal properties can be attained by addition of a secondary metal that has a strong interaction to the primary metal, beneficial for a given reaction. In addition, the accessibility of the metal surface is necessary for reliable performance of catalysts. For carbon supported catalysts, Temperature Programmed …

Rational Design And Synthesis Of Pt/Silica-Alumina Metal-Acid Bifunctional Catalysts, Jadid Ettaz Samad

Theses and Dissertations

In the domain of rational catalyst design and synthesis, Strong Electrostatic Adsorption (SEA) has been applied with tremendous potential and use. In this study, SEA method has been advanced to thick slurries as well as to mixed oxide systems with a view to synthesizing stable, active and selective catalysts fine-tuned for specific applications.

The main objective was to synthesize metal-acid bifunctional catalysts with controlled ratio and proximity between metal and acid sites in order to analyze their effects on a bifunctional reaction. At first, the difference in charging behavior of silica and alumina in solution was used to selectively deposit …

Mechanical Characterization Of Sicf-Sicm Nuclear Fuel Cladding By A Novel Hydraulic Internal Pressurization Method, Kirill Shapovalov

Theses and Dissertations

Ceramic Matrix Composites (CMC) have been actively researched for applications requiring high temperature strength and damage tolerance. Examples are turbine engine hot section components, leading edges for hypersonic vehicles, nuclear fusion reactor first wall and blanket, and recently nuclear fuel claddings. Predictable material damage behavior is desirable for these applications so early damage accumulation can be detected before a catastrophic failure occurs. Many ceramic materials can withstand high temperature environments, but due to inherent brittleness of ceramics the high damage tolerance and the predictable damage behavior are difficult to achieve. Ceramic fiber reinforced ceramic composites (CFCC) have demonstrated the above …

Numerical Studies Of Arterial Tissue Failure, Xiaochang Leng

Theses and Dissertations

Arterial tissue failure leads to a number of potentially life-threatening clinical conditions, such as atherosclerotic plaque rupture and aortic dissection which develop unpredictably and rapidly in vivo. Thus, a full understanding of the two conditions will provide a solid basis for medical advances in the intervention and prevention of the occurrence of this life-threatening event. The present work aims to develop a cohesive zone model (CZM) approach for analysis and simulation of arterial tissue failure, such as plaque and fibrous cap delamination and tearing, and to validate simulation predictions with experimental results.

To characterize the hysteresis phenomenon of diseased aortic …

Automated Image Analysis And Spatial Computational Modeling Of Nf-Kb In Cerebrovascular Endothelial Cells, Kasey Catalfomo

Theses and Dissertations

Cerebrovascular endothelial cells play a key part in the inflammatory response of the blood-brain barrier in pathological conditions such as Alzheimer’s disease. Specifically, the NF-κB signaling pathway plays a central role. Better understanding of the factors in inflammatory disease progression can lead to more effective treatments for such devastating illnesses like Alzheimer’s, asthma, arthritis, cancer, diabetes and many more inflammatory diseases. The proposed approach analyzes spatial NF-κB distribution contained in multispectral stacked micrograph images of cerebrovascular endothelial cells indexed based on dose of the activating protein and the length of activation. Image analysis code identifies the location of nuclear boundaries …

Studies Of Asphalt Roofing Sealant Failure For Shingle Systems Subjected To High Wind Conditions For Both Elastic And Viscoelastic Sealant Material Response, Artem Aleshin

Theses and Dissertations

It has been documented that the sealant between asphalt roof shingles may delaminate at significantly lower wind speeds than those for which they are rated, with major consequences on safety and repair costs. In perspective, developing more resilient material systems and devising more effective installation procedures are sensible strategies to mitigate this problem. A practical approach may also entail adding a second self-sealing strip. In the first portion of this thesis, the elastic structural response of an asphalt roof shingle-sealant system consisting of individual three-tab shingles, which are bonded to the underlying shingles with two sealant strips and are subjected …

Nano Oil Additives And Their Effect On Uh-60 Auxiliary Power Unit Performance, James Patrick Folk

Theses and Dissertations

This study is designed to research the tribological properties of nano oils developed by NanoPro MT and to determine their effects on fuel consumption in an UH-60 Blackhawk Auxiliary Power Unit (APU). For this work, two different nano oils were tested and compared against the performance of conventional oil. The first nano oil mixture contains proprietary nanodiamond particles and the second nano oil contains a mix of zinc sulfide, boron nitride, and graphene particles. Aeroshell 560 was used as the conventional oil and was blended with the nano particles to create both nano oils. This oil meets the military specifications …

Estimation Of Basic And Mission Benefit Of Condition-Based Maintenance Deployment In Hums Equipped Ah-64 Aircraft Using Nlp And Regression Analysis, Tanzina Zaman

Theses and Dissertations

Condition-based maintenance (CBM) is a maintenance practice that involves regular monitoring of the mechanical condition of components of interest, processing of information collected, and then decision-making to ensure both maximizing the time interval between repairs and minimizing the number of unscheduled failures. CBM also offers early detection of failure which can prevent major breakdowns and repairs. Vibration monitoring is one of the effective techniques for condition monitoring. Health and Usage Monitoring System (HUMS) is a powerful tool for aviation industry which monitors health status and trending data. Vibration Monitoring Unit (VMU) and Modernized Signal Processing Unit (MSPU) are two forms …

Deformation Induced Martensitic Transformation In 304 Stainless Steels, Junliang Liu

Theses and Dissertations

304 stainless steel is an austenitic steel widely used for various applications due to a good combination of strength and ductility and relative low cost. It is known to be metastable as the austenite phase can transform into martensite under stress. In this work, a new method (in-situ tensile TEM) and the traditional method (ex-situ tensile tests and TEM, XRD characterization) were used to investigate the mechanisms of deformation-induced martensitic transformation in 304SS samples at different temperatures.

The ex-situ tensile tests were conducted under a strain rate of 10-3 s-1 until rupture. After the tensile tests, the fractured area was …

Biodegradable Hybrid Tissue Engineering Scaffolds For Reconstruction Of Large Bone Defects, Danial Barati

Theses and Dissertations

Complex skeletal injuries and large bone fractures are still a significant clinical problem in US. Approximately 1.5 million Americans (veterans, their families, and civilians) every year suffer from bone loss due to traumatic skeletal injuries, infection, and resection of primary tumors that require extensive grafting to bridge the gap. The US bone graft market is over $2.2 billion a year. Due to insufficient mechanical stability, lack of vascularity, and inadequate resorption of the graft, patients with traumatic large skeletal injuries undergo multiple costly operations followed by extensive recovery steps to maintain proper bone alignment and length. Current strategies for repairing …

Regular Expression Synthesis For Blast Two-Hit Filtering, Jordan Bradshaw

Theses and Dissertations

Genomic databases are exhibiting a growth rate that is outpacing Moore's Law, which has made database search algorithms a popular application for use on emerging processor technologies. NCBI BLAST is the standard tool for performing searches against these databases, which operates by transforming each database query into a filter that is subsequently applied to the database. This requires a database scan for every query, fundamentally limiting its performance by I/O bandwidth. In this dissertation we present a functionally-equivalent variation on the NCBI BLAST algorithm that maps more suitably to an FPGA implementation. This variation of the algorithm attempts to reduce …