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Engineering

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University of Wollongong

2011

Coupling

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Two-Color Terahertz Response In Bilayer Graphene Nanoribbons With Spin-Orbit Coupling, Junfeng Liu, Bo Wang, Zhongshui Ma, Chao Zhang Jan 2011

Two-Color Terahertz Response In Bilayer Graphene Nanoribbons With Spin-Orbit Coupling, Junfeng Liu, Bo Wang, Zhongshui Ma, Chao Zhang

Faculty of Engineering - Papers (Archive)

We demonstrate that spin-orbit coupling can give rise to a strong terahertz response in metallic armchair bilayer graphene nanoribbons. The combination of the interlayer coupling and the spin-orbit coupling leads to double resonant optical response in the low frequency regime. The frequency separation of the two excitations is tunable with a gate voltage.


Coupling Effects Of Feed Solution Ph And Ionic Strength On The Rejection Of Boron By Nf/Ro Membranes, Kha Tu, Long Nghiem, Allan Chivas Jan 2011

Coupling Effects Of Feed Solution Ph And Ionic Strength On The Rejection Of Boron By Nf/Ro Membranes, Kha Tu, Long Nghiem, Allan Chivas

Faculty of Engineering - Papers (Archive)

The coupling effects of solution pH and ionic strength on boron rejection by nanofiltration (NF) and reverse osmosis (RO) membranes were investigated. Two NF membranes (namely NF270 and NF90) and three RO membranes (namely BW30, SW30 and UTC80) were used to provide a full spectrum of NF/RO membranes. The rejection of boron by all five membranes was pH-dependent. The dependency of boron rejection on the feed solution pH became much more substantial as the nominal salt (sodium or calcium) rejection value of the membrane decreased. At pH 11, boron rejections by the NF90 and the NF270 membranes were only 10% …


Oxidative Acetylenic Coupling Reactions As A Surface Chemistry Tool, Simone Ciampi, Michael James, Nadim A. Darwish, Erwann Luais, Bin Guan, Jason Brian Harper, J Justin Gooding Jan 2011

Oxidative Acetylenic Coupling Reactions As A Surface Chemistry Tool, Simone Ciampi, Michael James, Nadim A. Darwish, Erwann Luais, Bin Guan, Jason Brian Harper, J Justin Gooding

Australian Institute for Innovative Materials - Papers

A novel method to prepare redox monolayers on silicon electrodes has been developed that employs CuI-catalyzed oxidative acetylenic coupling reactions for molecular electronic type applications. As the first case study, ethynylferrocene was covalently immobilized onto an acetylene-terminated monolayer on a Si(100) surface to give a 1,3-diyne (CC-CC-) linked redox assembly. The derivatization process requires no protection/de-protection steps, nor activation procedures. The effect of the conjugated diyne linkage on the rate of electron transfer between tethered ferrocenyl units and the silicon electrode is benchmarked against well-established "click" products (i.e. 1,2,3-triazole linkage). The surfaces, after each step, are characterized thoroughly using X-ray …