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Rock-Fluid Interaction And The Incorporation Of Cations Into Calcite During Recrystallization In Multiple Hydrothermal Systems., Van Anh Nguyen

Theses and Dissertations

Fluid-rock interaction causes an exchange of isotopes or elements through various reactions. The rate of these reactions strongly depends on temperature. The interaction involves dissolution precipitation, chemical exchange reactions, redox reactions, diffusion, and their combinations. The goal of studying fluid-rock interaction is to understand the change in mineral chemistry of the rock materials when in contact with an aqueous solution. These processes occur in all regions of the Earth where aqueous solutions are found. This work is comprised of three independent studies which provide an understanding about crystallization processes under multiple hydrothermal conditions with geological and environmental applications.

In the …

Determining The Effects Of Elevated Carbon Dioxide On Soil Acidification, Cation Depletion, And Soil Inorganic Carbon And Mapping Soil Carbons Using Artificial Intelligence, Jannatul Ferdush

Theses and Dissertations

Soil carbon is the largest sink and source of the global carbon cycle and is disturbed by several natural, anthropogenic, and environmental factors. The global increase of atmospheric CO₂ affects soil carbon cycling through varied biogeochemical processes. The first chapter is a compilation of current information on potential factors triggering soil acidification and weathering mechanisms under elevated CO₂ and their consequences on soil inorganic carbon (SIC) pool and quality. Soil water content and precipitation were critical factors influencing elevated CO₂ effects on the SIC pool. The second chapter examines a detailed column experiment in which six soils …

Stratigraphy, Sedimentology, And Deformational Significance Of Cambrian And Early Ordovician Strata Along The Southeast Wisconsin Arch, Allison Raeann Kusick

Theses and Dissertations

A detailed study of the stratigraphic units in and around the Wisconsin Arch of central and southeast Wisconsin are presented to refine the sedimentologic record and the geologic implications within the Cambrian and early Ordovician strata. The Cambrian and early Ordovician sediments in central and southeast Wisconsin unconformably overlie a topographic high composed of Precambrian basement rocks, called the Wisconsin Arch, and consist of various clastic deposits, dolostones, and several horizons of deformation. Bedrock cores, made available through the Wisconsin Geological and Natural History Survey (WGNHS), were analyzed, to understand sedimentation in the Cambrian and early Ordovician. My analyses focused …

Swimming Ability Of The Enigmatic Carboniferous Fish: Tullimonstrum Gregarium, Jacob James Potter

Theses and Dissertations

Tullimonstrum gregarium, more commonly known as the Tully Monster, is one of the strangest creatures in the fossil record. While it was traditionally considered a problematic fossil, recent studies have firmly placed the Tully Monster with the vertebrates as a relative of lamprey and hagfish. This may offer insight into the Tully Monster’s ecology, but the Tully Monster’s Swimming ability remains uncertain due to its strange body plan. This study aims to investigate the hydrodynamics of these features to gain insight into the Tully Monster’s swimming ability using computational fluid dynamics (CFD). 3D and 2D simulations of the Tully Monster …

Assessment Of Nitrogen-Based Fertilizer Transport And Microbial Activities In Sandy Soil Profiles In South Texas, Gladys De La Rosa

Theses and Dissertations

Conventional farming is a common practice in Lower Rio Grande Valley (LRGV) and the application of nitrogen fertilizer is essential for plant growth and support. However, managing the rate of nitrogen that is applied can benefit farmers financially and reduce nitrate leaching that can have an adverse effect on the local environment and aquatic systems, e.g., rivers and estuaries. Sandy soils are more vulnerable to water infiltration due to the large proportion of macropores. This study aims to (i) assess how nitrate from a variety of fertilizers (i.e., synthetic and organic) distributes on the top 60 cm layer of a …

Growth And Reproduction In Gulf Of Mexico Black Corals (Antipatharians) In Field And Laboratory Studies, Victoria E. Salinas

Theses and Dissertations

Black corals provide an important ecosystem of marine life and are found throughout all the oceans of the world at depths between 2 and 8,600 m. However, little is understood about their life history and the factors that control the distribution of black corals, particularly in the Gulf of Mexico (GoM). Given the impacts of the Deepwater Horizon oil spill on soft corals (e.g., black corals and octocorals) in the GoM, studies of their growth and reproductive biology in both natural and aquaculture environments are crucial for restoration efforts. The objectives of this study were to examine reproductive processes, compare …

Network Analysis Of Scientific Research In The Gulf Of Mexico, Juliet S. Vallejo

Theses and Dissertations

The Gulf of Mexico ecosystem represents a significant management challenge in its 3,423-mile coastline and transnational regulatory setting, along five states from the United States, six states from Mexico, and Cuba which borders the southeastern quadrant. Providing various resources to the regional economies, the continued success of these resources depends on the collaboration among transnational participants in bringing together complementary skills and multidisciplinary approaches to producing, circulating, and utilizing scientific knowledge. Using bibliometric analysis of Gulf of Mexico-related published research over 18 years from 2000 to 2018 allows for identifying organizations, their connections, and trends in the production of scientific …

Effects Of Nutrient Enrichment On Mangrove And Saltmarsh Habitats, Elena A. Flores

Theses and Dissertations

Nutrient over-enrichment is a global threat to coastal and marine environments. Yet, system-specific attributes of estuarine and coastal ecosystems may result in large differences in their sensitivity and susceptibility to such threat. In tropical latitudes, plant species adapted to low-nutrient habitats generally have nutrient-conservation mechanisms that acquire, use, and internally recycle nutrients efficiently. Thus, a major challenge for managers and decision makers is to develop a predictive and holistic understanding of how nutrient loading alters ecosystem functions and therefore ecosystem services. The objective of the present research is to document short and long-term effects of persistent nutrient …

Differentiating Pleistocene Alloformations In The South Carolina Coastal Plain Through Lithologic, Textural, Mineralogical, And Cluster Analyses, Charles Andrew Wykel

Theses and Dissertations

Currently, there is no textural or mineralogic basis for identifying and differentiating Pleistocene strand deposits in the South Carolina (SC) Lower Coastal Plain (LCP). Historically, geologic mapping of the SC coastal plain uses geomorphologic and biostratigraphic techniques for identifying and mapping LCP surficial strand deposits. While useful, both approaches have problems. The aim of this study is to develop a cost-effective approach to differentiate and identify strand deposits of different Pleistocene alloformations occurring in the SC LCP. To accomplish this task, four strand samples were taken from the Ten Mile Hill, the Ladson, and Wicomico alloformations in Horry County, SC. …

An Assessment Of The Performance Of The Earthscope Automated Receiver Survey: A User’S Guide To Ears., Erin L. Taxon

Theses and Dissertations

An Assessment of the Performance of the EarthScope Automatic Receiver Survey: A User's Guide to EARS.

With the advent of digital seismic recording, the ability to process and interpret large quantities of seismic data has become increasingly vital. EarthScope Automated Receiver Survey, EARS, was launched in 2005 to estimate bulk crustal properties in real time, at all broadband seismograph stations, globally. EARS utilizes the receiver function HK stacking method to estimate a station’s crustal thickness (H) and ratio of P wave velocity (Vp) and S wave velocity (Vs), known as Vp/Vs (K). Receiver function analysis observes the arrival times …

Structural And Biological Analysis Of Faults In Basalts In Sheepshead Mountains, Oregon As An Earth Analogue To Mars, Allison Bohanon

Theses and Dissertations

Microbial life on Mars is not visible from orbit or by rover cameras, but the fracture networks and scarp morphologies associated with fractures they could live in are measurable. We conducted a field analogue study of 92 normal fault scarps in the Sheepshead Mountains, Oregon to examine the correlation between scarp morphology and vegetation growth in the Steens Basalt. While vegetation is not expected on Mars, the fracture networks that sustain vegetation offer the same micro-environment that would support and protect endoliths. Structural variables were measured in the field and infrared spectra of fault scarps were measured using a handheld …

Impact Of Climate Oscillations/Indices On Hydrological Variables In The Mississippi River Valley Alluvial Aquifer., Meena Raju

Theses and Dissertations

The Mississippi River Valley Alluvial Aquifer (MRVAA) is one of the most productive agricultural regions in the United States. The main objectives of this research are to identify long term trends and change points in hydrological variables (streamflow and rainfall), to assess the relationship between hydrological variables, and to evaluate the influence of global climate indices on hydrological variables. Non-parametric tests, MMK and Pettitt’s tests were used to analyze trend and change points. PCC and Streamflow elasticity analysis were used to analyze the relationship between streamflow and rainfall and the sensitivity of streamflow to rainfall changes. PCC and MLR analysis …

Characterization Of Quaternary Stratigraphy In The Mississippi Sound To Evaluate The Influence Of Geologic Heterogeneity On Submarine Groundwater Transport And Discharge, Zachary Peoples

Theses and Dissertations

Submarine Groundwater Discharge (SGD) through seafloor sediments is gaining recognition as an important component of coastal water quality. Stratigraphic features creating geologic heterogeneity, such as incised paleochannels, may influence preferential pathways for SGD. The central Mississippi Sound is underlain by paleochannels that were incised into Pleistocene sediments while the area was subaerially exposed during the last glacial maximum and are now buried by transgressive Holocene deposits. In this thesis, newly collected chirp, previously published seismic reflection, and sediment core data are used to characterize the three-dimensional structure of the Holocene-Pleistocene contact. Results indicate that Pleistocene paleochannels cross-cut the study area, …

Development And Evaluation Of Seasonal, Continental-Scale Streamflow Forecasts, Elissa Marie Yeates

Theses and Dissertations

Methods of forecasting streamflow using atmospheric ensembles and hydrologic routing have greatly improved over the past decades. These forecasts anticipate the timing and magnitude of streamflow peaks, enabling early warning of floods. Recent advances in atmospheric modeling have enabled production of forecasts months ahead, which are less precise but give a useful sense of trends.

The purpose of this study is to produce and evaluate a seasonal streamflow forecast model using a Muskingum routing hydrologic model coupled with runoff from a land surface model, and atmospheric input from a medium-term atmospheric and precipitation model. To evaluate the skill of the …

Baseflow Variability Due To Changes In Climate, Basin Characteristics, And Groundwater Withdrawals In The State Of Wisconsin, Usa, Susan Borchardt

Theses and Dissertations

ABSTRACT

BASEFLOW VARIABILITY DUE TO CHANGES IN CLIMATE,BASIN CHARACTERISTICS, AND GROUNDWATER WITHDRAWALS IN THE STATE OF WISCONSIN, USA

bySusan Borchardt The University of Wisconsin-Milwaukee, 2022 Under the Supervision of Professor Woonsup Choi

In Wisconsin, the number of high-capacity wells has increased substantially, and concerns have been raised about their impact on both groundwater levels and streamflow. At the same time Wisconsin’s climate has been changing, and both the annual precipitation (5%) and temperature (1.5oC) have been trending upward over the last 68 years and both are predicted to increase into the future. This study attempted to demonstrate the simultaneous effects …

Terrestrial Perspective On The Formation, Evolution, And Detection Of Zeolites In Lacustrine Environments On Early Mars, Gayantha Roshana Loku Kodikara

Theses and Dissertations

This study evaluates the possible formation and evolution mechanisms of zeolites on early Mars with possible explanations for their limited detections using Earth analogs. This study focuses on the formation of zeolites in the closed basin lakes where the largest relatively pure concentrations of natural zeolites are found on Earth. Five working hypotheses were formulated to explore the limited detection of zeolites in closed basin lakes on Mars and different styles of scientific reasoning with suitable examples were used to test the independent, converging lines of inquiry. Zeolites may not be identifiable in certain locations on Mars using orbital data …

The Effects Of Hybridization On Skeletal Morphology In Two Closely Related Populations Of Rhesus Macaques (Macaca Mulatta): A Geometric Morphometric Approach, Cody Zachery Schumacher

Theses and Dissertations

Precise identification and classification techniques are vital for the field of paleoanthropology to ensure that hominin fossilized remains are labeled accurately. The morphology of extinct hominin specimens will typically be compared to extant nonhuman primate species because of how closely related they are phylogenetically. Observable similarities in their morphological variation can be examined to infer which traits may be a result of evolution and this can update our understanding of their evolutionary relationships. The genus Macaca displays a level of morphological variation that is similar to that seen in the genus Homo, therefore macaques can be used as an analogous …

Alkalinity Enhanced Mass Reduction Of Uranium Contaminated Sediment, Cullen Edward Meurer

Theses and Dissertations

Uranium is a toxic and radioactive metal that is naturally occurring in the Earth’s crust. The uranium mining boom of the 1950’s produced many contaminated aquifers throughout the United States. Monitoring of groundwater data suggests that uranium concentrations may take 100’s of years to naturally attenuate to below the maximum contamination limit. This project examines a potential and novel remediation technique of groundwater contaminated with uranium through alkalinity enhanced desorption from the solid phase. Alkalinity enhances the desorption of uranium by complexing uranyl (UO22+) with Ca and CO3 which allows for further desorption. Since remediation is time consuming and expensive, …

Mass Transport Of Uranium During Recharge Of Surface Water To Contaminated Groundwater, Kendyl Nicole Hoss

Theses and Dissertations

This study characterized the predominant mass transport mechanisms of uranium during river water recharge to contaminated groundwater to better characterize its mobility. It was hypothesized that the mass transfer of uranium from the solid phase to the aqueous phase was occurring during periods of river water to groundwater recharge via concentration-driven desorption. Sediment data confirmed the presence of uranium on the solid phase via nitric acid extraction. The recharge of river water to the saturated zone of a uranium-contaminated aquifer was simulated in a multi-well tracer test. The injection fluid was Little Wind River water and was traced with added …

Investigation Of A Simultaneaous Direct And Indirect Contact Dehumidifier Using Parallel Strings For Hdh Desalination, Josue Perez Perez

Theses and Dissertations

Freshwater is a limited and precious resource. Currently, half a billion people in the world face sever water scarcity all year round. Humidification dehumidification (HDH) systems have received special attention among the variety of small-scale desalination technologies due to its potential to create affordable and sustainable seawater desalination, especially when combined with natural power sources such as waves, wind, and solar rays. Improvements in the development of HDH desalination systems have been achieved in recent years. Nonetheless, the improvements that have received most attention focus on solar heaters and humidifiers. Dehumidification systems have often been adapted from air conditioning condensation …

Hydrologic Modeling Study To Determine Hydrologic Impact Of Resacas On The Lower Laguna Madre Watershed, Antonio L. Reyna

Theses and Dissertations

During a high intensity storm events, a series of catastrophic events occur. These catastrophic events include flooding and destruction of infrastructure. Engineers have determined a method to design for high intensity storms based off hydrologic analysis of previous storms. With this data engineers can determine the outflow of major rivers and streams that may impact infrastructure. By determining the watershed engineers can predict the flow of the water and as well as the location of the outfall. In the Rio Grande Valley, water quality is very important because after rain events stormwater from cities is carried out towards the Laguna …

Quantifying The Controls Of Shear-Coupled P-Waves, Jackson Saftner

Theses and Dissertations

Shear-coupled P-waves have been shown to possess great utility in resolving crustal and upper mantle models, however these phases remain largely untapped due to their ephemeral nature. Shear-coupled P-waves are a type of seismic phase that undergo S-to-P conversion either at the free-surface or at the base of the crust. Under the proper conditions, it is possible for the converted crustal P phases to achieve total internal reflection, allowing these phases to remain large in amplitude and sample long segments of the crust. In this study, we use a combination of real-world observations collected from literature, and synthetic seismograms, to …

The Impact Of Framing On Natural Gas Pipeline Siting In Virginia, Ritvik Shukla

Theses and Dissertations

Natural gas has become a major share of energy consumption in the U.S. over the past two decades. This rise has resulted in considerable investment in the natural gas pipeline network so that the supply can be maximized. However, pipeline infrastructures, much like other fossil fuel energy infrastructures and activities, have an uneven distribution of benefits and costs across different regions. In regions where natural gas activities and infrastructure are being developed, local communities can become increasingly dependent on natural gas systems for stable revenue and employment. Such communities risk becoming “locked in” to carbon energy at a time when …

Hydrologic Profiles And Geospatial Trend Analysis Evaluating Recurrent Flooding At Coastal U.S. Air Force Installations, Dylan D. Bechen

Theses and Dissertations

Military installations are exposed to numerous threats, including a changing climate and the risk of recurrent flooding. The four components of recurrent flooding are sea-level rise, tidal fluctuations, storm surges, and precipitation. This research analyzed 40 years of historical precipitation and tidal data at 17 coastal U.S. Air Force installations using indicators of both peak and threshold exceedances to identify long-term temporal trends in the hydrologic components that make up recurrent flood risk, establishing an installation’s “hydrologic profile” which can be used to better inform decision makers when evaluating portfolio-wide adaptation strategies and prioritization of long-term infrastructure investments.

Biotic Characteristics Of Managed And Unmanaged Coastal Dunes In The Outer Banks, North Carolina, Andrew E. White

Theses and Dissertations

Under future climate change and sea level rise scenarios, Natural and Nature-Based Features (e.g., dunes) that protect coastal habitat and infrastructure will be exposed to increased wave energy and storm surge. Understanding how these forces will impact coastal dunes is necessary for their continued use as protective features. Coastal dunes develop through feedback between vegetation and sediment deposition, a process complicated by species-specific growth rates and responses to burial. Wave flume studies have tested the effects of dune vegetation on erosion and found multiple plant organs across several functional types to be important for resisting erosion. Although dune building and …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

The Effects Of Cover Crops In An Integrated Livestock/Continuous Corn Cropping System In East-Central Mississippi, Ken Randolph Waddell

Theses and Dissertations

There is growing interest within the agricultural industry on how cover crop systems affect soil health and economic productivity in integrated crop-livestock systems. This study investigated the combined effects of cover crop species; no-till and conventional till; and grazed (G) and un-grazed (UG) in a continuous corn (Zea mays) production system in east-central Mississippi. Cover crops were established in the fall of 2019 and 2020 in two separate field studies. Corn yield was not affected by grazing or tillage but was affected by cover crop species. We then compared the difference in cover crop species treatments with their respective corn …

Chemical And Physical Weathering Rates Of Basaltic Volcanic Regions: Utilizing Space In Place Of Time In The Hawaiian Archipelago, Benjamin Clyde Barton

Theses and Dissertations

With large populations living in tropical regions of the world with volcanic substrates, understanding basalt weathering processes is vital. The Hawaiian Islands are an excellent natural analogue to study chemical weathering rates due to a uniform bedrock (basalt), large variations in rainfall, and varying ages across the islands. Laterite weathering profiles (LWP) develop over time through chemical weathering, where LWP thickness is influenced by many factors, including precipitation and time. Using the rapid, non-invasive horizontal-to-vertical spectral ratio (HVSR) method, LWP thicknesses can be estimated to constrain chemical weathering rates. Studying the laterite weathering profiles developed from basaltic bedrock of varying …

Sorption Of 2-Naphthalene Sulfonate To Organic Carbon In Natural Saturated Porous Media, Jiyan Hatami

Theses and Dissertations

Organic carbon (OC) in aquifer sediments serves as a key geochemical control on contaminant fate and transport, potentially immobilizing or delaying mass transport downgradient. Quantifying the abundance of OC in aquifer sediments is therefore imperative in developing a conceptual understanding of local contaminant transport. Traditional methods involve time-intensive coring and lab analyses for total OC (TOC) at distinct intervals with depth. These methods fail to account for the heterogeneity between discrete points and do not interrogate TOC along groundwater flow pathways. 2-naphthalene sulfonate (2-NS), a novel groundwater tracer, was investigated here as a possible sorptive tracer for estimating the relative …

Analyzing Weathering Patterns In Modern And Paleolake Deposits Of Tecopa, California: Implications For The Detection Of Paleolakes On Mars, Jason Benjamin Carman

Theses and Dissertations

This study focuses on two stratigraphic sections from the Tecopa paleolake and samples from the modern Tecopa and Amargosa River basins as a terrestrial analogue to Martian paleolakes. Previous work shows that the later stages of Pleistocene Lake Tecopa were highly alkaline and saline due to evaporation, which led to the formation of authigenic lacustrine minerals such as zeolites, clays, and precipitates that are potentially similar to Martian paleolakes. Paleolakes can provide information on past aqueous processes, such as the changes in the hydrologic cycle that a particular area experienced over the lifespan of a lake on Earth or Mars. …