Digital Commons Network^™

Sulfur And Trace Metal Cycling At Convergent Margins, Jesse B. Walters

Electronic Theses and Dissertations

Subduction zones are the site of long-term chemical exchange between Earth’s surface and interior geochemical reservoirs. Subducting slabs are progressively depleted in volatiles and other mobile elements through dehydration and melting reactions. These elements are then introduced to the mantle wedge and volcanic arc. One consequence of this cycle is that volcanic arcs produce the most oxidized magmas on Earth. Sulfur, which exhibits a range in valence states from S^2- to S⁶⁺, is one of the few elements in the subducting slab capable of oxidizing the arc and mantle wedge. Sulfides in the slab may also act …

Variations In The Southern Hemisphere Westerlies Over The Last 23,000 Years From Lake Records In The Falkland Islands, Meghan M. Spoth

Electronic Theses and Dissertations

The Southern Hemisphere Westerlies (SHW) are an important driver of climate in the mid-latitudes of the Southern Hemisphere. Abrupt latitudinal migration of this coupled atmospheric-oceanic system is thought to be linked to the onset of the Termination at the end of the last ice age and to subsequent climatic variation through the late-glacial period and Holocene. However, the timing and spatial extent of these shifts, as well as variations in wind intensity, are poorly constrained, hindering our understanding of abrupt climate change in the Southern Hemisphere. In addition, future changes in the position and intensity of the SHW are a …

Fostering Climate Change Resilience: A Socio-Ecological Forest Systems Approach, Alyssa R. Soucy

Electronic Theses and Dissertations

As climate change continues to impact socio-ecological systems, those that rely on natural resources are highly sensitive to climatic changes. Maine’s forest industry provides for the economic and social well-being of many residents and is especially vulnerable to climate change impacts. Changes in growing season length and timing, forest health threats imposed by insects and pathogens, extreme weather events, shifting forest composition, and changes in natural disturbance severity and frequency have already begun, and are projected to continue, to impact forest systems in the Northeastern U.S. While climate change presents a threat to forest systems, opportunities also arise due to …

A Groundwater Flow Model To Aid In Water Resource Management For The Carraipia Basin In The Coastal Semi-Arid Region Of La Guajira State (Colombia), Efren D. Gomez Arevalo

Electronic Theses and Dissertations

About 160,000 inhabitants live in the 1,600 square kilometers Carraipia River Basin located in northeastern Colombia and northwestern Venezuela. Historically, water has been supplied to the inhabitants in this arid coastal region by shallow dug wells. Water supplied by these wells is frequently of poor quality due to high concentrations of total dissolved solids (TDS). Recently, due to the increasing demand for water, numerous deep wells have been drilled in the region to supply water to rural and urban areas from deep aquifers. Colombian agencies seek more quantitative information on groundwater resources, driven by increasingly severe water shortages over the …

An Algorithm To Estimate Suspended Particulate Matter Concentrations And Associated Uncertainties From Remote Sensing Reflectance In Coastal Environments, Juliana Tavora

Electronic Theses and Dissertations

Suspended Particulate Matter (SPM) is a major constituent in coastal waters, involved in processes such as light attenuation, pollutant propagation, and waterways blockage. The spatial distribution of SPM is an indicator of deposition and erosion patterns in estuaries and coastal zones and a necessary input to estimate the material fluxes from the land through rivers to the sea. In-situ methods to estimate SPM provide limited spatial data in comparison to the coverage that can be obtained remotely. Ocean color remote sensing complements field measurements by providing estimates of the spatial distributions of surface SPM concentration in natural waters, with high …

The Effects Of Sediment Acidification And Temperature On The Immune Capacity Of The Atlantic Jackknife (Razor) Clam (Ensis Leei M. Huber, 2015), Brian Preziosi

Electronic Theses and Dissertations

Sediment acidification has been shown to negatively impact clams of economic importance such as the soft-shell clam, Mya arenaria Linnaeus, 1758, and hard clam, Mercenaria mercenaria (Linnaeus, 1758). Effects of sediment acidification on razor clams, including the Atlantic jackknife clam Ensis leei M. Huber, 2015, are unknown. E. leei has been identified as a species with potential for aquaculture operations on the New England coast. E. leei may be resilient to acidification and thus persist in acidified sediments where other clams cannot. To this end, the impact of acidified surface sediment on the internal immune capacity of adult (mean shell …

Mechanisms Of Ice Core Stable Isotope Variability In The Upper Kaskawulsh-Donjek Region, St. Elias Mountains, Yukon, Canada, Erin A. Mcconnell

Electronic Theses and Dissertations

I use instrumental and ice core records to examine drivers of observed isotope variability in the Upper Kaskawulsh-Donjek (UKD) region of the St. Elias Mountains, Yukon, Canada over the time frame of instrument-proxy overlap (mid-1900s to present). One of the drivers of post-depositional isotope signal alteration is the vertical percolation of meltwater from the glacier surface through shallow layers of snow, which causes a reduction in the amplitude of the isotope signal recorded in ice cores. I examine isotope signal preservation in two sites in the St. Elias Mountains: Eclipse Icefield and Icefield Divide. These sites are relatively close (~30 …

Fractures, Fluids, And Metamorphism: Shear Zone Initiation In The Marcy Anorthosite Massif, Adirondacks, New York, Usa, James Hodge

Electronic Theses and Dissertations

Localized shear zones are important rheological features that influence deformation behavior throughout the Earth’s middle-to-lower crust. Therefore, the processes through which shear zones initiate and localize remains an important geologic question. The study of strain localization and shear zone initiation is made difficult due to continued deformation overprinting the microstructures which lead to initiation and obfuscating the context in which localization occurred. The Marcy anorthosite in the Adirondack Highlands, New York, is a nominally granulite-facies, plagioclase-rich massif cut by centimeter-to-meter scale shear zones which provides a natural example of shear zone localization within the middle-to-lower crust. My work focuses on …

Improved Estimates Of Tributary Nitrogen Load To Casco Bay, Maine, Whitley J. Gray

Electronic Theses and Dissertations

Over the past two decades, total nitrogen (TN) concentrations have increased in Casco Bay (CBEP 2015). The sources of the increased nitrogen are poorly understood but occur with simultaneous population growth and land use changes. The total riverine nitrogen load to Casco Bay was previously estimated by Liebman and Milstead (2012) using the United States Geologic Survey’s (USGS) SPAtially Referenced Regression On Watershed attributes (SPARROW) model. The SPARROW model uses watershed characteristics, regional monitoring data and nitrogen source data to estimate nitrogen loading but was not validated using measurements of nitrogen in the Casco Bay watershed. This study attempts to …

A Multi-Proxy Paleoecological Reconstruction Of Holocene Climate, Vegetation, Fire And Human Activity In Jamaica, West Indies, Mario A. Williams

Electronic Theses and Dissertations

Jamaica is located in the Caribbean biodiversity hotspot and has a rich flora and fauna, most notably characterized by exceptional levels of plant endemism. These natural resources are imperiled by climate change and increasing anthropogenic pressures, therefore highlighting the importance of implementing effective conservation programs to mitigate ecosystem degradation. Paleoecological studies that investigate the diversity and distributions of organisms and their habitats over millennial timescales provide critical long-term spatial and temporal context for the assessment of contemporary environmental problems. Lake sediments are a highly useful archive for the study of prehistoric climate and ecological changes, as biological, chemical and geophysical …

Past, Present, And Future Arctic Climate And National/Community Risk Assessment, Jeff Auger

Electronic Theses and Dissertations

The Arctic is warming at a rate nearly double that of the global average. The enhanced rate of warming impacts weather and climate across the Northern Hemisphere. As the meridional (south to north) thermal gradient weakens, the middle-latitude westerlies are expected to slow and become “wavier” increasing heat and moisture advection to higher latitudes. A quasi-stationary ridge-trough system of the jet stream increases chances for droughts, floods, heatwaves, and cold spells. These impacts have already been observed as North American forest fires and early or extended Great Lake ice out. It is more important than ever to understand how the …

Determining The Influence Of Lateral Margin Mechanical Properties On Glacial Flow, Kate Hruby

Electronic Theses and Dissertations

The lateral margins of glaciers and ice streams play a significant role in glacial flow. Depending on their properties, like temperature and ice crystal orientation, they can cause a resistance to flow or enhance it. In combination with our current changing climate, flow patterns can dictate the mass balance of an ice body. It is therefore more important than ever to understand the impact that variations at the margins can have on flow. However, the lateral margins of glaciers and ice streams are an often-neglected part of ice dynamics; they are harder to sample than the center of a glacier’s …

Root Biomass And Other Soil Properties Affecting The Co2 Flush From Laboratory Dried And Rewetted Soils, Audrey E. Laffely

Electronic Theses and Dissertations

Soil that has been dried and rewetted has been observed to release a ‘burst’ or ‘flush’ of carbon dioxide (CO 2 ) upon rewetting. This CO 2 flush has been proposed as an indicator of soil health. This may be a valuable indicator of soil health, however the CO 2 flush has yet to be fully evaluated. Roots and root exudates influence the soil in a variety of ways that may impact the CO 2 flush, such as increasing aggregation, organic carbon (C), and microbial biomass. We conducted both field and greenhouse experiments to elucidate the relationship of root biomass …

Investigations Into The Advancement Of Cryptotephra Geochemical Fingerprinting, Laura Hartman

Electronic Theses and Dissertations

The primary purpose of this work is to advance new sample preparation and analytical methods for ice core tephrochronology. When a volcanic source can be accurately identified using volcanic glass particle geochemistry, it may provide a robust time reference for the ice core’s timescale. The presence of an identifiable tephra layer may also suggest atmospheric pathways at the time of deposition, or assist in reconstructing volcanic forcing of climactic state for a specific event. One of the perpetual challenges in ice core based tephrochronological work is measuring the geochemical composition of ultra-fine particles (<10 >μm). Not only is it difficult …

Controls On Phosphorus Export From An Agricultural Watershed: Amsden Brook, Fort Fairfield, Maine Usa., Gregory J. Mcdonald

Electronic Theses and Dissertations

This study explores the sources and mechanisms of phosphorus (P) mobilization during base flow within the Amsden Brook watershed, Fort Fairfield, Maine, USA. Amsden Brook is an agriculturally dominated watershed drained by a spring-fed and perennial first- to second-order stream. We characterized the P concentrations within the watershed to investigate connections between soils, stream sediment, surface water, and groundwater. Waters were monitored monthly during the 2017 snow-free period for temperature, pH, dissolved oxygen, conductivity, soluble reactive P (SRP), total P, strong acid anions, strong base cations, dissolved organic carbon (DOC), Al, Fe, and Mn. Phosphorus speciation within soils and sediment …

Remote Sensing Of Icebergs In Greenland's Fjords And Coastal Waters, Jessica Scheick

Electronic Theses and Dissertations

Increases in ocean water temperature are implicated in driving recent accelerated rates of mass loss from the Greenland Ice Sheet. Icebergs provide a key tool for gaining insight into ice-ocean interactions and until recently have been relatively understudied. Here we develop several methods that exploit icebergs visible in optical satellite imagery to provide insight on the ice--ocean environment and explore how iceberg datasets can be used to examine the physics of iceberg decay and parent glacier properties. First, a semi-automated algorithm, which includes a machine learning-based cloud mask, is applied to six years (2000-2002 and 2013-2015) of the Landsat archive …

Stream Dynamics In The Headwaters Of Post-Glacial Watershed Systems, Brett Gerard

Electronic Theses and Dissertations

This dissertation summarizes research examining watershed processes across Northern New England, with an emphasis on the Central and Coastal regions of Maine. The research presented here focuses on the linkages between watershed geomorphic conditions, climate, and surface flow regimes driving stream channel hydraulic conditions and bed dynamics governing channel geometry. The geologic and human history of the landscape provides the context in which earth surface processes are examined within the dominant physiographic settings in Maine to describe vulnerabilities to climate change. Results are summarized to support the development of sustainability solutions for forecasted watershed management problems by natural resource management …

Climatic Range Filling Of North American Trees, Benjamin Seliger

Electronic Theses and Dissertations

Understanding the degree to which species distributions are controlled by climate is crucial for forecasting biodiversity responses to climate change. Climatic equilibrium, when species are found in all places which are climatically suitable, is a fundamental assumption of species distribution models, but there is evidence in support of climate disequilibria in species ranges. Long-lived, sessile organisms such as trees may be especially vulnerable to being outpaced by climate change, and thus prone to disequilibrium. In this dissertation, I tested the degree to which North American trees are in equilibrium with their potential climatic ranges using the ‘range filling’ metric, which …

Three-Dimensional Bedrock Channel Evolution With Smoothed Particle Hydrodynamics, Nick Richmond

Electronic Theses and Dissertations

Bedrock channels are responsible for balancing and communicating tectonic and climatic signals across landscapes, but it is difficult and dangerous to observe and measure the flows responsible for removing weakly-attached blocks of bedrock from the channel boundary. Consequently, quantitative descriptions of the dynamics of bedrock removal are scarce. Detailed numerical simulation of violent flows in three dimensions has been historically challenging due to technological limitations, but advances in computational fluid dynamics aided by high-performance computing have made it practical to generate approximate solutions to the governing equations of fluid dynamics. From these numerical solutions we gain detailed knowledge of the …

The Effects Of Seasonal Variations In Chemistry And Hydrology On The Microbial Community And Its Sulfide Oxidation Potential In A Naturally Acidic Maine Stream, Raymond C. Kahler Iii

Electronic Theses and Dissertations

Sulfide minerals oxidize through interaction with water and oxygen, releasing hydrogen ions. The process often occurs naturally near metal sulfide deposits, and can be accelerated through mining. Microorganisms accelerate the rate of sulfide oxidation. Acidified streams typically contain high metal concentrations (e.g. aluminum) and microbes in these systems may develop resistances to metal toxicity. Stream flow can affect sulfide oxidation and microbial community structure. Baseflow can influence stream chemistry from interactions with the surrounding bedrock, while stormflow affects stream chemistry and the local microbial community through dilution and addition of microbes transported by runoff. Microbial community composition is affected by …

Modern And Paleoecological Perspectives On A Terrestrial-Marine Linkage In The Falkland Islands, Dulcinea V. Groff

Electronic Theses and Dissertations

The Falkland Islands are a biodiversity hotspot in the South Atlantic Ocean, with some of the world’s most important populations of seabirds and seals. The impact of climate change on these marine populations and their coastal breeding habitat in the Falklands is unknown. Coastal grasslands of Poa flabellata (tussac grass) form critical breeding habitat for wildlife, but have been heavily degraded by the introduction of livestock in the 17^th century. This dissertation investigates the impacts of global change (climate change, grazing) on P. flabellata and its sensitivity to the fecal nutrient subsidies provided by marine wildlife. Chapter 1 provides …

Retreat Of The Antarctic Ice Sheet In The Southern Ross Embayment From Records At Amundsen And Liv Glaciers, Southern Transantarctic Mountains, Jillian Pelto

Electronic Theses and Dissertations

The Antarctic Ice Sheet contains ~58 m of global sea-level equivalent and thus its future behavior under global warming is of pressing concern. Examination of past ice-sheet behavior during periods of warming climate can afford insight useful for predicting future sea-level rise. This study focuses on a major unanswered question - namely, the cause of Antarctic Ice Sheet retreat following the last glaciation. Documenting the timing and nature of this deglaciation is crucial to understand the mechanisms behind ice-sheet behavior. Here, I examine how the marine portions of the ice sheet responded to the major warming that occurred at the …

Nitrogen Cycling During A Period Of Environmental Change, Kaizad Patel

Electronic Theses and Dissertations

Natural and anthropogenic disturbances have altered the N cycle on the regional to global scale. Although numerous studies have examined the effects of chronic atmospheric N deposition on ecosystem processes, less is known about intra-annual variability of these processes, or how these responses might be altered under conditions of changing climate. The work described in this dissertation focuses on the effects of a changing chemical and physical climate, particularly terrestrial N processes (a) during Maine’s changing winters, and (b) in response to chronic elevated N additions.

Subnivean winter soil processes were examined at the Dwight B. DeMerritt Forest (DBDF) and …

Fault-Adjacent Damage At The Base Of The Seismogenic Zone And Seismic Anisotropy Of Fold Structures, Won Joon Song

Electronic Theses and Dissertations

While earthquakes represent a major hazard to life and property, there are a number of open questions about how earthquake faults operate at depth, and how the energy released by earthquakes travels as elastic waves through Earth’s complexly deformed crustal rocks. The aims of my dissertation are to explore (a) the extent of co-seismic damage in an ancient earthquake fault exhumed from great depths, (b) the deformation processes and mechanics of the fault at depth during earthquake cycles, and (c) the role of different rock structures in determining the velocities of seismic waves.

When tectonic plates collide, deformation tends to …

A Glacial History Of Roberts Massif, Central Transantarctic Mountains, Antarctica, Using Cosmogenic 3he, 10be, And 21ne Surface Exposure Ages, Alexandra M. Balter

Electronic Theses and Dissertations

Ice-free areas at high elevation in the central Transantarctic Mountains preserve moraines and drift deposits that delineate the former thickness and extent of the East Antarctic Ice Sheet (EAIS); cosmogenic exposure ages on these features indicate when the ice sheet was as or more extensive than today. Approximately 30 existing cosmogenic-nuclide exposure ages from scattered locations within these deposits suggest that some moraines and drift sheets are at least 5 Ma old. Those ages imply that the age range of these deposits may span warm periods during the Miocene and Pliocene, during which the EAIS is hypothesized to have been …

Developing A Risk Assessment Protocol To Quantify Distribution And Uptake Of Persistent Organic Pollutants In Glacial Outflows, Kimberley Rain Miner

Electronic Theses and Dissertations

Pollutants released by industrialized nations between 1960 and 2004 have been transported northward through atmospheric processes and deposited into glaciated alpine ecosystems. Many of these chemicals retain their original structure and are absorbed into the biota thousands of miles away from where they were originally utilized. With a warming climate increasing the melt of alpine glaciers, these glaciers may be introducing growing amounts of toxins into the watershed. While studies have demonstrated the existence of resident pollutants within glaciated ecosystems, no one has developed a risk assessment to identify sources and quantity of risk posed by these compounds when released …

Assessing The Reliability Of The Benthic Mg/Ca–Temperature Proxy: A Uvigerina Core-Top Study From New Zealand, Cassandre R. Stirpe

Electronic Theses and Dissertations

Sediment cores from New Zealand’s Bay of Plenty and the Chatham Rise in the Southwest Pacific were sampled to establish a regional Mg/Ca–temperature calibration for the benthic foraminifer Uvigerina peregrina. Comparison of foraminiferal Mg/Ca from core-top sediments to local bottom water temperatures reveals a Mg/Ca–temperature relationship broadly consistent with previously published calibrations. In addition to bottom water temperatures, other environmental parameters are examined for possible influence on the Mg/Ca of foraminiferal calcite. Elderfield et al. (2006) proposed that such parameters may exert an influence at colder temperatures, particularly below temperatures of ~3oC (e.g. Lear et al., 2002; Elderfield et al., …

Utilizing Ground-Penetrating Radar In The Delineation And Cultural Resource Management Of Eroding Maine Coastal Shell Middens, Jacquelynn F. Miller

Electronic Theses and Dissertations

Shell middens along the Maine coast archive up to 5000 years of cultural and climatic change, but the record is continually and rapidly lost to the sea through climate-driven coastal erosion and sea-level rise. These sites were constructed by the ancestors of Maine Tribes, and are composed of centimeters to meters of clam (Mya arenaria) and/or oyster (Crassostrea virginica) shells, other faunal remains, and cultural materials. Shell middens record human interaction with the environment and early coastal occupation and adaptation. The faunal remains reflect paleoenvironmental conditions and the distribution of extinct and extant forage-species along the western Gulf of Maine. …

Echoes Of The Past: The Effect Of Background Experience On Far Transfer, Graham H. Hummel-Hall

Electronic Theses and Dissertations

Far transfer is the application of knowledge learned in one setting to a problem in a very different setting. This multi-method study looked at far transfer in humans and whether it could be facilitated, inhibited, or remain unaffected by the number of courses or years a student at a university spent learning about the subject matter of the knowledge being transferred. Through quantitative and qualitative analysis of pretest and post-test data from an introductory undergraduate earth science course, I found that students with more physical science background experience more frequently engaged in successful and accurate transfer of physics information to …

Glacial History Of The Tsagaan Gol- Potanin Glacier Valley, Altai Mountains, Mongolia, Mariah J. Radue

Electronic Theses and Dissertations

The last glacial termination (~19-11 ka) marks the end of the last ice age and the transition to modern interglacial conditions. The mechanisms that triggered deglaciation are unresolved. Various hypotheses for deglacial warming involve changes in Earth’s orbit, an 80-ppm increase in atmospheric CO­₂, a ‘bipolar seesaw’ in oceanic-heat redistribution, and shifting wind belts. Here, I present a ¹⁰Be surface-exposure chronology for a system of glacial landforms in the Tsagaan Gol-Potanin Glacier valley in the Mongolian Altai (49°N, 88°E) to determine the nature of the termination in interior Asia. Located near the center of Earth’s largest continent, …