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Biogeochemical Controls On Fate Of Subsurface Oiled Sands On A Coastal Headland Beach, Autumn Anastasia Westrick
Biogeochemical Controls On Fate Of Subsurface Oiled Sands On A Coastal Headland Beach, Autumn Anastasia Westrick
LSU Master's Theses
The fate of subsurface oiled sands collected from Fourchon Beach in Louisiana were determined while modifying biogeochemical controls on the degradation of PAHs. Groundwater on the beach has intrinsically low dissolved oxygen concentrations, which may limit natural biodegradation of the crude oil components. The intent of this research was to characterize the biogeochemical properties and degradability of oiled sands (with >10% of pore filled with MC252 oil) using a combination of laboratory flow-through reactor studies, field measurements and time-series microelectrode profiles of down-flow and cross flow geometries. Reactor experiments indicate that optimal conditions for substantial oil degradation are aerobic under …
Biogeochemical Controls On Biodegradation Of Mc252 Crude Oil In Coastal Wetland Systems, Matthew Paul Rodrigue
Biogeochemical Controls On Biodegradation Of Mc252 Crude Oil In Coastal Wetland Systems, Matthew Paul Rodrigue
LSU Master's Theses
Weathering of MC252 oil from the Deepwater Horizon oil spill is taking place in coastal Louisiana marsh and mangrove wetland systems. Alkylated phenanthrenes and dibenzothiophenes, which are the most prominent PAHs found at MC252 contaminated sites, are weathering at rates up to 5% per year relative to alkylated chrysenes 3 years after initial oiling. Flux chambers at marsh locations trapped CO2 that exhibited δ13C signatures lower than indigenous organic matter signifying hydrocarbon mineralization to CO2. Weathering rates at each of these locations are heavily influenced by the biogeochemistry of the surrounding environment. High-resolution nutrient profiles were obtained at different locations …
Degradation And Inhibition Of Chlorinated Ethanes And Ethenes In A Two Bed, Sequential Bioremediation System, Alex Boudreau
Degradation And Inhibition Of Chlorinated Ethanes And Ethenes In A Two Bed, Sequential Bioremediation System, Alex Boudreau
LSU Master's Theses
A continuous-flow system composed of two anaerobic bioreactor (ABR) columns (based on engineered wetland systems) connected in series was tested to observe the ability of such a system to treat multiple volatile organic compounds (VOCs) possessing suspected inhibitory effects on the dechlorination of other compounds with cis-1,2-dichloroethylene (cDCE) and 1,1-dichloroethane (1,1-DCA) as the main test chemicals. Following the establishment of cDCE and 1,1-DCA dechlorinating ability at baseline conditions, system perturbations of breakthrough and starvation were conducted to measure the response and recovery of the system dechlorination. In all column experiments, it was observed cDCE dechlorination inhibited the dechlorination of 1,1-DCA …
Influence Of Temperature On The Performance Of Wetlands Treating Chlorinated Volatile Organic Compounds, Maria G. Murillo
Influence Of Temperature On The Performance Of Wetlands Treating Chlorinated Volatile Organic Compounds, Maria G. Murillo
LSU Master's Theses
Various studies have presented models to predict the performance of constructed wetlands at different temperatures focused on the removal of conventional pollutants, and common configuration of constructed wetlands. Investigations on the effect of temperature on the performance of constructed wetlands treating chlorinated volatile organic compounds are limited to microcosm studies. This study is meant to come up with kinetic and energy balance input data for mathematical models that can be used to predict the performance of upflow constructed treatment wetlands treating chlorinated ethenes and ethanes at different ambient temperatures. Bench scale continuous upflow columns will be conducted to investigate the …
Enhanced Bioremediation Of 1,1,2,2-Tetrachloroethane In Wetland Soils, Jason S. House
Enhanced Bioremediation Of 1,1,2,2-Tetrachloroethane In Wetland Soils, Jason S. House
LSU Master's Theses
This research investigated the capability of wetland soils to function as a medium for the degradation of 1,1,2,2-TeCA and its daughter products, and the influence of different hydrogen donors and nutrients on this process. The rate constants calculated for this study, show that removal of 1,1,2,2-TeCA is occurring in the microcosms receiving hydrogen donors as well as the biotic controls. The parent compound was undergoing complete degradation to ethene, which was confirmed by ethene analysis, as well as monitoring the intermediate compounds. The analysis for the degradation products of 1,1,2,2-tetrachloroethene is important in determining the overall potential for successful degradation …
Polyurethane Foam Based Packing Media For Biofilters Removing Volatile Organic Compounds From Contaminated Air, Felipe A. Martinez
Polyurethane Foam Based Packing Media For Biofilters Removing Volatile Organic Compounds From Contaminated Air, Felipe A. Martinez
LSU Master's Theses
In recent years, biofiltration technology has gained acceptance worldwide as an economical and reliable air pollution control technology for treating gases contaminated by low concentrations of biodegradable volatile organic compounds (VOCs). Important applications include control of odors generated by wastewater treatment plants and control of VOC emissions from industrial sources. Although there have been many successful applications, several operational problems have been reported in the literature. These include difficulty in control over bed moisture content, high head loss caused by excessive biomass production, and inability to maintain removal efficiency during transient periods of high concentration loading. Use of a superior …