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A Model Compound Study In Syngas Tar Reforming, Jaren Lee
A Model Compound Study In Syngas Tar Reforming, Jaren Lee
LSU Master's Theses
Biomass or coal gasification are promising processes for renewable energy. However, a major operating problem in gasification is what to do with syngas byproducts such as H2S and tars (heavy hydrocarbons) that cause catalyst deactivation downstream. Studies have shown that rare earth oxides (REOs) doped with transition metals are promising catalysts for tar reforming in the presence of sulfur.(R. Li, Roy, Bridges, & Dooley, 2014) In Chapter 1, propane is studied as a model compound for tar reforming with transition metal-doped (e.g., Mn, Fe) REOs. These are compared to a typical commercial Ni/Al2O3 catalyst. The results showed that REO/TM catalysts …
Novel Separation Strategy For Processing Biopyrolysis Liquids, Chuanlin Zhao
Novel Separation Strategy For Processing Biopyrolysis Liquids, Chuanlin Zhao
LSU Master's Theses
The separation of pyrolysis bio-oil is important for its role in upgrading oil quality and acquiring commercial byproducts. A selective separation method for biopyrolysis liquids is developed in this work. Two parts in succession are involved as the first one aims at selectively removing some of the heaviest fractions from bio-oil. Chromatographic adsorption results show that Class C Fly ash and pyrolysis Bio-char have potential for this goal at <300 ºC, byproduct like combined adsorbates / adsorbents could also be used directly in asphalt cement processes. Thereafter, the second part focuses on adsorbing light fractions like lighter acids and aldehydes selectively. Basic (modified) activated carbons display relatively low selectivity at ~250ºC, but they have better selectivity compared to unmodified activated carbons. Thus some carbon-coated mesoporous silica and alumina materials are also prepared for the adsorption of these light compounds in the future. The combination of the two parts of adsorptions would leave behind a middle distillate fraction which is the bio-oil fraction most amenable to catalytic upgrading, to either a fuel or chemical feedstock.