Digital Commons Network^™

Community-Scale Water Treatment Systems In The Dominican Republic, Jonathan Racey, Annabelle Papai, Elise Fischer, Becca Johnson

Engagement & Service-Learning Summit

Engagement and Service-Learning Summit: Reciprocal and Sustainable Partnerships

Controlled Nanomorphology Of Hybrid Organic/Inorganic Multi-Component Composites Through Cooperative Non-Covalent Interactions, Lingyao Meng

Shared Knowledge Conference

Hybrid organic–inorganic nanocomposite polymers, with inorganic nanoparticles embedded in organic matrix have emerged as a special category of multifunctional materials. With rational materials design, these hybrids can show the synergistic effect of the properties from both phases. Homogenous dispersion and orderly arrangement of the organic and inorganic components are key in their functionalities. By controlling the interface and corresponding interfacial interactions between the organic and inorganic entities, we have developed a logical approach to form stable and controlled hybrid nanofiber structures. We demonstrate the formation of hybrid polymer/quantum dots (or iron oxide nanoparticles) nanocomposites through non-covalent interactions (hydrogen bonding, ionic …

Scaling Relationships Across Chemically Related Adsorbates For Fast Screening Of Alloy Catalysts For Propane Dehydrogenation, Anne Esther Serban, Ranga Rohit Seemakurthi, Brandon C. Bukowski, Jeffrey Greeley

The Summer Undergraduate Research Fellowship (SURF) Symposium

A catalyst is a material which speeds up the rate of a specific reaction. A reaction that is of significant importance to the chemical industry is the selective transformations of light alkanes (ethane, propane), which are largely available in shale gas, to olefins. These olefins can then be converted into higher-value chemicals, materials, and fuels. However, there are several undesired reactions that take place alongside the main dehydrogenation reaction, so a catalyst of high selectivity is desired. Apart from the industrially used PtSn catalyst, work by our experimental collaborators has shown that various other Pt and Pd alloys (In, Zn) …

Computational Catalysis: Creating A User-Friendly Tool For Research And Education, Kevin P. Greenman, Peilin Liao

The Summer Undergraduate Research Fellowship (SURF) Symposium

Catalysis is used in a significant portion of production processes in the industrialized world, including most processing of chemicals and fuels. This makes maximizing the efficiency of catalysts a high priority. However, the immense number of candidates for new catalysts precludes the possibility of testing all of them by experiments. Density functional theory (DFT) has been widely and successfully used to calculate material properties relevant to catalysis and to screen promising candidates for experimental testing, but there currently exists no publicly- available, user-friendly tool for performing these DFT calculations. This work details the development of such a tool for nanoHUB.org …

Thermophotovoltaic Devices: Combustion Chamber Optimization And Modelling To Maximize Fuel Efficiency, Arnold Chris Toppo, Ernesto Marinero, Zhaxylyk Kudyshev

The Summer Undergraduate Research Fellowship (SURF) Symposium

Currently, 110 billion cubic meters of natural gas (primarily methane), a potent greenhouse gas, are flared off for environmental and safety reasons. This process results in enough fuel to provide the combined natural gas consumption of Germany and France. The research team developed a thermophotovoltaic device to convert thermal energy to electricity at a high efficiency using proprietary emitters and combustion system. With the current focus being fuel efficiency and the combustion process, the assembly was simulated using ANSYS Fluent modelling software and the following parameters were optimized: air/fuel ratios, flow rates, and inlet sizes. Simultaneously the heat transfer across …

Evaluation And Analysis Of Ethane Transformation To Liquid Hydrocarbons Through Steam Cracking, Christian Omar Villa Santos, Wasiu Peter Oladipupo, Taufik Ridha, Rakesh Agrawal

The Summer Undergraduate Research Fellowship (SURF) Symposium

Process design and sensitivity studies for a steam cracking reactor was performed. Steam cracking is commonly employed to convert ethane to ethylene, a building block of many other products. Although this technology is generally employed at large scale (>6 Billion pounds of ethylene per year), understanding the process and its economic performance is critical to set target criteria for other processes under development. Aspen Plus was used to simulate the ethane steam cracking reactor and other process units. Sensitivity analysis was performed to determine the most efficient and cost-effective operation regarding product yield. The results show that the maximum …

Electronic Effect Of Platinum Alloy Catalysts On Olefin Hydrogenation Kinetics, Colin Reedy, Jeff Miller, Stephen Purdy

The Summer Undergraduate Research Fellowship (SURF) Symposium

Dehydrogenation of alkanes is the first step in transforming light hydrocarbons into liquid fuels and chemicals. This process has traditionally used platinum alloys as catalysts. Alloys are used industrially because they have a greater selectivity than monometallic platinum. Alloying platinum with an inactive promoter modifies the crystalline structure of the surface (geometric effect), and the 5d electrons in platinum responsible for chemistry (electronic effect); both have been suggested to be primarily responsible for dehydrogenation selectivity in platinum alloys. Alloy catalysts have been synthesized using early 3d transition metal promoters with the same Pt₃M crystal structure. X-Ray Absorption Spectroscopy …

Developing Strategies To Toughen Bio-Inspired Adhesives, Narelli P. Narciso, Samuel Lee Huntington, Jonathan J. Wilker

The Summer Undergraduate Research Fellowship (SURF) Symposium

Mussels and other marine creatures adhere very well in underwater environments, having the ability to withstand the force of the sea. These animals have inspired synthetic biomimetic adhesives for wet systems, presenting potential for biomedical applications. However, most current commercial adhesives tend to be brittle, not resisting repetitive movements. This study assesses toughening strategies to improve the mussel-inspired adhesives’ ductility while maintaining its strength. The strategies included altering the polymer’s chemical structure by changing the percentage of polyethylene glycol (PEG) in the molecule and by adding fillers, such as calcium carbonate, silica and nacre - a calcium carbonate compound found …

Bringing Particle Scale Properties Into Descriptions Of Powder Behavior Through The Enhanced Centrifuge Method, Andrew R. Roginski, Caralyn A. Coultas-Mckenney, Contessa G. Norris, Stephen P. Beaudoin

The Summer Undergraduate Research Fellowship (SURF) Symposium

Inconsistent powder behavior introduces problems such as agglomeration, poor flowability, dust hazards, and segregation that decrease efficiency in powder processing environments. Understanding how a powder interacts with a surface at the particle scale provides insight into how to accommodate individual particle properties and avoid process deficiencies. This project uses an enhanced centrifuge technique to evaluate the adhesion between a stainless-steel surface and a powder comprised of fluorescent particles. Particles are deposited onto stainless steel plates which are rotated in a centrifuge. The adhesion properties are monitored by tracking the rotational speed at which particles of a known size are removed …

Targeted Epigenetic Editing Using Optogenetic Tools, Joshua Hahn, Chongli Yuan

The Summer Undergraduate Research Fellowship (SURF) Symposium

Epigenetics markers, such as DNA methylation and histone post-translational modifications, are modifications to the structure of DNA that impact gene expression without altering the genetic code. Among them, DNA methylation plays a critical role in various biological processes including the differentiation of stem cells, regulation of gene expression, and adaptation to environmental signals. The ability to modify DNA methylation at particular genes in various cell types is thus desirable for engineering specific cell phenotypes. Although technologies exist that can alter DNA methylation at target genes, these techniques lack spatial and temporal resolution and are not able to selectively edit individual …

Identification Of Proximal And Isolated Aluminum Heteroatoms In Zeolites By Infrared Spectroscopy, Melanie A. Brunet Torres, Philip Kester, Rajamani Gounder

The Summer Undergraduate Research Fellowship (SURF) Symposium

High demand for energy production and limited fossil fuel reserves are two factors that motivate intense research for new alternative energy resources. While we are still far from completely moving to renewable energy solutions, a new solution that replaces crude oil and coal with shale gas is currently under investigation. For this modern technology, new zeolite catalysts need to be developed for the conversion of light hydrocarbons gases to liquid transportation fuels. These catalysts are of special interest in the production of liquid fuels since they exhibit high reaction rates, molecular sieving properties and selectivity behavior. In this work, the …

Steady-State Method To Measure The In-Plane Thermal Conductivity Of Thin Sheet Materials, Evgeny Pakhomenko, Andrew James Wildridge, Abraham Mathew Koshy, Souvik Das, Andreas Jung

The Summer Undergraduate Research Fellowship (SURF) Symposium

A new generation of silicon pixel detectors is required to cope with the unprecedented luminosities at the high-luminosity phase of the Large Hadron Collider (HL-LHC) in 2025. The HL-LHC provides a high radiation, high interaction rate environment for the innermost detector region of the CMS detector. This can lead to an uncontrolled increase in temperature of the detector that can destroy the silicon pixels. Moreover, too high operating temperature can add noise to the data obtained from the detector and can slow the read out cheap down. Therefore, the Phase II upgrade to the Compact Muon Solenoid (CMS) experiment requires …

Image Analysis Of A Vesicle To Calculate The Bending Modulus, Pheobe Appel, Charlie Lin, Vivek Narsimhan

The Summer Undergraduate Research Fellowship (SURF) Symposium

The cell membrane is an essential component of living cells and the dynamics of the membrane will provide insight into how a biological cell reacts to mechanical strain. Membrane mechanics are important in a variety of cellular processes like secretion, trafficking, signaling, and storage. Giant unilamellar vesicles are a model system for cellular membranes since the major component of all membranes is a phospholipid bilayer. Giant unilamellar vesicles allow one to examine physicochemical processes that occur in all cellular membranes, such as fusion, budding, and fission in a more controlled fashion. Contour fluctuations of the vesicles are analyzed to calculate …

Investigation Of The Effects Of Solid-State Treatments On The Structure And Mobility Of Copper In Zeolites, Jiayang Wu, Laura Wilcox, Rajamani Gounder

The Summer Undergraduate Research Fellowship (SURF) Symposium

Zeolites are microporous, aluminosilicate catalysts that play an important role in industrial applications as well as studies for the fundamental understanding of catalysts for emerging reactions of interest. The introduction of aluminum into the zeolite lattice introduces a negative charge on the framework that can be balanced with extra-framework cations. The control of the aluminum distribution and the choice of charge balancing cations allows for the ability to tailor the active sites to facilitate a desired reaction. This research focuses on studying copper active sites in zeolites. Copper oxide was used as a copper precursor to introduce copper ions in …

Platinum-Gallium (Pt-Ga) Intermetallic Alloys For Propane Dehydrogenation, Brittany K. Roopnarine, Nicole J. Libretto, Johnny Zhuchen, Zhenwei Wu, Evan Wegener, Griffin Canning, Abhaya K. Datye, Jeffrey T. Miller

The Summer Undergraduate Research Fellowship (SURF) Symposium

Natural gas is a source of energy for the United States. The Center for Innovative Strategic Transformation of Alkane Resources (CISTAR) plans to use shale gas extracted from shale rock formations as a bridge fuel to replace coal and oil while the US transitions to renewable energy like solar and wind. After methane, the largest components in shale gas are light alkanes such as ethane and propane. These can be catalytically converted to olefins, which can be further reacted to produce fuels, for example. Olefins from alkanes can be accomplished by dehydrogenation by promoted platinum alloys. This study compares the …

Synthesis Of Double Network Hydrogels Which Can Be Shaped Freely, Natsuki Morimoto, Norie Kato

The International Student Science Fair 2018

Double network (DN) hydrogels have specific characters such as flexibility and high mechanical strength. They are expected to use biomaterials such as artificial cartilages and meniscuses. The purpose of this study is to synthesize DN gels which can be shaped freely. DN gels were synthesized by polyvinyl alcohol (PVA) as a mold, 2-acrylamide-2-methylpropane sulfonic acid (AMPS) as a first monomer, N,N’-methylene-bis-acrylamide (MBAA) as a crosslinker, 2-oxoglutalic acid (OGA) as an initiator and acrylamide (AAm) as a second monomer. First, PVA (polymerization degree; 2000) was dissolved in the water and prepared to 15 % of aqueous solution. It was poured in …

An Entirely New Molecular Glue For Mof Using Unusual Structural Transformation Of A Coordination Polymer, Sukwoo Jung, Hangyeol Kim, Junseok Ahn

The International Student Science Fair 2018

In this research, an entirely new molecular glue is reported. This ‘coordination polymer glue’ is synthesized from zinc metal and BDC-NPE(2,5-bis{4-[1-(4-nitrophenyl)ethylamino]butoxy}terephthalic acid). Molecular glue transforms from 1D coordination polymer to a 3D cross-linked framework, resulting in a phase change of solution to solid. The carboxylate group of this glue makes the preformed MOF bind to its framework. Therefore, when the solution of molecular glue is mixed with preformed MOF powder and heated, homogeneous and thin MOF film – MOF/ZnNPE film – is fabricated. The film is irrelevant to the kind of its substrate, and its thermal stability was enhanced in …

An Entirely New Molecular Glue For Mof Using Unusual Structural Transformation Of A Coordination Polymer, Sukwoo Jung, Hangyeol Kim, Junseok Ahn

The International Student Science Fair 2018

In this research, an entirely new molecular glue is reported. This ‘coordination polymer glue’ is synthesized from zinc metal and BDC-NPE(2,5-bis{4-[1-(4-nitrophenyl)ethylamino]butoxy}terephthalic acid). Molecular glue transforms from 1D coordination polymer to a 3D cross-linked framework, resulting in a phase change of solution to solid. The carboxylate group of this glue makes the preformed MOF bind to its framework. Therefore, when the solution of molecular glue is mixed with preformed MOF powder and heated, homogeneous and thin MOF film – MOF/ZnNPE film – is fabricated. The film is irrelevant to the kind of its substrate, and its thermal stability was enhanced in …

Chemotherapeutic Drug Cytotoxicity Measurement With A 3d Biomimetic Microfluidic Device And Computational Fluid Dynamics Model, Maryam Moarefian, Caroline Jones, Luke Achenie, Danesh Tafti

Biology and Medicine Through Mathematics Conference

No abstract provided.

Elucidating The Action Of A Regulatory Lipid Ligand Via Molecular Simulation: Cholesterol Swarms And The Inwardly Rectifying Potassium Channel, Belinda Akpa, Nicolas Barbera, Irena Levitan

Biology and Medicine Through Mathematics Conference

No abstract provided.

Modeling Pharmaceutical Inhibition Of Glucose-Stimulated Renin-Angiotensin System In Kidneys, Ashlee N. Ford Versypt, Minu R. Pilvankar, Hui Ling Yong

Biology and Medicine Through Mathematics Conference

No abstract provided.

Putting The Generic Solution Of Transparent Thinking Approach (Tta) In Instructional Material Production, Mohammad A. Aliedeh, Sajedah Aliedeh

ICOT 18 - International Conference on Thinking - Cultivating Mindsets for Global Citizens

Humanity is overburdened by an overwhelming challenges, problems and failures that are plaguing global development system, in general, and global educational system in specific. Transparent Thinking Approach (TTA) is developed in response to these multi scale and multi domain problems by offering a generic reform approach that enable the thinker to employ a multi perspective, maneuvering, and modeling tools while looking for a solution. TTA is a newly developed value-engrained and thinking based educational reform approach. It is generic and unique features enables it to easily diffuse in all domains (Aliedeh, M. A., 2015 a, b, c, 2016, …

Variable Temperature Thermochromic Switching Under Varying Illumination, Alexis Corbett, Danielle Hall, John E. Sinko

Huskies Showcase

Award for "Runner-Up Poster Presentation".

Abstract

Minnesota is home to some of the greatest temperature ranges in the United States, with lows reaching below -40º Celsius and highs reaching nearly 40ºC. This results in higher than average spending on the heating and cooling of buildings. We have been investigating into responsive building materials to help address this. In particular, we have been studying a thermochromic paint that can capture solar energy and transfer it into the building as heat at low temperatures and reflect the energy at higher temperatures to keep the building cooler.

Adsorption Of Dyes On New Synthesised Layered Double Hydroxide Materials, Intissar Harizi

Western Research Forum

No abstract provided.