Physical Sciences and Mathematics Commons^™

Using Fluid Inclusions To Trace Formative Fluid Evolution At The Verde And Pancho Porphyry Au Deposits Of The Refugio District, Chile, Brian Joshua Aillaud

UNLV Theses, Dissertations, Professional Papers, and Capstones

Evolution of magmatically-derived formative fluids, and the processes that control the ratio of ore metals in porphyry and high-sulfidation epithermal deposits remain enigmatic. The Refugio district in the Maricunga Belt of Northern Chile hosts the temporally and spatially related Pancho and Verde porphyry gold deposits. Vein types at Pancho include A-veins, transitional veins, banded veins, D-veins and quartz-alunite ledges that formed by replacement. Verde East and West lack A-veins, and show an earliest vein type with transitional characteristics of A- to banded veins, banded veins and D-veins. Fluid inclusions and quartz textures were characterized by using optical microscopy and cathodoluminesence …

Mobility Of Plutonium In Zea Mays (Corn): Determination Of Transport Velocities, Spatial Distribution And Correlations With Iron., Shannon Thompson

All Dissertations

Understanding the environmental behavior of plutonium (Pu) is essential for proper radioactive waste disposal or for remedial activities following an accidental release of Pu. The environmental behavior of Pu is influenced by physical, chemical, and biotic factors, such as the simultaneous existence of multiple Pu species, redox transformations at mineral surfaces, colloid formation, and the potential of microbes and plants to affect its sorption to soil. Plant Pu studies have been conducted for quantifying bioaccumulation or phytoremediation. Until now, experimental studies have not focused on the capacity of plants to affect the transport behavior and distribution of Pu in the …

Self-Assembly Of Architecturally Complex Block Copolymers, Juan Hinestrosa

All Dissertations

The term self-assembly denotes the formation of complex structures from simpler building blocks, resembling the manner in which Nature generates functional systems. In this pursuit, block copolymers present a great opportunity to study the interactions, dynamics and self-assembly of soft matter. Block copolymers have the ability to self-assemble into thermodynamically stable microphase segregated domains of precise shape and size, which are controlled by the chemistry of the constituent blocks, their size and connectivity, temperature and solvent conditions. Specifically, in this body of work two different types of branched copolymers with polystyrene (PS) and polyisoprene (PI) constituents are studied. The complex …

Examining The Behavioral Intentions Of Older Adults As Virtual Tourists In The Context Of A Second Life Destination, Dorinda Christian

All Dissertations

ABSTRACT
Tourism opportunities are being promoted heavily on the web, yet one of the largest and most lucrative markets, older adults are least likely to use the internet. In an effort to explore barriers to and potential acceptance of technology for tourism experiences, this study followed closely ten older adults through a learning process with technology. Qualitative methodology was used to explore in-depth the experience of these older adults being exposed to online virtual world technology for the first time and exploring the process by which technology acceptance takes place. The findings indicate that online virtual world such as Second …

Improved Accuracy For Fluid Flow Problems Via Enhanced Physics, Michael Case

All Dissertations

This thesis is an investigation of numerical methods for approximating solutions to fluid flow problems, specifically the Navier-Stokes equations (NSE) and magnetohydrodynamic equations (MHD), with an overriding theme of enforcing more physical behavior in discrete solutions. It is well documented that numerical methods with more physical accuracy exhibit better long-time behavior than comparable methods that enforce less physics in their solutions. This work develops, analyzes and tests finite element methods that better enforce mass conservation in discrete velocity solutions to the NSE and MHD, helicity conservation for NSE, cross-helicity conservation in MHD, and magnetic field incompressibility in MHD.

An Experimental Investigation Of Chemical Mass Transfer Processes In Crystallizing, Hydrous Silicate Magmas: The Genesis Of Ore Deposits And Metasomatic Fluids, Aaron S. Bell

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is comprised of three broadly related experimental petrology projects on phase equilibria and noble metal solubility in hydrous silicate melts. Chapters two and three combine experimental petrology with high precision laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis of experimental run products in order to quantitatively constrain the behavior of the investigated metals. Chapter four presents experimental evidence detailing a novel oxidation mechanism for degassing silicate liquids as well as exploring the geochemical consequences of the proposed mechanism.

Chapter two presents the results of an experimental study on Au, Pt, and Pd behavior in coexisting silicate melt-sulfide-oxide …

Phyllosilicate Mineralogy, 40ar/39ar Geochronology, And Genesis Of Petrocalcic Soils In The Southwest U.S.A., Colin R. Robins

UNLV Theses, Dissertations, Professional Papers, and Capstones

Obtaining isotope ages for arid soils and paleosols, including carbonate-cemented (calcic and petrocalcic) horizons, constitutes a significant challenge for soil scientists, geomorphologists, and stratigraphers. Carbonate-cemented soils foster diverse suites of authigenic minerals with exciting potential for geochronology, however, this potential has not been realized. This dissertation describes the timing of pedogenic palygorskite and sepiolite crystallization in extremely old, extant petrocalcic soils of the southwest U.S.A., and assumes that these fibrous, high-magnesium phyllosilicates contain sufficient lattice-bound K to warrant vacuum-encapsulated 40Ar/39Ar geochronology. This three-part study evaluated the (1) selective extraction, (2) 40Ar/39Ar analysis, and (3) pedogenesis of palygorskite and sepiolite.

Effects …

Filtration And Growth Rate Of Lake Mead Quagga Mussels (Dreissena Bugensis) In Laboratory Studies And Analyses Of Bioaccumulation, Carolyn Louise Link

UNLV Theses, Dissertations, Professional Papers, and Capstones

In January of 2007, Quagga Mussels (Dreissena bugensis) were identified in Lake Mead, Nevada. An aquatic invasive species, these mussels can significantly alter ecosystems. This study sought to quantify three ecological traits of the species through a series of laboratory experiments and analyses, providing information both for comparison with Dreissena in other locations, as well as for limnologic management decisions. Filtration rate of quagga mussels was quantified using algal strains and natural seston. Two strains of green algae, Nannochloris and Scenedesmus were used to determine mussel filtration rates with a spectrophotometer. Quagga filtration rates of collected Lake Mead seston were …

Quikscat Analysis Of Hurricane Force Extratropical Cyclones In The Pacific Ocean, Peter Jzyk

Senior Honors Projects

Since June 1999, NASA’s Quick Scatterometer Spacecraft (QuikSCAT) has been providing forecasters at the Ocean Prediction Center (OPC) with Near-Real-Time (N.R.T.) surface wind speed and direction data over the world’s oceans. QuikSCAT has allowed forecasters to better predict potential hazards such as storm surges and issue warnings when necessary. Over the past decade, QuikSCAT has received a number of upgrades which improved the forecasters’ abilities to predict the weather more accurately and issue warnings, accordingly. Improvements included the availability of the QuikSCAT data within the forecasters’ workstations starting in October 2001, the introduction of higher resolution satellite data in May …

All-Sky Search For Gravitational-Wave Bursts In The First Joint Ligo-Geo-Virgo Run, J. Abadie, Marco Cavaglia, For Full List Of Authors, See Publisher's Website.

Physics Faculty Research & Creative Works

We present results from an all-sky search for unmodeled gravitational-wave bursts in the data collected by the LIGO, GEO 600 and Virgo detectors between November 2006 and October 2007. The search is performed by three different analysis algorithms over the frequency band 50-6000 Hz. Data are analyzed for times with at least two of the four LIGO-Virgo detectors in coincident operation, with a total live time of 266 days. No events produced by the search algorithms survive the selection cuts. We set a frequentist upper limit on the rate of gravitational-wave bursts impinging on our network of detectors. When combined …

Late Spring And Summer Phytoplankton Community Dynamics On Georges Bank With Emphasis On Diatoms, Alexandrium Spp., And Other Dinoflagellates, Rachel Gettings

Electronic Theses and Dissertations

Georges Bank is a highly productive continental shelf system in the Northwest Atlantic that has historically supported a rich fishery. Part of that productivity stems from annual spring diatom bloom, which is followed by post-bloom populations of flagellates, including the toxic dinoflagellate Alexandrium spp., responsible for paralytic shellfish poisoning. While the general oceanography of Georges Bank has been well studied, far less is known about phytoplankton community dynamics or even basic species distributions and abundance. This thesis is driven in part by the possible competitive interactions among species of phytoplankton which are thought to influence Alexandrium blooms on the Bank. …

Investigating Two-Photon Double Ionization Of D₂ By Xuv-Pump-Xuv-Probe Experiments, Yuhai Jiang, Artem Rudenko, Jhon Fredy Perez-Torres, Oliver Herrwerth, Lutz M. Foucar, Moritz Kurka, Kai Uwe Kuhnel, M. Toppin, Etienne Plesiat, Felipe Morales, Fernando Javier Martin, Matthias Lezius, Matthias F. Kling, Till Jahnke, Reinhard Dorner, Jose Luis Sanz-Vicario, Jeroen Van Tilborg, Ali Belkacem, Michael Schulz, Kiyoshi Ueda, Stefan Dusterer, Rolf Treusch, Claus Dieter Schroter, Robert Moshammer, Joachim Hermann Ullrich

Physics Faculty Research & Creative Works

We used a split-mirror setup attached to a reaction microscope at the free-electron laser in Hamburg (FLASH) to perform an XUV-pump-XUV-probe experiment by tracing the ultrafast nuclear wave-packet motion in the D2 ⁺(1sσg) with <10 fs time resolution. Comparison with time-dependent calculations shows excellent agreement with the measured vibrational period of 22±4 fs in D2⁺, points to the importance of accurately knowing the internuclear distance-dependent ionization probability, and paves the way to control sequential and nonsequential two-photon double-ionization contributions.

The Sitac Approach For Time-Aware Query Translation In Text Archives, Amal Kaluarachchi

Theses, Dissertations and Culminating Projects

With an exponential growth in archival of time-stamped documents such as newswire articles, blog posts and other web-pages, information retrieval (IR) has become a challenging task. The degree of complexity in this IR task increases when these archives cover long time-spans and the terminology in them has undergone significant changes. When users pose queries pertaining to historical information over such document collections, the queries need to be translated, incorporating temporal changes, to provide accurate responses. For example, a query on Sri Lanka should automatically retrieve documents with its former name Ceylon. We call such concepts SITACs i.e., Semantically Identical Temporally …

Towards Finding Robust Execution Strategies For Rcpsp/Max With Durational Uncertainty, Na Fu, Pradeep Varakantham, Hoong Chuin Lau

Research Collection School Of Computing and Information Systems

Resource Constrained Project Scheduling Problems with minimum and maximum time lags (RCPSP/max) have been studied extensively in the literature. However, the more realistic RCPSP/max problems — ones where durations of activities are not known with certainty – have received scant interest and hence are the main focus of the paper. Towards addressing the significant computational complexity involved in tackling RCPSP/max with durational uncertainty, we employ a local search mechanism to generate robust schedules. In this regard, we make two key contributions: (a) Introducing and studying the key properties of a new decision rule to specify start times of activities with …

Highly Visible Light Active Tio2-Xnx Heterojunction Photocatalysts, Vinodkumar Etacheri, Michael Seery, Steven Hinder, Suresh Pillai

Articles

Nitrogen doped anatase-rutile heterojunctions are successfully synthesized through an ethylene-diaminetetraacetic acid (EDTA) modified sol-gel process.An FT-IR study of EDTA modified TiO2 gel confirms the existence of an ionic intermediate (as indicated by a Δν value of 233 cm-1).Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and Raman spectroscopy are employed to study the phase evolution, phase purity, and crystallite size of samples. Formations of O-Ti-N and N-Ti-N bonds in calcined samples are confirmed using XPS and FT-IR spectro- scopy. AllEDTAmodified samples show significantly higher visible light photocatalytic activity than the unmodified sample. The most active nitrogen doped heterojunction obtained at 400C …

Self-Assembly And Gold Nanoparticle Cross-Linking Of Stimuliresponsive Block Copolymers Synthesized Bt Reversible Addition-Fragmentation Chain Transfer Polymerization, Adam Eugene Smith

Dissertations

The ability of amphiphilic block copolymers to self-assemble into various morphologies in aqueous solution in response to specific stimuli has attracted widespread interest for potential applications as targeted drug delivery and diagnostic vehicles. Stimuli-responsive block copolymers afford a facile method for tuning the hydrophilic mass fraction to provide access to various solution morphologies. Reversible additionfragmentation chain transfer (RAFT) polymerization provides the ability to prepare stimuli-responsive block copolymers while maintaining precise control over the macromolecular characteristics (molecular weight, copolymer composition, functionality, etc.) that dictate nanostructure morphology.

This work may be divided into four sections. In the first section the synthesis and …

Synthesis Of Functional Copolymers Via Aqueous Raft Polymerization For Bioconjugation And Targeted Delivery Of Small Interfering Rna, Adam Wesley York

Dissertations

The versatility of reversible addition-fragmentation chain transfer (RAFT) polymerization has moved this controlled radical technique to the forefront of copolymer construction for bioapplications including polymeric drug/gene delivery vehicles. Strengths of the RAFT process include the capacity to control the polymerization of a wide variety of vinyl monomers under mild conditions, its tolerance to numerous chemical groups that allow the preparation of functional copolymers for facile modification, and the range of copolymer architectures with predetermined end group functionalities which may be synthesized. Given these strengths, RAFT polymerization was utilized in this research to synthesize functional/reactive copolymers for bioconjugation and targeted delivery …

Assessing The Impact Of A Computer-Based College Algebra Course, Ningjun Ye

Dissertations

USM piloted the Math Zone in Spring 2007, a computer-based program in teaching MAT 101and MAT 099 in order to improve student performance. This research determined the effect of the re-design of MAT 101 on student achievements in comparison to a traditional approach to the same course. Meanwhile, the study investigated possible effects of the Math Zone program on students’ attitude toward studying mathematics.

This study shows that there was no statistically significant difference on MAT101 final exam scores between the Math Zone students and the Classroom students in Fall 2007, Spring 2008 and Fall 2008. At the same time, …

Polyisobutylene Chain End Transformations: Block Copolymer Synthesis And Click Chemistry Functionalizations, Andrew Jackson David Magenau

Dissertations

The primary objectives of this research were twofold: (1) development of synthetic procedures for combining quasiliving carbocationic polymerization (QLCCP) of isobutylene (IB) and reversible addition fragmentation chain transfer (RAFT) polymerization for block copolymer synthesis; (2) utilization of efficient, robust, and modular chemistries for facile functionalization of polyisobutylene (PIB). Two site transformation strategies were employed to create block copolymers effectively linking PIB with either poly(methylmethacrylate) (PMMA), polystyrene (PS), and poly(Nisopropylacrylamide) (PNIPAM) block segments. Functionalization of PIB was accomplished by utilizing two click chemistries, the azide-alkyne 1,3-dipolar cyclo addition and the thiol-ene hydrothiolation reaction, and by efficient transformation of the thiol functional …

Towards Multiplexed Electrogenerated Chemiluminescent Detection, Shijun Wang

Dissertations

The main objective of this dissertation is to understand and study the principle of electrogenerated chemiluminescence (ECL) and its applications to detect biomolecules simultaneously. Four aspects of ECL were studied. In order to carry out multiplexed ECL detection, both classical and several novel ECL systems have been investigated.

In the first aspect, significant effect of chloride ions on the ECL behavior of the tris(2,2′-bipyridyl) ruthenium(II) (Ru(bpy)3 2+)/tri-n-propylamine (TPrA) system at Au electrode was investigated. At low concentrations (e.g., [Cl-] < 5 mM), the ECL was enhanced; at relatively high concentrations, however, the ECL intensity decreased with the increase of the [Cl-]. At [Cl-] = 90 mM, ~ 50% and 100% ECL inhibition was observed for the first and the second ECL wave, respectively. The electrogenerated chloroaurate anions (AuCl2 - and AuCl4 -) which were verified using an electrochemical quartz-crystal microbalance (EQCM) method were found to be responsible for the ECL inhibition. This study suggests that care must be taken when Au working electrode is used for ECL studies in chloride-containing buffer solutions (widely used in DNA probes) and/or with the commonly used chloride-containing reference electrodes since in these cases the ECL behavior may significantly disagree with that obtained using other electrodes and reaction media.

In the second aspect, the electrochemical behavior of a trinuclear ruthenium(II)- containing complex, [((phen)2Ru(dpp))2RhCl2]5+ (where phen = 1,10-phenanthroline, dpp = 2,3-bis-2-pyridylpyrazine), …