Physical Sciences and Mathematics Commons^™

The Synthesis, Characterization, And Upconverting Properties Of Erbium Doped; Ytterbium, Erbium Co-Doped Yttrium Oxysulfide Phosphors Under 808, 980, And 1560 Nm Excitation, James Wilkins

Theses and Dissertations

Bulk yttrium oxysulfide phosphors were prepared using the polysulfide flux method. The morphology and structure was characterized using transmission electron microscopy and x-ray powdered diffraction. Visible emissions occurring near 530 and 550 nm and 660 - 670 nm consistent with the 2H11/2, 4S3/2 → 4I15/2 and 4F9/2 → 4I15/2 transitions, respectively, were observed under 808, 980, and 1560 nm excitation. The upconverting mechanisms excited at 808, 980, and 1560 nm have been investigated in detail. The power dependent behavior of the upconverted emission intensities for singly doped erbium phosphors excited at 808 and 980 nm indicated a two-photon excitation process. …

Fabrication And Catalytic Property Of Cerium Oxide Nanomaterials, Keren Jiang

Student Research Projects, Dissertations, and Theses - Chemistry Department

Cerium oxide, or ceria (CeO_x: x = 1.5 to 2), has been widely used as a heterogeneous catalyst. Ceria has several properties make it high catalytic active: the fluctuating valence of cerium, the high oxygen storage capacity and high oxygen mobility in the nonstoichiometric ceria. With the high abundance of cerium on earth crust, ceria is a highly effective alternative of the noble metal catalysts. Research has been focused on designing nanostructured ceria and ceria related materials in recent years. The catalytic activity of ceria can be enhanced by the nanoscale effect which can be applied for various …

Generalized Derivations On Lie Ideals In Prime Rings, Öznur Gölbaşi, Emi̇ne Koç

Turkish Journal of Mathematics

Let R be a prime ring with characteristic different from two, U a nonzero Lie ideal of R and f be a generalized derivation associated with d. We prove the following results: (i) If [u,f(u)] \in Z, for all u \in U, then U \subset Z. (ii) (f,d) and (g,h) be two generalized derivations of R such that f(u)v=ug(v), for all u,v \in U, then U \subset Z. (iii) f([u,v])=\pm \lbrack u,v], for all u,v\in U, then U \subset Z.

Historical Perspectives On Resource Use In Food Systems, John Jemison, Amanda Beal

Maine Policy Review

No one would deny that industrial agriculture and fishing have been highly productive—but at what cost? This article explores the historical development and contemporary impact of food production on the environment, availability of water and other resources, energy, food safety, and even our waistlines

Acceleration Techniques By Post-Processing Of Numerical Solutions Of The Hammerstein Equation, Khomsan Neamprem, Hideaki Kaneko

Mathematics & Statistics Faculty Publications

No abstract provided.

Uniform L1 Behavior Of A Time Discretization Method For A Volterra Integrodifferential Equation With Convex Kernel; Stability, Charles B. Harris, Richard D. Noren

Mathematics & Statistics Faculty Publications

We study stability of a numerical method in which the backward Euler method is combined with order one convolution quadrature for approximating the integral term of the linear Volterra integrodifferential equation u'(t) + ∫0 β (t - s)Au(s) ds = 0, t ≥ 0, u(0) = u0, which arises in the theory of linear viscoelasticity. Here A is a positive self-adjoint densely defined linear operator in a real Hilbert space, and β (t) is locally integrable, nonnegative, nonincreasing, convex, and -β'(t) is convex. We establish stability of the method under these hypotheses on β(t). Thus, …

Mesoscopic Methods In Engineering And Science, Chuguang Zheng, Jiding Lu, Zhaoli Guo, Li-Shi Luo, Manfred Krafczyk

Mathematics & Statistics Faculty Publications

Matter, conceptually classified into fluids and solids, can be completely described by the microscopic physics of its constituent atoms or molecules. However, for most engineering applications a macroscopic or continuum description has usually been sufficient, because of the large disparity between the spatial and temporal scales relevant to these applications and the scales of the underlying molecular dynamics. In this case, the microscopic physics merely determines material properties such as the viscosity of a fluid or the elastic constants of a solid. These material properties cannot be derived within the macroscopic framework, but the qualitative nature of the macroscopic dynamics …

Weighted Scores Method For Regression Models With Dependent Data, Aristidis K. Nikoloulopoulos, Harry Joe, N. Rao Chaganty

Mathematics & Statistics Faculty Publications

There are copula-based statistical models in the literature for regression with dependent data such as clustered and longitudinal overdispersed counts, for which parameter estimation and inference are straightforward. For situations where the main interest is in the regression and other univariate parameters and not the dependence, we propose a "weighted scores method", which is based on weighting score functions of the univariate margins. The weight matrices are obtained initially fitting a discretized multivariate normal distribution, which admits a wide range of dependence. The general methodology is applied to negative binomial regression models. Asymptotic and small-sample efficiency calculations show that our …

Analysis Of Biological Features Associated With Meiotic Recombination Hot And Cold Spots In Saccharomyces Cerevisiae, Loren Hansen, Nak-Kyeong Kim, Leonardo Mariño-Ramírez, David Landsman

Mathematics & Statistics Faculty Publications

Meiotic recombination is not distributed uniformly throughout the genome. There are regions of high and low recombination rates called hot and cold spots, respectively. The recombination rate parallels the frequency of DNA double-strand breaks (DSBs) that initiate meiotic recombination. The aim is to identify biological features associated with DSB frequency. We constructed vectors representing various chromatin and sequence-based features for 1179 DSB hot spots and 1028 DSB cold spots. Using a feature selection approach, we have identified five features that distinguish hot from cold spots in Saccharomyces cerevisiae with high accuracy, namely the histone marks H3K4me3, H3K14ac, H3K36me3, and H3K79me3; …

Speciation, Luminescence, And Alkaline Fluorescence Quenching Of 4-(2-Methylbutyl)Aminodipicolinic Acid (H2mebadpa), Gilles Muller, A. J. Ingram, A. G. Dunpal, R. Dipietro

Faculty Publications, Chemistry

4-(2-Methylbutyl)aminodipicolinic acid (H2MEBADPA) has been synthesized and fully characterized in terms of aqueous phase protonation constants (pKa's) and photophysical measurements. The pKa's were determined by spectrophotometric titrations, utilizing a fully sealed titration system. Photophysical measurements consisted of room temperature fluorescence and frozen solution phosphorescence as well as quantum yield determinations at various pH, which showed that only fully deprotonated MEBADPA2– is appreciably emissive. The fluorescence of MEBADPA2– has been determined to be quenched by hydroxide and methoxide anions, most likely through base-catalyzed excited-state tautomerism or proton transfer. This quenching phenomenon has been quantitatively explored through steady-state and time-resolved fluorescence measurements. …

Wide-Field Precision Kinematics Of The M87 Globular Cluster System, J. Strader, Aaron J. Romanowsky, J. P. Brodie, L. R. Spitler, M. A. Beasley, Jacob A. Arnold, N. Tamura, R. M. Sharples, N. Arimoto

Faculty Publications

We present the most extensive combined photometric and spectroscopic study to date of the enormous globular cluster (GC) system around M87, the central giant elliptical galaxy in the nearby Virgo Cluster. Using observations from DEIMOS and the Low Resolution Imaging Spectrometer at Keck, and Hectospec on the Multiple Mirror Telescope, we derive new, precise radial velocities for 451 GCs around M87, with projected radii from ~5 to 185 kpc. We combine these measurements with literature data for a total sample of 737 objects, which we use for a re-examination of the kinematics of the GC system of M87. The velocities …

Global Properties Of ‘Ordinary’ Early-Type Galaxies: Photometry And Spectroscopy Of Stars And Globular Clusters In Ngc 4494, C. Foster, L. R. Spitler, Aaron J. Romanowsky, D. A. Forbes, V. Pota, K. Bekki, J. Strader, R. N. Proctor, J. A. Arnold, J. P. Brodie

Faculty Publications

We present a comprehensive analysis of the spatial, kinematic and chemical properties of stars and globular clusters (GCs) in the ‘ordinary’ elliptical galaxy NGC 4494 using data from the Keck and Subaru telescopes. We derive galaxy surface brightness and colour profiles out to large galactocentric radii. We compare the latter to metallicities derived using the near-infrared Calcium Triplet. We obtain stellar kinematics out to ∼3.5 effective radii. The latter appear flattened or elongated beyond ∼1.8 effective radii in contrast to the relatively round photometric isophotes. In fact, NGC 4494 may be a flattened galaxy, possibly even an S0, seen at …

Evidence For Two Phases Of Galaxy Formation From Radial Trends In The Globular Cluster System Of Ngc 1407, D. A. Forbes, L. R. Spitler, J. Strader, Aaron J. Romanowsky, J. P. Brodie, C. Foster

Faculty Publications

Here we present the colours of individual globular clusters (GCs) around the massive elliptical galaxy NGC 1407 out to a projected galactocentric radius of 140 kpc or 17 galaxy effective radii (Re). Such data are a proxy for the halo metallicity. We find steep, and similar, metallicity gradients of ∼−0.4 dex dex−1 for both the blue (metal poor) and red (metal rich) GC subpopulations within 5–8.5 Re (40–70 kpc). At larger radii the mean GC colours (metallicity) are constant. A similar behaviour is seen in a wide-field study of M87's GC system, and in our own Galaxy. We interpret these …

Stellar Mass-To-Light Ratio Gradients In Galaxies: Correlations With Mass, C. Tortora, N. R. Napolitano, Aaron J. Romanowsky, Ph. Jetzer, V. F. Cardone, M. Capaccioli

Faculty Publications

We analyse the stellar mass-to-light ratio (M/L) gradients in a large sample of local galaxies taken from the Sloan Digital Sky Survey, spanning a wide range of stellar masses and morphological types. As suggested by the well-known relationship between M/L values and colours, we show that M/L gradients are strongly correlated with colour gradients, which we trace to the effects of age variations. Stellar M/L gradients generally follow patterns of variation with stellar mass and galaxy type that were previously found for colour and metallicity gradients. In late-type galaxies M/L gradients are negative, steepening with increasing mass. In early-type galaxies …

Galaxies In Cdm With Halo Abundance Matching: Luminosity-Velocity Relation, Baryonic Mass-Velocity Relation, Velocity Function, And Clustering, S. Trujillo-Gomez, A. Klypin, J. Primack, Aaron J. Romanowsky

Faculty Publications

It has long been regarded as difficult if not impossible for a cosmological model to account simultaneously for the galaxy luminosity, mass, and velocity distributions. We revisit this issue using a modern compilation of observational data along with the best available large-scale cosmological simulation of dark matter (DM). We find that the standard cosmological model, used in conjunction with halo abundance matching (HAM) and simple dynamical corrections, fits—at least on average—all basic statistics of galaxies with circular velocities V circ > 80 km s–1 calculated at a radius of ~10 kpc. Our primary observational constraint is the luminosity-velocity (LV) relation—which generalizes …

Numerics Of The Lattice Boltzmann Method: Effects Of Collision Models On The Lattice Boltzmann Simulations, Li-Shi Luo, Wei Liao, Xingwang Chen, Yan Peng, Wei Zhang

Mathematics & Statistics Faculty Publications

We conduct a comparative study to evaluate several lattice Boltzmann (LB) models for solving the near incompressible Navier-Stokes equations, including the lattice Boltzmann equation with the multiple-relaxation-time (MRT), the two-relaxation-time (TRT), the single-relaxation-time (SRT) collision models, and the entropic lattice Boltzmann equation (ELBE). The lid-driven square cavity flow in two dimensions is used as a benchmark test. Our results demonstrate that the ELBE does not improve the numerical stability of the SRT or the lattice Bhatnagar-Gross-Krook (LBGK) model. Our results also show that the MRT and TRT LB models are superior to the ELBE and LBGK models in terms of …

Population Structure Of Melon-Headed Whales (Peponocephala Electra) In The Hawaiian Archipelago: Evidence Of Multiple Populations Based On Photo Identification, Jessica M. Aschettino, Robin W. Baird, Daniel J. Mcsweeney, Daniel L. Webster, Gregory S. Schorr, Jessica L. Huggins, Karen K. Martin, Sabre D. Mahaffy, Kristi L. West

Publications, Agencies and Staff of the U.S. Department of Commerce

Despite the presence of melon-headed whales in tropical and subtropical waters worldwide, little is known about this species. To assess population structure in Hawai‘i, dedicated field efforts were undertaken from 2000 to 2009. Using only good quality photographs, there were 1,433 unique photo-identified individuals, of which 1,046 were distinctive. Of these, 31.5% were seen more than once. Resighting data combined with social network analyses showed evidence of two populations—a smaller, resident population, seen exclusively off the northwest region of the island of Hawai‘i, and a larger population, seen throughout all the main Hawaiian Islands (hereafter the “main Hawaiian Islands” population). …

Small-Scale Fisheries Of Peru: A Major Sink For Marine Turtles In The Pacific, Joanna Alfaro-Shigueto, Jeffrey C. Mangel, Francisco Bernedo, Peter H. Dutton, Jeffrey A. Seminoff, Brendan J. Godley

Publications, Agencies and Staff of the U.S. Department of Commerce

1. Over the last few decades, evidence of marine vertebrate bycatch has been collected for a range of industrial fisheries. It has recently been acknowledged that large impacts may also result from similar interactions with small-scale fisheries (SSF) due largely to their diffuse effort and large number of vessels in operation. Marine mammals, seabirds, turtles as well as some shark species have been reported as being impacted by SSF worldwide.

2. From 2000 to 2007, we used both shore-based and onboard observer programmes from three SSF ports in Peru to assess the impact on marine turtles of small-scale longline, bottom …

Humpback Whale Abundance In The North Pacific Estimated By Photographic Capture-Recapture With Bias Correction From Simulation Studies, Jay Barlow, John Calambokidis, Erin A. Falcone, C. Scott Baker, Alexander M. Burdin, Phillip J. Clapham, John K. B. Ford, Christine M. Gabriele, Richard Leduc, David K. Mattila, Terrance J. Quinn Ii, Lorenzo Rojas-Bracho, Janice M. Straley, Barbara L. Taylor, Jorge Urbán R., Paul Wade, David Weller, Briana H. Witteveen, Manami Yamaguchi

Publications, Agencies and Staff of the U.S. Department of Commerce

We estimated the abundance of humpback whales in the North Pacific by capture recapture methods using over 18,000 fluke identification photographs collected in 2004–2006. Our best estimate of abundance was 21,808 (CV=0.04). We estimated the biases in this value using a simulation model. Births and deaths, which violate the assumption of a closed population, resulted in a bias of +5.2%, exclusion of calves in samples resulted in a bias of−10.5%, failure to achieve random geographic sampling resulted in a bias of −0.4%, and missed matches resulted in a bias of +9.3%. Known sex-biased sampling favoring males in breeding areas did …

Multidecadal Otolith Growth Histories For Red And Gray Snapper (Lutjanus Spp.) In The Northern Gulf Of Mexico, Usa, Bryan A. Black, Robert J. Allman, Isaac D. Schroeder, Michael J. Schirripa

Publications, Agencies and Staff of the U.S. Department of Commerce

Dendrochronology (tree-ring analysis) techniques were applied to develop chronologies from the annual growth-increment widths of red snapper (Lutjanus campechanus) and gray snapper (Lutjanus griseus) otoliths sampled from the northern Gulf of Mexico, USA. Growth increment widths showed considerable synchrony within and across species, indicating that some component of environmental variability influenced growth. The final, exactly dated red snapper chronology continuously spanned 1975 through 2003, while the gray snapper chronology continuously spanned 1975 through 2006. To determine baseline climategrowth relationships, chronologies were compared to monthly averages of sea surface temperatures, U winds (west to east), V winds …