Atmospheric Sciences Commons^™

Snow Chemistry Across Antarctica, Nancy Bertler, Paul Andrew Mayewski, Alberto Aristarain, P. Barrett, S. Becagli, Ronaldo Torma Bernardo, Xiao Cunde, M. Curran, Qin Dahe, Daniel Dixon, Francisco Adolfo Ferron, H. Fischer, Markus Frey, M. Frezzotti, F. Fundel, Christophe Genthon, R. Gragani, Gordon Hamilton, M. Handley, Sungmin Hong, E. Isaksson, Ren Jiawen, Kokichi Kamiyama, Satoru Kanamori, Eija Karkas, L. Karlöf, S. Kaspari, K. Kreutz, A. Kurbatov, E. Meyerson, Hideaki Motoyama, R. Mulvaney, Zhang Mingjun, H. Oerter, E. Osterberg, M. Proposito, A. Pyne, U. Ruth, Jefferson Cardia Simoes, B. Smith, S. Sneed, Kimmo Teinila, F. Traufetter, R. Udisti, Aki Virkkula, Okitsugu Watanabe, B. Williamson, E. Wolff, Li Zhongqin

Earth Science Faculty Scholarship

An updated compilation of published and new data of major-ion (Ca, Cl, K, Mg, Na, NO₃, SO₄) and methylsulfonate (MS) concentrations in snow from 520 Antarctic sites is provided by the national ITASE (International Trans-Antarctic Scientific Expedition) programmes of Australia, Brazil, China, Germany, Italy, Japan, Korea, New Zealand, Norway, the United Kingdom, the United States and the national Antarctic programme of Finland. The comparison shows that snow chemistry concentrations vary by up to four orders of magnitude across Antarctica and exhibit distinct geographical patterns. The Antarctic-wide comparison of glaciochemical records provides a unique opportunity to improve …

Variability In Accumulation Rates From Gpr Profiling On The West Antarctic Plateau, Vandy B. Spikes, Gordon S. Hamilton, Steven A. Arcone, Susan Kaspari, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Isochronal layers in firn detected with ground-penetrating radar (GPR) and dated using results from ice-core analyses are used to calculate accumulation rates along a 100 km across-flow profile in West Antarctica. Accumulation rates are shown to be highly variable over short distances. Elevation measurements from global positioning system surveys show that accumulation rates derived from shallow horizons correlate well with surface undulations, which implies that wind redistribution of snow is the leading cause of this variability. Temporal changes in accumulation rate over 25-185 year intervals are smoothed to along-track length scales comparable to surface undulations in order to identify trends …

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …

Chemical Composition Of Fresh Snow On Xixabangma Peak, Central Himalaya, During The Summer Monsoon Season, Shichang Kang, Dahe Qin, Paul Andrew Mayewski, Sharon B. Sneed

Earth Science Faculty Scholarship

The physical and chemical analysis of ice cores recovered from glaciers in the Himalaya provide some of the best records of past climate change in the region (e.g. Qin and others, 2000; Thompson and others, 2000; Kang and others, 2001, 2002). In order to better understand the climatic and environmental records preserved in snow and ice, studies have investigated the precipitation chemistry in the high Himalaya, notably that the northern slopes of the central Himalaya (Mayewski and others, 1986; Jenkins and others 1987) and the southern slopes of the central Himalaya (Shrestha and others, 1997; Marinoni and others, 2001).

High-Precision Dating Of Volcanic Events (A.D. 1301–1995) Using Ice Cores From Law Dome, Antarctica, Anne S. Palmer, Tas D. Van Ommen, Mark A. J. Curran, Vin Morgan, Joe M. Souney, Paul Andrew Mayewski

Earth Science Faculty Scholarship

A record of volcanic activity over the period A.D. 1301–1995 has been extracted from three Law Dome ice cores (East Antarctica). The record dating is unambiguous at the annual level from A.D. 1807 to 1995 and has an uncertainty of ±1 year at A.D. 1301. Signals from 20 eruptions are preserved in the record, including those of two unknown eruptions with acid deposition beginning in A.D. 1810.8 and A.D. 1685.8. The beginning of the ice core signal from the A.D. 1815 Tambora eruption is observed in the austral summer of A.D. 1816/1817. The mean observed stratospheric transport and deposition time …

Monsoon And Dust Signals Recorded In Dasuopu Glacier, Tibetan Plateau, Kang Shichang, Cameron P. Wake, Qin Dahe, Paul Andrew Mayewski, Yao Tandong

Earth Science Faculty Scholarship

During summer 1997, a 15m firn core was recovered from Dasuopu glacier (28°23'N, 85° 44' E; 7000 m a.s.l.) on the northwest margin of Xixabangma Feng in the central Himalaya. Oxygen isotope values and concentrations of Ca²⁺, Mg²⁺, NH₄⁺, SO₄^2- and NO₃^- were measured over the 10 years of snow accumulation captured in the firn core. The seasonal variations of δ¹⁸O values and major-ion concentrations in the Dasuopu core indicated that summer monsoon and dust signals are clearly recorded in Dasuopu glacier. Annual variations in the δ …

Antarctic's Role Pursued In Global Climate Change, Paul Andrew Mayewski, I. Goodwin

Earth Science Faculty Scholarship

The impact of Antarctica on global climate change and the impact of global climate change on Antarctica are the focal points of a current series of expeditions there, and an international, interdisciplinary array of researchers met this past spring to go over the expeditions' progress. Advances were reported in describing the impact of the seasonal cycle, semiannual oscillation, and the El Niño-Southern Oscillation (ENSO) cycle on Antarctic accumulation in recent decades.

Difficulties still remain, however, in explaining fully the history and forcing of the Antarctic climate and the links between tropical forcing and high-latitude response. The difficulties arise largely because …

Spatial Variability Of Climate And Past Atmospheric Circulation Patterns From Central West Antarctic Glaciochemistry, David B. Reusch, Paul Andrew Mayewski, Sallie I. Whitlow, Iqbal I. Pittalawa, Mark S. Twickler

Earth Science Faculty Scholarship

Atmospheric circulation patterns and the spatial variability of atmospheric chemistry and moisture transport in central West Antarctica are investigated using new 40 year long (1954–1994 A.D.) glaciochemical and accumulation rate records developed from four firn cores from this region. The core sites lie on a 200 km traverse from 82° 22′ S, 119° 17′ W to 81° 22′ S, 107° 17′ W. The glaciochemical records represent the major ionic species present in Antarctic snow: Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃⁻, and SO₄²⁻. High spatial …

Climatological Significance Of Δ18O In Precipitation And Ice Cores: A Case Study At The Head Of The Ürütnqi River, Tien Shan, China, Hou Shugui, Qin Dahe, Paul Andrew Mayewski, Yang Qinzhao, Ren Jiawen, Li Zhongqin, Xiao Cunde

Earth Science Faculty Scholarship

Stable-oxygen-isotope ratios (δ¹⁸O) collected from the headwaters of the Ürümqi river, Tien Shan, China, were used to test the relationship between δ¹⁸O temporal relationship is found between δ¹⁸O monthly averages which remove synoptic-scale influences such as changes in condensation level, condensation temperature and moisture sources (Yao and others, 1996). Linear fits as high as 0.95‰°C^-1 for precipitation events and 1.23‰°C^-1 for monthly averages are found. Although the δ¹⁸O (∼2 km from the precipitation sampling site) decreased dramatically compared to the precipitation samples , the ice-core records of annually averaged δ …

Soluble Species In Aerosol And Snow And Their Relationship At Glacier 1, Tien Shan, China, Junying Sun, Dahe Qin, Paul Andrew Mayewski, Jack E. Dibb, Sallie Whitlow, Zhongqin Li, Qinzhao Yang

Earth Science Faculty Scholarship

Simultaneous sampling of aerosol (n = 20) and snow (n = 114) was made at Glacier 1, Tien Shan, between May 19 and June 29, 1996. Similar temporal patterns of some major ion (calcium, magnesium, potassium, sodium, chloride, and sulfate) concentrations between snow and aerosol show that snow chemistry basically reflects changes in the chemistry of the atmosphere. This gives us confidence in the reconstruction of past atmospheric change using some snow data. There are no significant correlations between aerosol and snow samples for ammonium and nitrate. This suggests that postdepositional and/or postcollection processes may alter ammonium and …

Limited Migration Of Soluble Ionic Species In A Siple Dome, Antarctica, Ice Core, Karl J. Kreutz, Paul Andrew Mayewski, Sallie I. Whitlow, Mark S. Twickler

Earth Science Faculty Scholarship

High-resolution (>10 samples a ^-1) glaciochemical analyses covering the last 110 years from a Siple Dome, Antarctica, ice core reveal limited migration of certain soluble ionic species (methane sulfonic acid, NO₃ and Mg²⁺). Th e observed chemical migration m ay be due in part to seasonal alternation between less acidic winter (from high sea-salt concentrations) and m ore acidic summer (from high marine biogenic acid concentrations) layers, common at coastal sites such as Siple Dome. Exact mechanisms to explain the migration are unclear, although simple diffusion and gravitational movement are unlikely since new peaks are …

Spatial Variability Of Snow Chemistry In Western Dronning Maud Land, Antarctica, Malin Stenberg, Elisabeth Isaksson, Margareta Hansson, Wibjörn Karlén, Paul Andrew Mayewski, Mark S. Twickler, Sallie I. Whitlow, Niels Gundestrup

Earth Science Faculty Scholarship

During the austral summer of 1993-94 a number of 1-2 m deep snow pits were sampled in connection with firn-coring in western Dronning Maud Land, Antarctica. The traverse went from 800 to about 3000 m a.s.l. upon the high-altitude plateau. Profiles of cations (Na⁺, K⁺, Mg²⁺, Ca²⁺), anions (CI^-, NO^3-, SO₄^2-, CH₃SO₃^-) and stable oxygen isotopes (δ¹⁸O) from II snow pits are presented here. Close to the coast 2 m of snow accumulates in about 2-3 years, whilst …

Assessment Of The Record Of The 1982 El Chichón Eruption As Preserved In Greenland Snow, Gregory A. Zielinski, Jack E. Dibb, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Mark S. Twickler, Mark S. Germani

Earth Science Faculty Scholarship

Variability in the SO 4 2 - and Cl⁻ time series for the 1980s from 12 shallow snow pits across the Greenland ice sheet is used to evaluate the record of the 1982 El Chichón eruption and the potential for recording a moderate northern equatorial eruption in a single Greenland ice core. Composition of volcanic glass found in spring 1983 snow in one of the pits in the Summit region matches that from El Chichón glass, thereby verifying the deposition of material from the eruption. High Na⁺ and Cl⁻ concentrations in this same layer probably represent deposition …

A 110,000-Year History Of Change In Continental Biogenic Emissions And Related Atmospheric Circulation Inferred From The Greenland Ice Sheet Project Ice Core, L. D. Meeker, Paul Andrew Mayewski, M. S. Twickler, S. I. Whitlow, D. Meese

Earth Science Faculty Scholarship

The 110,000-year record of ammonium concentrations from the Greenland Ice Sheet Project 2 (GISP2) ice core provides the basis for an analysis of terrestrial biological production and atmospheric circulation patterns involved in the transport of biologically produced ammonium to the Greenland atmosphere. The directly measured concentration series was selected for analysis, rather than that of estimated ammonium flux, after a detailed analysis of the relationship among ice core glaciochemical concentrations and a high-resolution simultaneous record of snow accumulation from the GISP2 core. Analysis of the ammonium concentration series shows that maxima in background levels of ammonium in the Greenland atmosphere …

Paleoclimatic Variability Inferred From The Spectral Analysis Of Greenland And Antarctic Ice-Core Data, R. Yiou, K. Fuher, L. D. Meeker, J. Jouzel, S. Johnsen, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Paleoclimate variations occur at various time scales, between a few centuries for the Heinrich events and several hundreds of millenia for the glacial to interglacial variations. The recent ice cores from Greenland (Greenland Ice Core Project and Greenland Ice Sheet Project 2) and Antarctica (Vostok) span at least one glacial oscillation and provide many opportunities to investigate climate variations with a very fine resolution. The joint study of cores from both hemispheres allows us to distinguish between the sources of variability and helps to propose mechanisms of variations for the different time scales involved. The climate proxies we analyze are …

Volcanic Aerosol Records And Tephrochronology Of The Summit, Greenland, Ice Cores, Gregory A. Zielinski, Paul Andrew Mayewski, L. David Meeker, Karl Grönvold, Mark D. Germani, Sallie Whitlow, Mark S. Twickler, Kendrick Taylor

Earth Science Faculty Scholarship

The recently collected Greenland Ice Sheet Project 2 (GISP2) and Greenland Ice Core Project ice cores from Summit, Greenland, provide lengthy and highly resolved records of the deposition of both the aerosol (H₂SO₄) and silicate (tephra) components of past volcanism. Both types of data are very beneficial in developing the hemispheric to global chronology of explosive volcanism and evaluating the entire volcanism-climate system. The continuous time series of volcanic SO₄²⁻ for the last 110,000 years show a strong relationship between periods of increased volcanism and periods of climatic change. The greatest number of volcanic …

Historical Biomass Burning: Late 19th Century Pioneer Agriculture Revolution In Northern Hemisphere Ice Core Data And Its Atmospheric Interpretation, G. Holdsworth, K. Hiuchi, G. A. Zielinski, Paul Andrew Mayewski, M. Wahlen, B. Deck, P. Chylek, B. Johnson, P. Damiano

Earth Science Faculty Scholarship

Ice core data from Yukon and Greenland spanning from ∼1750 to 1950 indicate that between ∼1850 and ≤1910 a clear atmospheric signal exists of an episodic biomass burning event that is referred to as the Pioneer Agriculture Revolution. This is best seen in NH₄⁺ ion and particulate concentrations but also in some limited black carbon concentration data, where for all three quantities maximum levels reach about 3 times the prerevolution background concentrations. Tree cellulose δ¹³C data and some early, controversial, French, air CO₂ data, occurring within the same time interval, are interpreted as providing other …

Chemical Species Spatial Distribution And Relationship To Elevation And Snow Accumulation Rate Over The Greenland Ice Sheet, Q. Yang, Paul Andrew Mayewski, E. Linder, S. Whitlow, M. Twickler

Earth Science Faculty Scholarship

Major chemical species (Cl⁻, NO⁻₃, SO²⁻₄, Na⁺, K⁺, Mg²⁺, Ca²⁺) from 24 snowpits (sampled at a resolution of 3 cm, total 2995 samples) collected from northern, central, and southern Greenland were used for this investigation. The annual and seasonal (winter and summer) concentration of each chemical species was calculated and used to study the spatial distribution of chemical species over the central portion of the Greenland Ice Sheet. A two-sided t-distribution test (α=0.05) suggests that concentrations of major chemical species in snow do …

Global Perspective Of Nitrate Flux In Ice Cores, Qinzhao Yang, Paul Andrew Mayewski, Sallie Whitlow, Michael Morrison, Robert Talbot, Jack Dibb, Ernst Linder

Earth Science Faculty Scholarship

The relationships between the concentration and the flux of chemical species(Cl^-, NO₃^-, SO₄^2-, Na⁺, K⁺, NH₄⁺, Mg²⁺, Ca²⁺) versus snow accumulation rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly(α = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally …

Changes In Continental And Sea-Salt Atmospheric Loadings In Central Greenland During The Most Recent Deglaciation: Model-Based Estimates, R. B. Alley, R. C. Finkel, K. Nishizumi, A. Anandakrishnan, C. A. Shuman, G. Mershon, G. A. Zielinski, Paul Andrew Mayewski

Earth Science Faculty Scholarship

By fitting a very simple atmospheric impurity model to high-resolution data on ice accumulation and contaminant f1uxes in the GISP2 ice core, we have estimated changes in the atmospheric concentrations of soluble major ions, insoluble particulates and ¹⁰Be during the transition from glacial to Holocene conditions. For many species, changes in concentration in the ice typically overestimate atmospheric changes, and changes in flux to the ice typically underestimate atmospheric changes, because times of increased atmospheric contaminant loading are also times of reduced snowfall. The model interpolates between the flux and concentration records by explicitly allowing [or wet- and dry- …

Two-Hundred-Year Record Of Biogenic Sulfur In A South Greenland Ice Core (20d), P. Y. Whung, E. S. Saltzman, M. J. Spencer, Paul Andrew Mayewski, N. Gundestrup

Earth Science Faculty Scholarship

The concentration of methanesulfonic acid (MSA) was determined in a shallow south central Greenland ice core(20D). This study provides a high-resolution record of the DMS-derived biogenic sulfur in Greenland precipitation over the past 200 years. The mean concentration of MSA is 3.30 ppb(σ = 2.38 ppb,n = 1134). The general trend of MSA is an increase from 3.01 to 4.10 ppb between 1767 and 1900, followed by a steady decrease to 2.34 ppb at the present time. This trend is in marked contrast to that of non-sea-salt sulfate (nss SO₄^2-), which increases dramatically after 1900 due to …

Greenland Ice Core Greenland Ice Core "Signal" Characteristics: An Expanded View Of Climate Change, Paul Andrew Mayewski, L. D. Meeker, M. C. Morrison, M. S. Twickler, S. I. Whitlow, K. K. Ferland, D. A. Meese, M. R. Legrand, J. P. Steffensen

Earth Science Faculty Scholarship

The last millenium of Earth history is of particular interest because it documents the environmental complexities of both natural variability and anthropogenic activity. We have analyzed the major ions contained in the Greenland Ice Sheet Project 2 (GISP 2) ice core from the present to ∼674 A.D. to yield an environmental reconstruction for this period that includes a description of nitrogen and sulfur cycling, volcanic emissions, sea salt and terrestrial influences. We have adapted and extended mathematical procedures for extracting sporadic (e.g., volcanic) events, secular trends, and periodicities found in the data sets. Finally, by not assuming that periodic components …

Anthropogenic Sulfate And Asian Dust Signals In Snow From Tien Shan, Northwest China, Cameron P. Wake, Paul Andrew Mayewski, Wang Ping, Yang Qinzhao, Han Jiankang, Xie Zichu

Earth Science Faculty Scholarship

Snow samples were collected from a 0.5 m snowpack at Glacier No. 1 and near Bogda Feng, eastern Tien Shan, northwest China. Samples that were melted in the field were analyzed for chloride, nitrate, sulfate, sodium, potassium, magnesium, calcium, and microparticles. Eight samples were returned frozen and were analyzed for the above ions plus ammonium, acetate, formate, methylsulfonate, and hydrogen peroxide. There was no significant difference in measured major ion concentrations between the melted and frozen samples. Measured cations in both sets of samples were two to three times greater than measured anions. Calcium and sodium are the dominant cations …

Detailed Glaciochemical Investigations In Southern Victoria Land, Antarctica — A Proxy Climate Record, Paul Andrew Mayewski

Earth Science Faculty Scholarship

The production of environmental change records using time-series data retrieved from ice cores has seen minimal application in the Transantarctic Mountains despite the existence of a well-developed lower resolution glacial geologic record for this area which forms the primary basis for understanding the glacial history of East Antarctica. In addition, records derived from marine and lake cores, glacier margin fluctuation studies, measures of volcanic activity, and meteorological data sets from within or close to the Transantarctic Mountains are available for comparison. This emerging environmental data-base provides the tools needed to define the change characteristics, over a period of thousands of …

A Glaciochemical Survey Of The Summit Region, Greenland, Paul Andrew Mayewski, M. J. Spencer, M. S. Twickler, S. Whitlow

Earth Science Faculty Scholarship

Spatial representativeness and an understanding of controls on chemical species distribution are essential requirements of any significant ice core investigation. Snowpit studies provide an essential tool in this process. In preparation for the central Greenland deep drilling effort a series of snowpits was sampled in detail for oxygen isotopes, major anions, major cations, total acidity and radionuclides. The results of this sampling program are used to define: (I) the chemical composition of the snow in the region, (2) the input timing and spatial distribution of major chemical species, (3) the potential dependence of species concentration on accumulation rate, and (4) …

Ice-Core Records And Ozone Depletion—Potential For A Proxy Ozone Record, Paul Andrew Mayewski, Mary Jo Spencer, William Berry Lyons, Mark S. Twickler, J. Dibb

Earth Science Faculty Scholarship

Time-series of the ionic composition in polar ice cores can provide detailed direct and proxy records of seasonal to Millenial scale fluctuations in climate, atmospheric chemistry, and volcanic activity. Even though problems of species-source links and air/snow fractionation have not all been entirely resolved,the fact remains that ice cores currently hold the best hope of retrieving detailed paleo-atmospheric records. While direct links between the chemistry in ice cores and the ozone depletion phenomenon cannot be guaranteed, ice-core records provide the only means by which signals related to the ozone cycle can be produced for pre-measurement periods or for unmonitored sites. …

Upper Rennick Glacier Ice Massfluctuation Study, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Glacial geologic mapping conducted during the 1974-75 field season revealed that at least two glacial events have affected the upper Rennick Glacier region: an older Evans glaciation probably correlative with a major expansion of the east antarctic ice sheet, and the Rennick glaciation, which since the end of the late Wisconsin has been in a retreat phase (Mayewski, Attig, and Drewry 1979). Ice surface reconstructions suggest that (1) in the area of the current Rennick Glacier grounding line, approximately 120 kilometers inland from its current terminus, Evansice was at least 1,000 meters higher and Rennick ice as much as 600meters …

Reconnaissance Glacio-Chemical Studies In The Indian Himalayas, Paul Andrew Mayewski, William Berry Lyons, Nasseruddin Ahmad

Earth Science Faculty Scholarship

Analysis of reactive silicate, ammonium, phosphate, iron and sodium from cores taken from three glaciers in the Kashmir portion of the Himalayas are reported as the first in a series of glacio-chemical studies designed to produce proxy paleoclimatic data for this region. This study stresses the elevation dependency of such studies and for the chemical species analyzed which are most reliable for the purpose of the study.

Acidity Of Recent Himalayan Snow, William Berry Lyons, Paul Andrew Mayewski, Nasseruddin Ahmad

Earth Science Faculty Scholarship

Surface snows collected at various elevations in the Indian Himalayas were analyzed in the field for pH as part of a broader study of the chemistry. The pH values are lower than the predicted ≅5.6 for unpolluted precipitation. Analysis of NO₃ + NO₂, Cl, SO₄ and NH₄ indicate that these low pH values are not completely due to the presence of strong mineral acids. The strong correlation of pH with elevation (i.e. temperature) suggests that the low pH values are due to the snow being supersaturated with CO₂.