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Full-Text Articles in Inorganic Chemistry
Synthesis Of Manganese(Ii) Containing Metal Chalcogen Cluster Complexes From Metal Trimethylsilylthiolate Precursors, Kyle Nw Rozic
Synthesis Of Manganese(Ii) Containing Metal Chalcogen Cluster Complexes From Metal Trimethylsilylthiolate Precursors, Kyle Nw Rozic
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The manganese(II)‐palladium(II)‐sulfide complex [MnCl2(μ3‐S)2Pd2(dppp)2] 2 has been isolated from the reaction of [(dppp)PdCl2] with [Li(N,N’‐tmeda)]2[Mn(SSiMe3)4] 1 in a 2:1 ratio under mild conditions. The trimethylsilyl thiolate complex [(dppp)Pd(SSiMe3)2] 3 has been synthesized from the reaction of [(dppp)PdCl2] with Li[SSiMe3] as well as the reaction of [(dppp)Pd(OAc)2] with Li[SSiMe3] under mild conditions. The newly synthesized complex [(dppp)Pd(SSiMe3)2] 3 was used in reaction with the manganese(II) salt [(CH …