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Articles 1 - 8 of 8
Full-Text Articles in Physical Sciences and Mathematics
Simplified Calculation Of The Stability Matrix For Semiclassical Propagation, Sophya Garashchuk, John C. Light
Simplified Calculation Of The Stability Matrix For Semiclassical Propagation, Sophya Garashchuk, John C. Light
Faculty Publications
We present a simple method of calculation of the stability (monodromy) matrix that enters the widely used semiclassical propagator of Herman and Kluk and almost all other semiclassical propagators. The method is based on the unitarity of classical propagation and does not involve any approximations. The number of auxiliary differential equations per trajectory scales linearly rather than quadratically with the system size. Just the first derivatives of the potential surface are needed. The method is illustrated on the collinear H[sub 3] system.
Conductivity Of Irradiated Pure Water, Jerry Goodisman, Rick Blades
Conductivity Of Irradiated Pure Water, Jerry Goodisman, Rick Blades
Chemistry - All Scholarship
The conductivity of water having parts per billion concentrations of oxygen, hydrogen, and bicarbonate was measured while the water was irradiated by a low-pressure mercury vapor lamp, which was turned on and off periodically. A cell normally used for measurement of dissolved oxidizable carbon was modified for use in these measurements. When the lamp is turned on, the conductivity increases (sometimes decreases) with a time constant of about 50 ms; when the lamp is turned off, the conductivity changes in the opposite direction with a time constant of about 275 ms, but does not return to its value before the …
Effect Of Collagen Turnover On The Accumulation Of Advanced Glycation End Products, Nicole Verzijl, Jeroen Degroot, Suzanne R. Thorpe, Ruud A. Bank, J. Nikki Shaw, Timothy J. Lyons, Johannes Wj Bijlsma, Floris Pjg Lafeber, John W. Baynes, Johan M. Tekoppele
Effect Of Collagen Turnover On The Accumulation Of Advanced Glycation End Products, Nicole Verzijl, Jeroen Degroot, Suzanne R. Thorpe, Ruud A. Bank, J. Nikki Shaw, Timothy J. Lyons, Johannes Wj Bijlsma, Floris Pjg Lafeber, John W. Baynes, Johan M. Tekoppele
Faculty Publications
Collagen molecules in articular cartilage have an exceptionally long lifetime, which makes them susceptible to the accumulation of advanced glycation end products (AGEs). In fact, in comparison to other collagen-rich tissues, articular cartilage contains relatively high amounts of the AGE pentosidine. To test the hypothesis that this higher AGE accumulation is primarily the result of the slow turnover of cartilage collagen, AGE levels in cartilage and skin collagen were compared with the degree of racemization of aspartic acid (% D-Asp, a measure of the residence time of a protein). AGE (Ne- (carboxymethyl)lysine, Ne-(carboxyethyl)lysine, and pentosidine) and % D-Asp concentrations increased …
Pyridoxamine, An Inhibitor Of Advanced Glycation Reactions, Also Inhibits Advanced Lipoxidation Reactions: Mechanism Of Action Of Pyridoxamine, Joelle M. Onorato, Alicia J. Jenkins, Suzanne R. Thorpe, John W. Baynes
Pyridoxamine, An Inhibitor Of Advanced Glycation Reactions, Also Inhibits Advanced Lipoxidation Reactions: Mechanism Of Action Of Pyridoxamine, Joelle M. Onorato, Alicia J. Jenkins, Suzanne R. Thorpe, John W. Baynes
Faculty Publications
Maillard or browning reactions lead to formation of advanced glycation end products (AGEs) on protein and contribute to the increase in chemical modification of proteins during aging and in diabetes. AGE inhibitors such as aminoguanidine and pyridoxamine (PM) have proven effective in animal model and clinical studies as inhibitors of AGE formation and development of diabetic complications. We report here that PM also inhibits the chemical modification of proteins during lipid peroxidation (lipoxidation) reactions in vitro, and we show that it traps reactive intermediates formed during lipid peroxidation. In reactions of arachidonate with the model protein RNase, PM prevented modification …
Ac Susceptibility Of Sr3CuptXIr1-XO6: A Magnetic System With Competing Interactions And Dimensionality, S H. Irons, T D. Sangrey, K M. Beauchamp, M D. Smith, Hans Conrad Zur Loye
Ac Susceptibility Of Sr3CuptXIr1-XO6: A Magnetic System With Competing Interactions And Dimensionality, S H. Irons, T D. Sangrey, K M. Beauchamp, M D. Smith, Hans Conrad Zur Loye
Faculty Publications
Sr3CuPtxIr1-xO6 has been cited as an example of a one-dimensional quantum spin chain with competing ferromagnetic and antiferromagnetic interactions. We have measured the ac susceptibility of Sr3CuPtxIr1-xO6 with x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, and 0.7, in magnetic fields of 0–60 kOe, and at temperatures down to 0.275 K. Our data show that the x=endpoint Sr3CuIrO6, exhibits long-range ferromagnetic order at T=20.1 K, contrary to results from dc susceptibility studies which indicated that it remained a one-dimensional ferromagnet to below 4 …
Fundamental Capillary Electrophoresis: An Evaluation Of Electrokinetic Sampling, Cindy Ann Mleziva Blake
Fundamental Capillary Electrophoresis: An Evaluation Of Electrokinetic Sampling, Cindy Ann Mleziva Blake
Seton Hall University Dissertations and Theses (ETDs)
Capillary electrophoresis has become a powerful separation technique in fields of biochemical separations, inorganic ions, and chiral separations. The technique has experienced exponential growth since the historic publication of Zone Electrophoresis in Open-Tubular Glass Capillaries by Lukacs and Jorgenson in 1981. However, the use of capillary electrophoresis as a primary research analysis tool still remains to be seen in many pharmaceutical laboratories. One of the main reasons for this is that it remains difficult to validate CE methods using the criteria of quantitation and accuracy posed by the current government regulating agencies, as developed for high performance liquid chromatography and …
Synthesis Of The Fungicide Propiconazole A Systemic Foliar Fungicide., Hazel Delaney
Synthesis Of The Fungicide Propiconazole A Systemic Foliar Fungicide., Hazel Delaney
Masters
Propiconazole, 1-[[2-(2,4-dichlorophenyl)-4-propyl-1, 3-dioxol-2-yl[methyl]-1H-1,2,4-triazole, commercially know as “Tilt” is a systemic foliar fungicide for cereals and is widely used in agriculture. The aim of this project was to develop an economically feasible process for the production of propiconazole and to maximise the yields of the intermediates in the developed process. Processes investigated included the original Ciba-Geigy process. In addition an investigation into the synthesis and characterisation of the impurities formed, and reported to be formed in each step of the reaction process was carried out and seven of the reported impurities were synthesised. One impurity was shown not to be present …
New Rare Cave Minerals From The Perolas-Santana Karst System (São Paulo State, Brazil), Paolo Forti, Ermanno Galli, Antonio Rossi
New Rare Cave Minerals From The Perolas-Santana Karst System (São Paulo State, Brazil), Paolo Forti, Ermanno Galli, Antonio Rossi
International Journal of Speleology
The Perolas-Santana karst system (São Paulo State, Brazil) has been partially studied from the mineralogical point of view. The present paper will contribute to the knowledge of the minerals in these caves, describing the occurrence of euhedral celestite crystals and of a rather rare mineral for a cavern environment: lithiophorite. Thanks to these new discoveries the Perolas-Santana karst system becomes one of the most important in Brazil from a mineralogical point of view. Finally, the result of the chemical analyses carried out on this newly discovered Monoxyhydroxide put in evidence a zonation in the distribution of the different elements which …