Physical Sciences and Mathematics Commons^™

Investigation Of Robust Optimization And Evidence Theory With Stochastic Expansions For Aerospace Applications Under Mixed Uncertainty, Harsheel R. Shah

Doctoral Dissertations

One of the primary objectives of this research is to develop a method to model and propagate mixed (aleatory and epistemic) uncertainty in aerospace simulations using DSTE. In order to avoid excessive computational cost associated with large scale applications and the evaluation of Dempster Shafer structures, stochastic expansions are implemented for efficient UQ. The mixed UQ with DSTE approach was demonstrated on an analytical example and high fidelity computational fluid dynamics (CFD) study of transonic flow over a RAE 2822 airfoil.

Another objective is to devise a DSTE based performance assessment framework through the use of quantification of margins and …

Microstructure And Geotechnical Properties Of St. Peter Sandstone In Clayton, Iowa, Amir Hossein Bagherieh

Doctoral Dissertations

"The St. Peter Sandstone is significantly different from the minerals and rocks which have been studied extensively in mining. It is brittle and characterized by an unusually high friction angle. On the other hand it is friable, and it is nearly cohesionless. The scarcity of the ground control techniques for this particular mining environment has created many difficulties for mine operators. This research aims to establish a fundamental understanding of the basic mechanical and strength properties of the St. Peter Sandstone for engineering design and scientific research. The specific objectives are 1) characterizing the strength of the St. Peter Sandstone, …

Using Higher Ionization States To Increase Coulomb Coupling In An Ultracold Neutral Plasma, M. Lyon, Scott D. Bergeson, A. Diaw, M. S. Murillo

Faculty Publications

We report measurements and simulations of the time-evolving rms velocity distribution in an ultracold neutral plasma. A strongly coupled ultracold neutral Ca⁺ plasma is generated by photoionizing laser-cooled atoms close to threshold. A fraction of these ions is then promoted to the second ionization state to form a mixed Ca⁺-Ca²⁺ plasma. By varying the time delay between the first and the second ionization events, a minimum in ion heating is achieved. We show that the Coulomb strong-coupling parameter Γ increases by a factor of 1.4 to a maximum value of 3.6. A pure Ca²⁺ plasma …

Strongly-Coupled Plasmas Formed From Laser-Heated Solids, M. Lyon, Scott D. Bergeson, G. Hart, M. S. Murillo

Faculty Publications

We present an analysis of ion temperatures in laser-produced plasmas formed from solids with different initial lattice structures. We show that the equilibrium ion temperature is limited by a mismatch between the initial crystallographic configuration and the close-packed configuration of a strongly-coupled plasma, similar to experiments in ultracold neutral plasmas. We propose experiments to demonstrate and exploit this crystallographic heating in order to produce a strongly coupled plasma with a coupling parameter of several hundred.

Frontier: A Framework For Extracting And Organizing Biographical Facts In Historical Documents, Joseph Park

Theses and Dissertations

The tasks of entity recognition through ontological commitment, fact extraction and organization with respect to a target schema, and entity deduplication have all been examined in recent years, and systems exist that can perform each individual task. A framework combining all these tasks, however, is still needed to accomplish the goal of automatically extracting and organizing biographical facts about persons found in historical documents into disambiguated entity records. We introduce FROntIER (Fact Recognizer for Ontologies with Inference and Entity Resolution) as the framework to recognize and extract facts using an ontology and organize facts of interest through inferring implicit facts …

Characterization Of Terrestrial Dissolved Organic Matter Fractionated By Ph And Polarity And Their Biological Effects On Plant Growth, Rachel L. Sleighter, Paolo Caricasole, Kristen M. Richards, Terry Hanson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Background: Humic substances are ubiquitous in the environment, complex mixtures, and known to be beneficial to plant growth. To better understand and identify components responsible for plant growth stimulation, a terrestrial aquatic DOM sample was fractionated according to pH and polarity, obtaining acid-soluble and acid-insoluble portions, as well as acid-soluble hydrophobic and hydrophilic fractions using C18. The various fractions were characterized then evaluated for their biological effects on plant growth using bioassays with corn at two carbon rates.

Results: Approximately 43% and 57% of the carbon, and 31% and 69% of the iron, was found in the acid-insoluble and acid-soluble …

Proton-Electrostatic Localization: Explaining The Bioenergetic Conundrum In Alkalophilic Bacteria, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

The decades-longstanding energetic conundrum of alkalophilic bacteria as to how they are able to synthesize ATP has now, for the first time, been clearly solved using the proton-electrostatics localization hypothesis. This is a major breakthrough advance in understanding proton-coupling bioenergetics over the Nobel-prize work of Peter Mitchell’s chemiosmotic theory. The widespread textbook Mitchellian proton motive force (pmf) equation has now been significantly revised. Use of the newly derived equation results in an overall pmf value (215~233 mV) that is more than 4 times larger than that (44.3 mV) calculated from the Mitchellian equation for the alkalophilic bacteria growing at pH …

Numerical Study Of The Supercritical Solution Of The Stationary Forced Korteweg-De Vries (Sfkdv) Equation, Sumi Dey

Open Access Theses & Dissertations

The time independent surface waves on a two dimensional incompressible and inviscid fluid flow passing over a bump on a flat bottom are considered. The stationary forced Korteweg-de Vries (fKdV) equation is defined in an unbounded interval. In this project, this unbounded interval is considered as three parts - on the bump, left hand side of the bump and right hand side of the bump. Exact boundary conditions are applied to the end points of the bump. All the possible combination of boundary conditions are used. A numerical approach is proposed to find the solitary wave solutions of fKdV equation …

Multi-Expert Multi-Criteria Decision Making, Joel Henderson

Open Access Theses & Dissertations

Expert analysis and decisions are highly valued assets in a wide variety of fields, from social services to grant funding committees. However, the use of experts can be prohibitive due to either lack of availability or cost. As such, it is desirable to be able to replicate such decisions. However, there are many obstacles that impede an accurate simulation of expert decisions. For example, despite looking at the same information, two experts may disagree on the decisions. In addition, a single expert may make inconsistent decisions across similar scenarios.

In this work, we focus on multi-criteria decision making and in …

Computation Offloading Decisions For Reducing Completion Time, Salvador Melendez

Open Access Theses & Dissertations

Mobile devices are being widely used in many applications such as image processing, computer vision (e.g. face detection and recognition), wearable computing, language translation, and battlefield operations. However, mobile devices are constrained in terms of their battery life, processor performance, storage capacity, and network bandwidth. To overcome these issues, there is an approach called Computation Offloading, also known as cyber-foraging and surrogate computing. Computation offloading consists of migrating computational jobs from a mobile device to more powerful remote computing resources. Upon completion of the job, the results are sent back to the mobile device. However, a decision must be made; …

Ac-Susceptibility And Epr Investigations Of Superspin Dynamics In Magnetite Nanoparticles, Alex D. Price

Open Access Theses & Dissertations

In this investigation we use two complementary techniques to distinguish between superparamagnetic blocking (SPB) and superspin-glass (SSG) freezing phenomena in magnetite nanoparticles. While these manifestations of the superspin dynamics are fundamentally different, they have similar "signatures", especially in dc-magnetization experiments. Even if ac-susceptibility measurements are employed, careful use of mathematical models to analyze the data are needed to uncover which type of phenomena (SPB or SSG freezing) occurs within the material. Yet, by utilizing electron paramagnetic resonance (EPR) on a 10 nm Fe3O4 nano-powder as well as on a ferrofluid (based on the same nanoparticle ensemble) we found a very …

Optimization Schemes For The Inversion Of Bouguer Gravity Anomalies, Azucena Zamora

Open Access Theses & Dissertations

Data sets obtained from measurable physical properties of the Earth structure have helped advance the understanding of its tectonic and structural processes and constitute key elements for resource prospecting. 2-Dimensional (2-D) and 3-D models obtained from the inversion of geophysical data sets are widely used to represent the structural composition of the Earth based on physical properties such as density, seismic wave velocities, magnetic susceptibility, conductivity, and resistivity. The inversion of each one of these data sets provides structural models whose consistency depends on the data collection process, methodology, and overall assumptions made in their individual mathematical processes. Although sampling …

Global Ozone Chemistry And Related Trace Gas Data Records For The Stratosphere (Gozcards): Methodology And Sample Results With A Focus On Hcl, H20, And 03, L. Froidevaux, J. Anderson, H. J. Wang, R. A. Fuller, M. J. Schwartz, M. L. Santee, N. J. Livesey, H. C. Pumphrey, P. F. Bernath, J. M. Russell Iii, M. P. Mccormick

Chemistry & Biochemistry Faculty Publications

We describe the publicly available data from the Global OZone Chemistry And Related trace gas Data records for the Stratosphere (GOZCARDS) project and provide some results, with a focus on hydrogen chloride (HCl), water vapor (H₂O), and ozone (O₃). This data set is a global long-term stratospheric Earth system data record, consisting of monthly zonal mean time series starting as early as 1979. The data records are based on high-quality measurements from several NASA satellite instruments and the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) on SCISAT. We examine consistency aspects between the various data sets. …

Plant Species Rather Than Climate Greatly Alters The Temporal Pattern Of Litter Chemical Composition During Long-Term Decomposition, Yongfu Li, Na Chen, Mark E. Harmon, Yuan Li, Xiaoyan Cao, Mark A. Chappell, Jingdong Mao

Chemistry & Biochemistry Faculty Publications

A feedback between decomposition and litter chemical composition occurs with decomposition altering composition that in turn influences the decomposition rate. Elucidating the temporal pattern of chemical composition is vital to understand this feedback, but the effects of plant species and climate on chemical changes remain poorly understood, especially over multiple years. In a 10-year decomposition experiment with litter of four species (Acer saccharum, Drypetes glauca, Pinus resinosa, and Thuja plicata) from four sites that range from the arctic to tropics, we determined the abundance of 11 litter chemical constituents that were grouped into waxes, carbohydrates, …

Molecular Level Characterization Of Diatom-Associated Biopolymers That Bind 234th, ²³³Pa, ²¹°Pb, And 7be In Seawater: A Case Study With Phaeodactylum Tricornutum, Chia-Ying Chuang, Peter H. Santschi, Chen Xu, Yuelu Jiang, Yi-Fang Ho, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

In order to investigate the importance of biogenic silica associated biopolymers on the scavenging of radionuclides, the diatom Phaeodactylum tricornutum was incubated together with the radionuclides Th-234, Pa-233, Pb-210, and Be-7 during their growth phase. Normalized affinity coefficients were determined for the radionuclides bound with different organic compound classes (i.e., proteins, total carbohydrates, uronic acids) in extracellular (nonattached and attached exopolymeric substances), intracellular (ethylene diamine tetraacetic acid and sodium dodecyl sulfate extractable), and frustule embedded biopolymeric fractions (BF). Results indicated that radionuclides were mostly concentrated in frustule BF. Among three measured organic components, Uronic acids showed the strongest affinities to …

Initial Evaluations Of A U.S. Navy Rapidly Relocatable Gulf Of Mexico/Caribbean Ocean Forecast System In The Context Of The Deepwater Horizon Oil Spill Disaster, Edward D. Zaron, Patrick J. Fitzpatrick, Scott L. Cross, John M. Harding, Frank L. Bub, Jerry D. Wiggert, Dong S. Ko, Yee Lau, Katharine Woodward, Christopher N.K. Mooers

Civil and Environmental Engineering Faculty Publications and Presentations

In response to the Deepwater Horizon (DwH) oil spill event in 2010, the Naval Oceanographic Office deployed a nowcast-forecast system covering the Gulf of Mexico and adjacent Caribbean Sea that was designated Americas Seas, or AMSEAS, which is documented in this manuscript. The DwH disaster provided a challenge to the application of available ocean-forecast capabilities, and also generated a historically large observational dataset. AMSEAS was evaluated by four complementary efforts, each with somewhat different aims and approaches: a university research consortium within an Integrated Ocean Observing System (IOOS) testbed; a petroleum industry consortium, the Gulf of Mexico 3-D Operational Ocean …

Spectroscopic Characterization Of Oceanic Dissolved Organic Matter Isolated By Reverse Osmosis Coupled With Electrodialysis, John R. Helms, Jingdong Mao, Hongmei Chen, E. Michael Perdue, Nelson W. Green, Patrick G. Hatcher, Kenneth Mopper, Aron Stubbins

Chemistry & Biochemistry Faculty Publications

Oceanic dissolved organic matter (DOM) is one of the largest pools of reduced carbon on Earth, yet DOM remains poorly chemically characterized. Studies to determine the chemical nature of oceanic DOM have been impeded by the lack of efficient and non-fractioning methods to recover oceanic DOM. Here, a DOM fraction (~40 to 86% recovery) was isolated using reverse osmosis/electrodialysis (RO/ED) and analyzed by solid-state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Samples were obtained from biogeochemically distinct environments: photobleached surface gyre, productive coastal upwelling zone, oxygen minimum, North Atlantic Deep Water, and North Pacific Deep Water. A ubiquitous ‘background’ refractory …

Interesting Properties Of P-, D-, And F-Block Elements When Coordinated With Dipicolinic Acid And Its Derivatives As Ligands: Their Use As Inorganic Pharmaceuticals, Michael J. Celestine, Jimmie L. Bullock, Shivani Boodram, Varma H. Rambaran, Alvin A. Holder

Chemistry & Biochemistry Faculty Publications

This is a review of the literature concerning the interesting properties of p-, d-, and f-block elements when coordinated with 2,6-pyridinedicarboxylic acid (dipicolinic acid, H₂dipic) and its derivatives as ligands, with a focus on their use as inorganic pharmaceuticals. Some of the complexes reported were used as insulin-like, bioimaging contrasting agents, antimicrobial agents, and anticancer agents.

The Expression Problem, Gracefully, Andrew P. Black

Computer Science Faculty Publications and Presentations

The “Expression Problem” was brought to prominence by Wadler in 1998. It is widely regarded as illustrating that the two mainstream approaches to data abstraction — procedural abstraction and type abstraction— are complementary, with the strengths of one being the weaknesses of the other. Despite an extensive literature, the origin of the problem remains ill-understood. I show that the core problem is in fact the use of global constants, and demonstrate that an important aspect of the problem goes away when Java is replaced by a language like Grace, which eliminates them.

The Grace Programming Language Draft Specification Version 0.5. 2025, Andrew P. Black, Kim B. Bruce, James Noble

Computer Science Faculty Publications and Presentations

This is a specification of the Grace Programming Language. This specification is notably incomplete, and everything is subject to change. For discussion and rationale, see http://gracelang.org.

S-Store: Streaming Meets Transaction Processing, John Meehan, Nesime Tatbul, Cansu Aslantas, Ugur Cetintemel, Jiang Du, Tim Kraska, Samuel Madden, David Maier, Andrew Pavlo, Michael Stonebraker, Kristin A. Tufte, Hao Wang

Computer Science Faculty Publications and Presentations

Stream processing addresses the needs of real-time applications. Transaction processing addresses the coordination and safety of short atomic computations. Heretofore, these two modes of operation existed in separate, stove-piped systems. In this work, we attempt to fuse the two computational paradigms in a single system called S-Store. In this way, S-Store can simultaneously accommodate OLTP and streaming applications. We present a simple transaction model for streams that integrates seamlessly with a traditional OLTP system. We chose to build S-Store as an extension of H-Store, an open-source, in-memory, distributed OLTP database system. By implementing S-Store in this way, we can make …

A Theory Of Name Resolution, Pierre Néron, Andrew Tolmach, Eelco Visser, Guido Wachsmuth

Computer Science Faculty Publications and Presentations

We describe a language-independent theory for name binding and resolution, suitable for programming languages with complex scoping rules including both lexical scoping and modules. We formulate name resolution as a two-stage problem. First a language-independent scope graph is constructed using language-specific rules from an abstract syntax tree. Then references in the scope graph are resolved to corresponding declarations using a language-independent resolution process. We introduce a resolution calculus as a concise, declarative, and language- independent specification of name resolution. We develop a resolution algorithm that is sound and complete with respect to the calculus. Based on the resolution calculus we …

Usage Based Topology For Dcns, Qing Yi, Suresh Singh

Computer Science Faculty Publications and Presentations

Many data center network topologies are designed to provide full bisection bandwidth for tens of thousands of servers in order to achieve high network throughput and server agility. However, the utilization rate of DCNs on average is below 10%, which results in a significant waste of network resources and energy. Many researchers propose consolidating network traffic flows to maximize the set of idle network equipment and switching them to low power mode to save energy. In this paper, we propose using skinnier network topologies to meet performance requirements of realistic loads thus saving not only energy but capital cost as …

A Demonstration Of The Bigdawg Polystore System, Aaron J. Elmore, Jennie Duggan, Michael Stonebraker, Magdalena Balazinska, Ugur Cetintemel, Vijay Gadepally, J. Heer, Bill Howe, Jeremy Kepner, Tim Kraska, Samuel Madden, David Maier, Timothy G. Mattson, S. Papadopoulos, J. Parkhurst, Nesime Tatbul, Manasi Vartak, Stan Zdonik

Computer Science Faculty Publications and Presentations

This paper presents BigDAWG, a reference implementation of a new architecture for “Big Data” applications. Such applications not only call for large-scale analytics, but also for real-time streaming support, smaller analytics at interactive speeds, data visualization, and cross-storage-system queries. Guided by the principle that “one size does not fit all”, we build on top of a variety of storage engines, each designed for a specialized use case. To illustrate the promise of this approach, we demonstrate its effectiveness on a hospital application using data from an intensive care unit (ICU). This complex application serves the needs of doctors and researchers …

Effect Of Methoxy Substituents On The Activation Barriers Of The Glutathione Peroxidase-Like Mechanism Of An Aromatic Cyclic Seleninate, Craig A. Bayse, Ashley L. Shoaf

Chemistry & Biochemistry Faculty Publications

Density functional theory (DFT) models including explicit water molecules have been used to model the redox scavenging mechanism of aromatic cyclic seleninates. Experimental studies have shown that methoxy substitutions affect the rate of scavenging of reactive oxygen species differently depending upon the position. Activities are enhanced in the para position, unaffected in the meta, and decreased in the ortho. DFT calculations show that the activation barrier for the oxidation of the selenenyl sulfide, a proposed key intermediate, is higher for the ortho methoxy derivative than for other positions, consistent with the low experimental conversion rate.

Retrieval And Validation Of Carbon Dioxide, Methane, And Water Vapor For The Canary Islands Ir-Laser Occultation Experiment, V. Proschek, G. Kirchengast, S. Schweitzer, J.S. A. Brooke, P. F. Bernath, C. B. Thomas, J. G. Wang, K. A. Tereszchuk, G. González Abad, R. J. Hargreaves, C. A. Beale, J. J. Harrison, P. A. Martin, V. L. Kasyutich, C. Gerbig, O. Kolle, A. Loescher

Chemistry & Biochemistry Faculty Publications

The first ground-based experiment to prove the concept of a novel space-based observation technique for microwave and infrared-laser occultation between low-Earthorbit satellites was performed in the Canary Islands between La Palma and Tenerife. For two nights from 21 to 22 July 2011 the experiment delivered the infrared-laser differential transmission principle for the measurement of greenhouse gases (GHGs) in the free atmosphere. Such global and long-term stable measurements of GHGs, accompanied also by measurements of thermodynamic parameters and line-of-sight wind in a self-calibrating way, have become very important for climate change monitoring. The experiment delivered promising initial data for demonstrating the …

Relative Drifts And Biases Between Six Ozone Limb Satellite Measurements From The Last Decade, N. Rahpoe, M. Weber, A. V. Rozanov, K. Weigel, H. Bovensmann, J. P. Burrows, A. Laeng, G. Stiller, T. Von Clarmann, E. Kyrölä, V. F. Sofieva, J. Tamminen, K. Walker, D. Degenstein, A. E. Bourassa, R. Hargreaves, P. Bernath, J. Urban, D. P. Murtagh

Chemistry & Biochemistry Faculty Publications

As part of European Space Agency's (ESA) climate change initiative, high vertical resolution ozone profiles from three instruments all aboard ESA's Envisat (GOMOS, MIPAS, SCIAMACHY) and ESA's third party missions (OSIRIS, SMR, ACE-FTS) are to be combined in order to create an essential climate variable data record for the last decade. A prerequisite before combining data is the examination of differences and drifts between the data sets. In this paper, we present a detailed analysis of ozone profile differences based on pairwise collocated measurements, including the evolution of the differences with time. Such a diagnosis is helpful to identify strengths …

Mass Loss And Chemical Structures Of Wheat And Maize Straws In Response To Ultravoilet-B Radiation And Soil Contact, Guixiang Zhou, Jiabao Zhang, Jingdong Mao, Congzhi Zhang, Lin Chen, Xiuli Xin, Bingzi Zhao

Chemistry & Biochemistry Faculty Publications

The role of photodegradation, an abiotic process, has been largely overlooked during straw decomposition in mesic ecosystems. We investigated the mass loss and chemical structures of straw decomposition in response to elevated UV-B radiation with or without soil contact over a 12-month litterbag experiment. Wheat and maize straw samples with and without soil contact were exposed to three radiation levels: a no-sunlight control, ambient solar UV-B, and artificially elevated UV-B radiation. A block control with soil contact was not included. Compared with the no-sunlight control, UV-B radiation increased the mass loss by 14-19% and the ambient radiation by 9-16% for …

Comparing Group Means When Nonresponse Rates Differ, Gabriela M. Stegmann

UNF Graduate Theses and Dissertations

Missing data bias results if adjustments are not made accordingly. This thesis addresses this issue by exploring a scenario where data is missing at random depending on a covariate x. Four methods for comparing groups while adjusting for missingness are explored by conducting simulations: independent samples t-test with predicted mean stratification, independent samples t-test with response propensity stratification, independent samples t-test with response propensity weighting, and an analysis of covariance. Results show that independent samples t-test with response propensity weighting and analysis of covariance can appropriately adjust for bias. ANCOVA is the stronger method when …

Improved Full-Newton-Step Infeasible Interior-Point Method For Linear Complementarity Problems, Mustafa Ozen

Electronic Theses and Dissertations

In this thesis, we present an improved version of Infeasible Interior-Point Method (IIPM) for monotone Linear Complementarity Problem (LCP). One of the most important advantages of this version in compare to old version is that it only requires feasibility steps. In the earlier version, each iteration consisted of one feasibility step and some centering steps (at most three in practice). The improved version guarantees that after one feasibility step, the new iterated point is feasible and close enough to central path. Thus, the centering steps are eliminated. This improvement is based on the Lemma(Roos, 2015). Thanks to this lemma, proximity …