Physical Sciences and Mathematics Commons^™

Two Cys Or Not Two Cys? That Is The Question; Alternative Oxidase In The Thermogenic Plant Sacred Lotus, Nicole M. Grant, Yoshihiko Onda, Yusuke Kakizaki, Kkikukatsu Ito, Jennifer R. Watling, Sharon A. Robinson

Faculty of Science - Papers (Archive)

Sacred lotus (Nelumbo nucifera) regulates temperature in its floral chamber to 32°C to 35°C across ambient temperatures of 8°C to 40°C with heating achieved through high alternative pathway fluxes. In most alternative oxidase (AOX) isoforms, two cysteine residues, Cys₁ and Cys₂, are highly conserved and play a role in posttranslational regulation of AOX. Further control occurs via interaction of reduced Cys₁ with α-keto acids, such as pyruvate. Here, we report on the in vitro regulation of AOX isolated from thermogenic receptacle tissues of sacred lotus. AOX protein was mostly present in the reduced form, …

Source Regions For Co2 At Cape Point Assessed By Modelling, 222rn And Meteorological Data, S. Whittlestone, E. Kowalczyk, E.-G Brunke, C. Labuschagne

Faculty of Science - Papers (Archive)

This study explores methods of characterising experimental and modelling data to see if trace gas measurements at the Cape Point GAW station could improve our understanding of sources from the continent. Selection criteria have been defined which make it possible to divide the samples into categories with predominant transport to Cape Point from one of four source regions: City (greater Cape Town); close rural (within about 150 km of Cape Point); distant rural (from 150 to about 500 km) and very distant rural covering the rest of southern Africa. For species with fairly uniform source such as radon or CO, …

Accumulation Of Dna Damage In Antarctic Mosses: Correlations With Ultraviolet-B Radiation, Temperature And Turf Water Content Vary Amongst Species, J. D. Turnbull, Sharon A. Robinson

Faculty of Science - Papers (Archive)

The susceptibility of three East Antarctic moss species to UV-B radiation was examined by measuring accumulation of cyclobutane pyrimidine dimers under natural sunlight during the austral summer season of 2002/03. The 2002/03 season was characterised by unusually low springtime ozone depletion and as such our results likely underestimate the DNA damage possible in a more typical UV-B radiation season. Despite this all three species accumulated significant DNA photoproducts. We also found a positive association between photoproduct accumulation and incident UV-B radiation in the two cosmopolitan species, Bryum pseudotriquetrum and Ceratodon purpureus, with more DNA damage in samples collected early …

Genetic Structure Of East Antarctic Populations Of The Moss Ceratodon Purpureus, L. J. Clarke, D. J. Ayre, Sharon A. Robinson

Faculty of Science - Papers (Archive)

The capacity of the polar flora to adapt is of increasing concern given current and predicted environmental change in these regions. Previous genetic studies of Antarctic mosses have been of limited value due to a lack of variation in the markers or non-specificity of the methods used. We examined the power of five microsatellite loci developed for the cosmopolitan moss Ceratodon purpureus to detect genetically distinct clones and infer the distribution of clones within and among populations from the Windmill Islands, East Antarctica. Our microsatellite data suggest extraordinarily high levels of variation reported in RAPD studies were artificially elevated by …

Just Add Water: Colonisation, Water Governance, And The Australian Inland, Leah Maree Gibbs

Faculty of Science - Papers (Archive)

Water has played a key role in the development of the Australian inland and the nation. For European colonists, the dry and variable landscape challenged ideas about nature imported from northern temperate regions. I argue first, that colonists brought with them ideas for ordering nature and tools for transforming landscapes that led to inappropriate and destructive water management and the silencing of local voices and knowledge systems. Secondly, colonial patterns of ordering and transforming landscapes are ongoing, but new ways of governing water, which challenge colonialism, are emerging. In the first section of the paper I discuss colonial relationships with …

Gremo: A Gis-Based Generic Model For Estimating Relative Wave Exposure, Austen Pepper, Marjetta L. Puotinen

Faculty of Science - Papers (Archive)

Wave exposure plays a major role in shaping the ecological structure of nearshore communities, with different community types able to survive and/or thrive when typically exposed to different levels of wave energy. This can be quantified by taking direct field measurements with wave buoys over time and then manipulating the data to derive typical conditions. However, taking these measurements is only feasible for very limited areas due to logistical constraints, and generating them with numerical wave models can also be expensive to run and may require data inputs that are either lacking or are highly uncertain. Instead, the relative differences …

The Tràng An Project: Late-To-Post Pleistocene Settlement Of The Lower Song Hong Valley, North Vietnam, Ryan Rabett, G Barker, C O. Hunt, C O. Hunt, P Piper, E Raddatz, T Reynolds, Nguyen Van Son, C Stimpson, Katherine A. Szabo, Nguyen Cao Tan, J Wilson

Faculty of Science - Papers (Archive)

Tràng An is a Vietnamese government supported cultural and ecological park development covering 2,500 hectares that is centred on an isolated massif on the southern edge of the Song Hong delta in Ninh Bình Province, north Vietnam (Fig. 1). The archaeological investigation of Tràng An is being led jointly by the Xuan Truong Construction Corporation and the McDonald Institute for Archaeological Research, University of Cambridge, under the direction of the lead author. The Corporation is creating an ecologically sensitive development – the ‘Tràng An Tourism Resort’ – within this karstic landscape, which is also the subject of a planned application …

Electrocatalytic Reduction Of Carbon Dioxide By Cobalt-Phthalocyanine-Incorporated Polypyrrole, Jun Chen, Gordon G. Wallace, Jiaxing Lu, Aijian Zhang, Weimin Zhang

Faculty of Science - Papers (Archive)

In the quest for catalysts for the electrocatalytic reduction of , a cobalt phthalocyanine/polypyrrole (CoPc/PPy) composite electrode has been developed. The electrode is prepared by drop casting CoPc onto the PPy film from the CoPc/tetrahydrofuran solution (1 mg/mL). The onset potential for reduction occurred at potentials 160 mV more positive than observed with a simple PPy electrode. Furthermore, in the potentiostatic electrolysis, the catalytic current for reduction at CoPc/PPy was very stable, with a higher current density and current efficiency when compared to the PPy electrode.

Late Llandovery (Early Silurian) Dendroid Graptolites From The Cotton Formation Near Forbes, New South Wales, R B. Rickards, Anthony J. Wright, G Thomas

Faculty of Science - Papers (Archive)

A well-preserved dendroid graptolite fauna of Early Silurian (late Llandovery: probable turriculatus graptolite zone) age is described from the Cotton Formation near Forbes, New South Wales. A possible rhabdopleuran hemichordate is described from Australia for the fi rst time. The fauna consists of 13 taxa as follows: Dendrograptus sp. aff. D. avonleaensis, Dictyonema zalasiewiczi sp. nov., Dictyonema sp. aff. D. paululum australis, Dictyonema paululum australis, Dictyonema sp. aff. D. sp. cf. D. venustus of Bulman (?ssp. nov.), Dictyonema venustum, Dictyonema sp. cf. D. falciferum, Callograptus bridgecreekensis, Callograptus rigbyae, Callograptus sp. aff. C. ulahensis, Stelechocladia sp. cf. S. praeattenuata, Acanthograptus praedeckeri …

Development Of Non-Antibiotic-Resistant, Chromosomally Based, Constitutive And Inducible Expression Systems For Aroa-Attenuated Salmonella Enterica Serovar Typhimurium, Jake Matic, Tamsin D. Terry, David Van Bockel, Tracy A. Maddocks, David Tinworth, Michael Jennings, Steven P Djordjevic, Mark J. Walker

Faculty of Science - Papers (Archive)

Live-vaccine delivery systems expressing two model antigens from Mycoplasma hyopneumoniae, F2(P97) (Adh) and NrdF, were constructed using Salmonella enterica serovar Typhimurium aroA (STM-1), and immunogenicity in mice was evaluated. Recombinant plasmid-based expression (PBE) and chromosomally based expression (CBE) systems were constructed. The PBE system was formed by cloning both antigen genes into pJLA507 to create an operon downstream of temperature-inducible promoters. Constitutive CBE was achieved using a promoter-trapping technique whereby the promoterless operon was stably integrated into the chromosome of STM-1, and the expression of antigens was assessed. The chromosomal position of the operon was mapped in four clones. Inducible …

Beads, Boats And Switches: Making Things Happen With Molecular Photoswitches, Robert P. Byrne, Silvia Scaramagnani, Michael J. Higgins, Gordon G. Wallace, Dermot Diamond

Faculty of Science - Papers (Archive)

In this paper we present recent results obtained with a stimulus-responsive materials based on the photo-switchable behaviour exhibited by spiro-cyclic derivatives. Our results suggest that these highly novel materials offer unique capabilities hitherto inaccessible using conventional materials. In particular, we will focus on photocontrolled guest binding and release, inherent signalling of status, photo-actuation and solvent driven motion of small structures as examples of the fascinating behaviour of these exceptional materials. Copyright 2009 IEEE NANO Organizers.

Establishment And Persistence Of Species-Rich Patches In A Species-Poor Landscape: Role Of A Structure-Forming Subtidal Barnacle, A. R. Davis, David. W. Ward

Faculty of Science - Papers (Archive)

Some sessile invertebrates are capable of maintaining space in barren habitats produced by sea urchins, thereby creating species-rich patches in a species-poor landscape. We sought to determine the role of a large and common barnacle, Austrobalanus imperator, in the establishment and persistence of these species-rich patches. Barnacle density was modified in 2 experiments at sites in southeastern Australia. The first experiment concerned community establishment and involved the addition of barnacles in 4 densities (zero [control], low, medium and high) to plots on vertical rock surfaces. The addition of barnacles at ecologically realistic densities and spatial arrangements rapidly resulted in statistically …

A Novel Zinc-Binding Fold In The Helicase Interaction Domain Of The Bacillus Subtilis Dnal Helicase Loader, Karin V. Loscha, Kristaps Jaudzems, Charikleia Ioannou, Xun-Cheng Su, Flynn R. Hill, Gottfried Otting, Nicholas E. Dixon, Edvards Liepinsh

Faculty of Science - Papers (Archive)

The helicase loader protein DnaI (the Bacillus subtilis homologue of Escherichia coli DnaC) is required to load the hexameric helicase DnaC (the B. subtilis homologue of E. coli DnaB) onto DNA at the start of replication. While the C-terminal domain of DnaI belongs to the structurally well-characterized AAA+ family of ATPases, the structure of the N-terminal domain, DnaI-N, has no homology to a known structure. Three-dimensional structure determination by nuclear magnetic resonance (NMR) spectroscopy shows that DnaI presents a novel fold containing a structurally important zinc ion. Surface plasmon resonance experiments indicate that DnaI-N is largely responsible for binding of …

Predicting Avian Distributions To Evaluate Spatiotemporal Overlap With Locust Control Operations In Eastern Australia, Judit K. Szabo, Pamela J. Davy, Michael Hooper, Lee Astheimer

Faculty of Science - Papers (Archive)

Locusts and grasshoppers cause considerable economic damage to agriculture worldwide. The Australian Plague Locust Commission uses multiple pesticides to control locusts in eastern Australia. Avian exposure to agricultural pesticides is of conservation concern, especially in the case of rare and threatened species. The aim of this study was to evaluate the probability of pesticide exposure of native avian species during operational locust control based on knowledge of species occurrence in areas and times of application. Using presence-absence data provided by the Birds Australia Atlas for 1998 to 2002, we developed a series of generalized linear models to predict avian occurrences …

Real-Time Single-Molecule Observation Of Rolling-Circle Dna Replication, Nathan A. Tanner, Joseph J. Loparo, Samir M. Hamdan, Slobodan Jergic, Nicholas E. Dixon, Antoine M. Van Oijen

Faculty of Science - Papers (Archive)

We present a simple technique for visualizing replication of individual DNA molecules in real time. By attaching a rolling-circle substrate to a TIRF microscope-mounted flow chamber, we are able to monitor the progression of single-DNA synthesis events and accurately measure rates and processivities of single T7 and Escherichia coli replisomes as they replicate DNA. This method allows for rapid and precise characterization of the kinetics of DNA synthesis and the effects of replication inhibitors.

A Hypomorphic Vasopressin Allele Prevents Anxiety-Related Behavior, Mirjam Bunck, Ludwig Czibere, Charlotte Horvath, Cornelia Graf, Elisabeth T. Frank, Melanie S. Kebler, Chris Murgatroyd, Bertram Muller-Myhsok, Mariya Gonik, Peter Weber, Benno Putz, Patrik Muigg, Markus Panhuysen, Nicolas Singewald, Thomas Bettecken, Jan M. Deussing, Florian Holsboer, Dietmar Spengler, Rainer Landgraf

Faculty of Science - Papers (Archive)

In this study, microarray analysis, in situ hybridization, quantitative real-time PCR and immunohistochemistry revealed decreased expression of the vasopressin gene (Avp) in the hypothalamic paraventricular (PVN) and supraoptic (SON) nuclei of adult LAB mice compared to HAB, NAB (normal anxiety-related behavior) and HABxLAB F1 intercross controls, without detecting differences in receptor expression or density. By sequencing the regions 2.5 kbp up- and downstream of the Avp gene locus, we could identify several polymorphic loci, differing between the HAB and LAB lines. In the gene promoter, a deletion of twelve bp Δ(−2180–2191) is particularly likely to contribute to the reduced Avp …

Consistent Paternity Skew Through Ontogeny In Peron's Tree Frog (Litoria Peronii), Craig D. Sherman, Erik Wapstra, Mats M. Olsson

Faculty of Science - Papers (Archive)

Background: A large number of studies in postcopulatory sexual selection use paternity success as a proxy for fertilization success. However, selective mortality during embryonic development can lead to skews in paternity in situations of polyandry and sperm competition. Thus, when assessment of paternity fails to incorporate mortality skews during early ontogeny, this may interfere with correct interpretation of results and subsequent evolutionary inference. In a previous series of in vitro sperm competition experiments with amphibians (Litoria peronii), we showed skewed paternity patterns towards males more genetically similar to the female.

Methodology/Principal Findings: Here we use in vitro fertilizations and sperm …

Characterisation Of Anthracyclines From A Cosmomycin D-Producing Species Of Streptomyces By Collisionally-Activated Dissociation And Ion Mobility Mass Spectrometry, Celine Kelso, Juan Diego Rojas, Renata L.A Furlan, Gabriel Padilla, Jennifer L. Beck

Faculty of Science - Papers (Archive)

Cultures of cosmomycin D-producing Streptomyces olindensis ICB20 that were propagated for many generations underwent mutations that resulted in production of a range of related anthracyclines by the bacteria. The anthracyclines that retained the two trisaccharide chains of the parent compound were separated by HPLC. Exact mass determination of these compounds revealed that they differed from cosmomycin D (CosD) in that they contained one to three fewer oxygen atoms (loss of hydroxyl groups). Some of the anthracyclines that were separated by HPLC had the same mass. The location from which the hydroxyl groups had been lost relative to CosD (on the …

Site-Specific Covalent Attachment Of Dna To Proteins Using A Photoactivatable Tus-Ter Complex, Dahdah B. Dahdah, Isabelle Morin, Morgane Moreau, Nicholas E. Dixon, Patrick M. Schaeffer

Faculty of Science - Papers (Archive)

Investigations into the photocrosslinking kinetics of the protein Tus with various bromodeoxyuridine-substituted Ter DNA variants highlight the potential use of this complex as a photoactivatable connector between proteins of interest and specific DNA sequences.

Interactions Between Deformation And Fluids In The Frontal Thrust Region Of The Nantroseize Transect Offshore The Kii Peninsula, Japan: Results From Iodp Expedition 316 Sites C0006 And C0007, E Screaton, G Kimura, D Curewitz, G Moore, F Chester, O Fabbri, Christopher L. Fergusson, F Girault, D Goldsby, R Harris, F Inagaki, T Jiang, Y Kitamura, M Knuth, C-F Li, L Claesson Liljedahl, L Louis, K Milliken, U Nicholson, N Riedinger, A Sakaguchi, E Solomon, M Strasser, X Su, A Tsutsumi, A Yamaguchi, K Ujiee, X. Zhao

Faculty of Science - Papers (Archive)

Integrated Ocean Drilling Program (IODP) Expedition 316 Sites C0006 and C0007 examined the deformation front of the Nankai accretionary prism offshore the Kii Peninsula, Japan. In the drilling area, the frontal thrust shows unusual behavior as compared to other regions of the Nankai Trough. Drilling results, integrated with observations from seismic reflection profiles, suggest that the frontal thrust has been active since similar to 0.78-0.436 Ma and accommodated similar to 13 to 34% of the estimated plate convergence during that time. The remainder has likely been distributed among out-of-sequence thrusts further landward and/or accommodated through diffuse shortening. Unlike results of …

Dynamic Supplying Desired Web Service For E-Business, Xuejuan Huang, Xinmeng Chen, Jiazhen Xu, Jie Yang

Faculty of Science - Papers (Archive)

With the number of available Web services growing large, supplying the appropriate services for e-business becomes crucial. Dynamic change of customer requirement and available service space challenges the service discovery and selection process. In this paper, we propose a Web service dynamic supplying framework, called Web service community (WSC), to facilitate invocation of one single service or the composition of several services to complete various business tasks. The prominent features of Web service description, discovery and selection in the circumstance of WSC are depicted based on the explanation of the structure of WSC. The desired Web services are dynamically discovered …

Validation Of Ozone Measurements From The Atmospheric Chemistry Experiment (Ace), Nicholas B. Jones, David W. Griffith, M Wolff, E Mahieu, G Bodeker, I Boyd, M De Maziere, P Demoulin, T Blumenstock, Y. Murayama, A. Kagawa, J Jin, Christopher Mcelroy, J Hannigan, M Coffey, M Hopfner, H W. Fischer, T Kerzenmacher, I Kramer, J Mellqvist, R Sussmann, K Strong, J R. Taylor, K Mizutani, Y Kasai, J Urban, D Murtagh, E Dupuy, V Catoire, S Chabrillat, P Baron, C Brogniez, G L. Manney, C Piccolo, C Randall, C Robert, C Senten, C Tetard, N J. Livesey, A Kleinbohl, S Godin-Beekmann, T Borsdorff, James Drummond, C De Clercq, J C. Lambert, U Cortesi, K W. Jucks, C Boone, H Oelhaf, M Schneider, T Steck, K A. Walker, P Bernath, T Von Clarmann, R Hughes, C Vigouroux, J Kuttippurath, A Bracher, J Mcconnell, C Mclinden, H Kullmann, L Froidevaux, J Dodion, F Vanhellemont, J P. Burrows, J Kar, F Goutail, D G. Dufour, J M. Zawodny, F Nichitiu, J-P Pommereau, C Nowlan, D Fussen, J Zou, A R Klekociuk, G Forbes, H Bovensmann, R M Bevilacqua, C Haley, S Ceccherini, S D Mcleod, P Gerard, R Skelton, B Firanski, A E Bourassa, D A Degenstein, J Davies, T Christensen, J Granville, A Parrish, C Roth, J W. Waters, C Von Savigny, A Standberg, M Mchugh, A M. Thompson, E J Llewellyn, P Von Der Gathen, M B. Tully, J C. Witte, C Roth, B T. Marshall, K B. Strawbridge, E Kyrola, M P. Mccormick, D P J Swart, N D Lloyd, D W. Tarasick, S V. Petelina, L W. Thomason, A Jones, I S. Mcdermid

Faculty of Science - Papers (Archive)

This paper presents extensive bias determination analyses of ozone observations from the Atmospheric Chemistry Experiment (ACE) satellite instruments: the ACE Fourier Transform Spectrometer (ACE-FTS) and the Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (ACE-MAESTRO) instrument. Here we compare the latest ozone data products from ACE-FTS and ACE-MAESTRO with coincident observations from nearly 20 satellite-borne, airborne, balloonborne and ground-based instruments, by analysing volume mixing ratio profiles and partial column densities. The ACEFTS version 2.2 Ozone Update product reports more ozone than most correlative measurements from the upper troposphere to the lower mesosphere. At altitude levels from …

A Hybrid Approach To Estuary Modelling, O. Gould, J. Hinwood, Errol J. Mclean

Faculty of Science - Papers (Archive)

A hybrid model incorporating process and system modelling characteristics has been developed and applied to the evolution of a theoretical estuary with a small lake basin, partially enclosed by a barrier with an entrance open to the sea. The one-dimensional model is capable of modelling changes in sedimentation both spatially and temporally and hence, tracks changes in crosssection dimensions along the estuary. The model structure is a series of linked modules to solve the hydrodynamics, the sediment transport equation and a distribution of the sediment to bed and bank. An evolution simulation was conducted for a generic coastal lagoon over …

Carbon-Nanotube Biofiber Microelectrodes, Carol M. Lynam, Gordon G. Wallace, Willo Grosse

Faculty of Science - Papers (Archive)

All-biocompatible carbon-nanotube fibers were formed using wet spinning. In this process the spinning solutions used are carbon nanotubes dispersed using biomolecules such as hyaluronic acid and chitosan. We compare the effect of a coagulation bath containing either a polymer binder, e.g., polyethyleneimine, or simply a precipitating solvent system, e.g., acetone. The electrical, mechanical, and morphological properties of the resulting fibers were studied. Biocompatible electrode structures were generated suitable for a variety of biomedical applications, e.g.,in biosensors or in systems where the application of an electrical field is advantageous e.g., stimulation of electrically excitable cells such as nerve and muscle cells.

The Major Toxin From The Australian Common Brown Snake Is A Hexamer With Unusual Gas-Phase Dissociation Properties, Andrew Aquilina

Faculty of Science - Papers (Archive)

Asymmetric dissociation of multiply charged proteins assemblies has been frequently reported. This phenomenon, which relies on the dissociation of one or more highly charged monomers, has been shown to provide insights into the structure and organization of large monodisperse and polydisperse assemblies. Here, the process of asymmetric dissociation is investigated using the multi-subunit protein, textilotoxin, which has unusually high structural constraints on its monomers due to multiple disulfide linkages. Initially, it is shown that, contrary to previous reports, textilotoxin is made up of 6, rather than 5 subunits. Furthermore, the hexamer exists as two isoforms, one of which is substantially …

Synthesis Of Novel N-Protected Hydrophobic Phenylalanines And Their Application In Potential Antibacterials, Timothy P. Boyle, J. B. Bremner, Jonathan A. Coates, John Deadman, Paul A. Keller, Stephen G. Pyne, Kittiya Somphol

Faculty of Science - Papers (Archive)

An efficient synthesis of two new N-acetyl-4’-arylphenylalanines is described together with their incorporation in to a number of cationic peptoid antibacterial agents, one of which had an MIC of 7.8 μg/mL against Staphylococcus aureus.

The Synthesis Of Carbon Linked Bis-Benzylisoquinolines Using Mizoroki–Heck And Sonagashira Coupling Reactions, Uta Batenburg-Nguyen, Alison T. Ung, Stephen G. Pyne

Faculty of Science - Papers (Archive)

Novel laudanosine dimers in which two laudanosine units are linked at C-2′ via a two or three-carbon linker (alkane, alkene or alkyne) have been prepared using palladium-catalysed cross-coupling reactions (Mizoroki–Heck and Sonagashira reactions). In one example, a second three-carbon linker between the two isoquinoline N-atoms was also present leading to a novel macrocyclic ring system.

Intermolecular Addition Reactions Of N-Acyliminium Ions (Part I), Arife Yazici, Stephen G. Pyne

Faculty of Science - Papers (Archive)

This review highlights the advances in the literature up to July 2008 on the intermolecular reactions of acyclic and cyclic N-acyliminium ions. This is an update of an earlier review in 2000 on this topic and does not include intramolecular addition reactions to N-acyliminium ions which was recently reviewed. This review is presented in two parts, with the first part dealing with acyclic and pyrrolidinone-based N-acyliminium ions. Part II continues with other five-membered heterocyclic derivatives and higher systems.

Infrared Spectra Of Mass-Selected Mg+-H2 And Mg +-D2 Complexes, Viktoras Dryza, Berwyck L. Poad, Evan J. Bieske

Faculty of Science - Papers (Archive)

Rotationally resolved infrared spectra of Mg(+)-H(2) and Mg(+)-D(2) are recorded in the H-H (4025-4080 cm(-1)) and D-D (2895-2945 cm(-1)) stretch regions by monitoring Mg(+) photofragments. The nu(HH) and nu(DD) transitions of Mg(+)-H(2) and Mg(+)-D(2) are red-shifted by 106.2 +/- 1.5 and 76.0 +/- 0.1 cm(-1) respectively from the fundamental vibrational transitions of the free H(2) and D(2) molecules. The spectra are consistent with a T-shaped equilibrium structure in which the Mg(+) ion interacts with a slightly perturbed H(2) or D(2) molecule. From the spectroscopic constants, a vibrationally averaged intermolecular separation of 2.716 A (2.687 A) is deduced for the ground …

Spectroscopic Study Of The Benchmark Mn+-H2 Complex, Viktoras Dryza, Berwyck L. J Poad, Evan J. Bieske

Faculty of Science - Papers (Archive)

We have recorded the rotationally resolved infrared spectrum of the weakly bound Mn+-H2 complex in the H-H stretch region (4022-4078 cm(-1)) by monitoring Mn+ photodissociation products. The band center of Mn+-H2, the H-H stretch transition, is shifted by -111.8 cm(-1) from the transition of the free H2 molecule. The spectroscopic data suggest that the Mn+-H2 complex consists of a slightly perturbed H2 molecule attached to the Mn+ ion in a T-shaped configuration with a vibrationally averaged intermolecular separation of 2.73 A. Together with the measured Mn+...H2 binding energy of 7.9 kJ/mol (Weis, P.; et al. J. Phys. Chem. A 1997, …