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Physical Sciences and Mathematics Commons

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2003

Dissertations, Theses, and Masters Projects

Geochemistry

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Laboratory Oxide Coatings: Physical Form And Surface Chemistry, Kea U. Duckenfield Jan 2003

Laboratory Oxide Coatings: Physical Form And Surface Chemistry, Kea U. Duckenfield

Dissertations, Theses, and Masters Projects

The impact of dissolved trace metals on aquatic ecosystems and human health is controlled by sorption, i.e., binding to the surfaces of environmental particles. Since many environmental particles are coated with highly reactive substances, and since discrepancies in trace metal sorption behavior persist between oxides developed in the laboratory and environmental oxide phases, it was hypothesized that the physical form of oxide coatings may influence the chemical properties of the coated particle. Therefore, relationships between the physical forms of several different Fe(III) oxide coatings and the Cu(II) sorption behavior of the coated solids were investigated in comparison with the component …


Polycyclic Aromatic Hydrocarbon Sources And Distribution In An Urban Estuary, Shelby E. Walker Jan 2003

Polycyclic Aromatic Hydrocarbon Sources And Distribution In An Urban Estuary, Shelby E. Walker

Dissertations, Theses, and Masters Projects

As part of the assessment of the potential risk posed by contaminated sediments to the environment and human health, the United States Environmental Protection Agency (USEPA) is developing a set of sediment quality criteria (SQC) that are based on equilibrium partitioning (EqP). While EqP theory has often been used to predict contaminant concentrations within a factor of two for a range of sediment types, substantial deviations from predicted values have also been documented. The objective of this research was to evaluate the influence of PAH source on PAH sediment-pore water partitioning and distribution in sediments. The Elizabeth River is one …