Physical Sciences and Mathematics Commons^™

An Evaluation Of Five Perfluorinated Hydrocarbons As Tracers In Non-Aqueous Phase Liquids, Jennifer K. Bergin

Masters Theses

Tracers are used in many facets of hydrogeological investigations. At this time, only tracers for aqueous phase liquids are known. The object of this investigation is to assess the viability of a suite of hydrocarbons as tracers m underground spills of non-aqueous phase liquids.

Laboratory experiments were performed to determine if the potential tracers were soluble in common petroleum hydrocarbons, non-volatile, differentiable and quantifiable by GC/MS, and conservative.

The first compound tested, perfluorokerosene, was detected but could not effectively be determined quantitatively with the GC/MS. Its use should be restricted to investigations in which only its presence, and not its …

Geological And Hydrogeological Characterization Of The Schoolcraft Aquifer, Schoolcraft, Michigan, William K. Steinmann

Masters Theses

Newly installed monitoring wells, county well logs, gamma-ray logs, head measurements, flow nets, slug tests, and full aquifer pumping tests were utilized to characterize the geologic and hydrogeologic conditions of the area. Evaluation of the geologic conditions indicate that the study area is best described as a glacially generated, humid type, alluvial fan. A hydrogeologic facies model concept aided in the initial evaluation of the hydrogeologic conditions and was utilized for the placement of several vertically nested monitoring wells. Further evaluation indicates an unconfined aquifer comprised of two separate flow systems: a shallow, local flow system interacting with flow-through surface …

The Photonic Band Structure Of Dielectric Systems With A Frequency Dependent Dielectric Function, Jiezhou Liu

Masters Theses

The concepts of band theory for electrons can be employed to describe the behavior of electromagnetic waves propagaiting in periodic dielectric structures with a frequency independent dielectric function. These periodic structures can produce photonic band gaps in which the propagation of electromagnetic waves is strictly prohibited. The introduction of a frequency dependent dielectric function in such systems gives rise to strong changes of the photonic bands in the neighborhood of the frequency resonance of the dielectric function.

In my thesis, the photonic band structure of a dielectric system with a frequency dependent dielectric function which undergoes a dielectric resonance will …

Subsurface Glacial Geology Of The Area Between The Tekonsha And Kalamazoo Moraines, Kalamazoo County, Michigan, Kim Finkbeiner

Masters Theses

Cross sections profiling the stratigraphy of the glacial sediments were created using the geological logs recorded on water well records. Glacial sediments in the study area comprise a large outwash complex between two moraines. The surficial landforms are the result of the last Wisconsinan advance and retreat through the area.

Cross sections contructed for this project reveal at least three major till units. An additional till unit contains a weathered soil sequence. Therefore, it is possible that this paleosol represents the Sangamon Interglacial period between the Wisconsinan and Illinoian stages. No obvious evidence of movement of the Saginaw Lobe remains …

Investigations Of Glacial-Drift Aquifer-Lake Interactions Using Hydrogeology, Geochemistry, And Stable Isotopes At Asylum Lake, Michigan, Vincent E. Buening

Masters Theses

A hydrogeological investigation of Asylum Lake and its associated unconfined glacial-drift aquifer in Kalamazoo, Michigan was undertaken to define the lake-aquifer interaction at the study area. In addition, the impact of development proximal to the study area on ground water and lake-water quality was evaluated. Hydrogeology, inorganic water chemistry, and stable isotopic ratios of deuterium to hydrogen were employed to establish the interaction of the lake and the aquifer.

The findings from this study indicated that: (a) the sandy unconfined glacial-drift aquifer discharges into the lake along its western margin and is recharged by the lake along its eastern margin; …

Determination Of The Bulk Modulus Of A Lennard-Jones Solid, Spencer A. Van Roekel

Masters Theses

The quantum Monte Carlo method is used to determine the bulk modulus of a Lennard-Jones solid. The quantum Monte Carlo method is discussed in detail and is compared with other numerical methods used previously.

The zero pressure bulk modulus of a Lennard-Jones solid is computed at a number of different temperatures and compared with experimental data.

An Experimental Apparatus For Studying Double Differential Scattering By Low-Energy Multiply Charged Ions From Atomic Targets, Meenatchi S. Gopinathan

Masters Theses

A new differential energy-gain spectrometer with a movable parallel-plate electrostatic energy analyzer has been constructed and tested for the study of double differential (in energy and angle) cross sections for state-selective electron capture processes in collisions of low-energy multiply charged ions with atomic gases. The ion beam is produced by extracting recoil ions from a primary interaction region where these ions are generated in collisions between a neutral target gas and a fast fluorine beam from the WMU tandem Van de Graaff accelerator. An einzel lens is used to focus the ion beam extracted from the recoil-ion source into a …

Absolute Photonic Band Gaps Of Zincblende, Ulrich Bass

Masters Theses

One concept of examining the propagation of an electromagnetic wave through a periodic structure is the dispersion curve which relates the frequency of the propagating wave to its wave vector. In some cases frequency ranges occur where no propagation is possible. These ranges are called absolute photonic band gaps as far as periodic dielectric structures are concerned.

In my thesis I am interested in the dispersion curve of a Zincblende type dielectric array. Zincblende is a diamond-like structure and it has been shown that diamond structures possess absolute photonic band gaps. In studying Zincblende we want to gain deeper insight …

The Reaction Of Caffeic Acid And Copper (Ii) In Natural Water, Ling Xiaozheng Xu

Masters Theses

The interaction of the lignin precursor compound caffeic acid with copper(lI) in aqueous solution was studied. In the presence of a reducible transition metal, such as copper, caffeic acid undergoes oxidation. Oxygen was shown to play an important role in the reaction. The UV-visible data demonstrated that the conjugated double bond in the propenoic acid side chain of caffeic acid slowly disappeared during the reaction. The molecular weight experiments indicated that the product was a dimer. FTIR spectrum agreed with two possible dimer structures involving the side chain of caffeic acid. In addition, the reaction was shown to be reversible. …

Photoionization With Excitation Of The 4s And 4p Subshells In Krypton, Ahmad Farhat

Masters Theses

High-resolution photoelectron spectra of the nd, Rydberg satellites in krypton have been measured for the first time for six different angles and for photon energies between 68.5 and 250 eV. The relative intensities of these satellites with respect to the 4s and 4p main lines are in very good accord with the most recent measurements of Krause et al. (1992) at 68.5 eV. They also confirm that the theoretical predictions for the relative intensity of these satellites are too high. We determine the ratios for nd satellites with respect to the 4s and 4p main lines, and extract the angular …

Allozyrne Variation Within And Between Populations Of Ruth's Golden Aster, Pityopsis Ruthii (Small) Small, Steven A. Sloan

Masters Theses

Genetic structure of the two known populations of Ruth's golden aster, Pityopsis ruthii (Small) Small, was determined. Pityopsis ruthii is a rare, endemic plant species restricted to exposed phyllite and graywacke rock outcrops in the flooding zones of the Hiwassee and Ocoee River drainages in Polk County, Tennessee. There are an estimated 10,000 to 15,000 P. ruthii plants on the Hiwassee and ~600 on the Ocoee River. Patterns of variation at three enzyme loci were examined. Two loci, Pgm-2 and Prx-1, were polymorphic in both river populations. Despite limited habitat and subsequent restricted ranges (~ 5 kmalong each river), populations …

Problems Associated With Using Ground Penetrating Radar To Locate A Lnapl Plume, Jodie Mcneil

Masters Theses

The Crystal Refinery in Carson City, Michigan was the site used to test the hypothesis that Ground Penetrating Radar can locate LNAPL plumes. The contamination at the site is in the form of two tree product plumes and a dissolved plume. Three Ground Penetrating Radar antennas were used, a 100 MHz, a 300 MHz and a 500 MHz. Borings with a hand auger were made on some of the GPR lines. Gravel and coarse sand along with product in the form of residual stain and tree product were found in some locations. A vertical electrical sounding and a resistivity profile …

A Procedure For G-Matrix Calculation From A Momentum Space Potential, Zhaohui Gao Busche

Masters Theses

In this work a numerical procedure was found to calculate the G-matrix in momentum space with a momentum space potential. The integral equation for the G-matrix was solved by conversion to a matrix equation. Two numerical integral methods, three-point Simpson method and Gaussian integral method, were employed in this process to determine the more efficient method.

The resulting G-matrix in momentum space was Fourier transformed into coordinate space. This was compared with the results of the G-matrix calculated from coordinate space directly as well as the results from solving the Bethe-Goldstone equation. A 2% accuracy was achieved with both the …

Total Organic Carbon In A Glacial Aquifer: Measurement And Effects Upon Transport Of Organic Compounds, Jiang Wu

Masters Theses

Organic contaminant transport processes in subsurface systems have been paid increasing attention recently. Sorption of organic compounds on the aquifer solid matrix (retardation) is one of the most important processes influencing contaminant transport. The extent of sorption has been estimated by determination of organic carbon in aquifer materials and assumptions concerning sorption constants.

This paper focuses upon the sensitivity of organic contaminant transport to the total organic carbon (TOC) content in a natural aquifer. This study was composed of two phases. The first phase was methodology development and laboratory analysis of organic carbon contents in soil samples. Acidification and furnace …

Application Of A Modified Analytical Derivatization Method To The Determination Of Microbial Metabolites In Aquifer Systems, Jie Lu

Masters Theses

The geochemical evolution of Low Molecular Weight Fatty Acids (LMWFA's) in various ground water samples and aquifer solid samples from both contaminated and uncontaminated sites has been studied. An improved analytical method has been established for both qualitative and quantitative determination of LMWFA's. The low molecular weight (LMW) organic acids are metabolic intermediates of the oxidative biodegradation of hydrocarbon contaminants. The hydrocarbons are believed to be the electron donors in these redox reactions. Formic and acetic acids were found to be the major LMWFA's in these ground water samples and aquifer solid samples. Their concentrations increase as the redox condition …

Floorplanning For Mixed Block And Cell Designs, Arun G. Shanbhag

Masters Theses

Floorplanning is one of the important phases of the VLSI Physical Design cycle. The quality of a floorplan is usually not evident until the routing phase. A bad floorplan can lead to an unroutable design requiring another iteration of the floorplanning phase. Use of over-the-cell routing has led to zero routing footprints. Any further reduction in area of the layout is possible only by reducing the white space or the vacant space from the floorplan, that is by improving the floorplan of the layout.

Currently, the Mixed Block and Cell (MBC) design style is gaining popularity. This evolving design style …

The Effects Of A Wetland On Ground-Water Quality In An Agriculturally Impacted Aquifer, Marilyn Ann Betts

Masters Theses

Nitrate concentrations in excess of U.S. EPA standards have been documented for farm wells in an area where hog production and row crops are the predominant forms of agribusiness. The aquifer serving this area is in glacial deposits of interbedded sand, clay, gravel and till. The upper, unconfined, sand and gravel unit of the aquifer is connected to a flow-through wetland. Five well nests, with wells at various depths, were installed in and around the wetland. Samples were taken from the wells in both winter and summer to establish temporal and spatial changes in ground-water quality parameters.

Concentrations of nitrate, …

Laser-Rf Double Resonance Measurements Of The Hyperfine Structure Of V Ii, Gregory Michael Matous

Masters Theses

We have measured the hyperfine structure of ⁵¹V II using the technique of collinear fast-ion-beam laser spectroscopy. The output of a dye laser was applied collinearly to an accelerated 50 ke V ion beam to produce laser induced fluorescence spectra for the metastable 3d³4s and 3d⁴ configurations. The technique of laserradio- frequency double resonance, which utilizes an optical photon to deplete a hyperfine state and an rf photon to repopulate the state, was used to measure the hyperfine intervals to a high precision. These measurements of the hyperfine intervals allowed the determination of the magnetic …

Stratigraphy And Structure Of Part Of The Western Blue Ridge Foothills, Polk And Monroe Counties, Tennessee, Mark W. Carter

Masters Theses

The Upper Proterozoic Walden Creek Group (Ocoee Supergroup) is a thick sequence of metasedimentary rocks that underlies the western Blue Ridge Foothills belt in eastern Tennessee. Traditional interpretation suggests that rocks of the Walden Creek Group represent synrift sedimentation along the Late Proterozoic Laruentian margin. These rocks were later regionally metamorphosed, cleaved, folded, and thrust westward during two Paleozoic orogenies (Taconic and Alleghanian). Recent hypotheses from uncorroborated paleontological evidence suggest that the Walden Creek Group is no older than Silurian, deposited into a post-Taconic successor basin, and subsequently metamorphosed and deformed only during the Alleghanian orogeny. Stratigraphic and structural data …

Structure, Stratigraphy, And Metamorphism Of A Part Of The Columbus Promontory, Western Inner Piedmont, North Carolina, Gregory M. Yanagihara

Masters Theses

The geology of the Inner Piedmont in a part of southwestern North Carolina, called the Columbus Promontory, is characterized by a complex history involving high grade metamorphism and penetrative ductile deformation. This study involved detailed (1:24,000) geologic mapping, petrography, whole rock geochemical analysis, and structural analysis to study the stratigraphy, structural geology, and metamorphism of a part of the Columbus Promontory.

Rocks in the study area can be divided into three major lithotectonic units, each separated by a ductile thrust fault, and strike NE and dip gently to the SE. Unit 1, theStructurally lowermost and northwesternmost unit in the study …

A Performance-Driven Routing Approach For Mcm-C, Qiong Yu

Masters Theses

In this paper, a new routing methodology for Ceramic MultiChip Module (MCM-C) is presented. In the proposed approach, the routing space is partitioned into several towers and the routing process is decomposed into three phases, namely, routing distribution, terminal assignment, and tower routing. During the routing distribution phase, the routing is uniformly distributed among towers. The locations of nets on the faces of each tower are assigned during the terminal assignment phase whereas the exact paths for the nets in each tower are determined during the tower routing phase.

The existing approaches to MCM routing are extensions of two-dimensional approaches …

Identification Of Aromatic Acids As Microbial Metabolites Of Fossil-Fuel Compounds Present In Aquifer Systems, Daniel Michael Tomczak

Masters Theses

The identification and quantitation of aromatic acids as transformation products present in contaminated aquifer systems was studied from selected sites. These acids are formed as microbial metabolites in the oxidative degradation of aromatic compounds. The microbial activity in the subsurface can be coupled to the oxidation of the aromatic compounds and the reduction of specific inorganic indicators. Inorganic indicators identified from the sample sites include the reduced forms of iron, nitrate, sulfate, and dissolved oxygen.

The highest concentrations of the aromatic acids were found in the plumes of the contaminated sites. These concentrations also correlated with specific changes in concentrations …

Approaches To And Synthesis Of Chalcone Amides, Gregory S. Marczak

Masters Theses

A series of "chalcone" amides have been prepared. These amides are unique in the position of the substituted hydroxy and methoxy functional groups. Early approaches to the synthesis of the amides proved difficult when preparing intermediates from the phenolic substituents. These phenols were then protected to lead to easier formation of the intermediates, and then deprotected to yield the corresponding chalcone amides. The approaches to the preparation of these compounds is presented, along with the physical data used to characterize the chalcone amides.

Quantitative Analysis Of Steroids By 13C Nmr Spectroscopy, Pei Wang

Masters Theses

Steroids are usually analyzed quantitatively by using HPLC with ultraviolet detection and are confirmed by FTIR, GC-MS. Quantitative ¹³C NMR method provide an alternative means to analyze steroids. Chromatographic separation and subsequent identification by match with a spectroscopic data base spectrum is not required for quantitative analysis of mixture components. Instead, equivalent information is obtained by creating subspectra from resonances with equivalent peak areas within a quantitative NMR spectrum. Techniques for eliminating Nuclear Overhauser Enhancement (NOE) effect is described.

The Relationship Between Basement Structure And Overlying Sediments In The Michigan Basin: A Detailed Gravity Investigation, Mitchell Joseph Gutaj

Masters Theses

A detailed gravity study consisting of 945 measurements was carried out in Branch County, Michigan. The objectives of this study are to determine if: (a) structural trends interpreted from regional gravity data in southwestern Michigan are also observed in a more detailed survey in Branch County and (b) any relationship exists between observed geophysical anomalies, geological structures and overlying basin sediments.

The resulting gravity map indicates that NW-SE, NE-SW, and N-S trends are more clearly identified comprising several elliptical highs and lows. Variations in the isopachs of some of the overlying Phanerozoic formations area are also coincident with gravity anomalies. …

Studies Of The Effect Of Hydrophobic Filter Packs In Free Product Hydrocarbon Recovery Wells, Stephen J. Shank

Masters Theses

Most free product hydrocarbon recovery wells are filter packed in order to prevent aquifer material from entering the well and to increase their effective diameter. Historically there are five factors in filter pack designs: grain size, grain shape, mineralogy, uniformity, and the filter pack diameter. Previous laboratory experiments found that filter packs treated with a water repellant chemical could dramatically improve well performance. This adds wettability as a sixth factor.

A desorption experiment was conducted to determine the feasibility of using a chemically treated filter pack in the subsurface. Analytical results of the leachate from the chemically treated sand indicated …

Studies Of Silica As A Polymer Support For Regioselective Reactions On Sucrose, Lei Cheng

Masters Theses

Sucrose is a material that has potential for replacing oil as an industrial feedstock, at least in some instances. A major difficulty in utilizing sucrose is the lack of regioselectivity in its reactions due to the many reactive sites on the sucrose molecule.

This research is part of an attempt to study the technique of molecular recognition in an effort to increase reaction regioselectivity. Molecular recognition by template imprinting should be a way to create a material that would "recognize" and bind to sucrose in such a way as to block certain of the hydroxyl groups on the sucrose. The …

Studies Directed Toward The Synthesis Of Germacranolides Via [2+2] Cycloaddition Followed By Ring Expansion/Elimination Of Β-Lactones, Bryan E. Yates

Masters Theses

Exposure of α-trimethylsilyl β-lactones to magnesium bromide or boron trifluoride etherate in diethyl ether solvent resulted in the smooth generation of β,γ-unsaturated acid derivatives in good yield and isomeric purity. It is believed that this reaction occurs via the formation of a stable tertiary carbocation at the γ-carbon resulting from cleavage of the carbon-oxygen sigma bond due to the complexation of the Lewis acid with the ring oxygen atom. Rapid loss of an adjacent electrofuge then furnishes the unsaturated acids. The β-lactone precursors were prepared by a [2+2] cycloaddition of an aldehyde and an alkyl trimethylsilyl ketene. This method was …

Skin Cancer Diagnosis Using Hierarchical Neural Networks And Fuzzy Logic, Hsi-Chieh Lee

Masters Theses

"Skin cancer, the most common cancer in the United States that affects about 600,000 Americans every year, accounts for 1 % of all cancer deaths. Among all, Malignant Melanoma is the most virulent form of skin cancer that is responsible for 75% of all deaths from skin cancer. In 1992, approximately 32,000 people are expected to develop melanoma and about 6,700 will die. However, even malignant melanoma can be treated successfully if detected in the early phase. Therefore, our research goal is to diagnose skin cancer, especially malignant melanoma.

In this study, only the digitized images obtained from color tumor …

Effect Of Reservoir Function On Water Quality And Phytoplankton In Lake Taylorville, Christian County, Illinois, Scott Warren Phipps

Masters Theses

As is true for most reservoirs in agricultural areas, Lake Taylorville is currently impacted by excess sedimentation. A system of floodplain wetlands, holding ponds, and sediment basins is being constructed on the tributaries to the reservoir in effort to reduce sediment and nutrient loads. A comprehensive twelve-month assessment of water quality has been conducted to provide a baseline for evaluating the success of this restoration project and to allow predictions regarding future management strategies.

In reservoirs, a continuum of longitudinal gradients result in the establishment of three distinct zones possessing unique physical, chemical and biological properties. The function of these …