Physical Sciences and Mathematics Commons^™

Chemical Studies On Oxomolybdenum(Vi,Iv) Complexes As Bioinorganic Models For The Molybdenum Oxidases, James Thomas Lyon Iii

Theses and Dissertations

The synthesis, characterization, and chemical properties of Mo(VI)o₂(5-X-SSP) and Mo(VI)o₂(5-X-SSE), (5-X- SSP²- = 2-((5-X-salicylidene)amino)benzenethiolate; 5-X- SSE^2- = 2-((5-X-salicylidene)amino)ethanethiolate; X = Br, Cl, H, CH₃O), which contain tridentate (ONS) Schiff base ligands is described. The chemical properties of these molybdenum complexes are compared with those which possess tridentate (ONO) Schiff base ligands. Cyclic voltammetry was used to obtain cathodic reduction potentials (E_PC) for the quasi-reversible reduction of the cis-dioxomolybdenum (VI) complexes. Although the reductions are quasi-reversible, trends are observed in E_PC both within series and when different series are …

Designing A Relational Data Base For A Problem Solving Environment, Kathryn S. Dawson

Theses and Dissertations

When choosing a system design in which to solve a recurring problem which depends on interrelated data a relational data base environment should be considered. The original problem can be solved through this design and by allowing users to view the data in the relational constructs the data can be easily used in numerous other applications. Theoretical support insures the design is sound avoiding inaccurate results. Independence between the logical and physical views of the data enables the data base administrator to adjust the physical data structures in order to optimize system performance without affecting existing user applications.

Metamorphism In The Eastern Lac Seul Region Of The English River Subprovince, Ontario, Steve J. Chipera

Theses and Dissertations

The English River subprovince of the Superior Province, Canada, is a linear, east-west trending high-grade metamorphic belt which extends from Lake Winnipeg in the west, to the James Bay lowlands in the east. It is composed of two prominent lithologic domains: a northern sedimentary gneiss-migmatite domain, and a southern plutonic domain. The northern domain consists primarily of alternating migmatized layers of garnet-biotite "wacke" and garnet-cordierite-biotite "pelitic" metasediments. The southern domain is composed mainly of intermediate granitic to trondhjemitic plutons. Bordering to the north and south are the lower grade Uchi and Wabigoon greenstone belts. Metamorphism and migmatization occurred during the …

Metamorphism And Migmatization Of Metasediments In The Precambrian English River Subprovince, Western Ontario, Rodney M. Baumann

Theses and Dissertations

Metasediments of the Precambrian English River subprovince, a subdivision of the Superior province, are conspicuously migmatized by 'bands of light-colored, igneous-appearing material. The metasediments them.selves consist of alternating layers of pelite and wacke lithologies, which represent original mudstones and graywackes respectively. Their deposition is thought to represent subaqueous turbidity flows.

For the metasediments of the study area, a 250 square kilometer portion of the English River subprovince, metamorphic grade increases southward from the English River subprovince's northern border. Two isograds have been mapped: the disappearance of muscovite and the disappearance of stable sillimanite. Geothermometry studies are consistent with the trend …

Middle And Late Wisconsinan (Pleistocene) Insect Assemblages From Illinois, Kristine D. Carter

Theses and Dissertations

Two highly organic sediment sequences from central and western Illinois (the Athens North Quarry and Biggsville sites, respectively) of Middle and Late Wisconsinan age were studied to gain knowledge about the environment and climate of this area during the time immediately prior to the maximum extent of the last glaciation. Paleoenvironmental and paleoclimatic inferences are based principally upon knowledge of the habitat preferences and geographic distributions of extant species of beetles that are represented as fossils. These data are supplemented by information from sedimentological and taphonomic studies and from previously published palynological and plant-macrofossil studies.

The Athens North Quarry site …

Petrology Of The Beulah-Zap Lignite Bed, Sentinel Butte Formation (Paleocene), Mercer County, North Dakota, David R. Kleesattel

Theses and Dissertations

The Beulah-Zap lignite bed is one of several economically important lignites in the Sentinel Butte Formation (Paleocene). This lignite occurs as a subsurface unit in the Knife River Basin of Mercer and I Oliver counties of North Dakota. The Beulah-Zap lignite is a heterogeneous carbonaceous rock unit composed of megascopic and microscopic I components, which are lithotypes and macerals, respectively. Relationships between the maceral contents of the lithotypes follow patterns similar to those of bituminous coals. Coal petrology, the study of maceral and lithotype occurrence and I distribution, was applied to determine: 1) mode of coalification, and 2) depositional environment …

Depositional Environments And Diagenesis Of Carbonates And Associated Evaporites, Frobisher-Alida Interval, Madison Group (Mississippian), Williston Basin, Northwestern North Dakota, Thomas J. Obelenus

Theses and Dissertations

The Frobisher-Alida interval is a subsurface, marker-defined unit, one of several units designated for rocks of the Madison Group (Mississippian) in the Williston Basin of North Dakota. The Frobisher Alida conformably overlies the Tilston interval and is conformably overlain by the Ratcliffe interval. 1t attains a maximum thickness of a little over 400 feet (123 m) and thins to an erosional edge along the eastern margin of the Basin.

The Frobisher-Alida is composed of limestones, dolomitic limestones, and dolostones of the Mission Canyon Formation and anhydrites of the overlying Charles Formation which exist in a complex facies relationship within the …

Late Quaternary Environmental And Climatic History Of The Southern Chilean Lake Region Interpreted From Coleopteran (Beetle) Assemblages, John W. Hoganson

Theses and Dissertations

A diverse Coleoptera fauna of 462 species in 48 families was collected from 41 locations in the Parque Nacional de Puyehue and adjacent parts of the Lake Region of southern Chile. The sample locations ranged from rain forest habitats at sea-level to Andean tundra habitats at 1500 m msl. Cluster analysis of a Dice similarity coefficient matrix revealed a broad pattern of bioassociations within the large data base, Boundaries between the bioassociations correspond largely with those of the major vegetation zones implying that the distribution of the fauna is strongly influenced by the distribution of plants. Evidence from fossils indicates …

Petrology Of The Sentinel Butte Formation (Paleocene), North Dakota, Nels F. Forsman

Theses and Dissertations

Sedimentary materials of the Sentinel Butte Formation have been petrographically examined using optical and scanning electron micro scope/microprobe techniques. The formation consists of fine-grained materials which generally are classified mineralogically as volcanic litharenites or feldspathic litharenites. Most rock units in the formation are siltstones and mudstones. Multiple source rock types, including volcanic, metamorphic, and sedimentary, are represented by mineralogic constituents, but volcanic rock fragments are most abundant. Petrographic distinctions between basal and uppermost sandstone units suggest that a change in sediment supply took place near the end of Sentinel Butte time. Authigenic cement development appears concentrated in more porous and …

A Quantitative Analysis Of Shoreline Erosion Processes, Lake Sakakawea, North Dakota, Mark D. Millsop

Theses and Dissertations

Shoreline erosion is a problem at Lake Sakakawea and Lake Audubon, North Dakota. Land is lost, water quality is adversely affected, and reservoir storage capacity is decreased.

Instrumentation of the eastern shores of both lakes began in 1983 to quantify bank erosion by process (e.g., wave erosion, rainsplash and runoff, and frost-thaw failure). Other data gathered included: pool level fluctuations; wind velocity, direction, and duration; precipita tion; soil moisture; frost penetration; freeze-thaw cycles; and geology (e.g., texture, clay mineralogy and structure).

The magnitude of shoreline erosion is highly variable, especially within Lake Sakakawea. For the interval of May 1983 through …

The Geology And Hydrocarbon Potential Of The Dawson Bay Formation Carbonate Unit (Middle Devonian), Williston Basin, North Dakota, Wayne R. Pound

Theses and Dissertations

The Middle Devonian Dawson Bay Formation carbonate unit is present in the subsurface of North Dakota except where truncated by post-depositional erosion. The carbonate unit thickens from the erosional limit to a maximum thickness of 47.5 m (156 ft.) in Renville County and reaches a maximum depth of 3798 m (12, 432 ft.) below the surface in McKenzie County. In North Dakota, a submarine hardground separates the carbonate unit from the underlying “Second Red Bed member” of the Dawson Bay Formation. The upper contact with the Souris River Formation is conformable except in those areas where the Dawson Bay Formation …

Geochemistry And Petrology Of The Lake Vermilion Formation, Ely Greenstone Belt, Northeastern Minnesota, Scott E. Robinson

Theses and Dissertations

Alteration in the Lake Vermilion Formation took place at low water/rock ratios. Calculations using the method of Grescens (1967) indicate that the amount of open-system elemental exchange was slight. During secondary alteration, Ca, Na, K, Rb, Sr, and Ba were very mobile; Mg and Fe were less mobile; Si, Al, Ti, Zr, Y, and Ni were slightly mobile. Chemically the rocks resemble modern spilites and keratophyres.

The dacites and basalts are depleted in Ti, Zr, and Y relative to Tertiary igneous rocks of similar composition. The Lake Vermilion Formation basalts display a volcanic arc basalt trend of constant Ti02 with …

Palynology Of The Hagel Lignite Bed And Associated Strata, Sentinel Butte Formation (Paleocene), In Central North Dakota, Edward N. Steadman

Theses and Dissertations

The Hagel bed is an economically important lignite and is the lowest named lignite in the Sentinel Butte Formation, Fort Union Group. The Hagel bed extends throughout the Knife River Basin coal-mining area of central North Dakota. Stratigraphic sections of the Hagel bed, including intercalated clastic rocks, were measured in the highwalls of the Center mine, Glenharold mine, and Falkirk mine.

Samples from the stratigraphic sections were described and analyzed, using standard palynological techniques, for their palynomorph content. Palynomorphs proved to be well preserved and abundant. Maceration of Hagel bed samples yielded a diverse collection of palynomorphs. A total of …

Macrofossils And Biostratigraphy Of The Bakken Formation (Devonian And Mississippian) In Western North Dakota, Lawrence C. Thrasher

Theses and Dissertations

The Bakken Formation, up to 145 feet thick in North Dakota, is a subsurface formation in the Williston Basin that typically consists of two black shale members separated by a middle member of predominantly gray siltstone or silty limestone up to 85 feet thick.

Well over 500 macrofossils representing more than 50 taxa were collected from cores of 40 wells. Brachiopods, the most common fossil, represent 17 genera, 1 of which have not been previously reported from the Bakken. Nonbrachiopod fossils of this study, mostly not previously reported from the Bakken, are a hylothyrid, a conulariid, a syringoporid coral, several …