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Full-Text Articles in Physical Sciences and Mathematics
Coordination Environment And Thermodynamics Of Colloidal Quantum Dots In Polar Solvents, Nuwanthaka Prasad Jayaweera Millaniyage
Coordination Environment And Thermodynamics Of Colloidal Quantum Dots In Polar Solvents, Nuwanthaka Prasad Jayaweera Millaniyage
Theses and Dissertations
Colloidal semiconductor quantum dots (QDs) have been extensively investigated due to their attractive properties such as size-tunable absorption and emission spectra, large molar extinction coefficients, and significant photostability. These properties make them promising candidates for optoelectronic, photocatalytic, and biomedical applications. Common synthetic procedures of QDs produce nanocrystals capped with long-chain fatty acid derivatives which are stabilized in high boiling point solvents. Especially for bioimaging applications, the exchange of these native hydrophobic ligands with hydrophilic ligands should be performed, while preserving the smaller hydrodynamic radius. The coordination environment and thermodynamic parameters of the ligand exchanges should be carefully investigated to engineer …
Optical Investigation Of A Hybrid System Of Plasmonic Structures And Semiconductor Quantum Dots, Matthew B. Seaton
Optical Investigation Of A Hybrid System Of Plasmonic Structures And Semiconductor Quantum Dots, Matthew B. Seaton
Theses and Dissertations
Next generation integrated nanophotonic devices must fabricate large numbers of nanoscaled light coupling structures onto a single wafer: emitters such as quantum dots, resonators such as nanocavities and plasmonic nanoparticles, photonic crystal and nano-plasmonic waveguides, among others. Before precision planning and engi- neering will be possible a thorough understanding of the interaction between these structures must be documented. We present in this work an investigation of the interaction between quantum dots and plasmonic structures in the weak coupling regime. We found that surface plasmon supporting silver structures placed about 100nm from InGaAs quantum dots enabled an all optical polarization dependent …
Characterization Of Ingaas Quantum Dot Chains, Tyler Drue Park
Characterization Of Ingaas Quantum Dot Chains, Tyler Drue Park
Theses and Dissertations
InGaAs quantum dot chains were grown with a low-temperature variation of the Stranski-Krastanov method, the conventional epitaxial method. This new method seeks to reduce indium segregation and intermixing in addition to giving greater control in the growth process. We used photoluminescence spectroscopy techniques to characterize the quality and electronic structure of these samples. We have recently used a transmission electron microscope to show how the quantum dots vary with annealing temperature. Some questions relating to the morphology of the samples cannot be answered by photoluminescence spectroscopy alone. Using transmission electron microscopy, we verified flattening of the quantum dots with annealing …
Graphene-Based Semiconductor And Metallic Nanostructured Materials, Abdallah Zedan
Graphene-Based Semiconductor And Metallic Nanostructured Materials, Abdallah Zedan
Theses and Dissertations
Exciting periods of scientific research are often associated with discoveries of novel materials. Such period was brought about by the successful preparation of graphene which is a 2D allotrope of carbon with remarkable electronic, optical and mechanical properties. Functional graphene-based nanocomposites have great promise for applications in various fields such as energy conversion, opteoelectronics, solar cells, sensing, catalysis and biomedicine. Herein, microwave and laser-assisted synthetic approaches were developed for decorating graphene with various semiconductor, metallic or magnetic nanostructures of controlled size and shape. We developed a scalable microwave irradiation method for the synthesis of graphene decorated with CdSe nanocrystals of …
Electroluminescence Studies On Longwavelength Indium Arsenide Quantum Dot Microcavities Grown On Gallium Arsenide, John C. Ramsey
Electroluminescence Studies On Longwavelength Indium Arsenide Quantum Dot Microcavities Grown On Gallium Arsenide, John C. Ramsey
Theses and Dissertations
A comprehensive study of the electroluminescence of four GaAs/AlGaAs microcavity devices with InAs/GaInAs quantum dot active regions emitting near 1.3 µm was conducted. The four molecular beam epitaxial grown samples with AlAs oxide aperture confinement layers were fabricated, characterized, and optically modeled. Optical power transmission of the samples was modeled using Matlab and compared with measured transmission data. Resonant cavity light emitting diodes (RCLEDs) and three vertical cavity surface emitting laser (VCSEL) samples were fabricated and electro-optically characterized over a range of injection currents and temperatures. Devices achieved continuous wave room temperature lasing at 1.28 µm with an output power …
Density Functional Investigations Of Pure And Ligated Clusters, Kristen Casalenuovo
Density Functional Investigations Of Pure And Ligated Clusters, Kristen Casalenuovo
Theses and Dissertations
Atomic clusters are attractive candidates for building motifs for new nano-assembled materials with desirable properties. At this nano-regime of matter, the size, shape, and composition of clusters changes their electronic structure and hence their properties. Computational modeling must work hand in hand with experiment to provide robust descriptions of the geometries and energetics of atomic clusters and how they might behave in a nano-assembled material. To this end, we have investigated three distinct species as model systems: antimony oxides SbxOy (x = 1, 2; y = 0 - 3), metal ion-solvent complexes Mm(NH3)n (M = Bi, Pb; m = 1 …