Physical Sciences and Mathematics Commons^™

Calorimetric Determination Of The Interaction Of Cu, Fe, And V Oxides With So₂ And Measurement Of Sulfur (Iv) And Sulfur (Vi) In Particulate Samples From Utah Valley, Douglas F. Cannon

Theses and Dissertations

The adsorption of SO2 by metal oxides suspended in decane were studied by calorimetric titration. The adsorption per surface area decreases in order CuO > Cu2O > Fe2O3 > V2O5. An Andersen High Volume sampler was used to obtain particulate samples from five sites in Utah County. Particulate sulfur (IV) and sulfur (VI) was analyzed by thermometric titration with K2Cr2O7 and by a direct injection enthalpimetric determination using BaCl2. Results show that little oxidation of the S(IV) occurs after it is released from the Kennecott smelter stack.

Studies Of N⁵, N¹⁰-Methylene Tetrahydrofolate Reductase From Porcine Kidney And Mouse L1210-Induced Tumor Tissues, Purification And Interaction With Antifolates, David W. Jayme

Theses and Dissertations

Methylene tetrahydrofolate reductase has been purified 1000-fold from porcine kidney and 400-fold from mouse L1210-induced tumor tissue by classical methods. The enzyme preparations have been demonstrated to be essentially free of contaminating methionine synthetase and serine transhydroxymethylase activity. Studies of the kinetic properties of the kidney and tumor enzymes, with respect to the reverse reaction using N5-methyl tetrahydrofolate as the variable substrate, have indicated Km values of 2.0 and 2.4 x 10-4 M, respectively. Inhibition of this key branch point enzyme in folate metabolism by a number of antimetabolites indicates that several of these antifolate compounds exhibit enzyme inhibition superior …

Synthesis And Stereochemistry Of 2,6,10-Triazatricyclo [5.2.1.0⁴ ¹⁰] Decane Derivatives, Susan Elaine Foulger

Theses and Dissertations

The synthesis and stereochemical aspects of derivatives of the new ring system 2,6,10-triazatricyclo [5.2.1.04,10] decane are discussed. Sythesis of 2-nitro-2-methyl-1,3-disubstitutedaminopropanes, followed by reduction of these compounds to 2-amino-2-methyl-1,3-disubstituted aminopropanes afforded the necessary starting materials for a cyclization reaction similar to that resulting in already known 2,6-dioxa-10-azatricyclo [5.2.1.04,10] decanes. Reaction of the triamines with 2,5-hexanedione resulted in 2,6-disubstituted-1,4,7-trimethyl-2,6,10-triazatricyclo [5.2.1.04,10] decanes. The stereochemical aspects of this ring system are interesting from the standpoint of nitrogen inversion barriers on nitrogens 2 and 6. Existence of a high inversion barrier for these nitrogens in shown by isolation of different diastereomers of the tricycle. Methods …

The Effect Of Recreational Uses On Vegetation And Soil In The Buffalo Campground, Targhee National Forest, Island Park, Idaho, Susan Daines Foster

Theses and Dissertations

The effect of trampling on vegetation and soil, as a result of recreational pressure, was studied in the Buffalo campground of the Targhee National Forest, Idaho. Site deterioration was most evident in the forty-two year old site. The tree stand had matured, but there were few young trees and tree reproduction had been reduced to ten seedlings per acre for Pinus contorta. Only two shrub species were sampled with a combined population of eight individuals per acre. Most of the grass species had been seeded; forbs provided 20% of the ground cover, 13% was bare ground and 71% litter. The …

The Effect Of Nitroalkanes On The Electrolytic Oxidation Of Tertiary Butyl Amine And Tertiary Amyl Amine, Karl Lloyd Bergen

Theses and Dissertations

The electrolyses of tert.-butyl and tert.-amyl amines were run with a voltage of approximately 3v., as measured across the cell, with and without the presence of 1-2% nitro-tert.-alkane. A graphite anode was used; the supporting electrolyte was NaClO4; the solvent was the reacting amine(s) with 10-20% water to solubilize the NaClO4. The products were azo compounds, azoxy compounds, 1,3-disubstituted ureas and traces of nitroso compounds. In the case of tert.-butyl amine di-tert.-butyl carbodiimide was also shown to be a product. The presence of nitro compounds increased the yields of azoxy and nitroso compounds and decreased the yields of azo compounds. …

Macrocyclic Polyether Sulfide Syntheses :|Bthe Preparation Of Thia-Crown-6, 7, And 8 Compounds, Robert Askew Reeder

Theses and Dissertations

Macrocyclic polyether sulfides have been prepared by reacting an oligoethylene glycol dichloride with a dithiol in refluxing basic ethanol. The following new compounds were prepared: 1,5-dithia-(19- crown-6), 3-hydroxy-1,5-dithia-(19-crown-6), 1,4-dithia-(21-crown-7), 3-hydroxy-1,5-dithia-(22-crown-7), and 1,4-dithia-(24-crown-8). One other previously reported macrocyclic polyether sulfide was also prepared. The thesis includes a review of macrocyclic sulfides and other related compounds, the thermodynamics of interaction of several macrocyclic polyether sulfides with Ag^+, Hg^2+, and Pb^2+ ions, and a discussion of the structure of these materials.

Composition, Time, And Size Distributions Of Airborne Particulate Material In Utah Valley, Douglas R. Lawson

Theses and Dissertations

The Lundgren impactor is used to determine the variations in time and size distributions of particulate matter in Utah Valley. Charged particle X-ray fluorescence is employed in this study to determine elemental concentrations. Air samples are taken during two 24-hour periods in downtown Provo, 24 hours near U.S. Steel Corporation, Geneva Works, and 12 hours at Lindon Elementary School, and diurnal particulate variations are compared. The amounts of lead and bromine are four times greater on a weekday than on a Sunday in downtown Provo, suggesting the effect of the automobile on atmospheric particulate concentrations. Paraffin coated impaction surfaces are …

The Kinetics And Mechanism Of A Free Radical Decay In Aqueous Solution, Denzel Lee Fillmore

Theses and Dissertations

The decomposition of nitrosyl disulfonate ion was studied in strongly alkaline solution of 10-2 to 5 m sodium hydroxide. The decomposition was found to be first-order in both hydroxide and nitrosyl disulfonate ions. A multi-step mechanism involving sulfite ion, sulfite ion radical and nitrosyl monosulfonate ion radical as intermediates was proposed, with the initiating step being the SN2 replacement of a sulfite ion by a hydroxide ion. The rate constant for the initiating step ranged from 1.2 x 10-7 to 2.25 x 10-5 M-1s-1 for the solution concentration range of the study. The products of the decomposition were identified as …

Development Of Proton-Induced X-Ray Emission Techniques With Application To Multielement Analyses Of Human Autopsy Tissues And Obsidian Artifacts, Kirk Kay Nielson

Theses and Dissertations

A method of trace element analysis using proton-induced X-ray emission (PIXE) techniques with energy dispersive X-ray detection methods is described. Data were processed using the computer program ANALEX. PIXE analysis methods were applied to the analysis of liver, spleen, aorta, kidney medulla, kidney cortex, abdominal fat, pancreas and hair from autopsies of Pima Indians. Tissues were freeze dried and low temperature ashed before analysis. Concentrations were tabulated for K, Ca, Ti, Mn, Fe, Co, Ni, Cu, Zn, Pb, Se, Br, Rb, Sr, Cd and Cs and examined for significant differences related to diabetes. Concentrations of Ca and Sr in aorta, …

A Comparative Investigation Of Mammalian Serine Transhydroxymethylases, Sanha Panichajakul

Theses and Dissertations

Serine transhydroxymethylase was purified one thousand-fold from bovine brain and one hundred and twenty-fold from bovine liver. Both enzymes were yellow due to the presence of the coenzyme pyridoxal 5'-phosphate. Polyacrylamide gel electrophoresis of the liver enzyme showed one major band containing 95% of the protein, while in the case of the brain enzyme two major bands of nearly equal intensity were observable. The specific activity of the crude liver enzyme was about sixty times higher than that of brain. The liver enzyme was also more heat stable than the brain enzyme. The purified enzymes exhibited L-allothreonine and L-threonine aldolase …

Use Of Selected Macroinvertebrates As Indicators Of Sedimentation Effects On Huntington River, Utah, Michael Kenneth Reichert

Theses and Dissertations

Benthic macroinvertebrate communities of Huntington River, Emery County, Utah were studied to determine effects of sedimentation from construction of Electric Lake Dam, a state highway, and two bridges. Approximately 900 benthic samples were collected from riffle areas above, in, and below the construction zone from January, 1971 to December, 1973. Two settling basins below construction sites were effective in limiting scouring of downstream communities. Heavy silt deposition was limited to a 1-km stream reach. Number of indicators, density, and biomass were reduced in the construction zone during periods of sediment input. During periods of scouring, density and biomass were reduced; …

Stratigraphy Of Offshore Sediment Of Lake Agassiz, North Dakota, Michael B. Arndt

Theses and Dissertations

Lake Agassiz occupied the Red River Valley between about 13,800 and 9,000 years ago. The Late Wisconsinan ice sheet that covered the Red River Valley retreated far enough to expose the drainage divide in northern South Dakota and south-central Minnesota sometime after 14,000 B.P. and meltwater ponded behind this divide in Richland County. Before 13,800 the ice readvanced over this area and then retreated again. As the ice margin retreated northward, deposition of the Argusville and Wylie Formations took place. Sometime before 12,800 the ice advanced again into the Red River Valley as far as Traill County; the terminus of …

Natural Science Of The Great Plains As It Relates To The American Indian : A Syllabus And Sourcebook, Mary E. Bluemle

Theses and Dissertations

This dissertation, which includes a sourcebook of pertinent reference materials, sample lesson plans, and natural science roadlogs, is an initial attempt at providing an Indian Studies field course in natural science. It also includes a syllabus which stresses natural science processes and serves as a unifying factor for field work, lecture, and course discussions. The dissertation stresses geographical and ecological concepts, climatic and geological processes, and the natural habitats of North Dakota. It includes discussions of North Dakota vertebrates and early man and his relation to his environment; discussions of_ the geologic features, geologic history, vegetation and animal life of …

Late Pleistocene And Holocene Geology Of The Moe Site, New Town, North Dakota, Richard W. Kornbrath

Theses and Dissertations

Eight stratigraphic units of Late Cenoioic age are present around the Moe Archeological Site near New Town, North Dakota. Unit Zero is a layer of glacial sediment consisting of grayish brown pebbly clay loam. Unit One consists of fluvial and beach sand and gravel. Unit Two consists of light yellowish brown, offshore lake silt that was deposited into a glacial lake in Late Wisconsinan time. Unit Three is a layer of glacial sediment consisting of grayish brown pebbly clay loam (Late Wisconsinan). Unit Four consists of fluvial sand and gravel (Late Wisconsinan}. Unit Five is a layer of slough sediment …

Stratigraphy Of The Upper Part Of The Fort Union Group In Southwestern Mclean County, North Dakota, Leroy A. Hemish

Theses and Dissertations

Southwestern McLean County is an area characterized by glacial topography and glacially-modified bedrock topography, with limited exposures of bedrock. Outcropping bedrock formations include the Cannonball, Tongue River, and Sentinel Butte Formations, all in the Fort Union Group of Paleocene age.

The Cannonball Formation crops out only in the southeastern part of the area studied (at Washburn), where 18 feet of laminated, gray-brown sandy mudstone is exposed. A yellow-brown, cross-bedded sand unit directly overlies the mudstone. I have tentatively selected the base of this sand unit, which is present in the subsurface throughout southwestern McLean County and reaches thicknesses of more …

Glacial Stratigraphy Of Northeastern North Dakota, Howard Hobbs

Theses and Dissertations

Seven lithostratigraphic units (formations} composed dominantly of glacial sediment have been recognized in northeastern North Dakota. Three formations, the Falconer Formation (Harris and others, 1974}, the Dahlen, and Gardar Formations (Salomon, 1975). Have been previously recognized. Four formations, the Hansboro, Vang, Tiber and Cando Formations are newly recognized. Uncorrelated units of glacial sediment are described but not named. The formations are differentiated and correlated primarily by the proportion of crystalline (igneous and metamorphic rock fragments), carbonate, and shale grains in the coarse sand fraction (1 to 2 mm) of the glacial sediment. The proportion of shale grains was. Found to …

Petrology And Geochemistry Of The Killdeer Carbonates, John J. Delimata

Theses and Dissertations

The strata of the proposed Killdeer Formation (Stone, W. J., 1972) in the Killdeer Mountains of Dunn County, North Dakota is composed of a sequence of tuffaceous, calcareous, dolomitized and silicified flat lying sedimentary rocks of Tertiary age. It is the purpose of this report to describe and integrate the petrology and geochemistry of these sediments.

Fieldwork was conducted during the summer of 1972. Forty-three stratigraphic sections were measured and representative samples of each were collected for further analysis. Seven section were selected as representative of the area, and samples from these were studied in thin section with the petrographic …

Geology Of The North Beulah, Center, And Glenharold Lignite Mines In Mercer And Oliver Counties, Southwestern North Dakota, Roy E. Kulland

Theses and Dissertations

The geology of the North Beulah, Center, and Glenharold lignite mines in Mercer and Oliver Counties, southwestern North Dakota, were examined. Stratigraphically, all mines lie within the Sentinel Butte Formatiom. The North Beulah Mine lies 70 m below the top of the Sentinel Butte Formation and the Center and Glenharold Mines lie about 80 m above the base of the Tongue River Formation.

Four sedimentary types are recognized arid common to all mines; these are: silt and clay, silty sand, sand, and lignite. The silt and clay were deposited in floodbasins and shallow lakes occupying the lowest parts of the …

Pleistocene Geology Of The Grand Forks-Bemidji Area, Northwestern Minnesota, Kenneth L. Harris

Theses and Dissertations

This is a report of a reconnaissance study of the Quaternary geology of an area in northwestern Minnesota. Surface geology was studied in an area extending from Grand Forks, North Dakota, in the northwest to Bemidji, Minnesota, in the southeast, an area of 10 723 square kilometres (4140 square miles). Near-surface stratigraphy was studied in the area of surface study and an adjacent area of equal size to the south.

Surface materials mapped range in age from Pleistocene to Holocene and include glacial, glaciofluvial, lacustrine, bog, eolian, and alluvial sediments.

Sixteen power-auger test holes, two measured sections along the Red …

Quaternary Geology Of The Southern Part Of The Grand Forks And Bemidji Quadrangles, Donald K. Sackreiter

Theses and Dissertations

Northwestern Minnesota is an area at the southwestern edge of the Canadian Shield that is mantled by thick Pleistocene sediment. The Pleistocene material included a variety of glacial, shoreline, offshore, fluvial, and eolian sediment.

The lithology of the glacial sediment reflects the rock and sediment over which the depositing glacier flowed. Glaciers that advanced from the northeast (Canadian Shield) deposited sandy, granitic-rich material. Glaciers that advanced from the north· (Manitoba Lowland) deposited loamy, calcareous-rich material. Glaciers that advanced from the northwest (eastern North Dakota and southwestern Manitobal deposited clayey, shale-ridt material. A variety of fluvial and lacustrine sediments are typically …

The Historical Development Of Wasatch Trails In Salt Lake County, Clyde Brian Hardy

Theses and Dissertations

In this study investigation was made concerning the etiology of the foot trails that thread their way through Wasatch Forest lands in Salt Lake county. The time delimitation was 1847 to 1975.

The origin of the majority of these trails dates back to the nineteenth century and is closely tied to the efforts of pioneers who labored to wrest a living from semi-arid land. Early lumbering, livestock operations, mining activities, water collection systems, and pioneer recreation all provided impetus for trail development. In a sense these trails are a kind of anthology of human endeavor.

Passing into the twentieth century …

Petrography Of Precambrian Iron Formation, Pembina County, North Dakota, Ronald E. Richardson

Theses and Dissertations

In October of 1964 the Topographic Branch of the United States Geological Survey reported difficulties in using magnetic compasses while mapping in the areas of Akra and Hensel, Pembina County, North Dakota. University of North Dakota geologists located anomalies of 67,500 gammas 1.6 lon east of Akra and 71,500 gammas 4 km east of Hensel, the normal magnetic field in this area being about 60,000 gammas. The rock bodies producing the magnetic anomalies were drilled and examination of diamond drill core showed them to consist of oxide and silicate facies iron formation interlayered with quartz-biotite schist of Precambrian age. The …

The Keller Plan In College Introductory Physical Geology : A Comparison With The Conventional Teaching Method, Robert G. Walsh Sr.

Theses and Dissertations

The purpose of this study is to compare the learning and attitudinal changes that took place in a college introductory physical geology class between a self-paced method of instruction called the Keller Plan and the conventional lecture-laboratory method.

The sample population was 56 students enrolled in Earth Science 120, an introductory physical geology course at Minot State College ·~ during the fall quarter, 1973. An experimental section of 20 students experienced the Keller Plan treatment and two control groups consisting of 18 students each received the conventional method of instruction.

Four specific areas of investigation were tested: (1) knowledge of …